Issued: 14 02 2006 Material Safety Revised: 25 06 2008 .

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Material SafetyData Sheet1.Page:Issued:Revised:Rev. No.:Page 1 of 914 02 200625 06 20081Product: USEDLUBRICATING OILPRODUCT AND COMPANY IDENTIFICATIONAPPLICATIONUsed lubricating oil or waste oil typically from the crankcase of internal combustionengines (which run on diesel and petrol). Used oil is produced by other operatingequipment and includes products such as hydraulic oils, gear and transmission oils. Itis not recommended that used oils from transformers and switchgear be mixed withother waste oils but this MSDS also accommodates the possibility of unwanteddumping of used transformer oils with these oils.COMPANY IDENTIFICATIONROSE FoundationSuite A9Waverley Court7 Kotzee RoadMowbray 77002.Phone: (021) 448 7492Fax: (021) 448 7563 / 0866527384e-mail: usedoil@iafrica.comWebsite: www.rosefoundation.org.zaMobile: 082 378 8556COMPOSITIONMaterial is of a variable composition depending on the composition of the original oiland the degree of degradation.This material is a complex mixture of paraffinic, naphthenic and aromatic petroleumhydrocarbons that may contain one or more of the following:carbon deposits, sludge, aromatic and non-aromatic solvents, water (as a water-in-oilemulsion), glycols, wear metals and metallic salts, silicon-based antifoamingcompounds, fuels, polycyclic aromatic hydrocarbons (PCAH’s) and miscellaneouslubricating oil additive materials.Used engine oil may be contaminated with fuel causing it to become a flammablematerial. Hazardous materials such as solvents and chlorinated chemicals may befound in used lubricating oil from unwanted dumping. There have been instanceswhere transformer oils containing PCBs (polychlorinated biphenyls) have been mixedwith used lubricating oils.DangerousSubstancesAromatics% (m/m)Risk Phrase 1.5Carcinogen

Material SafetyData Sheet3.Page:Issued:Revised:Rev. No.:Page 2 of 914 02 200625 06 20081Product: USEDLUBRICATING OILHAZARD IDENTIFICATIONInflammable liquid; may be fatal if inhaled; harmful if swallowed or if absorbedthrough skin; probable carcinogen.WARNING: AVOID PROLONGED REPEATED CONTACT WITH USED MOTOROIL. IF SKIN CONTACT OCCURS, WASH EXPOSED AREAS WITH SOAP ANDWATER. LAUNDER CONTAMINATED CLOTHING.Long Term Toxic Effects: Suspected carcinogen. Contains component(s) that maycause cancer. Risk of cancer depends on duration and level of exposure.Used Oils from Transformers and switchgear: Polychlorinated biphenyls (PCBs) wereoften used in old transformer switchgear equipment; there is a possibility that oildrained from older equipment may have become contaminated with PCBs.Used Quench Oils: Quench oils will degrade in service leading to the generation ofdecomposition products which will contaminate the oil. These may include polycyclicaromatic hydrocarbons (PCAH), some of which have been shown by experimentalstudies to induce skin cancer.Used oils from refrigerant compressors: Used oils may be contaminated withrefrigerant gases, some of which may be hazardous (e.g. ammonia).Used dielectric fluids: Small quantities of PCAH's, some of which are known to becarcinogenic, may be generated during use. Avoid skin contact with used fluid andcontaminated fibres.Used neat metal working oils: During metal working solid particles from work piecesor tools will contaminate the product and may cause abrasions to the skin. Wheresuch abrasions result in a penetration of the skin, first aid treatment should be appliedas soon as reasonably possible. The presence of certain metals in the work place ortools, such as chromium, cobalt, and nickel, can contaminate the product and mayinduce allergic skin reactions, especially if personal hygiene is inadequate.Used oils may contain fuel which may reduce the flash point and make the materialflammable. It is probably necessary to assign R10 – Flammable, as thepresence of fuels at greater than 3.5% w/w in the used oil will potentially reducethe flash point to below 55 C.

