Material Safety Data Sheet - CMB
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Revision Date: 01.03.2017SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1 Product identifierTrade name: KEMACRYL HARDENER 2k Acrylic paint hardener1.2 Relevant identified uses of the substance or mixture and uses advised against: Curing chemicalUse of the Substance/MixtureRecommended restrictionson use: For use in industrial installations or professional treatmentonly.1.3 Details of the supplier of the safety data sheetCompany: CHEMIACL FOR MODERN BUILDING CMB319 Elharam, Giza Egyptcmb@cmbegypt.comTelephone: (202) 35854118Telefax: (202) 35859858E-mail address of personresponsible for the SDS: hosny.ahmed@cmbegypt.com1.4 Emergency telephone number 201285804555 (8:00 AM -5:00 PM )SECTION 2: Hazards identification2.1 Classification of the substance or mixtureClassification (REGULATION (EC) No 1272/2008)Flammable liquids, Category 3H226: Flammable liquid and vapour.Acute toxicity, Category 4H332: Harmful if inhaled.Specific target organ toxicity - single exposure, Category 3, Respiratory systemH335: May cause respiratory irritation.Skin irritation, Category 2H315: Causes skin irritation.Specific target organ toxicity - single exposure, Category 3, Central nervoussystemH336: May cause drowsiness or dizziness.1 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Revision Date: 01.03.2017Skin sensitisation, Category 1H317: May cause an allergic skin reaction.Chronic aquatic toxicity, Category 3H412: Harmful to aquatic life with long lasting effects.Classification (67/548/EEC, 1999/45/EC)FlammableR10: Flammable.HarmfulR20: Harmful by inhalation.IrritantR37: Irritating to respiratory system.R38: Irritating to skin.R43: May cause sensitisation by skin contact.R67: Vapours may cause drowsiness and dizziness.Dangerous for the environmentR52/53: Harmful to aquatic organisms, may causelong-term adverse effects in the aquatic environment.2.2 Label elementsLabelling (REGULATION (EC) No 1272/2008)Hazard pictograms:Signal word:WarningHazard statements:H226H332H335H315H336H317H412Flammable liquid and vapour.Harmful if inhaled.May cause respiratory irritation.Causes skin irritation.May cause drowsiness or dizziness.May cause an allergic skin reaction.Harmful to aquatic life with long lasting effects.Supplemental HazardStatements:EUH066Repeated exposure may cause skin dryness or cracking.Precautionary statements:Prevention:P210P280P2602 / 15Keep away from heat/sparks/openflames/hot surfaces. - No smoking.Wear protective gloves/ protective clothing/eye protection/ face protection.Do not breathe vapours.
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050P260Response:P301 P310P331P362 P364P370 P378Storage:P403Disposal:P501Revision Date: 01.03.2017Do not breathe spray.IF SWALLOWED: Immediately call aPOISON CENTER or doctor/ physician.Do NOT induce vomiting.Take off contaminated clothing and wash itbefore reuse.In case of fire: Use dry sand, dry chemicalor alcohol-resistant foam to extinguish.Store in a well-ventilated place.Dispose of contents/ container to an approved waste disposal plant.Hazardous components which must be listed on the label:HDI oligomers, isocyanurateAdditional Labelling:EUH204Contains isocyanates. May produce an allergic reaction.2.3 Other hazardsThis substance/mixture contains no components considered to be either persistent, bioaccumulativeand toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.SECTION 3: Composition/information on ingredients3.2 MixturesChemical nature: PaintHazardous componentsChemical NameHDI oligomers,isocyanuraten-butyl ) No1272/2008)Xn-Xi; R20-R37- Acute Tox.4; H332R43Skin Sens.1; H317STOT SE3; R6601R672119485493-29Solvent naphtha (petro- 64742-95-6Xn; R653 / 15Concentration(%) 30 - 50Flam. Liq.3; H226STOT SE3; H336 20 - 30Flam. Liq.3; H226 2.5 - 10
