Dunlop Wall & Floor Tile Adhesive

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Dunlop Wall & Floor Tile AdhesiveHazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 25-Jan-2013A317LPCHEMWATCH 4639-16Version No:4.1.1.1Page 1 of 15Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAMEDunlop Wall & Floor Tile AdhesiveSYNONYMS"cement based ceramic tile adhesive"PRODUCT USE Material is mixed and used in accordance with manufacturers directions.Used to fix ceramic tiles over walls, timber floors and other floor surfaces.SUPPLIERCompany: Ardex Australia Pty LtdAddress:20 Powers RoadSeven HillsNSW, 2147AustraliaTelephone: 1800 224 070Emergency Tel:1800 222 841Fax: 61 2 9838 7817Section 2 - HAZARDS IDENTIFICATIONSTATEMENT OF HAZARDOUS NATUREHAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADGCode.CHEMWATCH HAZARD RATINGSFlammabilityToxicityBody ContactReactivityChronicSCALE:RISK Causes burns.Min/Nil 0Low 1Moderate 2High 3Extreme 4SAFETY Keep locked up.continued.

Dunlop Wall & Floor Tile AdhesiveHazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 25-Jan-2013A317LP Risk of serious damage toeyes. Inhalation may produce healthdamage*. Cumulative effects may resultfollowing exposure*. Limited evidence of acarcinogenic effect*. Possible respiratory and skinsensitiser*.* (limited evidence).CHEMWATCH 4639-16Version No:4.1.1.1Page 2 of 15Section 2 - HAZARDS IDENTIFICATION Do not breathe dust. Avoid contact with skin. Avoid contact with eyes. Wear suitable protective clothing. Wear suitable gloves. Wear eye/face protection. Use only in well ventilated areas. Keep container in a well ventilated place. To clean the floor and all objects contaminated by thismaterial, use water and detergent. Take off immediately all contaminated clothing. In case of contact with eyes, rinse with plenty of water andcontact Doctor or Poisons Information Centre. In case of accident or if you feel unwell IMMEDIATELY contactDoctor or Poisons Information Centre (show label if possible). In case of accident by inhalation: remove casualty to freshair and keep at rest.Section 3 - COMPOSITION / INFORMATION ON INGREDIENTSNAMEportland cementrubber powdergraded sandCAS RN65997-15-1Not avail.14808-60-7.%10-4010-3010-40Section 4 - FIRST AID MEASURESSWALLOWED For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) tomaintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becomingunconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.EYE If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids byoccasionally lifting the upper and lower lids.continued.

Dunlop Wall & Floor Tile AdhesiveHazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 25-Jan-2013A317LPCHEMWATCH 4639-16Version No:4.1.1.1Page 3 of 15Section 4 - FIRST AID MEASURES Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.SKIN If skin or hair contact occurs: Immediately flush body and clothes with large amounts of water, using safety shower if available. Quickly remove all contaminated clothing, including footwear. Wash skin and hair with running water. Continue flushing with water until advised to stop by the PoisonsInformation Centre. Transport to hospital, or doctor.INHALED If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior toinitiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve maskdevice, or pocket mask as trained. Perform CPR if necessary. Transport to hospital, or doctor.NOTES TO PHYSICIANTreat symptomatically.For acute or short-term repeated exposures to highly alkaline materials: Respiratory stress is uncommon but present occasionally because of soft tissue edema. Unless endotracheal intubation can be accomplished under direct vision, cricothyroidotomy or tracheotomymay be necessary. Oxygen is given as indicated. The presence of shock suggests perforation and mandates an intravenous line and fluid administration. Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the saponification of fats andsolubilisation of proteins allow deep penetration into the tissue.Alkalis continue to cause damage after exposure.INGESTION: Milk and water are the preferred diluentsNo more than 2 glasses of water should be given to an adult. Neutralising agents should never be given since exothermic heat reaction may compound injury.* Catharsis and emesis are absolutely contra-indicated.* Activated charcoal does not absorb alkali.* Gastric lavage should not be used.Supportive care involves the following: Withhold oral feedings initially. If endoscopy confirms transmucosal injury start steroids only within the first 48 hours. Carefully evaluate the amount of tissue necrosis before assessing the need for surgical intervention. Patients should be instructed to seek medical attention whenever they develop difficulty in swallowing(dysphagia).SKIN AND EYE: Injury should be irrigated for 20-30 minutes.Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology].continued.

