SAFETY DATA SHEET DUNLOP CF-03 FLEXIBLE FAST SET ADHESIVE GREY

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Revision date: 22/01/2020SAFETY DATA SHEETDUNLOP CF-03 FLEXIBLE FAST SET ADHESIVE GREYSECTION 1: Identification of the substance/mixture and of the company/undertaking1.1. Product identifierProduct nameDUNLOP CF-03 FLEXIBLE FAST SET ADHESIVE GREY1.2. Relevant identified uses of the substance or mixture and uses advised againstIdentified usesCement based adhesive.Uses advised againstNo specific uses advised against are identified.1.3. Details of the supplier of the safety data sheetSupplierBUILDING ADHESIVES LTDLongton Road,Trentham,Stoke-on-TrentST4 8JB01782 591100Contact personsdsreply@building-adhesives.com1.4. Emergency telephone numberEmergency telephone01865 407 333 (24hr)SECTION 2: Hazards identification2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazardsNot ClassifiedHealth hazardsSkin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1 - H317 STOT SE 3 - H335Environmental hazardsNot ClassifiedHuman healthWhen the cement based powder is mixed with water or admixture, a strongly alkaline paste isproduced. Cement based products may, until set, cause both irritant and allergic contactdermatitis. Irritrant contact dermatitis is due to a combination of the wetness, alkalinity andabrasiveness of the constituent materials. Allergic contact dermatitis is caused mainly by thesensitivity of the individual's skin to hexavalent chromium salts. Corrosive. Prolonged contactcauses serious eye and tissue damage.EnvironmentalThe product is not expected to be hazardous to the environment.2.2. Label elementsHazard pictogramsSignal wordDanger1/8

Revision date: 22/01/2020DUNLOP CF-03 FLEXIBLE FAST SET ADHESIVE GREYHazard statementsH315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H335 May cause respiratory irritation.Precautionary statementsP102 Keep out of reach of children.P261 Avoid breathing dust.P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.P305 P351 P338 IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.P501 Dispose of contents/ container in accordance with local regulations.ContainsORDINARY PORTLAND CEMENT, CALCIUM SULFOALUMINATE CEMENT2.3. Other hazardsThis product does not contain any substances classified as PBT or vPvB.SECTION 3: Composition/information on ingredients3.2. MixturesORDINARY PORTLAND CEMENTCAS number: 65997-15-110-30%EC number: 266-043-4ClassificationSkin Irrit. 2 - H315Eye Dam. 1 - H318Skin Sens. 1 - H317STOT SE 3 - H335CALCIUM SULFOALUMINATE CEMENT1-5%CAS number: 12004-14-7ClassificationSkin Irrit. 2 - H315Eye Dam. 1 - H318Skin Sens. 1 - H317STOT SE 3 - H335The full text for all hazard statements is displayed in Section 16.Composition commentsThis product contains a reducing agent to ensure that the CrVI content of the cement in theproduct remains below 2ppm during the defined shelf life of the product.SECTION 4: First aid measures4.1. Description of first aid measuresGeneral informationGet medical attention if any discomfort continues.InhalationMove affected person to fresh air at once. Rinse nose and mouth with water. Get medicalattention if any discomfort continues.IngestionNever give anything by mouth to an unconscious person. Do not induce vomiting. Rinsemouth thoroughly with water. Get medical attention immediately.Skin contactRemove affected person from source of contamination. Remove contaminated clothing. Washskin thoroughly with soap and water. Get medical attention if irritation persists after washing.2/8

Revision date: 22/01/2020DUNLOP CF-03 FLEXIBLE FAST SET ADHESIVE GREYEye contactRemove affected person from source of contamination. Do not rub eye. Remove any contactlenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medicalattention immediately. Continue to rinse.4.2. Most important symptoms and effects, both acute and delayedInhalationFrequent inhalation of dust over a long period of time increases the risk of developing lungdiseases.IngestionMay cause chemical burns in mouth and throat.Skin contactMay cause serious chemical burns to the skin.Eye contactMay cause severe eye irritation. May cause blurred vision and serious eye damage.4.3. Indication of any immediate medical attention and special treatment neededNotes for the doctorNo specific recommendations. If in doubt, get medical attention promptly.SECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing mediaThe product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.5.2. Special hazards arising from the substance or mixtureSpecific hazardsProtection against nuisance dust must be used when the airborne concentration exceeds 10mg/m3. Oxides of carbon. Oxides of nitrogen. No unusual fire or explosion hazards noted.Hazardous combustionproductsFire creates: Carbon monoxide (CO). Carbon dioxide (CO2).5.3. Advice for firefightersProtective actions duringfirefightingNo specific firefighting precautions known. Avoid breathing fire gases or vapours.Special protective equipmentfor firefightersWear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protectiveclothing.SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresPersonal precautionsWear protective clothing as described in Section 8 of this safety data sheet.6.2. Environmental precautionsEnvironmental precautionsDo not discharge into drains or watercourses or onto the ground.6.3. Methods and material for containment and cleaning upMethods for cleaning upAvoid contact with skin or inhalation of spillage, dust or vapour. Dampen spillage with water.Absorb in vermiculite, dry sand or earth and place into containers. Avoid the spillage or runoffentering drains, sewers or watercourses. Collect and place in suitable waste disposalcontainers and seal securely. Label the containers containing waste and contaminatedmaterials and remove from the area as soon as possible. Flush contaminated area with plentyof water.6.4. Reference to other sectionsReference to other sectionsWear protective clothing as described in Section 8 of this safety data sheet. See Section 11for additional information on health hazards. For waste disposal, see section 13.SECTION 7: Handling and storage7.1. Precautions for safe handling3/8