Material SafetyData Sheet4.Page:Issued:Revised:Rev. No.:Page 3 of 914 02 200625 06 20081Product: USEDLUBRICATING OILFIRST AID MEASURESSkinEyesIngestionInhalationSymptom & EffectProlonged and repeated contact with skinmay cause severe irritation; Toxic ifabsorbed through the skin; potentiallycarcinogenicContact with eyes may cause redness,tearing, blurred vision and moderateirritation.Harmful or fatal if swallowed. Ingestion ofthis product may cause central nervoussystem effects, abdominal discomfort,nausea and diarrhoeaExcessive exposure may cause re to high concentrations may leadto central nervous system effects,headaches, dizziness and loss of coordination.First AidWash with soap and water until noodour remains. Remove contaminatedclothing and wash underlying skin assoon as possible.Flush eyes with clean water for 15minutes. Seek medical advice ifirritation persists.If victim is alert, give large amounts ofwater or milk, seek medical advice.Small amounts can be washed frommouth until no taste remains. If advicecannot be obtained, take person withcontainer and label to nearestemergency treatment centre. Nevergive anything by mouth to anunconscious person.Immediately remove to fresh air. Giveoxygen if required. Seek medicaladvice if required.Advice to doctor: Gastric lavage by qualified medical personnel may be considered,depending on the quantity of material that has been ingested.5.FIRE FIGHTING MEASURESSpecific hazard: Combustible liquid. Emits toxic fumes under fire conditions.This material is harmful to aquatic organisms. Fire water contaminated withthis material must be contained and prevented from being discharged to anywaterway, sewer or drain.SMALL FIRES: Use CO2, foam or dry chemical.LARGE FIRES: Use CO2, fluoro protein foam or dry chemicals to extinguish the fire.Use water to cool fire-exposed containers / structures and to protect personnel.Avoid spraying directly into the containers because of the danger of boil over.Trained personnel wearing approved breathing apparatus should deal with fires inconfined spaces. Combustion may release harmful chemicals; utilise respirators;avoid low-lying areas.EXPLOSIONS HAZARDS: For fires involving this material do not enter any enclosedor confined space without self-contained breathing apparatus to protect against thehazardous effects of combustion products or oxygen deficiency.

Material SafetyData Sheet6.Page:Issued:Revised:Rev. No.:Page 4 of 914 02 200625 06 20081Product: USEDLUBRICATING OILACCIDENTAL RELEASE MEASURESFull protective clothing, rubber gloves (PVC, Neoprene, Nitrile, or Viton), gumbootsand respirator to be worn. Shut off leaks. Remove all sources of heat or flame.Control spill by use of booms, sand, oil-absorbent material or any other suitableavailable medium. Recover as much free product as possible using pumps ormechanical means. Absorb residue with oil-absorbent material, sand or otherabsorbent material. Ensure that the product does not enter the storm water drains orwaterways. Sweep up and place in disposable container. Scrub contaminated areawith detergent and water using a stiff broom.Environmental precautions: Protect drains from potential spills to minimisecontamination. Do not wash product into drainage system. Contact the appropriateauthorities in all cases where the consequences cannot be quickly and effectivelycontrolled. In the case of spillage on water, prevent the spread of the product by theuse of suitable barrier equipment. Recover product from the surface. Protectenvironmentally sensitive areas and water supplies. In the case of spillage at seaapproved, dispersants may be used where authorised by the appropriate government/ regulatory authorities. Regular surveillance on the location of the spill should bemaintained.7.HANDLING AND STORAGEHandling: Avoid contact with eyes. If splashing is likely to occur wear a full face visoror chemical goggles as appropriate. Full protective clothing should be worn whenhandling the product. A high standard of personal hygiene is essential. Application ofprotective hand creams may be beneficial. Wash hands thoroughly after use, andalways wash hands before eating, drinking and smoking. Change heavilycontaminated clothes as soon as reasonably possible and launder before re-use.Wash any contaminated underlying skin with soap and water. Avoid, as far asreasonably practicable, inhalation of mists, fumes or vapour generated during use.Take particular care to avoid prolonged skin contact with used engine oils.Handling temperature: Minimum feasible handling temperatures should bemaintained. Periods of exposure to high temperatures should be minimised. Watercontamination should be avoided. Misuse of empty containers can be hazardous.Storage: DO NOT cut, weld or drill containers. Residue may ignite with explosiveviolence if heated sufficiently. Do not pressurise or expose to open flames or heat.Store under cover away from strong oxidisers and ensure containers are closed anddrum bungs are in place. Incompatible with sulphuric acid, nitric acid, caustics,aliphatic amines and amides. Keep away from children. Store in accordance withlocal regulations.

