Joining Technologies For Automotive Battery Systems .

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ArticleJoining Technologies for Automotive BatterySystems ManufacturingAbhishek Das *ID, Dezhi Li, David Williams and David GreenwoodWMG, The University of Warwick, Coventry CV4 7AL, UK; Dezhi.Li@warwick.ac.uk (D.L.);David.K.Williams@warwick.ac.uk (D.W.); D.Greenwood@warwick.ac.uk (D.G.)* Correspondence: a.das.1@warwick.ac.uk; Tel.: 44-247-657-3742 Received: 13 June 2018; Accepted: 3 July 2018; Published: 5 July 2018Abstract: An automotive battery pack for use in electric vehicles consists of a large number ofindividual battery cells that are structurally held and electrically connected. Making the requiredelectrical and structural joints represents several challenges, including, joining of multiple andthin highly conductive/reflective materials of varying thicknesses, potential damage (thermal,mechanical, or vibrational) during joining, a high joint durability requirement, and so on. This paperreviews the applicability of major and emerging joining techniques to support the wide range ofjoining requirements that exist during battery pack manufacturing. It identifies the advantages,disadvantages, limitations, and concerns of the joining technologies. The maturity and applicationpotential of current joining technologies are mapped with respect to manufacturing readiness levels(MRLs). Further, a Pugh matrix is used to evaluate suitable joining candidates for cylindrical, pouch,and prismatic cells by addressing the aforementioned challenges. Combining Pugh matrix scores,MRLs, and application domains, this paper identifies the potential direction of automotive batterypack joining.Keywords: EV (electric vehicle); thin metal film; electrode; materials; powertrain; joining1. IntroductionRecent advances in developing secondary batteries enables their extensive use in everyday life,from portable technologies to high energy applications. Lithium-ion based secondary batteries showenormous potential to be used for low to high capacity applications, such as portable electronics andelectric vehicles, respectively. High energy density, low self-discharge, and portability characteristicsof Li-ion based automotive battery packs make them an emerging alternative power source that arebeing increasingly used in electric vehicles (EVs), hybrid or plug-in hybrid electric vehicles (HEVs orPHEVs) [1–3]. Often, these vehicles are exposed to different driving conditions having a huge impacton the energy consumption [4]. Typically, a standard automotive battery pack consists of hundreds,even thousands, of individual Li-ion batteries that are connected in series or parallel in order to achievethe required power and energy. Additionally, there is an increasing requirement for manufacturing ofbattery packs, reflecting the increased demand for this energy storage technology, which is predictedto grow as the volume of automotive product using it develops.In general, an automotive battery pack can be hierarchically decomposed into three levels:(a) emphcell level: an individual battery cell is primarily composed of positive and negative electrodes,separators, electrolyte, and case; (b) module level: a collection of multiple cells generally connected inseries and parallel, encased in a mechanical structure; and (c) pack level: a battery pack is assembledby connecting modules together, either in series or parallel, with sensors and controllers, and then isencased in a housing structure. Typically, design and construction of an automotive Li-ion batterypack, as illustrated in Figure 1, involve producing robust and reliable joints as per hierarchical levelsWorld Electric Vehicle Journal 2018, 9, 22; doi:10.3390/wevj9020022www.mdpi.com/journal/wevj

