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ORIGINAL(red)"APPENDIX FDATA OBTAINED FROM PREVIOUS SITE INVESTIGATIONS(SECTION 6.0 OF NUS WORK PLANPREVIOUSLY SUBMITTED IN NOVEMBER 1983)ARI00667DRAFT

6.0ENVIRONMENTAL CONCENTRATIONSS.'iAirORIGINAL(rpr\\An air sampling program was conducted at the site on November 16 and 17, 1982 bytrie Environmental Response Team (ERT) from ERA Region III. Ten onsitelocations and two background locations were sampled using calibrated portable airpumps with different capturing media for various chemical groups. These mediawere analyzed for total organics, organic solvents, aromatic amines, inorganic.acids. ?C3s, and metal parciculat'es. No airborne vapor/gas contaminants werepresent above the detection limits.Air samples were collected in the crawl spaces of houses adjacent to the landfillusing similar collection equipment as the onsite air survey. "Grab samples werecollected and analyzed using a Photovac 10A10 portable gas chromatograph (QC).The samples that gave a response were sampled with the pumping system for alonger period of time. Table 5-1 presents the analytical .results, which indicatethat some form of hydrocarbons were present in all samples. Since there werecompounds present at or slightly above the GC's detection limit, but not insufficient concentration to be identified on a GC/MS, all compounds detected in asample were totalled and reported as total hydrocarbons (as if it were toluene).The orfsite sampling did not show the presence of compounds in sufficientconcentrations to be identified on a GC/MS with the exception of carbontetrachloride in one sample ( 20 -g) in a 500 mg charcoal tube (ERT. I983b).SoilTable 5-2 lists the locations and descriptions of soil samples collected at or nearthe site by various agencies. PADER collected three soil samples from on site andfour samples from adjacent, offsite property. ERT collected soil samples from 23locations on sits, some of which were sampled at various depths. ERT samplinglocations are shown on Figure 5-1. The analytical results are presented inTables 5-3. 5-«t 6-5. and 5-5.6-1

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ft" I*'*TABLE 6-2MJLLCREEK SITEQ IV 1 Li I - - SOIL SAMPLE LOCATIONS V, -SampleCodeSample Locationor Number" "DescriptionSMC01Middle of siteOily wasteSMC02Composite of siteSMC0350 yd south-Well 1 Sample at 6-tnintervals- ER(18 in. to 24 in.)SMC04Sample #1Samples at surface, 1 ft, 4 ft11/82ERTSMC05Sample #2Samples at surface, 1 ft. 4 ft11/82ERTSMC06Sample #3Surface - saturated silt muck- 1 ft - saturated gray clay muck4 ft - saturated gray clay, sandSMC07Sample *4SMC08SMC0911/82ERTSurface - black loam1 ft - black silt fill4 ft - black silt fill11/82E3TSamplersSurface - black silt fill1 ft - black silt fill11/82ESTSample 6Surface - black muck11/82ERT1 ft - light brown clay, silt4 ft - saturated fine brown sandSMC10Sample #7Surface - black clay, silt1 ft - brown clay, silt4 ft - saturated sand11/82ERTSMC11Sample 811/82ERTSMC12/Sample #9Surface - black muck1 ft - clay.4 ft - brown sandSurface - black muck, peat1 ft - brown clay, silt4 ft - saturated brown muck11/82ERTSMC13Sample 10Surface - black clay3 ft - brown saturated6 ft - brown sand, loam11/82ERTSMC14Sample *11Surface - black clay, sand1 ft - saturated brown sand4 ft - brown gravel, loam11/82ERT6-3