Dunlop Wall & Floor Tile AdhesiveHazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 25-Jan-2013A317LPCHEMWATCH 4639-16Version No:4.1.1.1Page 4 of 15Section 5 - FIRE FIGHTING MEASURESEXTINGUISHING MEDIA There is no restriction on the type of extinguisher which may be used. Use extinguishing media suitable for surrounding area.FIRE FIGHTING Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves in the event of a fire. Prevent, by any means available, spillage from entering drains or water courses. Use fire fighting procedures suitable for surrounding area. DO NOT approach containers suspected to be hot. Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. Equipment should be thoroughly decontaminated after use.FIRE/EXPLOSION HAZARD Solid which exhibits difficult combustion or is difficult to ignite. Avoid generating dust, particularly clouds of dust in a confined or unventilated space as dusts may form anexplosive mixture with air, and any source of ignition, i.e. flame or spark, will cause fire or explosion. Dust clouds generated by the fine grinding of the solid are a particular hazard; accumulations of fine dust(420 micron or less) may burn rapidly and fiercely if ignited; once initiated larger particles up to 1400microns diameter will contribute to the propagation of an explosion. A dust explosion may release of large quantities of gaseous products; this in turn creates a subsequentpressure rise of explosive force capable of damaging plant and buildings and injuring people. Usually the initial or primary explosion takes place in a confined space such as plant or machinery, andcan be of sufficient force to damage or rupture the plant. If the shock wave from the primary explosionenters the surrounding area, it will disturb any settled dust layers, forming a second dust cloud, andoften initiate a much larger secondary explosion. All large scale explosions have resulted from chainreactions of this type. Dry dust can also be charged electrostatically by turbulence, pneumatic transport, pouring, in exhaustducts and during transport. Build-up of electrostatic charge may be prevented by bonding and grounding. Powder handling equipment such as dust collectors, dryers and mills may require additional protectionmeasures such as explosion venting. All movable parts coming in contact with this material should have a speed of less than 1-metre/sec.Decomposition may produce toxic fumes of: carbon dioxide (CO2), aldehydes, metal oxides, other pyrolysisproducts typical of burning organic material.May emit poisonous fumes.May emit corrosive fumes.FIRE INCOMPATIBILITY Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorineetc. as ignition may result.HAZCHEMNonecontinued.

Dunlop Wall & Floor Tile AdhesiveHazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 25-Jan-2013A317LPCHEMWATCH 4639-16Version No:4.1.1.1Page 5 of 15Section 6 - ACCIDENTAL RELEASE MEASURESMINOR SPILLS Remove all ignition sources. Clean up all spills immediately. Avoid contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Use dry clean up procedures and avoid generating dust. Place in a suitable, labelled container for waste disposal.MAJOR SPILLSModerate hazard. CAUTION: Advise personnel in area. Alert Emergency Services and tell them location and nature of hazard. Control personal contact by wearing protective clothing. Prevent, by any means available, spillage from entering drains or water courses. Recover product wherever possible. IF DRY: Use dry clean up procedures and avoid generating dust. Collect residues and place in sealed plasticbags or other containers for disposal. IF WET: Vacuum/shovel up and place in labelled containers fordisposal. ALWAYS: Wash area down with large amounts of water and prevent runoff into drains. If contamination of drains or waterways occurs, advise Emergency Services.Personal Protective Equipment advice is contained in Section 8 of the MSDS.Section 7 - HANDLING AND STORAGEPROCEDURE FOR HANDLING Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. DO NOT allow material to contact humans, exposed food or food utensils. Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers securely sealed when not in use. Avoid physical damage to containers. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Launder contaminated clothing before re-use. Use good occupational work practice. Observe manufacturer's storage and handling recommendations contained within this MSDS. Atmosphere should be regularly checked against established exposure standards to ensure safe workingconditions are maintained.SUITABLE CONTAINER Polyethylene or polypropylene container. Check all containers are clearly labelled and free from leaks.continued.