Material SafetyData SheetPage:Issued:Revised:Rev. No.:Page 5 of 914 02 200625 06 20081Product: USEDLUBRICATING OILStorage conditions: Storage conditions should comply with SABS Code 0131:1979-2and SANS Code 10089:2003-1. Product should be stored in a well-ventilated area.Sparks, flames and other sources of ignition near the product should be avoided. Donot eat, drink or smoke in storage area.8.EXPOSURE CONTROLS / PERSONAL PROTECTION3OccupationalExposure Limits:OHSA 16 mg/m TWA OEL-CLControls:Store in accordance with SABS089:1999-1or SABS0131:1979Ensure adequate tank ventilationPersonal Protection:If engineering controls and work practices are not effective in controlling thismaterial, then wear suitable personal protection equipment includingoveralls, impervious gloves, respirators, safety goggles, safety boots orgumboots.EyesNo special eye protection is mandated but safety glasses with side shields can berecommended when handling used oils.SkinExposed employees should exercise reasonable personal cleanliness; thisincludes cleansing exposed skin several times daily with soap and water andlaundering or dry cleaning soiled work clothing at least weekly.Any routine contact with used motor oil should require the use of protectiveclothing such as gloves or apron made of neoprene, nitrile, or n-butyl rubbersuitable for the application.InhalationRespiratory protection is normally not required. However, if operating conditionscreate airborne concentrations which exceed the recommended exposurestandard(s), the use of an approved respirator is recommended.Wear approved respiratory protection such as toxic dust, mist and fume respirator.VentilationUse adequate ventilation to keep the airborne concentrations of this materialbelow the ACGIH TLV for mineral oil mists. Local exhausts’ ventilation and/orenclosure of the process is preferred in these cases.Exposure LimitsDue to possible carcinogenic effects, exposure should be reduced to the lowestfeasible level.

Material SafetyData Sheet9.Page:Issued:Revised:Rev. No.:Page 6 of 914 02 200625 06 20081Product: USEDLUBRICATING OILPHYSICAL AND CHEMICAL PROPERTIESUsed lubricating oilsPhysical stateDensity @ 200CFlashpoint @101.325kPaTest methodASTM D 4052ASTM D 93Solubility in waterViscosity @ 400CBoiling pointWaterAshFuel solventsElemental miniumBariumChromium, Tin,Nickel, VanadiumASTM D 445ASTM D95ASTM D482ASTM D322Atomic absorptionUnitsKg/l0CMass @20 CMm2/s0C%%%ppm (mg/l)Typical valueBlack oil, slightly oily odour0.89 60.50C (depends ifcontaminated with fuel orsolvent)Varies, usually 0.1%80 1850C10-201.0 3.57300115065014060010065555040152015151 5 510. STABILITY AND REACTIVITYPartially volatile at temperatures in excess of 30ºC; avoid strong oxidisers.Incompatible with sulphuric acid, nitric acid, caustics, aliphatic amines and amides.Products of combustion: Carbon monoxide, carbon dioxide, and aldehydes andketones, combustion products of nitrogen and sulphur.Conditions to avoid: Strong monoxides such as chlorates, nitrates, peroxides.