MILLCREEK SITESOIL SAMPLE LOCATIONSPAGE TWO ('—'/5 3" ORIGINALSampleCodeSample Locationor Number(-f6(i)Description - DateSMC15Sample #12Surface - saturated black sand1 ft - saturated brown clay4 ft - gray sand, silt11/82EHTSMC16Sample #13Surface - saturated brown sar-d, silt3 ft - saturated brown clay, sand6 ft - saturated gray gravel, sand11/82ERTSMC17Sample #14 .Surface - brown silt loam3 ft - light brown clay6 ft - saturated brown clay11/82ERTSMC18Sample #15Surface - brown loam11/82ERTSampler1 ft - saturated black muck4 ft - saturated gray gravel, sandSMC19Sample #16Surface - black loam"6 ft - saturated brown sand, silt11/82ERTSMC20Soil Sample #17Surface - brown loam6 ft - saturated gray sand, clay11/82ERTSMC21Soil Sample #18Surface - black fill, sand, gravel11/82ERTSMC22 'Sample #19Surface - black loam11/82ERTSMC23Sample #20Surface - black fill11/82ERTSMC24Sample #21Surface - black fill11/82ERTSMC25 Sample #22Surface - black fill11/82ERTSMC25Sample #23Surface - black loam11/82ERTSMC27Oros backyardComposite10/26/82 PADERSMC28George backyardComposite10/26/82 PADERSMC29Hetrick backyardComposite10/26/82 PADERSMC30Front yardsComposite10/26/82 PADERSources:PADER. March 23, 1932; PADER, July 23. 1982; PADER. July 29, 1932;PADER. October 25, 1982; ERT, April 19S3.ERT:PADER:Environmental ResponserjTftf1}") r 7 iPennsylvania DeparrmsW JfUi.M/PoTimental Resources6-4

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ORIGINALTABLE 6-3MILLCREEK SITE . .SOIL ANALYSES - METALS, INORGANICS"(fed)Sample Number Parameter———————————— Parameter,SMC01(mo/ka)SMC02(ma/ka)SMC03fmg/kg) -2668.00o35,712OilpHTotal Organic CarbonChemical Oxygen DemandCyanide (total)Cyanide (free)PhenolsAmmonia (as IM)ArsenicCadmium Chromium OJ 0.1—.,.o01Q3MercuryyNickelSeleniumSilverZincI O mm514011,944i,331—103956 0.246,6396224,7770.65SariumIronMolybdenum— : :mg/kg:— 5Q 3Not analyzedLass thanmilligrams per kilogram1See Table 5-2 and Figure 5-1 for sample locations————&R10Q673Sources: PADER. March 23, 1982; PADER. J,,y 23, 1932; PADER. July 29. 1932.o-o

ORIGINALMILLCREEX SITESOIL ANALYSES - EP TOXJCJTY RESULTSSample Number .8103—140—————EP Laachate(ma/]]5MC02Soil(mg/kg)EP Leachatefmg/n—130.005—620.05 0.01 3 0.010.0282 0.01—11,944 .3.220.071,331 0.20—103 0.002—956 0.02— 0.2 0.01—4 0.01—6,63912.73mg/l: milligrams per litermg/kg: milligrams per kilogram :Less thanNot analyzed''See Table 6r2 and Figure 6-1 for sample locationsSources: PADER, March 23, 1982; PADER, July 23, 19826-7

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Of the three onsite samples collected by PADER, SMC01 and SMC02 wereanalyzed for metals and were leached using the RCRA extraction procedure andanalyzed. SMC02 w-as also analyzed for other inorganic compounds. SMC03 wasanalyzed for oil and PCS. SMC01 and SMC02 contained metals at variousconcentrations. SMC03 contained 12 pg/kg of PCS (as Aroclor 1248) and 35,712mg/kg of oil. "The samples that PADER collected off site (SMC 27 through SMC 30) wereanalyzed by GC/MS for priority pollutant organics. No acid extractables, volatiles.PCSs, or pesticides were detected in the four samples. All four samples containednumerous base/neutral extractables. The concentrations ranged from 1 ug/kg foracenaphtylene to 680 ; g/kg for di-n-butyl phthalate.Samples SMCO4 through SMC08, collected by ERT, had water extracts from themanalyzed using the Microtox System. The Microtox is intended for use indetermining the acute toxicity of aqueous samples. The system uses a specialstrain of bioluminescent bacteria. A photomultiplier tube measures the relativelight output of these organisms before and after exposure to serial dilutions of asample. Toxicity is indicated by a percent decrease in light output. The resultsfrom duplicate samples are averaged to calculate- a normalized percent lightdecrease (NPLD) corresponding to each dilution. Marginal toxicity is sometimesindicated by an 'increase in light output due to biostimulation of the bacteria (ERT,1983b). The results of the Microtox System analysis are shown in Table 6-7.Samples SMC09 through SMC26, collected by ERT, were analyzed for organicpriority pollutants.3ase/neutral extractable compounds were detected in SMC09and SMC20 through SMC26. Volatile organics were detected in SMC13, SMC16.SMC17. and SMC26. PCS was detected in SMC21, SMC23, and SMC25. Thevolatile organics appeared to penetrate further into the ground and to accumulatein the saturated zone, in contrast to the base/neutral extractable compounds.Especially evident were 1,2-trans-dichloroethylene and trichlorcethylene, whichappeared in deeper soils while absent from the surface soils. The base/neutraiextractable compounds were Generally confined to the top foot of soil.

