SAFETY DATA SHEET ROUNDUP PRO HERBICIDE
SAFETY DATA SHEETROUNDUP PRO HERBICIDEVersion 1.0 / USA1020000376021/11Revision Date: 08/06/2020Print Date: 08/17/2020SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THECOMPANY/UNDERTAKINGProduct identifierTrade nameROUNDUP PRO HERBICIDEProduct code (UVP)86771497SDS Number102000037602EPA Registration No.524-475Relevant identified uses of the substance or mixture and uses advised againstIdentified usesHerbicideRestrictions on useSee product label for restrictions.Information on supplierSupplierBayer Environmental ScienceA division of Bayer CropScience LP500 Centregreen Way, Suite 400Cary, NC 27513USAResponsible DepartmentEmail: SDSINFO.BCS-NA@bayer.comEmergency telephone no.Emergency TelephoneNumber (24hr/ 7 days)1-800-334-7577Product InformationTelephone Number1-800-331-2867SECTION 2: HAZARDS IDENTIFICATIONClassification in accordance with regulation HCS 29CFR §1910.1200Acute toxicity(Inhalation): Category 4Labelling in accordance with regulation HCS 29CFR §1910.1200Signal word: WarningHazard statementsHarmful if inhaled.
SAFETY DATA SHEETROUNDUP PRO HERBICIDE2/11Revision Date: 08/06/2020Print Date: 08/17/2020Version 1.0 / USA102000037602Precautionary statementsAvoid breathing mist/ vapours/ spray.Use only outdoors or in a well-ventilated area.IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER/doctor/physician if you feel unwell.Hazards Not Otherwise Classified (HNOC)No physical hazards not otherwise classified.No health hazards not otherwise classified.SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTSHazardous Component NameIsopropylamine salt of glyphosateSurfactant blend (proprietary)CAS-No.38641-94-0Concentration % by weight41.0 7.0 – 13.0The specific chemical identity and/or concentration range is being withheld because it is trade secretinformation.SECTION 4: FIRST AID MEASURESDescription of first aid measuresGeneral adviceWhen possible, have the product container or label with you whencalling a poison control center or doctor or going for treatment.InhalationMove to fresh air. If person is not breathing, call 911 or an ambulance,then give artificial respiration, preferably mouth-to-mouth if possible.Call a physician or poison control center immediately.Skin contactWash off immediately with plenty of water for at least 15 minutes. Takeoff contaminated clothing and shoes immediately. Call a physician orpoison control center immediately.Eye contactHold eye open and rinse slowly and gently with water for 15-20minutes. Remove contact lenses, if present, after the first 5 minutes,then continue rinsing eye. Call a physician or poison control centerimmediately.IngestionCall a physician or poison control center immediately. Rinse out mouthand give water in small sips to drink. DO NOT induce vomiting unlessdirected to do so by a physician or poison control center. Never giveanything by mouth to an unconscious person. Do not leave victimunattended.Most important symptoms and effects, both acute and delayedSymptomsTo date no symptoms are known.Indication of any immediate medical attention and special treatment neededRisksThis product is not a cholinesterase inhibitor.
SAFETY DATA SHEETROUNDUP PRO HERBICIDEVersion 1.0 / USA102000037602Treatment3/11Revision Date: 08/06/2020Print Date: 08/17/2020Treatment with atropine and oximes is not indicated. Appropriatesupportive and symptomatic treatment as indicated by the patient'scondition is recommended.SECTION 5: FIREFIGHTING MEASURESExtinguishing mediaSuitableUse water spray, alcohol-resistant foam, dry chemical or carbondioxide.UnsuitableHigh volume water jetSpecial hazards arisingfrom the substance ormixtureIn the event of fire the following may be released:, Carbon monoxide(CO), Carbon dioxide (CO2), Nitrogen oxides (NOx), Oxides ofphosphorusAdvice for firefightersSpecial protectiveequipment for firefightersIn the event of fire and/or explosion do not breathe fumes. Firefightersshould wear NIOSH approved self-contained breathing apparatus andfull protective clothing. Equipment should be thoroughlydecontaminated after use.Further informationKeep out of smoke. Fight fire from upwind position. Cool closedcontainers exposed to fire with water spray. Do not allow run-off fromfire fighting to enter drains or water courses.Flash pointdoes not flashAuto-ignition temperature452 C / 845.6 FLower explosion limitNot applicableUpper explosion limitNot applicableExplosivityNot explosiveSECTION 6: ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency proceduresPrecautionsUse personal protective equipment. Keep unauthorized people away.Avoid contact with spilled product or contaminated surfaces.Methods and materials for containment and cleaning upMethods for cleaning upSoak up with inert absorbent material (e.g. sand, silica gel, acidbinder, universal binder, sawdust). Collect and transfer the productinto a properly labelled and tightly closed container. Keep in suitable,closed containers for disposal. Clean contaminated floors and objectsthoroughly, observing environmental regulations.