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050leum), light arom.265-199-0Xi; R3701N; R51/532119455851-35 R10R66R67Substances with a workplace exposure limit :108-65-6R102-methoxy-1methylethyl acetate203-603-9012119475791-29Revision Date: 01.03.2017Asp. Tox.1; H304STOT SE3; H335,H336Aquatic Chronic2;H411Flam. Liq.3; H226 20 - 30For explanation of abbreviations see section 16.SECTION 4: First aid measures4.1 Description of first aid measuresGeneral advice: Move out of dangerous area.Consult a physician.Show this safety data sheet to the doctor in attendance.If inhaled: Move to fresh air.Consult a physician after significant exposure.In case of skin contact: Take off contaminated clothing and shoes immediately.Wash off with soap and plenty of water.If symptoms persist, call a physician.In case of eye contact: Flush eyes with water as a precaution.Remove contact lenses.Protect unharmed eye.Keep eye wide open while rinsing.If eye irritation persists, consult a specialist.If swallowed: Clean mouth with water and drink afterwards plenty of water.Do NOT induce vomiting.Do not give milk or alcoholic beverages.Never give anything by mouth to an unconscious person.Obtain medical attention.4.2 Most important symptoms and effects, both acute and delayedSymptoms: Inhalation may provoke the following symptoms:HeadacheVertigoFatigueSkin contact may provoke the following symptoms:RednessIngestion may provoke the following symptoms:Abdominal painVomiting4 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Revision Date: 01.03.2017Diarrhoea4.3 Indication of any immediate medical attention and special treatment neededTreatment: In case of ingestion, the stomach should be emptied by gastriclavage under qualified medical supervision.SECTION 5: Firefighting measures5.1 Extinguishing mediaSuitable extinguishing mediaUnsuitable extinguishingmedia: Alcohol-resistant foamDry chemical: High volume water jet5.2 Special hazards arising from the substance or mixture: Do not use a solid water stream as it may scatter and spreadSpecific hazards during firefightingfire.Hazardous combustion products5.3 Advice for firefightersSpecial protective equipmentfor firefightersFurther information: No hazardous combustion products are known: In the event of fire, wear self-contained breathing apparatus.: Collect contaminated fire extinguishing water separately. Thismust not be discharged into drains.Fire residues and contaminated fire extinguishing water mustbe disposed of in accordance with local regulations.For safety reasons in case of fire, cans should be stored separately in closed containments.SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency proceduresPersonal precautions: Use personal protective equipment.Ensure adequate ventilation.6.2 Environmental precautionsEnvironmental precautions: Try to prevent the material from entering drains or watercourses.If the product contaminates rivers and lakes or drains informrespective authorities.5 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Revision Date: 01.03.20176.3 Methods and material for containment and cleaning upMethods for cleaning up: Soak up with inert absorbent material (e.g. sand, silica gel,acid binder, universal binder, sawdust).Keep in suitable, closed containers for disposal.6.4 Reference to other sectionsFor contact information in case of emergency, see section 1. For information on safe handling, seesection 7. For exposure controls and personal protection measures, see section 8. For subsequentwaste disposal, follow the recommendations in section 13.SECTION 7: Handling and storage7.1 Precautions for safe handlingAdvice on safe handling: Avoid exceeding the given occupational exposure limits (seesection 8).Avoid contact with skin and eyes.For personal protection see section 8.Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease shouldnot be employed in any process in which this mixture is beingused.Smoking, eating and drinking should be prohibited in the application area.Provide sufficient air exchange and/or exhaust in work rooms.Dispose of rinse water in accordance with local and nationalregulations.Advice on protection againstfire and explosion: Avoid formation of aerosol. Keep away from sources of ignition - No smoking. Take measures to prevent the build up ofelectrostatic charge.Hygiene measures: Handle in accordance with good industrial hygiene and safetypractice. When using do not eat or drink. When using do notsmoke. Wash hands before breaks and at the end of workday.7.2 Conditions for safe storage, including any incompatibilitiesRequirements for storage: No smoking. Keep in a well-ventilated place.areas and containersOther data7.3 Specific end use(s)Specific use(s): No decomposition if stored and applied as directed.: For the use of this product do not exist particular recommendations apart from that already indicated.6 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Revision Date: 01.03.2017SECTION 8: Exposure controls/personal protection8.1 Control parametersDerived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:n-butyl acetate: End Use: WorkersExposure routes: InhalationPotential health effects: Long-term systemic effectsValue: 480 mg/m3: End Use: WorkersLow boiling point naphtha unspecifiedExposure routes: InhalationPotential health effects: Long-term systemic effectsValue: 608 mg/m3: End Use: Workers2-methoxy-1-methylethyl acetateExposure routes: InhalationPotential health effects: Long-term systemic effectsValue: 275 mg/m38.2 Exposure controlsPersonal protective equipmentEye protection: Eye wash bottle with pure waterTightly fitting safety gogglesHand protectionRemarks: Solvent-resistant gloves The selected protective gloves haveto satisfy the specifications of EU Directive 89/686/EEC andthe standard EN 374 derived from it. Before removing glovesclean them with soap and water.Skin and body protection: impervious clothingChoose body protection according to the amount and concentration of the dangerous substance at the work place.Respiratory protection: In the case of vapour formation use a respirator with an approved filter.SECTION 9: Physical and chemical properties9.1 Information on basic physical and chemical propertiesAppearance: liquidColour: colourlessOdour: characteristicMelting point/range: Not applicableBoiling point/boiling range: 126.3 C7 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Revision Date: 01.03.2017(7.6 hPa)Flash point: 32 CMethod: ISO 1523, closed cupSetaflashUpper explosion limit: No data availableLower explosion limit: No data availableVapour pressure: 6 hPa (20 C)42 hPa (50 C)DensitySolubility(ies)Water solubilityViscosityViscosity, dynamicViscosity, kinematic: 1.03 g/cm3 (20 C)Method: ISO 2811-1immiscible30 mPa.s (20 C)Method: ISO 2555: 20.5 mm2/s (40 C)9.2 Other informationNo data availableSECTION 10: Stability and reactivity10.1 ReactivityStable under recommended storage conditions.10.2 Chemical stabilityNo decomposition if stored and applied as directed.10.3 Possibility of hazardous reactionsHazardous reactions: No decomposition if used as directed.Vapours may form explosive mixture with air.10.4 Conditions to avoidConditions to avoid: Heat, flames and sparks.8 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.010.5 Incompatible materialsMaterials to avoidMSDS Number: 00050Revision Date: 01.03.2017: Strong acids and oxidizing agents10.6 Hazardous decomposition products: IsocyanatesHazardous decompositionproductsSECTION 11: Toxicological information11.1 Information on toxicological effectsAcute toxicityProduct:Acute inhalation toxicity: Acute toxicity estimate : 10 - 20 mg/lExposure time: 4 hTest atmosphere: vapourMethod: Calculation methodComponents:HDI oligomers, isocyanurate:Acute oral toxicity: LD50 Oral (Rat): 2,000 mg/kgMethod: OECD Test Guideline 401Acute inhalation toxicity: LC50 (Rat): 0.543 mg/lExposure time: 4 hMethod: OECD Test Guideline 403Acute dermal toxicity: LD50 (Rat): 2,000 mg/kgMethod: OECD Test Guideline 402n-butyl acetate:Acute oral toxicity: LD50 Oral (Rat): 10,768 mg/kgMethod: OECD Test Guideline 401Acute inhalation toxicity: LC50 (Rat): 23.4 mg/lExposure time: 4 hMethod: OECD Test Guideline 403Acute dermal toxicity: LD50 (Rabbit): 17,600 mg/kgMethod: OECD Test Guideline 402Solvent naphtha (petroleum), light arom.:Acute oral toxicity: LD50 Oral (Rat): 3,592 mg/kgMethod: OECD Test Guideline 401Acute inhalation toxicity: LC50 (Rat): 20 mg/lExposure time: 4 h9 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Acute dermal toxicityRevision Date: 01.03.2017: LD50 (Rabbit): 3,160 mg/kgMethod: OECD Test Guideline 4022-methoxy-1-methylethyl acetate:Acute oral toxicity: LD50 Oral (Rat): 8,532 mg/kgMethod: OECD Test Guideline 401Acute inhalation toxicity: LC50 (Rat): 35.7 mg/lExposure time: 4 hMethod: OECD Test Guideline 403Acute dermal toxicity: LD50 (Rat): 5,000 mg/kgMethod: OECD Test Guideline 402Skin corrosion/irritationProduct:Result: Skin irritationSerious eye damage/eye irritationProduct:Remarks: Based on available data, the classification criteria are not met.Respiratory or skin sensitisationProduct:Remarks: Causes sensitisation.Germ cell mutagenicityProduct:Germ cell mutagenicity- AssessmentBased on available data, the classification criteria are not met.CarcinogenicityProduct:Carcinogenicity - AssessmentBased on available data, the classification criteria are not met.Reproductive toxicityProduct:Reproductive toxicity - AssessmentBased on available data, the classification criteria are not met.10 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Revision Date: 01.03.2017STOT - single exposureProduct:Assessment: The substance or mixture is classified as specific target organ toxicant, single exposure, category 3 with respiratory tract irritation., The substance or mixture is classified as specific target organ toxicant, single exposure, category 3 with narcotic effects.STOT - repeated exposureProduct:Remarks: Based on available data, the classification criteria are not met.Aspiration toxicityProduct:Based on available data, the classification criteria are not met.Further informationProduct:Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting., Concentrations substantially above the TLV value may cause narcotic effects., Solventsmay degrease the skin.SECTION 12: Ecological information12.1 ToxicityComponents:HDI oligomers, isocyanurate:Toxicity to algae: EC50 (Algae): 370 mg/lExposure time: 72 hMethod: OECD Test Guideline 201n-butyl acetate:Toxicity to fish: LC50 (Fish): 18 mg/lExposure time: 96 hMethod: OECD Test Guideline 203Toxicity to daphnia and otheraquatic invertebrates: EC50 (Daphnia (water flea)): 32 mg/lExposure time: 48 hMethod: OECD Test Guideline 202Toxicity to algae: EC50 (Algae): 675 mg/lExposure time: 72 hMethod: OECD Test Guideline 201Solvent naphtha (petroleum), light arom.:Toxicity to fish: LC50 (Fish): 9.2 mg/l11 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Revision Date: 01.03.2017Exposure time: 96 hMethod: OECD Test Guideline 203Toxicity to daphnia and otheraquatic invertebrates: EC50 (Daphnia (water flea)): 3.2 mg/lExposure time: 48 hMethod: OECD Test Guideline 202Toxicity to algae: EC50 (Algae): 2.9 mg/lExposure time: 72 hMethod: OECD Test Guideline 2012-methoxy-1-methylethyl acetate:Toxicity to fish: LC50 (Fish): 100 mg/lExposure time: 96 hMethod: OECD Test Guideline 203Toxicity to daphnia and otheraquatic invertebrates: EC50 (Daphnia (water flea)): 408 mg/lExposure time: 48 hMethod: OECD Test Guideline 202Toxicity to algae: EC50 (Algae): 1,000 mg/lExposure time: 72 hMethod: OECD Test Guideline 20112.2 Persistence and degradabilityNo data available12.3 Bioaccumulative potentialNo data available12.4 Mobility in soilNo data available12.5 Results of PBT and vPvB assessmentProduct:AssessmentThis substance/mixture contains no components consideredto be either persistent, bioaccumulative and toxic (PBT), orvery persistent and very bioaccumulative (vPvB) at levels of0.1% or higher.12.6 Other adverse effectsProduct:Additional ecological informationAn environmental hazard cannot be excluded in the event ofunprofessional handling or disposal., Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.12 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Revision Date: 01.03.2017SECTION 13: Disposal considerations13.1 Waste treatment methodsProductContaminated packaging: The product