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6.3ORIGINALGroundwater.- (red)Table 6-8 lists the locations of groundwater.-samples collected by various agencies.PADER collected 14 groundwater samples at or near the Millcraek Site, ERT andTAT collected 12 onsite groundwater samples, and a Technical Advisory Team(TAT) collected 3 groundwater samples off the site. Analytical results arepresented in Tables 6-9, 6-10 and 6-11.Millcreek Township had installed 5 monitoring wells on its portion of the site. Nineadditional wells were installed around the site for the ERT investigation. Threepublic drinking water wells (Yoder Wells) and two private wells were also sampled.PADER sampled the township monitoring wells in July 1982. These samples(GWMC01, GWMC03, GWMC04, GWMC08, and GWMC09) were analyzed for allpriority pollutants and other inorganic parameters. Some metals and volatileorganics were detected in the five wells at van/ing concentrations. PADERresampled two of the wells (GWMC04 and GWMC07) in January 1983. Metals andvolatile organics were detected again, in addition to low concentrations (23 ug/1) ofisophorone and bis(2-ethylhexyl)phthaiate, base/neutral extractables, in GWMCC4.PADER sampled all five township monitoring wells .(GWMC26 through GVVMC30) inApril 1983 and -analyzed them for gross alpha and gross beta radioactivity. Thevery low levels measured were below drinking water standards and do not indicatea radioactivity hazard.ERT and TAT sampled three of the five wells installed by the townsmp and the nineadditional onsite wells (No. 6-14) in December 1982. These samples (GWMC02,GWMC06, and GWMC10 through GWMC19) were analyzed for metals, volatileorganics, and polynuclear aromatic hydrocarbons (PAH's).Mo PAH's weredetected. Volatile organics were detected in GWMC02, GVVMC06, and GVVMC11through GWMC16. Metals were detected in even/ sample.TAT sampled the Ycdsr public drinking water supply wells in February 1983. Thesesamples (GVVMC20 through GWMC22) were analyzed for priority pollutant craanicARI0068Q6-13

0 R! GI N ALMILLC8EEK. SITE.GROUNDWATER SAMPLE LOCATIONSSampleCodeSample Locationor 04Twp. WellTwp. WellTwp. WellTwp. Well#1#1 2 2Black iron casingBlack iron casingBlack iron casingBlack iron casing(not purged)7/21/8212/5/327/21/321/12/83PADERERT, TATPADERP OERGWMC05Twp. Well 43Black iron casing7/21/82PADERGWMC06Twp. Well #3Black iron casing12/5/82ERT, WMC23Twp. Well 3Twp. Well *4Twp. Well #5Twp. Well #5Well #6Well #7Well #8Well 9Well 10Well #11Well * 12Well #13iWell #14Yoder Well #1Yoder Well #2Yoder Well 3Knost3133 W. 12thStreetBlack iron casingBlack iron casingBlack iron casingBlack iron casingPVCPVCPVCPVCPVCPVCPVCPVCPVCPublic water supplyPublic water supplytr Public water supplyPrivate wellARI00685-141/12/83PADER .7/21/32PADER7/21/82PADER12/5/32ERT, TAT12/5/32ERT, TAT12/5/82ERT, TAT12/5/82ERT, TAT12/5/82ERT, TAT12/5/82ERT, TAT-12/5/82ERT, TAT12/5/32ERT. TAT12/5/82ERT, TAT12/5/82ERT. TAT'2/83TAT2/83 TAT2/83 TAT12/14/82PADER