World Electric Vehicle Journal 2018, 9, 222 of 13World Electric Vehicle Journal 2018, 9, x FOR PEER REVIEW2 of 13and types of cells used to build the battery pack. Relying on the geometry and form factor, lithium-ionand types of cells used to build the battery pack. Relying on the geometry and form factor, lithiumcells are manufactured as (i) cylindrical cells; (ii) pouch encased prismatic cell (typically called a pouchion cells are manufactured as (i) cylindrical cells, (ii) pouch encased prismatic cell (typically called acell); and (iii) solid-container encased prismatic cell (typically called a prismatic cell). Choice of joiningpouch cell), and (iii) solid-container encased prismatic cell (typically called a prismatic cell). Choice ofmethodslargely isbasedon basedthe typeof cellandsubsequently,to satisfythermal,joining ismethodslargelyon thetypeused,of cellused,and subsequently,to electrical,satisfy l, and mechanical key criteria. This paper identifies major and emerging joining technologiesa comprehensivereviewreviewand providesguidancefor appropriatejoiningmethodselection.with a comprehensiveand providesguidancefor appropriatejoiningmethodselection.CompletepackPack hierarchicallevelsJoining requirementsCell TypeAutomotive Battery Pack(used for Automotive ElectricVehicle Battery Pack)Electrode-to-tab within thecellCell LevelCase Sealing of outer cellcontainerModuleLevelCell-to-Cell (i.e. tab-to-tab /tab-to-busbar) electrical andstructural jointsPack LevelModule-to-Moduleelectrical & structural jointsCylindricalCellterminals and safetyventSolid-container encasedPrismatic Cell (orsimply Prismatic cell)Pouch encasedPrismatic Cell (orsimply Pouch cell) ve/-ve terminals ve/-ve terminalsPressurerelief ventAnode(a)CathodeFoil PouchAnodeMetal CaseMetal caseCathodeAnodeSeparator Cathode(b)Figure 1. Battery packs of electric vehicles, and hybrid or plug-in hybrid electric vehiclesFigure 1. Battery packs of electric vehicles, and hybrid or plug-in hybrid electric vehicles(EVs/HEVs/PHEVs) (a) joining at hierarchical/assembly levels and (b) cell types [5].(EVs/HEVs/PHEVs) (a) joining at hierarchical/assembly levels and (b) cell types [5].1.1. Overview of Key Joining ChallengesOverview of Key Joining ChallengesExtensive research has been conducted on developing and characterising Li-ion battery cellsExtensiveresearchandhassimulation,been conducteddeveloping performanceand characterisingLi-ion aldevelopment,performanceand safety.Limited modellingliterature isandavailableon joiningpreferencesand addressingtheirenhancement,associated challenges,Limitedis availableon joining preferences and addressing their associated challenges,which literaturecan be summarisedas follows:which can be summarised as follows: Electrical and thermal challenges: (i) Producing joints with low electrical resistance—lowerelectricalandresistanceat challenges:the joint resultsin low energygeneration,and subsequently, Electricalthermal(i) eduringcharginganddischarging.(ii)Producingjoints lowerwith lowresistance at the joint results in low energy loss, low heat generation, and subsequently,jointthermal input—lowis preferable,especially ncreasethermalduringinputchargingand discharging.(ii) joiningProducingthermalprocesses, thermalas exposingtheiscellto high heatmay meltwhenor disturbthewithsafetyfusionvent, ningtype ls,ofprocesses, as exposing the cell to high heat may melt or disturb the safety vent, compromisebattery interconnects is an important criterion for long-term durability and reliabilityor cause internal shorting. (iii) High thermal fatigue resistance—thermal fatigue resistance of batteryperformance.interconnects is an important criterion for long-term durability and reliability performance. Material and metallurgical challenges: (i) Compatibility for dissimilar materials joining—dissimilar Material and metallurgical challenges: (i) Compatibility for dissimilar materials joining—dissimilarmaterials may create intermetallic layers, which are not preferred because of their ithare parentnot preferredof jointstheir withhigherelectricalmayresistancebrittle ials.Therefore,jointswithlowlow intermetallic is preferable. (ii) Variability of materials and surfaces—highly conductive andintermetallicis preferable.Variabilityof ectivereflective materials,any (ii)surfacecoatingsor oxideandlayers,joint essesthicknesses and/or multiple sheets) also need to be overcome for satisfactory joints.multiplesheets) alsoneed tojointbe overcomeforjointsatisfactoryjoints. and/orMechanicalchallenges:(i) Durablestrength—thearea/nuggetsize that can be achieved a/nuggetthat variability.can be achievedby the trengthwith low sizestrength(ii)mechanicaland vibrationalwhen joining—excessivedeformationor transmissionbyAvoidthe joiningmethodsshould damagehave satisfactoryjoint strengthwith low of,strengthvariability.vibrationinto, themay damageconnection. Precautionsmust beto internalwhen joining—excessivedeformationof,takenor transmissionas inducedresidualstressor vibrationalmay bePrecautionsreleased andmustcausebejointfailure.of thesevibrationinto, thecell maydamageinternalenergyconnection.takento avoidthese as induced residual stress or vibrational energy may be released and cause joint failure.