Material SafetyData SheetPage:Issued:Revised:Rev. No.:Page 7 of 914 02 200625 06 20081Product: USEDLUBRICATING OIL11. TOXICOLOGICAL INFORMATIONSome components of the product are suspected human carcinogens. Potentialharmful effects to liver, kidneys, heart, lungs and nervous system may result fromchronic over-exposure. Some of the components of the product have beenassociated with immunological, reproductive, fetotoxic and genotoxic effects. Briefintermittent skin contact with used motor oil is not expected to have serious effects inhumans if the oil is thoroughly removed by washing with soap and water. Avoidprolonged contact with used motor oil.Acute ToxicityUnlikely to cause more than transient stinging or redness if accidental eye contactoccurs.Unlikely to cause harm to the skin on brief or occasional contact but prolonged orrepeated exposure may lead to dermatitis and should be avoided.Harmful if swallowed.As with all such products containing potentially harmful levels of PCAH’s,prolonged or repeated skin contact may eventually result in dermatitis or moreserious irreversible skin disorders, including cancer.At normal ambient temperatures this product will be unlikely to present aninhalation hazard because of its low volatility. It may be harmful by inhalation ifexposure to vapour, mists or fumes resulting from thermal decomposition productsoccurs.Chronic ToxicityUsed motor oilsCombustion products resulting from the operation of internal combustion enginescontaminate engine oils during use. Used motor oil may contain hazardouscomponents which have been shown to cause skin cancer in mice followingrepeated application and continuous exposure. Frequent or prolonged contactwith all types and makes of used engine oil must therefore be avoided and a highstandard of personal hygiene maintained. Brief or intermittent skin contact withused motor oil is not expected to have serious effects in humans if the oil isthoroughly removed by washing with soap and water.Transformer / switchgear oilsUsed transformer / switchgear oil may contain hazardous components that havelimited evidence for human carcinogenicity. These products should be stored andhandled separately from other used oil.

Material SafetyData SheetPage:Issued:Revised:Rev. No.:Page 8 of 914 02 200625 06 20081Product: USEDLUBRICATING OIL12. ECOLOGICAL INFORMATIONEnvironmental effectsThis material is inherently biodegradable. Where present, components such aspolychlorinated biphenyls and terpenyls (PCB’s and PCT’s) are harmful to aquaticorganisms and may cause long term adverse effects in the aquatic environment.Spillages may penetrate the soil causing groundwater contamination.Spills may form a film on water surfaces causing physical damage to organisms.Oxygen transfer could also be impaired.13. DISPOSAL CONSIDERATIONSWaste DisposalPlace contaminated materials in disposable containers and dispose of in amanner consistent with applicable regulations. Contact local environmental orhealth authorities for approved disposal of this material. Do not flush to drain /storm water system.RemarksThis material may present risks common to oil spills. Contact oil spill responsegroup and applicable government agencies if a spill occurs.14. TRANSPORT INFORMATIONUN no./ SIN12683802N/AName ofProductICS:IMDG CodeMarine Pollutant:Petroleum distillate(N.O.S.)Class 3: Group IIIClass 3YesWaste EnvironmentalHazardous Substance (N.O.S.)Not determinedNot knownYesLow HazardN/AN/AEnvironmental hazard15. REGULATORY INFORMATIONNational LegislationNational Road Traffic Act 1996National Road Traffic Regulations 1999Hazardous Substances Act 1973Occupational Health and Safety Act 1993; Reg1179 HazardousChemical Substances

Material SafetyData SheetPage:Issued:Revised:Rev. No.:Page 9 of 914 02 200625 06 20081Product: USEDLUBRICATING OILRespirator information: Respirators must follow AS/NZS 1715/1716 standard forapproved respirators. In the absence of local approved authorities, follow U.S.NIOSH/MSHA, U.K. BSI, or joint Australia-New Zealand AS/NZS 1715/1716.Risk PhasesR10 – FlammableR45 – May cause cancerR52/53 – Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.16. OTHER INFORMATIONTo the best of our knowledge, the information provided in this MSDS is correct.Access to this information is also being provided via the Internet so that it can bemade available to as many potential users as possible. We do not assume anyliability for consequences of the use of this information since it may be applied underconditions beyond our control or knowledge. Also it is possible that additional datacould be available after this MSDS was issued.Certain hazards are described herein; however these may not be the only hazardsthat exist. All materials may present unknown hazards and should be used withcaution. Customers are encouraged to review this information, follow precautions,and comply with all legislation regarding the use and disposal of the product. Forspecific technical data or advice concerning this product as supplied in your countryplease contact:NORA-SAFax: (021) 448 7563Tel: (021) 448 7492E-Mail: usedoil@iafrica.comThe final determination of the suitability of any material is the sole responsibility of theuser.MSDS content extracted from ROSE and FFS Refiners MSDS's for Used LubricatingOils.

and SANS Code 10089:2003-1. Product should be stored in a well-ventilated area. Sparks, flames and other sources of ignition near the product should be avoided. Do not eat, drink or smoke in storage area. 8. EXPOSURE CONTROLS / PERSONAL PROTECTI

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