TABLE 6-8MILLCREEK SITEGROUNDWATER SAMPLE LOCATIONSPAGE TWOSampleCodeSample Locationor raschneskeKraschneskeTwp. Well #1Twp. Well #2Twp. Well #3Twp. Well #4Twp. Well #5.DescriptionKitchen faucetPrivate wellBlack iron casingBlack iron casingBlack iron casingBlack iron casingBlack iron 834/11/834/11/824/1J/83PADER:ECHO:Pennsylvania Department of Environmental ResourcesErie County Health DepartmentTAT:Technical Advisory TeamERT:Environmental Response es: Vrenna, C., January 12, 1981; PADER, July 1, 1982; PADER, July 21,1982;'PADER, December 14, 1982; PADER, January 12, 1983; Dreisch,R., February 1, 1983; Austin, J., February 2, 1983; Kayser, S., February16, 1983; Sammons, 3., February 18, 1983; ERT, April 1983; PADER,April 11, 1983.6-15

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Imrltrr/ compounds and some metals. Barium was detected in al! tr je !kaifrp*es.ltrwas detected near the detection limit in GWMC2'i. No organics -weq&'ggrtcted inCWMC20. Trichlorofluoromethane was -detected in GWIVTC21 at a concentrationbetween 1 ug/l and 10 ug/i. 1,1,1-Trichloroethane was estimated at a concentratfonof 0.2 ug/l in GWMC22.PADER sampled private wells owned by Knost (GWMC23) in December 1982 andKraschneske (GWMC24) in July 1982. The Kraschneske well (GWMC25) wassampled by Erie County in November 1980. GWMC23 was analyzed for inorganicsand priority pollutants. No organics were detected. GWMC24 was analyzed fororganic priority pollutants; the results were negative. GWMC25 was analyzed onlyfor inorganics.6.4Surface WatersTable 6-12 lists locations where surface water and sediment samples werecollected by various agencies. PADER collected six surface water samples at- ornear the site. The EPA collected two surface water samples on site, while Ecology and Environment, Inc. (E & E) collected two sediment samples. The ERT and TATcollected four surface water samples. The Erie County Health Department (ECHO)collected six samples from Marshalls Run and one sample from the swamp. Theanalytical results' from all samplings are presented in Table 6-13 through'6-16.The onsite pond was sampled once by PADER (SWMC01) and once by EPA(SWMC02). SWMC01 was analyzed for inorganics and priority pollutants wnileSWMC02 was- analyzed for priority pollutants. Small quantities of various meraiswere detected in both samples. Trace quantities of organics were detected in bothsamples.The drainage ditch (SWMC03) north of the site was sampled by ERT and TAT andanalyzed fc. metals, volatile organics. and polynuciear aromatic hydrocarbons(PAHs). All of tne PAHs tested for were base/neutral extractable compounds. Novoiatiles or PAHs were detected, but some metals were.ARI006895-22

UKItilNAL(red)The drainage ditch (SVVMC04) separating the Halmi and Riehl properties wassampled once by PADER and analyzedfor inorganics andpriority pollutants.i„ « Phenol (1.4 ug/l) and pentachlorophenol (0.3 ug/l) were detected along with metalsa n d other inorganics. , - - - - Water from the south swamp was sampled once by EPA (SWMC05), once by ECHO(SWMC07), and once by ERT and TAT (SWMC08). The swamp sediment wassampled once by E & E (SWMC06). SWMC05 and 06 were analyzed for prioritypollutants. SWMC08 was analyzed for metals, volatile organics, and PAHs.SWMC07 was analyzed for pH, oil, and metals. Metals were detected in allsamples. SWMC06 contained phenol (220ug/kg) and tetrachloroethylene (5 -g/kg).No volatiles or PAHs were detected in SWMC08. No organics were detected inSWMC05.PADER collected.two water samples from Marshalls Run, one upstream (SWMC10)and one downstream (SWMC11) of the Millcreek Township portion of the site. E &E collected a stream sediment sample from Marshalls Run (SWMC09). The aqueoussamples were analyzed for organic priority pollutants. Diethyl phthalate (0.5 ug/l)was detected in SWMC10. SWMC09 was analyzed for priority pollutants. Novolatiles were detected. Numerous metals and base/neutral extractables weredetected along with lesser numbers of PCS, pesticides, and phenol.Marshalls Run, upstream of the site, was sampled once-by PADER (SWMC12) andonce by ERT and TAT (SWMC13). Both samples were analyzed for prioritypollutants while more inorganics were analyzed for in SWMC12. Some metals andvolatile organics were detected in both samples.Marshalls Run, downstream of the site, was sampled once by PADER (SWMC14),once by ECHO (SWMC16), and once by ERT and TAT (SWMC15). SWMC14 wasana yzed for priority pollutants; SWMC15 for metals, volatiles, and PAHs; andSWMC16 for inorganics and metals. Various metals were detected in all samples.Volatile organics were detected in 3WMC14.RR1006906-30

