Electron Configuration (Section 5.2)

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Electron Configuration(Section 5.2)Dr. Walker

Objectives To determine the electron configuration of anyof the first 38 elements of the periodic table To determine the identity of an element fromits electron configuration To complete an orbital diagram using arrowsto represent electrons

Where are Electrons? Electrons exist in different energy levels(previously described as “shells”) The energy levels correspond to the horizontalrows on the periodic table

Where are Electrons? Orbitals are areas within shells where the electrons arelocated– These orbitals may have different shapes– There may be different numbers of orbitals within a shell We know the electron is somewhere in the orbital, butwe can’t know exactly where it is or how fast it ismoving– Heisenberg’s Uncertainty Principle Each orbital can hold two electrons (Pauli ExclusionPrinciple)

Learning Check What are orbitals? Where are orbitals? How many electrons reside in each orbital?

Learning Check What are orbitals? A place where electronscan be found Where are orbitals? Outside the nucleus How many electrons reside in each orbital? 2

Types of Orbitals (subshells) S orbitals – 1 orbital per shell – holds electronstotal P orbitals – 3 orbitals per shell – holds electronstotal D orbitals – 5 orbitals per shell – holds electronstotal F orbitals – 7 orbitals per shell – holds electronstotal

Types of Orbitals (subshells) S orbitals – 1 orbital per shell – holds 2 electrons total P orbitals – 3 orbitals per shell – holds 6 electrons total D orbitals – 5 orbitals per shell – holds 10 electronstotal F orbitals – 7 orbitals per shell – holds 14 electronstotal

Electron Configuration Defined– Electron configuration is the arrangement ofelectrons around the nucleus of an atom based ontheir energy level.

Actual Electron Configurations Total electrons atomic number Electrons are added one at a time to thelowest energy levels first (Aufbau principle) Fill energy levels with electrons until you runout A superscript states how many electrons are ineach level

Order of Orbitals Low Energy to High Energy (# of electrons)–––––––––––1s (2)2s (2)2p (6)3s (2)3p (6)4s (2)3d (10)4 p (6)5s (2)Continues for the whole periodic tableYou’re expected to know through here

Making Sense of the Order

Another option Draw the orbitals in this format, use diagonallines to determine order of orbitals to fill

Actual Electron Configurations Total electrons atomic number Fill energy levels with electrons until you runout A superscript states how many electrons are ineach level– Hydrogen – 1s1 – 1 electron total– Helium – 1s2 – 2 electrons total– Lithium – 1s22s1 – 3 electrons total– Beryllium – 1s22s2 – 4 electrons total

Write allActual Electron Configurations Bigger Elements– Fill the energy levels until you run out of electrons– Oxygen– Sodium– Titanium

Actual Electron Configurations Bigger Elements– Fill the energy levels until you run out of electrons– Oxygen 1s22s22p4– Sodium 1s22s22p63s1– Titanium 1s22s22p63s23p64s23d2

Practice Potassium

Practice Potassium– Atomic Number 19– 1s22s22p63s23p64s1– Superscripts add up to atomic number

The orbitals and the periodic tableThe s suborbitalfills

The orbitals and the periodic tableThe psuborbitals fill

The orbitals and the periodic tableThe dsuborbitals fill

Shorthand Shorter form of electron configuration [Ne] 1s22s22p6 [Ar] 1s22s22p63s23p6 Potassium– Atomic Number 19– 1s22s22p63s23p64s1– [Ar]4s1

Pauli Exclusion Principle Two electrons in same orbital have differentspins

Orbital Diagrams-Each electron is an arrow-They have opposing “spins” – think of two bar magnets together-Orbital diagrams are visual representations of electron configuration

Hund’s Rule When electrons are filling orbitals of the sameenergy, they prefer to enter empty orbitalsfirst. These electrons all have the same spin A diagram of nitrogen is shown below (7 totalelectrons)

Benchmark Alert!!Hund’s Rule The orbital diagram below violates Hund’s rulebecause the third electron does not enter theempty 2p orbitalBenchmark Alert!!!

Terms to Know & Skills to Master Terms––––OrbitalsHund’s RuleAufbau principlePauli Exclusion principle Skills– Determining electron configuration from number ofelectrons– Determining the identity of an element from its electronconfiguration– Completing orbital diagrams using arrows to representelectrons

To determine the electron configuration of any of the first 38 elements of the periodic table To determine the identity of an element from its electron configuration To complete an orbital diagram using arrows to represent electrons . . rows on the periodic table .File Size: 863KBPage Count: 31Explore furtherElectron Configuration Chart for All Elements in the .sciencestruck.comElectron configuration of every element in the periodic tablewww.biochemhelp.comElectron Configuration Chart - ThoughtCowww.thoughtco.comList of Electron Configurations of Elementssciencenotes.orgElectron Configuration - Detailed Explanation with Examplesbyjus.comRecommended to you based on what's popular Feedback

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