Copper Alloys - ThyssenKrupp

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Copper & AlloysThe electric metal.ThyssenKrupp Materials NACopper and Brass Sales Division

Copper and AlloysWelcome to Copper and Brass Sales. 1C385. 50Introduction to Copper and Alloys. 2C443. 52Processing Services. 4C464. 53Stock AvailabilityC485. 55C101, C102. 6C510. 56C110. 13C544. 58C122. 20C623. 59C145. 24C624. 59C147. 25C625. 59C172. 26C630. 60C173. 30C642. 62C175. 30C655. 63C180. 31C673. 63C181. 31C675. 63C182. 32C676. 63C187. 34C693. 63C191. 34C725. 64C210. 35C752. 64C220. 35C863. 64C230. 35C932. 65C260. 36C954. 68C272. 39MoldMAX . 72C274. 39ToughMet . 73C314. 40Physical Properties. 74C330. 41Fabrication Properties. 75C335. 41Mechanical Properties. 76C353. 42Chemical Compositions. 80C360. 43Specification Cross Reference. 82C365. 49Weight Formulas.inside back coverNote: The data contained in this brochure hasbeen compiled from many sources. Although every effort has been made to crosscheck and verifythis information, Copper and Brass Sales is notresponsible for its accuracy. This data is not to beused for design or specification purposes. Copyright 2013, ThyssenKrupp Materials NA, Inc.MoldMAX and ToughMet are registered trademarks of Materion.Contents

Welcome to Copper and Brass SalesConsider this catalog your key to the vast storehouseof copper and copper alloy products comprising theCopper and Brass Sales Division of ThyssenKrupp Materials NA. Within these pages, you’ll find one of the largestselections of copper and alloy sizes and shapes availableanywhere — all in stock and ready for immediate deliveryto your door.You’ll also find helpful technical data and informationon how to put these items to work for you. You’llfind information on specifications, chemicalcompositions, physical properties, tolerances,fabrication properties, and more — all arrangedto allow you to make the comparisons necessary to match the right material to the job at hand.After you’ve found the alloy you need, you’ll also find oneof the most comprehensive lineups of precision preprocessing services in the industry. These services will saveyou much time and money by supplying your order inimmediately usable condition. Our precision saws, slitters,shears, cut-to-length, edge conditioning, leveling, andtraverse-winding equipment will minimize additional handling on your part to maximize your bottom line. Additionally, we operate our own re-rolling mills to supply you withthose hard-to-find in-between sizes and tempers. It’s likegetting a custom mill order with the added advantage ofservice-center response.We think that you’ll find many other advantages to dealingwith the Copper and Brass Sales Division for all of yourmaterials needs. Because we’re a nationwide company,you’ll have access to a national inventory of metals.Because we have stocking locations across the country,you’ll have the reliability of local service. Because weoperate and maintain our own national logistics system,you’ll know that we can get your order to you when andwhere you need it.And finally, if you don’t see what you need within thespace of these pages, call us at (800) 926-2600. Because this is a stock catalog, we haven’t listed the manyspecial items we have or can access to meet your mostunusual requirements.We take great pride in the ability of our people to serveyour needs and we look forward to doing so in the nearfuture.Just remember, when it comes to copper and alloys andall your nonferrous needs, your best source is theCopper and Brass Sales Division.Not For Design Purposes1