SAFETY DATA SHEETROUNDUP PRO HERBICIDEVersion 1.0 / USA1020000376024/11Revision Date: 08/06/2020Print Date: 08/17/2020Additional adviceUse personal protective equipment. If the product is accidentallyspilled, do not allow to enter soil, waterways or waste water canal. Donot allow product to contact non-target plants.Reference to other sectionsInformation regarding safe handling, see section 7.Information regarding personal protective equipment, see section 8.Information regarding waste disposal, see section 13.SECTION 7: HANDLING AND STORAGEPrecautions for safe handlingAdvice on safe handlingAvoid contact with skin, eyes and clothing. Ensure adequate ventilation.Hygiene measuresWash hands thoroughly with soap and water after handling and beforeeating, drinking, chewing gum, using tobacco, using the toilet orapplying cosmetics.Remove Personal Protective Equipment (PPE) immediately afterhandling this product. Remove soiled clothing immediately and cleanthoroughly before using again. Wash thoroughly and put on cleanclothing. Keep working clothes separately. Garments that cannot becleaned must be destroyed (burnt).Conditions for safe storage, including any incompatibilitiesRequirements for storageareas and containersStore in original container. Store in a cool, dry place and in such amanner as to prevent cross contamination with other crop protectionproducts, fertilizers, food, and feed. Store in a place accessible byauthorized persons only. Reacts with galvanised steel or unlined mildsteel to produce hydrogen, a highly flammable gas that could explode.Protect from freezing. Partial crystallization may occur on prolongedstorage below the minimum storage temperature. Freezing will affect thephysical condition but will not damage the material. Thaw and mixbefore using.Advice on common storageKeep away from food, drink and animal feedingstuffs.SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parametersNo known occupational limit values.Exposure controlsPersonal protective equipmentIn normal use and handling conditions please refer to the label and/or leaflet. In all other cases thefollowing recommendations would apply.Respiratory protectionWhen respirators are required, select NIOSH approved equipmentbased on actual or potential airborne concentrations and inaccordance with the appropriate regulatory standards and/or industryrecommendations.
SAFETY DATA SHEETROUNDUP PRO HERBICIDEVersion 1.0 / USA1020000376025/11Revision Date: 08/06/2020Print Date: 08/17/2020Hand protectionPlease observe the instructions regarding permeability andbreakthrough time which are provided by the supplier of the gloves.Also take into consideration the specific local conditions under whichthe product is used, such as the danger of cuts, abrasion, and thecontact time.Chemical-resistant gloves (barrier laminate, butyl rubber, nitrilerubber or Viton)Wash gloves when contaminated. Dispose of when contaminatedinside, when perforated or when contamination on the outside cannotbe removed. Wash hands frequently and always before eating,drinking, smoking or using the toilet.Eye protectionUse tightly sealed goggles and face protection.Skin and body protectionWear long-sleeved shirt and long pants and shoes plus socks.General protective measuresFollow manufacturer's instructions for cleaning/maintaining PPE. Ifno such instructions for washables, use detergent and warm/tepidwater.Keep and wash PPE separately from other laundry.SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical propertiesFormLiquid, clearColourlight yellow to amberOdoursweetOdour ThresholdNo data availablepH4.4 - 5.0 (8 %) (23 C) (deionized water)Melting point/rangeNo data availableBoiling PointNo data availableFlash pointdoes not flashFlammabilityNo data availableAuto-ignition temperature452 CMinimum ignition energyNot applicableSelf-accelaratingdecomposition temperature(SADT)No data availableUpper explosion limitNot applicableLower explosion limitNot applicableVapour pressure25 mmHg (24 C)
SAFETY DATA SHEETROUNDUP PRO HERBICIDEVersion 1.0 / USA1020000376026/11Revision Date: 08/06/2020Print Date: 08/17/2020Evaporation rateNo data availableRelative vapour densityNo data availableRelative density1.169 (20 C)Density1.17 g/cm³ (20 C)Water solubilitycompletely misciblePartition coefficient: noctanol/waterGlyphosate: log Pow: -3.2Viscosity, dynamic73.2 cpsViscosity, kinematic62.47 cSt (20 C)Oxidizing propertiesNo data availableExplosivityNot explosiveOther informationFurther safety related physical-chemical data are not known.SECTION 10: STABILITY AND REACTIVITYReactivityThermal decompositionStable under normal conditions.Chemical stabilityStable under recommended storage conditions.Possibility of hazardousreactionsReacts with galvanised steel or unlined mild steel to produce hydrogen,a highly flammable gas that could explode.Conditions to avoidExtremes of temperature and direct sunlight.Incompatible materialsGalvanised steel, Unlined mild steelHazardous decompositionproductsNo decomposition products expected under normal conditions of use.SECTION 11: TOXICOLOGICAL INFORMATIONExposure routesSkin contact, Eye contact, InhalationImmediate EffectsEyeMay cause eye irritation.SkinNot expected to produce significant adverse effects whenrecommended use instructions are followed.IngestionNot expected to produce significant adverse effects whenrecommended use instructions are followed.