World Electric Vehicle Journal 2018, 9, 223 of 132. Major and Emerging Joining Technologies—A Comprehensive ReviewThis section reviews the advantages, disadvantages, limitations, and concerns of major joiningtechnologies (See Table 1) including ultrasonic, resistance spot/projection, micro-Tungsten InertGas (TIG) welding/pulsed arc welding, ultrasonic wedge bonding, micro-clinching, magnetic pulsewelding, laser welding, and mechanical fastening.Table 1. Summary of joining technologies.IdJoining TechnologyAdvantagesDisadvantagesOnly suitable for pouch cells,two sided access, slowjoiningIssues and ConcernsAccess of anvil and sonotrodeneeds to be well designed1Ultrasonic weldingFast process, high strength andlow resistance, able to joindissimilar materials, low energyconsumption2Resistancespot/projection weldingFast process, low cost, goodquality control, easy automationDifficult for highlyconductive and dissimilarmaterialsDifficulty to produce large joints,joining of more than two layers3Micro-TIG/pulsed arcweldingLow cost, high joint strengthand low resistance, able to joindissimilar materials, easyautomationHigh thermal input and heataffected zone, porosityDifficult to join Al to steel4Ultrasonic wedgebondingFast process, acting as fuses,able to join dissimilar materials,low energy consumption andeasy automationOnly suitable for smallwires, low wire and jointstrengthClamping of the batteries iscritical5Micro-ClinchingCold process, no additional part,clean process, able to joindissimilar materialsOnly suitable for pouch cells,two side access, slow joiningLoosening under vibration,moisture ingress6SolderingJoining dissimilar materials,wide spread in electronicsindustryHigh heat, fluxes requiredJoint strength, debris,neutralisation of fluxes7Laser weldingHigh speed, less thermal input,non-contact process, easyAutomationHigh initial cost, additionalshielding system mayrequiredNeed good joint fit-up (intimatecontact), high reflectivematerials8Magnetic pulse weldingSolid state process, able to joindissimilar materials, high jointstrength, dissimilar materialsPotential large distortion,rigid support requiredPossibility of eddy currentpassing through the cells9Mechanical assemblyEasy dismounting and recycling,easy repair, cold processAdditional weight, highresistance, expensivePotential mechanical damageand go loose2.1. Ultrasonic Welding or Ultrasonic Metal Welding (UMW)Ultrasonic metal welding (UMW) is one of the most commonly used joining methods for batterysystems manufacturing and has been applied to a wide range of metals and thin metal films (e.g., foils).It utilises high frequency ultrasonic vibration, typically 20 kHz or above, to join substrate materials bycreating solid-state bonds under a clamping pressure [6]. In principle, high frequency relative motioncreates progressive shearing and plastic deformation between mating interfaces and produces anatomic bond at elevated temperature (i.e., typically at 0.3 to 0.5 times the absolute melting temperatureof the substrate materials) [7]. However, it needs two sided access, as shown in Figure 2a; one side usesan anvil to support the parts to be joined, and the other side a sonotrode that passes ultrasonic energyto the assembly. Ultrasonic welding is applied for joining of multiple thin foils, dissimilar materials,or highly conductive materials (e.g., Al, Cu, or others) [8,9], especially for pouch cells [10]. However,it may not be suitable for terminal-to-busbar joints of cylindrical or prismatic cells as vibration underpressure may damage structural integrity. UMW has been used for various EVs/PHEVs, includingNissan LEAF, General Motors Chevrolet-Volt, Spark, and Bolt.2.2. Resistance Spot/Projection WeldingResistance spot welding (RSW) works on the principle of electrical resistance at the matingsurfaces when high current passes through them, creating localised heating and fusion of materialsunder pressure [11]. Resistance spot welding is used to join different tab materials, up to 0.4 mmthickness, which are being used for battery connections, including steel, nickel (Ni), copper (Cu), andaluminium (Al) [12]. However, RSW of Al and Cu tabs is difficult because of high electric and thermal