Introduction to Copper and AlloysAs one of the oldest names in metallurgical history, copper exhibits a uniquecombination of properties includinghigh electrical and thermal conductivity,and high resistance to corrosion.Mankind’s First MetalCopper has been in use at least 10,000 years, but more than 95% ofall copper ever mined and smelted has been extracted since 1900.As with many natural resources, the total amount of copper on Earthis vast (around 1014 tons just in the top kilometer of Earth’s crust, orabout 5 million years worth at the current rate of extraction). However,only a tiny fraction of these reserves is economically viable, givenpresent-day prices and technologies. Various estimates of existingcopper reserves available for mining vary from 25 years to 60 years,depending on core assumptions such as the growth rate.While copper in its purest form is a very soft metal, almost any elementthat can be added to copper will increase its hardness. The additionof tin not only imparts strength but also results in an alloy, known asbronze, that can be readily cast in molds. Early on, man discoveredthat bronze would flow evenly into molds and produce reliable castingswith intricate shapes and patterns.Later, the Egyptians developed the art of further hardening copper withthe addition of alloying elements and then work hardening the metalby hammering. In addition to advancing the metalworking art, theEgyptians also contributed an early symbol for copper still used today.In the form of a cross with an oval loop on top, this symbol, the ankh,was the one they used for enduring life and was found repeatedly inthe writings on the tombs of ancient kings.The ancient symbol for eternal life, theAnkh, was also used to represent copper.Copper AlloysOver the years, as new uses for copper have been discovered, so toohave an entire range of copper-based alloys developed to meet specificneeds and applications.Copper alloys are metal alloys that have copper as their principalcomponent. They have high resistance against corrosion. The bestknown traditional types are bronze, where tin is a significant addition,and brass, using zinc instead. Both of these are imprecise terms, having been commonly referred to as lattens in the past. Today we tend tosubstitute the term copper alloy instead.The similarity in external appearance of the various alloys, along withthe different combinations of elements used when making each alloy,can lead to confusion when categorizing the different compositions.There are as many as 400 different copper and copper-alloy composi-2The old Kennecott mine is perched on the edge of a glacialmoraine, in the deep interior of Alaska’s Wrangell-St. EliasNational Park and Preserve, the nation’s largest.The Guggenheims and Morgans (of J.P. Morgan fame) financedthe construction of this self-contained mining town in the early20th century and brought in the railroad to boot. It was all to takeadvantage of a geologic wonder in the mountains above — one ofthe richest deposits of copper ore ever recorded.tions loosely grouped into the categories of copper, high-copper alloy,brasses, bronzes, copper-nickels, copper–nickel–zinc (nickel silver),leaded copper, and specialty alloys. The table that follows lists theprincipal alloying element for five of the more common types used inmodern industry, along with the name of each type. Historically, othertypes, such as those that are characteristic of the Bronze Age, arevague as the mixtures were generally variable.Not For Design Purposes

Introduction to Copper and AlloysAlloy Classifications500 Series (C50000) Phosphor BronzesFamilyPrincipal alloying elementUNS numbersCopper alloys, brassZinc (Zn)C1xxxx – C4xxxx,C66400 – C69800Phosphor bronzeTin (Sn)C5xxxxAluminium bronzesAluminium (Al)C60600 – C64200Silicon bronzesSilicon (Si)C64700 – C66100Copper nickel, nickelsilversNickel (Ni)C7xxxxFor purposes of identification, copper and copper alloys are dividedinto characteristic groups, each group determined by its composition,and referenced by a system of three-digit numbers originally designated by the Copper Development Association, or CDA. Today thesedesignations have been expanded to five digits, following a prefix letterC, and made a part of the Unified Numbering System for Metals andAlloys which is jointly managed by the American Society for Testingand Materials, ASTM; and by the Society of Automotive Engineers,SAE. These groups are summarized as follows:100 Series (C10000) CoppersThis group comprises the pure coppers, those with a designated minimum copper content of 99.3%, for high electrical conductivity.Also included within this group are the high copper alloys, those withcopper contents of between 99.3% and 96%; which contain additionalalloying elements such as beryllium, cadmium, chromium, cobalt, nickel, or iron forgreater strength without drastically reducingthe electrical conductivity.These alloys feature greater resistance to alternating or cyclic stressas required in applications for springs, diaphragms, bellows, andcontacts.This series also includes the leaded phosphor bronzes which providebetter performance under load conditions found in sleeve bushings,bearings, thrust washers, and engine and drive train applications.600 Series (C60000) BronzesThis series of alloys includes the aluminum bronzes, which contain 2 to3% of aluminum for strength while maintaining formability. These alloys are often used for wear plates, bushings, bearings, and hydraulicvalve parts.Also included in this group are the silicon bronzes which are suitablefor all types of welding in addition to having good hot forming and coldworking properties.Other miscellaneous copper-zinc alloys are also included within thisclassification series.700 Series (C70000) Nickel SilversThese special alloys composed of copper, nickel, and sometimes lead,have high strength and increased resistance to corrosion along withgood formability.200 Series (C20000) BrassesThese are the basic copper-zinc alloys whichfeature ease of manufacturing while still maintaining fair electrical characteristics. Thesealloys are excellent for drawing and formingwhile still providing good strength.300 Series (C30000) LeadedBrassesThese are basically brass alloys that containan addition of 1 to 3% lead to provide greaterease of machining, blanking, shearing, sawing, and milling.400 Series (C40000) Tin BrassesThese alloys contain 1 to 2% of tin as well ascopper and zinc to provide greater corrosionresistance while maintaining strength. Thesealloys find many uses in electrical applicationssuch as contact springs, fuse clips, terminals,and connectors.Loading copper ingots in Houghton, Michigan, circa 1905. This at a time whenMichigan’s Upper Peninsula was an important source of the metal necessary to feedthe nation’s hunger for the new electrification technology. Notice the advanced electriclighting facilities provided dock side.Not For Design Purposes3