Dunlop Wall & Floor Tile AdhesiveHazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 25-Jan-2013A317LPCHEMWATCH 4639-16Version No:4.1.1.1Page 6 of 15Section 7 - HANDLING AND STORAGESTORAGE INCOMPATIBILITY Avoid reaction with oxidising agents.STORAGE REQUIREMENTS Store in original containers. Keep containers securely sealed. Store in a cool, dry area protected from environmental extremes. Store away from incompatible materials and foodstuff containers. Protect containers against physical damage and check regularly for leaks. Observe manufacturer's storage and handling recommendations contained within this MSDS.For major quantities: Consider storage in bunded areas - ensure storage areas are isolated from sources of community water(including stormwater, ground water, lakes and streams}. Ensure that accidental discharge to air or water is the subject of a contingency disaster management plan;this may require consultation with local authorities.SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS X : May be stored togetherO: May be stored together with specific preventionsX: Must not be stored togetherSection 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE rtland cement(Portland cement(a))TWATWASTELSTELPeakPeakTWANotesppmmg/m³ ppmmg/m³ ppmmg/m³ F/CC10(see Chapter 14)The following materials had no OELs on our records graded sand:EMERGENCY EXPOSURE LIMITSMaterialRevised IDLH Value (mg/m3)portland cement 137635,000graded sand 8501450CAS:14808- 60- 7Revised IDLH Value (ppm)MATERIAL DATAGRADED SAND:RUBBER POWDER:These "dusts" have little adverse effect on the lungs and do not produce toxic effects or organic disease.Although there is no dust which does not evoke some cellular response at sufficiently high concentrations,continued.

Dunlop Wall & Floor Tile AdhesiveHazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 25-Jan-2013A317LPCHEMWATCH 4639-16Version No:4.1.1.1Page 7 of 15Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONthe cellular response caused by P.N.O.C.s has the following characteristics: the architecture of the air spaces remain intact, scar tissue (collagen) is not synthesised to any degree, tissue reaction is potentially reversible.Extensive concentrations of P.N.O.C.s may: seriously reduce visibility cause unpleasant deposits in the eyes, ears and nasal passages, contribute to skin or mucous membrane injury by chemical or mechanical action, per se, or by therigorous skin cleansing procedures necessary for their removal. [ACGIH]This limit does not apply: to brief exposures to higher concentrations nor does it apply to those substances that may cause physiological impairment at lower concentrationsbut for which a TLV has as yet to be determined.This exposure standard applies to particles which are insoluble or poorly soluble* in water or, preferably, in aqueous lung fluid (if data is available)and have a low toxicity (i.e. are not cytotoxic, genotoxic, or otherwise chemically reactive with lungtissue, and do not emit ionizing radiation, cause immune sensitization, or cause toxic effects other than byinflammation or by a mechanism of lung overload).DUNLOP WALL & FLOOR TILE ADHESIVE:None assigned. Refer to individual constituents.PORTLAND CEMENT:for calcium silicate:containing no asbestos and 1% crystalline silicaES TWA: 10 mg/m3 inspirable dustTLV TWA: 10 mg/m3 total dust (synthetic nonfibrous) A4Although in vitro studies indicate that calcium silicate is more toxic than substances described as"nuisance dusts" is thought that adverse health effects which might occur following exposure to 10-20 mg/m3are likely to be minimal. The TLV-TWA is thought to be protective against the physical risk of eye and upperrespiratory tract irritation in workers and to prevent interference with vision and deposition of particulatein the eyes, ears, nose and mouth.NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as causing Cancer in humans.For calcium oxide:The TLV-TWA is thought to be protective against undue irritation and is analogous to that recommended forsodium hydroxide.For aluminium oxide:The experimental and clinical data indicate that aluminium oxide acts as an "inert" material when inhaledand seems to have little effect on the lungs nor does it produce significant organic disease or toxic effectswhen exposures are kept under reasonable control.[Documentation of the Threshold Limit Values], ACGIH, Sixth Edition.The concentration of dust, for application of respirable dust limits, is to be determined from thefraction that penetrates a separator whose size collection efficiency is described by a cumulative log-normalfunction with a median aerodynamic diameter of 4.0 µm ( -) 0.3 µm and with a geometric standard deviation of1.5 µm ( -) 0.1 µm, i.e.generally less than 5 µm.for chrome(VI) containing substances:Some jurisdictions require that health surveillance be carried on workers occupationally exposed toinorganic chromium. Such surveillance should emphasise demography, occupational and medical history and health advice physical examination with emphasis on the respiratory system and skin weekly skin inspection of hands and forearms by a "responsible person".Portland cement is considered to be a nuisance dust that does not cause fibrosis and has little potentialto induce adverse effects on the lung.continued.