ORIGIN*!The Erie County Health Department conducted a study of Marshallssource to Lake Erie. Macroinvertebrates were collected in addition to watersamples at five locations (SWMC 17 to 21)."Samples were' analyzed for inorganicsand metals.6.5BiotaThe Erie County Health Department conducted a stream survey of Marshalls Run inJune 1982. The sun/ey involved water sample collection along with macroinvertebrate collection. From this survey, the department concluded that the streamexhibits a depressed macroinvertebrats population, and that the presence ofcontaminants in the stream has contributed to this depressed state.It alsorecommended that a more comprehensive study be conducted (Wellington, 1982).6-31

ORIGIN:- (red)APPENDIX G WELL LOCATION, SCREEN SETTING, TEST PIT LOCATIONS,AND SAMPLE LOCATION RATIONALERRS00692LDRAFT

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//ORIGINAL0*. aI «—§.§ § «- &iCO , . o. .IO§ cc§2-2-a-a -a5-c-II f1c .'II IJw* -.co .2 Seoei ass.-sI ;« ;2 II-IOCO!erEo-a2coSOeo oC D C2uIOIwSIs a s §2 1 t 1 t 1is §« 15 I« aI 2au2 *-0 0 0a3IoiS*M U01COoC —§UoI5 I5 f!ris t sa 3112II1ARI00695.53G-3- "(red)

(red)u.aw93iaaS3§ *9JO" :(H JO'i»1I S Oo—SI »w-S *I"S , J,2Ja* i s ' : « s i i. *. 5.3iaeu 5Seu' *— u .(»'-3 — oS !r2eOnt i3a '—(: 50W—5«a Q' "aJO' "a0 . 0 . 2 . 2 . 0 . 9 . 9 9 . 9 .aaaa5aqSaLU0.2oooo» «ooo(0.W3 LOori sq s*«l*J«p L f j i r ) p i O L e 5 o ' i r ! i D ' i T :i c a i ' T ri . i ' ' -i ! i ;Loqquiaqap'THen«?eoco"ericrioz1RII06I6 IicjiaiuioioG-4'ciolcjloiu

ORIGINAL(red)s »CO21ISc2-a.o I. 3Iaattn'5'S13133 !«3a oOwOwS3« O—aICCB ff :«oMOCOlOri— CNb7CN'IiLUc9PCMI035/3Z-1J2CN00 oocC/310ICOe/3ICO1/3IiC2;C2ITiAR100697C2G-5

DRAFT.SampleSURFACE SOIL SAMPLE .RATIONALEft[} f* MA Rationale (fed)« H«B SO-001"Near Small Willow Clump S.W. of Central Mound wheredumping observed by PANDER PersonnelSO-002Dark Stained area south of drum stage araaSO-003Stream bed for drainageway adjacent to W. 17th St. nearbaseball fields where drums were observed earlier in the yearSO-004Stream bed of the north wet vveather drainage ditch t: 3 nine!W. 13th St.SO-005Barren area in woods behind W 13th St. containes car batterypile and old railroad-tiesSO-006Pile of rubble (looks like coal waste) benind well 19A 2-3CYSO-007Barren furnace dust pile in center of siteSO-008Near Pallet pile where PANDER reported possible bulk dumpingSO-009Barren sandy soil adjacent to Well 14SO-010SO-011-"On Sitter property by pile of 5 slag drums.Barren area within a grassy area near slag drumsSO-012Stained soil on Halmi property near swampSO-013Stained soil on Sitter property near front.end loaderSO-014Stained soil in Drum Stage AreaSO-015Stained Soil near gas well on Halmi propertySO-016In area of alleged bulk dumping or drum burial near daadtwisted tree SW of central moundSO-017500 ft. North of SO-016SO-018In former open pit area behind homes on W. 14th St.ARI00698G-6