Processing ServicesAt Copper and Brass Sales, our servicedoesn't stop with the sale. We processall products to strict mill specificationsand precise tolerances with the shortlead time and dependable delivery thatyou can count on every day.AnnealingOur custom-designed strand and bell annealing furnaces processcopper and alloy strip plus nickel and special purpose alloys in a widerange of tempers and target grain sizes.AnnealingThickness Capability.004" to .150"Minimum Widthno minimum widthMaximum Width13.5"SlittingCopper and Brass Sales precision coil slitting machinery is used onlyfor nonferrous metals to ensure peak performance at all times. Our slitters accommodate widths up to 36" and thicknesses up to .125" withwidth tolerances as close as .002".SlittingRe-rollingCopper and Brass Sales re-rolls strip and coil on precision mills toprovide customers the exact thickness of material necessary for lightgauge close-tolerance requirements. The result is the consistent thickness and uniform temper essential for critical electronic, aerospace,automotive and similar applications.Re-Rolling4.004" to .150"Minimum Widthno minimum widthMaximum Width13.5"TolerancesThicknessTolerance.004" to .035" .0005".035" to .060".060" to .150"Aluminum, Copper, Copper Alloy, StainlessSteel, ZincThickness CapabilityUp to .187" depending on alloyWidth Capability.100" to 36" depending on thicknessTolerances .002" on widthCamberOne-half commercial tolerance, tighter onrequestOtherID capabilities: 3", 4", 6", 10", 12", 14",16", 20"; OD capabilities: up to 60"; Pinchroll capabilities for burr height controlTension LevelingOur unique coil-to-coil tension levelers remove high crowns andedgewise curvature from coiled strip products. This allows us to deliverproduct processed with the close-tolerance flatness required for criticalstamping, lead frame (nickel alloys) and chemical etching.Tension LevelingThickness CapabilityMaximum ODAlloysThickness Capability.004" to .045"Minimum Width.250"Maximum Width4"Tolerances1/4 commercial tolerance on camber,dish, and coil set .00075"ProcessCoil-to-coil .001"Coil Sizes3" to 16" ID; 36" max. OD40"Not For Design Purposes