Revision date: 22/01/2020DUNLOP CF-03 FLEXIBLE FAST SET ADHESIVE GREYUsage precautionsAvoid spilling. Avoid contact with skin and eyes. Provide adequate ventilation. Avoid handlingwhich leads to dust formation.7.2. Conditions for safe storage, including any incompatibilitiesStorage precautionsStore in tightly-closed, original container in a dry, cool and well-ventilated place. Keep only inthe original container.7.3. Specific end use(s)Specific end use(s)The identified uses for this product are detailed in Section 1.2.SECTION 8: Exposure controls/Personal protection8.1. Control parametersOccupational exposure limitsORDINARY PORTLAND CEMENTLong-term exposure limit (8-hour TWA): WEL 10 mg/m³ inhalable dustLong-term exposure limit (8-hour TWA): WEL 4 mg/m³ respirable dustCALCIUM SULFOALUMINATE CEMENTLong-term exposure limit (8-hour TWA): WEL 10 mg/m³ inhalable dustLong-term exposure limit (8-hour TWA): WEL 4 mg/m³ respirable dustWEL Workplace Exposure LimitIngredient commentsWEL Workplace Exposure LimitsLITHIUM CARBONATE (CAS: 554-13-2)DNEL- Inhalation; Long term systemic effects: 10 mg/m³- Dermal; Long term systemic effects: 64 mg/kg/dayPNEC- Fresh water; Intermittent release 0.9 mg/l8.2. Exposure controlsProtective equipmentAppropriate engineeringcontrolsProvide adequate ventilation. Avoid inhalation of vapours. Observe any occupationalexposure limits for the product or ingredients.Eye/face protectionWear chemical splash goggles. Personal protective equipment for eye and face protectionshould comply with European Standard EN166.Hand protectionGloves made from the following material may provide suitable chemical protection: Nitrilerubber. The selected gloves should have a breakthrough time of at least 8 hours. The mostsuitable glove should be chosen in consultation with the glove supplier/manufacturer, who canprovide information about the breakthrough time of the glove material.Other skin and bodyprotectionWear appropriate clothing to prevent any possibility of skin contact.Hygiene measuresProvide eyewash station. Do not smoke in work area. Wash at the end of each work shift andbefore eating, smoking and using the toilet. Promptly remove any clothing that becomescontaminated. Do not eat, drink or smoke when using this product.Respiratory protectionIf ventilation is inadequate, suitable respiratory protection must be worn. Use respiratoryequipment with particle filter type P24/8

Revision date: 22/01/2020DUNLOP CF-03 FLEXIBLE FAST SET ADHESIVE GREYThermal hazardsNot applicable.Environmental exposurecontrolsAvoid release to the environment.SECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesAppearanceDusty powder.ColourGrey.OdourOdourless.pHpH (concentrated solution): pH12-13 after mixingMelting pointNot applicable.Initial boiling point and rangeNot applicable.Solubility(ies)Slightly soluble in water.9.2. Other informationOther informationNo information required.SECTION 10: Stability and reactivity10.1. ReactivityReactivityThere are no known reactivity hazards associated with this product.10.2. Chemical stabilityStabilityStable at normal ambient temperatures.10.3. Possibility of hazardous reactionsPossibility of hazardousreactionsNot determined.10.4. Conditions to avoidConditions to avoidAvoid contact with acids. Water, moisture.10.5. Incompatible materialsMaterials to avoidAcids - oxidising.10.6. Hazardous decomposition productsHazardous decompositionproductsFire creates: Carbon monoxide (CO). Carbon dioxide (CO2).SECTION 11: Toxicological information11.1. Information on toxicological effectsSkin corrosion/irritationSkin corrosion/irritationSevere skin irritation.Extreme pH 11.5Serious eye damage/irritationSerious eye damage/irritationSeverely irritating to skin. Irritation of eyes is assumed. No testing is needed.Respiratory sensitisationRespiratory sensitisationNot known.5/8