ORIGINAL-(red) DRAFTSURFACE SOIL SAMPLE RATIONALEPAGE TWOSampleRationaleSO-019In barren fill adjacent re swampSO-020In barren fill adjacent to swarnp behind dead, twisted treeSO-021In area suspected of bulk dumping SE of central mound near3 drumsSO-022 In pond area at outflow to intermit pondSO-023By wreckage of Green Ford Pinto - Area of suspected BulkDumpingSO-024Stained soil near access roadSO-025On dike between pondsSO-0261326 Harper Drive Hetrick in area flooded by Marshall's RunShallow Soil—SO-027SO-028Same as SO-026 but deep soil to collect potential contaminationby GW Discharge-1413 Honeywood LN - Groeger - area downgradient of site wet throughout year - Shallow SoilSO-029Same as 028 but deep soilSO-0303227 W. 13th St. - Churchill - Back by stream bed of weweather drainage di\ch - downgradient "and within flooding ofditchSO-031SO-032'Same as SO-030 but deep3071 W. 12th St. - Mazza - In garden, wet spot throughout theyear - evelated OVA readingsSO-033Same as SO-032 but deep - downgradientSO-034Shallow Soil - Background - frontier ParkSO-035Deep Soil - Background - Frontier ParkSO-036Shallow Garden Sample - Ai Nobbs TransmissionARIQQ699G-7

/"".ORIGINAL.( d) ORAFTSURFACE WATER/SEDIMENT SAMPLE all's Run upstream of outflow from culvertbeneath the railroad tracksSW-02/SD-02SW-02-Dry sediment taken at Marshall's Run convergewith northern wet weather drainage ditchSW-03/SD-03Downstream Marshall's Run - North of West 12thStreet. Appeared to be collection of road drainage.SW-04/SD-04West Branch of Marshall's Run - DownstreamSW-05/SD-05Onsite PondtSW-06/SD-06In swamp near SO-19SW-07/SD-07In swap near Sittlsr PropertySW-08/SD-08.In lowland marshy area near the end of Marshall'sRoad. SW-08-DrySW-09/SD-09In lowland marshy area between the Riehl and theHalmi property near MW-14. SW-09-DrySW-010/SD-010West Branch of Marshall's Run upstream near baseballfieldsSW-010A/SD-010ADuplicates of SW-010 and SD-010BRI00700G-8

ORIGINAL(red)TEST PIT LOCATION" RATIONALETest PitDRAFT' 'Location/RationaleTP-1Near wreckage of Green Ford Pinto - reported area ofbulk dumpingTP-2East side of foundry sand mound reported area ofburial/bulk dumpingTP-3Same as TP-2TP-4Same as TP-2 and TP-3TP-4AIn an effort to delineate the areal extent of a highOVA reading layer TP-4A and 5 were excavatedTP-5See TP-4ATP-6Near area previously excavated by ERT to locate adrumTP-7In lowland oily area previously found to contain PCBTP-8.'8 and 8A were in the area west of the mound reportedto have drums buriedTP-9Same as TP-8TP-10Ne.ir small willow clump where PADER personnelnoted bulk dumpingAR10070I0-9

ORIGINALTEST PIT LOCATION RATIONALEPAGE TWOTest Pit ". -/,xDRAFT(red)Location/RationaleTP-10AContinued excavation in area reportedly containingburied drumsTP-11Same as TP-10ATP-12, 13, and 14In area of dead twisted tree - bulk or buried dumpingreporting in the areaTP-15In wooden pallet area report to have bulk dumpingTP-16Excavation exploraton of the Halmi propertyTP-17Excavation in the area of the gas well explosion andstained soil areaSoil samples taken from test pits either represented saturated samples, samplesexhibiting elevated OVA reading, samples from near buried drums or in some casesactual drum contents (solids).ARI00702G-10

RIGINALDRAFT(red)APPENDIX HCHEMICAL ANALYTICAL RESULTSARI0

1 ft - saturated brown clay 4 ft - gray sand, silt SMC16 Sample #13 Surface - saturated brown sar-d, silt 11/82 ERT 3 ft - saturated brown clay, sand 6 ft - saturated gray gravel, sand SMC17 Sample #14 . Surface - brown silt loam 11/82 ERT 3 ft - light brown clay 6 ft - saturated brown clay SMC18

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