SAFETY DATA SHEETROUNDUP PRO HERBICIDE7/11Revision Date: 08/06/2020Print Date: 08/17/2020Version 1.0 / USA102000037602InhalationMay be harmful if inhaled.Information on toxicological effectsAcute oral toxicityLD50 (Rat) 5,108 mg/kgAcute inhalation toxicityLC50 (Rat) 2.9 mg/lExposure time: 4 hDetermined in the form of liquid aerosol.Acute dermal toxicityLD50 (Rat) 5,000 mg/kgNo deathsSkin corrosion/irritationNo skin irritation (Rabbit)Serious eye damage/eyeirritationSlight irritant effect - does not require labelling. (Rabbit)Respiratory or skinsensitisationSkin: Non-sensitizing. (Guinea pig)OECD Test Guideline 406, Buehler testAssessment STOT Specific target organ toxicity – single exposureGlyphosate: Based on available data, the classification criteria are not met.Assessment STOT Specific target organ toxicity – repeated exposureGlyphosate did not cause specific target organ toxicity in experimental animal studies.Assessment mutagenicityGlyphosate was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.Assessment carcinogenicityGlyphosate was not carcinogenic in lifetime feeding studies in rats and mice.Important comment to IARC Listing:, Our expert opinion is that classification as a carcinogen is notwarranted.ACGIHNone.NTPNone.IARCIsopropylamine salt of glyphosate38641-94-0Overall evaluation: 2AOSHANone.Assessment toxicity to reproductionGlyphosate did not cause reproductive toxicity in a two-generation study in rats.Assessment developmental toxicityGlyphosate did not cause developmental toxicity in rats and rabbits.Aspiration hazard
SAFETY DATA SHEETROUNDUP PRO HERBICIDEVersion 1.0 / USA1020000376028/11Revision Date: 08/06/2020Print Date: 08/17/2020Based on available data, the classification criteria are not met.Further informationThe toxicological data refer to a similar formulation.SECTION 12: ECOLOGICAL INFORMATIONToxicity to fishLC50 (Oncorhynchus mykiss (rainbow trout)) 5.4 mg/lstatic test; Exposure time: 96 hChronic toxicity to fishOncorhynchus mykiss (rainbow trout)flow-through testNOEC: 9.63 mg/lThe value mentioned relates to the active ingredient glyphosate.Toxicity to aquaticinvertebratesEC50 (Daphnia magna (Water flea)) 11 mg/l static test; Exposure time:48 hChronic toxicity to aquaticinvertebratesEC50 (Daphnia magna (Water flea)): 12.5 mg/lExposure time: 21 dThe value mentioned relates to the active ingredient glyphosate.Toxicity to aquatic plantsEbC50 (Raphidocelis subcapitata (freshwater green alga)) 12.4 mg/lstatic test; Exposure time: 72 hTest conducted with a similar formulation.NOEC (Raphidocelis subcapitata (freshwater green alga)) 6.3 mg/lstatic test; Exposure time: 72 hTest conducted with a similar formulation.BiodegradabilityGlyphosate:Not rapidly biodegradableKocGlyphosate: Koc: 6920BioaccumulationGlyphosate:Does not bioaccumulate.Mobility in soilGlyphosate: Immobile in soilResults of PBT and vPvB assessmentPBT and vPvB assessmentGlyphosate: This substance is not considered to be persistent,bioaccumulative and toxic (PBT). This substance is not considered to bevery persistent and very bioaccumulative (vPvB).Additional ecologicalinformationNo further ecological information is available.Environmental precautionsApply this product as specified on the label.Do not apply directly to water, to areas where surface water is presentor to intertidal areas below the mean high water mark.Do not contaminate surface or ground water by cleaning equipment ordisposal of wastes, including equipment wash water.Retain and dispose of contaminated wash water.