Processing ServicesTraverse WindingBar SawingOur custom built 5-head traverse winders provide reels with strip thatis smooth and free of distortion and functional welds that won’t harmtooling. Traverse winding gives you longer coils for greater run time,efficiency, and productivity.Rod, bar, tube and extrusions can be cut to your exact specificationson our high-speed equipment.Traverse WindingThickness Capability.005" to .040"Minimum Width.25"Maximum Width2.25"Spool SizeStandard 1000# spools; Can provide500# or 2000# spools on requestLeveling & Cut-To-LengthOur investment in advanced equipment and experienced, highlytrained operators allows us to deliver nonferrous and specialty alloysto mill certified flatness precisely as you need them, so you get exactlythe size flat strip you need to minimize scrap.Leveling & Cut-To-LengthBar SawingStandard .062", all bar sizesPrecision .010", up to 8" round and square, closertolerances can be performed by requestEdge ConditioningEdge conditioning removes the edge burrs left from slitting for criticalapplications such as transformer winding and precision stamping.Edge ConditioningEdge Burr Crush.003" to .125" thickFormed Edge Conditioning.025" to .125"PlatingAlloysCopper & Alloys, Aluminum, StainlessSteel, ZincTin plating and other secondary processes are available on request.Call (800) 926-2600 for more information on plating services.Thickness Capability.010" to .125"Minimum Width.250"Testing & Quality ControlMaximum Width60"Length14" to 192" depending on widthLength ToleranceFrom .0625" to .250"/–.000Note: Cut-to-length services for sheet products are available up to60" wide.Plate SawingOur plate sawing capability allows us to save you time and money bysupplying your material in immediately usable condition.Plate SawingStandardThickness .125" to 3" .032"Precision .010"Sawed Rings & CirclesODIDThickness .1875" thru 2" .125"/-0 0/-.125"Thickness 2" thru 5" .25"/-0 0/-.25"Quality assurance at Copper and Brass Sales is an integral part of ourentire process. Each incoming shipment we receive is inspected fordamage, dimensions, water stains, and blemishes before it is acceptedfor further processing.All outbound processed material is inspected by visual and dimensional methods to ensure that you receive the highest quality productavailable. All certification is also double-checked to guarantee materialmeets order requirements. And when necessary, as in the case ofinternally annealed and/or re-rolled material, our in-house laboratoryservices test for mechanical properties and grain size.All of our locations are ISO 9001:2008 certified andmany locations are certified to AS9100:2009.Our Commitment To YouEverything we do at Copper and Brass Sales — from precisionprocessing, to quality control, to dependable delivery — is focusedon you, our customer. One call to (800) 926-2600 gets you the finestquality nonferrous and specialty alloys available. Just the way you wantthem — when you want them — where you want them.Not For Design Purposes5

C101, C102C10100 and C10200 Oxygen Free CopperNominal CompositionMechanical PropertiesC10100 — 99.99% minimum copper with maximum limits in parts permillion (ppm) for the following impurities: antimony – 4, arsenic – 5,bismuth – 1, cadmium – 1, iron – 10, lead – 5, manganese – 0.5,nickel – 10, oxygen – 5, phosphorus – 3, selenium – 3, silver – 25,sulfur – 15, tellurium – 2, tin – 2, and zinc – 1.C10200 — 99.95% minimum copper (including silver), 10 ppm maximum oxygenPhysical PropertiesTensileStrength(psi)Yield Strength(0.5% Ext.)(psi)%Elongation(in 2")RockwellHardness0.250" Dia. —H04 Hard (20%)55,00050,00010HRB 601.000" Dia. —M20 As Hot Rolled32,00010,00055HRF 401.000" Dia. —0.050 mm OS05032,00010,00055HRF 401.000" Dia. —H04 Hard (35%)48,00044,00016HRB 472.000" Dia. —H04 Hard (16%)45,00040,00020HRB 45TensileStrength(psi)Yield Strength(0.5% Ext.)(psi)%Elongation(in 2")RockwellHardnessRodMelting Point (Liquidus):1,083 C (1,981 F)Melting Point (Solidus):1,083 C (1,981 F)Density at 68 F:0.323 lb/in3Coefficient of Linear Expansion:(per F)9.4 x 10-6 (68-212 F),9.6 x 10-6 (68-392 F),9.8 x 10-6 (68-572 F)0.080" Dia. —0.050 mm35,000—35 (in 10")—0.080" Dia. —H04 Hard55,000———101% IACS for C10100,100% IACS for C10200(in annealed condition;lower in hard temper)0.080" Dia. —H08 Spring66,000———TensileStrength(psi)Yield Strength(0.5% Ext.)(psi)%Elongation(in 2")RockwellHardnessThermal Conductivity:226 Btu/ft2/ft/hr/ F at 68 F0.040" Thick —H02 Half Hard42,00036,00014HRB 40Modulus of Elasticity — Tension:17,000 ksi0.040" Thick —H04 Hard50,00045,0006HRB 50Modulus of Rigidity:6,400 ksi0.040" Thick —M20 As Hot Rolled34,00010,00045HRF 450.

and Materials, ASTM; and by the Society of Automotive Engineers, SAE. These groups are summarized as follows: 100 Series (C10000) Coppers This group comprises the pure coppers, those with a designated mini-mum copper content of 99.3%, for high electrical conductivity. Also included within this group are the high copper alloys, those with

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