Dunlop Wall & Floor Tile AdhesiveHazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 25-Jan-2013A317LPCHEMWATCH 4639-16Version No:4.1.1.1Page 8 of 15Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTIONRUBBER POWDER:TLV TWA: 0.001 mg/m3 (as total proteins) Inhalable fraction skin sensitiseras rubber processing fume:MEL-TWA: 0.6 mg/m3 as cyclohexane solubles [HSE, UK]BRMA-TWA: 0.25 mg/m3 as cyclohexane solubles [BRMA Code of Practice]Rubber fume is a complex and indeterminate mixture of substances and is defined as "fume evolved in themixing, milling and blending of natural rubber and synthetic polymers combined with chemicals, and in theprocesses which convert the resultant blend into finished products or parts thereof, and including anyinspection procedures where fume continues to be evolved"."Fume" generally describes solid particles generated by chemical reactions, or by condensation from thegaseous state, usually after volatilisation from melted substances, and often accompanied by a chemicalreaction such as oxidation or thermal breakdown.Several chemical agents may occur in rubber fume which are experimental or animal carcinogens, however,given the number of chemicals used or formed during rubber making, difficulties arise in attributing aparticular effect to a given exposure.Stomach cancer has been associated with work in jobs early in the production line; lung and loweroesophagus cancer with all work processes; and lymphomas with jobs where co-exposure to solvents occurs.Other cancers have also been reported with liver tumours appearing as a secondary phenomenon. No no-effectlevels have been determined.Two studies showed no excess of bladder cancer in workers entering the industry after 1950: the excessrisk before that date is thought to result from exposure to residual beta-naphthylamines previously used asanti-oxidants.as rubber process dust:MEL-TWA: 6 mg/m3 [HSE, UK]Rubber process dust is a complex, variable mixture of particulates defined as "dust arising in the stagesof rubber manufacture where ingredients are handled, weighed, added to or mixed with natural or syntheticelastomers. It does not include dusts arising from the abrasion of cured rubber but occurs during thepreparation of compounds of either synthetic or natural rubber.There is some evidence that occupational exposure to rubber dusts produces an excess incidence of stomachcancer. HSE data concluded that there was a small but significant excess of stomach cancer associated withthe initial processes in rubber manufacture. Stomach cancer shows a marked social class gradient, which maylead to an over-estimation of the risk.One report from the USA stated that exposure in rubber processing areas produces pulmonary disease butthis has not been supported by UK epidemiology nor reports from the industry.No no-effect level has been determined. The MEL was considered appropriate because it was felt reasonablypractical for industry to comply with this value.GRADED SAND:NOTE: This product contains negligible amount of respirable dust.PERSONAL PROTECTIONcontinued.

Dunlop Wall & Floor Tile AdhesiveHazard Alert Code: HIGHChemwatch Material Safety Data SheetIssue Date: 25-Jan-20

Dunlop Wall & Floor Tile Adhesive Hazard Alert Code: HIGH Chemwatch Material Safety Data Sheet Issue Date: 25-Jan-2013 CHEMWATCH 4639-16 A317LP Version No:4.1.1.1 Page 3 of 15 Section 4 - FIRST AID MEASURES Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.

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and more importantly out of the tank while the pump is running. This constant flushing ensures that the water in the tank remains fresh and eliminates the risk of stagnant water during normal system operation. See fig 2. GT-C, composite tank The GT-C pressure tank is a lightweight pressure tank. The diaphragm is a chlorine-resistant 100 % butyl