SAFETY DATA SHEETROUNDUP PRO HERBICIDEVersion 1.0 / USA1020000376029/11Revision Date: 08/06/2020Print Date: 08/17/2020SECTION 13: DISPOSAL CONSIDERATIONSWaste treatment methodsProductIt is best to use all of the product in accordance with label directions. If itis necessary to dispose of unused product, please follow container labelinstructions and applicable local guidelines.Do not contaminate water, food, or feed by disposal.Follow all local/regional/national/international regulations.Contaminated packagingFollow advice on product label and/or leaflet.Do not re-use empty containers.Triple rinse containers.Puncture container to avoid re-use.Completely empty container into application equipment, then dispose ofempty container in a sanitary landfill, by incineration or by otherprocedures approved by state/provincial and local authorities.If burned, stay out of smoke.RCRA InformationCharacterization and proper disposal of this material as a special orhazardous waste is dependent upon Federal, State and local laws andare the user's responsibility. RCRA classification may apply.SECTION 14: TRANSPORT INFORMATIONAccording to national and international transport regulations this material is not classified as dangerousgoods / hazardous material.SECTION 15: REGULATORY INFORMATIONEPA Registration No.524-475US Federal RegulationsTSCA listWater7732-18-5Polyethylene glycol25322-68-3US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)No export notification needs to be made.SARA Title III - Section 302 - Notification and InformationNot applicable.SARA Title III - Section 313 - Toxic Chemical Release ReportingNone.US States Regulatory ReportingCA Prop65This product does not contain any substances known to the State of California to cause cancer.
SAFETY DATA SHEETROUNDUP PRO HERBICIDE10/11Revision Date: 08/06/2020Print Date: 08/17/2020Version 1.0 / USA102000037602This product does not contain any substances known to the State of California to causereproductive harm.US State Right-To-Know IngredientsPolyethylene glycol25322-68-3MNEnvironmentalCERCLANone.Clean Water Section 307(a)(1)None.Safe Drinking Water Act Maximum Contaminant LevelsNone.EPA/FIFRA Information:This chemical is a pesticide product registered by the Environmental Protection Agency and is subject tocertain labeling requirements under federal pesticide law. These requirements differ from the classificationcriteria and hazard information required for safety data sheets, and for workplace labels of non-pesticidechemicals. Following is the hazard information required on the pesticide label:Signal word:Caution!Hazard statements:Causes eye irritation.SECTION 16: OTHER INFORMATIONAbbreviations and acronyms49CFRCode of Federal Regulations, Title 49ACGIHUS. ACGIH Threshold Limit ValuesATEAcute toxicity estimateCAS-Nr.Chemical Abstracts Service numberCERCLAComprehensive Environmental Response, Compensation, and Liability ActEINECSEuropean inventory of existing commercial substancesELINCSEuropean list of notified chemical substancesIARCInternational Agency for Research on CancerIATAInternational Air Transport AssociationIMDGInternational Maritime Dangerous GoodsN.O.S.Not otherwise specifiedNTPUS. National Toxicology Program (NTP) Report on CarcinogensOECDOrganization for Economic Co-operation and DevelopmentTDGTransportation of Dangerous GoodsTWATime weighted averageUNUnited NationsWHOWorld health organisation
SAFETY DATA SHEETROUNDUP PRO HERBICIDEVersion 1.0 / USA102000037602NFPA 704 (National Fire Protection Association):Health - 1Flammability - 1Instability - 111/11Revision Date: 08/06/2020Print Date: 08/17/2020Others - noneHMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide)Health - 2Flammability - 1Physical Hazard - 1PPE 0 minimal hazard, 1 slight hazard, 2 moderate hazard, 3 severe hazard, 4 extreme hazardReason for Revision: New Safety Data Sheet.Revision Date: 08/06/2020This information is provided in good faith but without express or implied warranty. The customer assumesall responsibility for safety and use not in accordance with label instructions. The product names areregistered trademarks of Bayer.
recommended use instructions are followed. SAFETY DATA SHEET ROUNDUP PRO HERBICIDE 7/11 Version 1.0 / USA Revision Date: 08/06/2020 102000037602 Print Date: 08/17/2020 Inhalation May be harmful if inhaled. Information on toxicol
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