Revision date: 22/01/2020DUNLOP CF-03 FLEXIBLE FAST SET ADHESIVE GREYSkin sensitisationSkin sensitisationMay cause sensitisation or allergic reactions in sensitive individuals.Germ cell mutagenicityGenotoxicity - in vitroBased on available data the classification criteria are not met.Genotoxicity - in vivoBased on available data the classification criteria are not met.CarcinogenicityCarcinogenicityThere is no evidence that the product can cause cancer.Reproductive toxicityReproductive toxicity - fertilityBased on available data the classification criteria are not met.Specific target organ toxicity - single exposureSTOT - single exposureBased on available data the classification criteria are not met.Specific target organ toxicity - repeated exposureSTOT - repeated exposureNot classified as a specific target organ toxicant after repeated exposure.Aspiration hazardAspiration hazardNot relevant.InhalationMay cause respiratory system irritation. May cause damage to mucous membranes in nose,throat, lungs and bronchial system. Harmful: danger of serious damage to health by prolongedexposure through inhalation.IngestionIngestion may cause severe irritation of the mouth, the oesophagus and the gastrointestinaltract.Skin contactThe product contains a small amount of sensitising substance. May cause sensitisation orallergic reactions in sensitive individuals.Eye contactRisk of serious damage to eyes. May cause chemical eye burns.Acute and chronic healthhazardsRepeated exposure in excess of the WEL has been linked with rhinitis and coughing. Skinexposure has been linked to allergic chromium dermatitis.SECTION 12: Ecological informationEcotoxicityThe product may affect the acidity (pH) of water which may have hazardous effects on aquaticorganisms.12.1. ToxicityToxicityThe product is not expected to be hazardous to the environment (LC50 aquatic toxicity ratingnot determined). The addition of cement based product to water will, however, cause the pHto rise and may, therefore, be toxic to aquatic life in some circumstances.12.2. Persistence and degradabilityPersistence and degradability Not relevant. After hardening, cement presents no toxicity risks.12.3. Bioaccumulative potentialBioaccumulative potentialThe product is not bioaccumulating.12.4. Mobility in soilMobilityThe product is non-volatile. The product is insoluble in water and will sediment in watersystems.6/8

Revision date: 22/01/2020DUNLOP CF-03 FLEXIBLE FAST SET ADHESIVE GREY12.5. Results of PBT and vPvB assessmentResults of PBT and vPvBassessmentThis product does not contain any substances classified as PBT or vPvB.12.6. Other adverse effectsOther adverse effectsNone known.SECTION 13: Disposal considerations13.1. Waste treatment methodsDisposal methodsProduct that has exceeded defined shelf life should be treated with a reducing agent ordisposed of according to the National or Devolved Administration legislation. For smallspillages, isolate spillage then harden with water before disposing in accordance with Nationalor Devloved Administration legislation.SECTION 14: Transport informationGeneralThe product is not covered by international regulations on the transport of dangerous goods(IMDG, IATA, ADR/RID).Road transport notesNot classified.Rail transport notesNot classified.Sea transport notesNot classified.Air transport notesNot classified.14.1. UN numberNot applicable.14.2. UN proper shipping nameNot applicable.14.3. Transport hazard class(es)Not applicable.Transport labelsNo transport warning sign required.14.4. Packing groupNot applicable.14.5. Environmental hazardsEnvironmentally hazardous substance/marine pollutantNo.14.6. Special precautions for userNot applicable.14.7. Transport in bulk according to Annex II of MARPOL and the IBC CodeTransport in bulk according to Not applicable.Annex II of MARPOL 73/78and the IBC CodeSECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture7/8

Revision date: 22/01/2020DUNLOP CF-03 FLEXIBLE FAST SET ADHESIVE GREYNational regulationsThe Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No. 2677) (asamended).GuidanceWorkplace Exposure Limits EH40.CHIP for everyone HSG228.Safety Data Sheets for Substances and Preparations.Approved Classification and Labelling Guide (Sixth edition) L131.15.2. Chemical safety assessmentNo chemical safety assessment has been carried out.SECTION 16: Other informationRevision comments1Issued byTechnical ManagerRevision date22/01/2020SDS number20565Hazard statements in fullH315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H335 May cause respiratory irritation.This information relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurateand reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability orcompleteness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.8/8

Product name DUNLOP CF-03 FLEXIBLE FAST SET ADHESIVE GREY 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Cement based adhesive. Uses advised against No specific uses advised against are identified. 1.3. Details of the supplier of the safety data sheet Supplier BUILDING ADHESIVES LTD Longton .

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