2.2. Resistance Spot/Projection e(b)Clamping stance spot welding (RSW) works on the principle of electrical resistance at the matingsurfaces when high current passes through them, creating localised heating and fusion of materialsWorld Electric Vehicle Journal 2018, 9, 224 of 13under pressure [11]. Resistance spot welding is used to join different tab materials, up to 0.4 mmthickness, which are being used for battery connections, including steel, nickel (Ni), copper (Cu), andaluminium (Al)However, theRSWof Al andis difficultof highand thermalconductivityand[12].in particular,presenceofCuantabsoxidelayer onbecausethe surfaceof electricAl. To overcometheseconductivity and in particular, the presence of an oxide layer on the surface of Al. To overcome thesechallenges, projection welding, a variant of RSW, shows a significant improvement, where projection onchallenges, projection welding, a variant of RSW, shows a significant improvement, where projectiontabs will increase the joint quality and make welding easier. As indicated in Figure 2b, the projectionson tabs will increase the joint quality and make welding easier. As indicated in Figure 2b, thenot only act as energy concentrators for the weld, but also greatly increase electrode lifetimes, becauseprojections not only act as energy concentrators for the weld, but also greatly increase electrodea flat-end RSW-electrode can be used instead of a domed one [13]. In spite of easy automation andlifetimes, because a flat-end RSW-electrode can be used instead of a domed one [13]. In spite of easygoodquality andcontrol,hascontrol,challengesapplied towhenbatteryweldingbecauseof RSW-electrodeautomationgoodRSWqualityRSWwhenhas challengesappliedto s,dissimilarof RSW-electrode sticking (i.e., pick-up of material on the electrode tips) [14], highly dtemperatures,the smaller terialshavingdifferent meltingand thesmallerweld causeoftheincreasedcurrentdensity.experiencing heat generation during charging–discharging because of the increased current density.RSWElectrodeWeld ZoneCell terminal tabsWeld ZoneExternalbusbarCellterminaltabsAnvil(Stationary Part)ProjectionExternalbusbarUltrasonic WeldingSupport PlateSchematic of ultrasonic weldingApplication of ultrasonic welding for pouchcell-to-cell connection (adapted from GMChevy Volt)Resistance Spot WeldingProjection Welding VariantApplication of projectionwelding using bi-furcatedstrip for increased currentflow through tab and cellterminal (adapted fromMacGregor Systems)Figure2. 2.Schematicof workingprinciplesand applications:(a) ultrasonicwelding(b)FigureSchematicof workingprinciplesand applications:(a) ultrasonicweldingand (b)andresistance/resistance/projection welding. RSW—resistance spot welding.projection welding. RSW—resistance spot welding.2.3. Micro-TIG or Pulsed Arc Welding (PAW)Pulsed arc welding, also known as micro-TIG welding, uses a pulsed TIG arc without filler wire tojoin thin materials by localised fusion, see Figure 3a [15]. The arc pulse has a very short duration, in tensof milliseconds, such that heat input is much less than in conventional TIG welding, and can be usedfor welding dissimilar materials [16]. However, even with a significantly reduced heat input, it is stillcrucial to control the welding parameters to avoid overheating of the battery. PAW is suitable for nickel,copper, or steel tabs and copper bus bars. Al tabs and bus bar joining using PAW is difficult and notpreferable (because of the typical direct current (DC)–electrode negative configuration). Alternatingcurrent (AC) PAW is more typically used for Al welding, this is because of the cleaning mechanism,which breaks down the electrically resistive aluminium oxide skin of aluminium alloys. AC pulsed arcwelding has not yet been commercially developed for micro-joining applications. For copper tab tocopper bus bar welding, micro-TIG can produce a single spot nugget in diameter up to 4 mm. There isno report of the application of pulsed arc welding for joining of existing EV or HEV battery packs.2.4. Ultrasonic Wedge BondingUltrasonic wedge bonding (UWB) is a joining technique typically used for electronic connectionsbetween circuit boards or electronic chips [17]. During the welding process, a small (typically 500 µmin diameter) wire (of Al, Cu, or Au) is fed through a welding head; the welding head applies ultrasonicvibration and pressure forcing the wire against the welding target, for example, the battery terminalsor bus bar, as shown in Figure 3b. The main mechanism of UWB is cleaning of mating surfaces andbringing surfaces to the distance required for atomic bonding to create the connections, althoughother mechanisms, such as inter-diffusion of wire into the mating surface and mechanical interlocking,also contribute to the joining process [18]. UWB can be used for joining of dissimilar materials and thebonded wire can be used as a fuse to protect the battery pack against extreme thermal and mechanicalimpact or internal defects. However, because transfer of ultrasonic energy into the material to be joinedis critical for welding, any significant lateral movement of the welding substrate will be detrimentalas it will decrease the vibration amplitude, thereby diminishing the power of the welding operation.Consequently, the cells and the bus bar in the battery module need to be fixed rigidly to allow the

although other mechanisms, such as inter-diffusion of wire into the mating surface and mechanicalinterlocking, also contribute to the joining process [18]. UWB can be used for joining of d

High speed, less thermal input, non-contact process, easy Automation High initial cost, additional shielding system may required Need good joint fit-up (intimate contact), high reflective materials 8 Magnetic pulse welding Solid state process, able to join dissimilar materials, high joint strength, dissimilar materials Potential large distortion,

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