should not be allowed to enter drains, watercourses or the soil.Do not contaminate ponds, waterways or ditches with chemical or used container.Offer surplus and non-recyclable solutions to a licensed disposal company.: Empty remaining contents.Dispose of as unused product.Do not re-use empty containers.Do not burn, or use a cutting torch on, the empty drum.SECTION 14: Transport information14.1 UN numberADR: UN 1263IMDG: UN 1263IATA: UN 126314.2 UN proper shipping nameADR: PAINT RELATED MATERIALIMDG: PAINT RELATED MATERIALIATA: Paint related material14.3 Transport hazard class(es)ADR: 3IMDG: 3IATA: 314.4 Packing groupADRPacking groupClassification CodeHazard Identification NumberLabels::::IMDGPacking groupLabelsEmS Code: III: 3: F-E, S-EIIIF1303IATA13 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Packing instruction (cargoaircraft)Packing instruction (LQ)Packing groupLabelsRevision Date: 01.03.2017: 366: Y344: III: Flammable Liquids14.5 Environmental hazardsADREnvironmentally hazardous: noIMDGMarine pollutant: no14.6 Special precautions for userNot applicable14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable for product as supplied.SECTION 15: Regulatory information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture15.2 Chemical Safety AssessmentNot applicableSECTION 16: Other informationFull text of ful by inhalation.Irritating to respiratory system.May cause sensitisation by skin contact.Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.Harmful: may cause lung damage if swallowed.Repeated exposure may cause skin dryness or cracking.Vapours may cause drowsiness and dizziness.Full text of H-StatementsH226H304H317H332H335H336H411Flammable liquid and vapour.May be fatal if swallowed and enters airways.May cause an allergic skin reaction.Harmful if inhaled.May cause respiratory irritation.May cause drowsiness or dizziness.Toxic to aquatic life with long lasting effects.Further information14 / 15
Material Safety Data SheetKEMACRYL HARDENER 2k Acrylic paint hardenerVersion 1.0MSDS Number: 00050Revision Date: 01.03.2017The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not tobe considered a warranty or quality specification. The information relates only to the specific mater
Version 1.0 MSDS Number: 00050 Revision Date: 01.03.2017 2 / 15 Material Safety Data Sheet KEMACRYL HARDENER 2k Acrylic paint hardener Skin sensitisation, Category 1 H317: May cause an allergic skin reaction. Chronic aquatic toxicity, Category 3 H412: Harmful to aquatic life with long lasting ef- fects. Classification (67/548/EEC, 1999/45/EC)
Report on the Inaugural CMB Analysis Summer School . The future of CMB cosmology is one in which maps of the microwave sky can be cross-correlated with mea-surements at other wavelengths (including large-scale optical surveys) to constrain a host of cosmological and astrophysical . the participants were
bulk. Thus KA-B suggested measuring the dipole component of δ ν(y). Below we use the notation for C 1,kin normalized so that a coherent motion at velocity V bulk wouldleadto C 1,kin T 2 CMB τ 2V2 bulk /c 2,whereT CMB 2.725K is the present-day CMB temperature. For reference, C 1,kin 1(τ /10 3)(V bulk/100km/sec) µK. When computed from .
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MATERIAL SAFETY DATA SHEET _ Product Name Pool Season Chlorinating Concentrate Product id EPA Reg. No. 69470-20-71141 _ Supersedes 14/12/2000 Revision date 28/07/2003 Revision: 2 16. Other information This data sheet contains changes from the previous version in section(s) 3, 15 The information in this Material Safety Data Sheet should .
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di erent engineering associations such as the mechanical engineers, the civil engineers, and the electronic engineers. But these definitions have a common core. There’s a fairly common simple definition, which a lot of the more complicated definitions are variations on. On this definition, engineering is the process of utilizing knowledge and principles to design, build, and analyze .
