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ABSTRACT BOOK
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016The material in the book may not be copied or reproduced without permissionof authors.ISBN 978-969-8040-31-4Book of Abstracts3rd Conference onSustainability in processIndustry (SPI 2016)October 2016Published by: Pakistan Scientific and Technological Information Centre,(PASTC), IslamabadPrinted at Reprographic Unit, Pakistan Scientific and TechnologicalInformation Centre (PASTIC), Islamabad2
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016TABLE OF CONTENTSEDITORIAL BOARD. 13ORGANIZING COMMITTEE . 14SCIENTIFIC EXPERT COMMITTEE . 17PREFACE . 18ACKNOWLEDGEMENT . 20ABOUT PASTIC. 22ABOUT NAYS . 24CONFERENCE PROGRAM . 26ABSTRACTS . 36Optimizing Membrane Processes for Carbon Dioxide Capture . 37Modelling and simulation of multichannel enzymatic membranereactors . 38Membranes and Membrane reactors for Energy applications. 39Greener energy: Issues and challenges for Pakistan-Biomass energyprospects. 40Fabrication of Novel Nano Ag-TiOX Composite by Sustainable RedoxProcess for Energy and Environment Applications . 41Fabrication and Characterization of Cellulose Acetate based MixedMatrix Membranes for Gas Separations . 42Air Pollution Control Techniques and Technologies for Process Industries. 43Root Cause Analysis of Catastrophic fire in paints industry . 44Mathematical Modelling and Simulation . 46Synthesis of Zeolite from Coal Power Plant Ash . 473
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016Mixed Matrix Membranes comprising of fluorinated and sulfonatedPEEK and functionalized mesoporous COK-12 for CO2 separation . 48Entropy Generation and Work Lost Analysis of Rice Husk Fired ThermalPower Plant: A Case Study . 50Photocatalytical Degradation of Congo Red (CR) Dye by nano TitaniumDioxide Coated Glass Beads Exposed to U.V Light Irradiation. 51Dimension of Uncertainty in Models of Industrial Processes . 52Numerical approximation of rapidly oscillatory Bessel integraltransforms . 53Technology Entrepreneurship: A Mind-set Required for Sustainability ofChemical Process Industries and Economic Growth. 54Effective utilization of Pakistani Reserves for Sustainable EnergyProduction. 55Effect of Operating Parameters on Tyre Derived Fuel from Pyrolysis ofWaste Tyres. 56Hazard and Operability (HAZOP) study of wastewater treatment . 57Modified iron ore for the removal of Arsenic from underground water atMatiari city . 58Theme 1: Energy Engineering . 59Physicochemical Properties of Agricultural Biomass Residues in Pakistanfor Future ‘Energy Mix’ Potential. 60Electrochemically deposited Pure and Metal-doped α-Fe2O3 Thin filmsfor Hydrogen Production from Photoelectrochemical Water Splitting . 61Energy Harvesting from Vehicle’s Suspension Vibrations . 63Feasibility and Potential of Parabolic Trough Solar Thermal Power Plantsin Pakistan . 64Sedimentation, Eustasy and Tectonic Constraints of the Eocene to LowerMiocene Hydrocarbon Systems of the Gulf of Gabes Basin in Tunisia . 654
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016To Study the Performance of Diesel Engine Using Blends of Bio-Dieselfrom Jatropha Curcas . 67Design of an Optimized Hybrid Power System . 68Downstream pH control and process-efficient kinetics duringcopolymer-induced pelagic cultivation of benthal Chlorella vulgaris . 69Computational Fluid Dynamic (CFD) based Exergy Analysis of NaphthaReforming process . 70Hydrotalcites Based Cobalt Catalyst for Synthesis of Hydrocarbons fromSyngas . 71Promoted Hydrotalcite Based Cobalt Catalyst for Fischer-TropschSynthesis Application . 72Theme 2: Separation Science & Technology. 74Ionic Liquid as a Green Solvent for Biomass Dissolution and Separation. 75Slotted Pore Membranes and Oil/Water Separation . 76Functionalized UiO-66 Sulfonated ISA Membranes for Gas Separation. 77Alkali Activated Coal Fly Ash for the Adsorption of Ni (II) from anAqueous Solution . 78Removal of chromium (VI) from aqueous solution by adsorptionusingAcacia Nilotica (keekar) saw dust . 79Surface energetics of protein adsorption onto chromatographicsupports . 80Synthesis and Functionalization of Mesoporous Silica for EffectiveRemoval of Metal Ions From Aqueous Solutions. 81Separation of Nitrogen from Air using Polymeric Membranes . 82High CO2Selective Novel Supported Ionic Liquid Membranes using (3Aminopropyl) Trimethoxysilane and Acetic Acid . 835
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016Characterization and Evaluation of Grafted Chitosan for Congo RedRemoval from Aqueous Media . 84Zeolitic Imidazolate Framework (ZIF) based Mixed Matrix Membranesfor Organic Solvent Resistant Nanofiltration . 85Theme 3: Health Safety & Environment . 87A Laboratory Scale Investigation of N2O Catalytic Reduction Over CobaltAnd Iron Catalysts . 88Assessment of Different Industrial Ceramic Wastes and Their Potentialfor Possible Applications: A Pilot Scale Renewable MaterialsInvestigation. 90Slow Release Urea Fertilizer from Sulphur, Gypsum and Starch CoatedFormulations . 91Environmental Terrorist: Electric Generators Increasing Lead inEnvironment . 92Increase of Aluminium Particles in the Environment due to Chemtrailsduring the period of Autumn 2012 to Summer 2015 within Lahore,Pakistan . 93Degradation of contaminants of emerging concern by electrochemicallygenerated active chlorine species on the surface of Ti/Ru0.3Ti0.7O2 anode. 94Theme 4: Modelling & Simulation . 96Numerical Evaluation of Multi-Dimensional Integral over Planar andNon-Planar Regions. 98Numerical Solution Of An Integro-Differential Equation Model For TheSpread Of Alcohol Abuse Using Radial Basis Function And fourth orderRunge-Kutta methods . 99Higher Order Compact Finite Difference Method for the Solution ofTwo-Dimensional Time Fractional Diffusion Equation . 1006
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016Evolution Strategies Based on Multiple Crossover Operator for GlobalOptimization Problems . 101Numerical Solution 0f Fisher’s Equation by Using Meshless Method ofLines . 102A numerical Solution Technique of 1D Fredholm Integral Equationhaving Oscillatory Kernel with Stationary Points . 103Solving the Non-Linear Harry Dym Equation by Kansa’s Method . 104Analysis of Unsteady Squeezing Flow Between Two Porous Plates withVariable Magnetic Field . 105A Fuzzy based Active Contour Model for Image Segmentation UsingGaussian Distribution . 106Alternate Smoothing and Segmentation of Texture Images via L0 Norm. 107Theme 5: Mineral Processing and Material Engineering . 108Bauxite Washing: Kinetic Modelling Approach. 109Beneficiation of Barite ore from Teerah by Chemical Treatment . 110Effect of Soluble and Neat Cutting Oils On Machining Alloy Steel . 111Effects of Infill Wall Modelling on Design of Reinforced ConcreteBuildings . 112A Study on Gelatin based Metal Powder Conductive Composites . 113Crushing Circuit Design for Processing of North Waziristan Copper Ore. 114Exploration Framework for the Sustainable Development of DimensionStone Industry: A Case Study of Buner . 115Functionalized UiO-66 Polyimide ISA Membranes for Nanofiltration . 116Application of Monte Carlo Simulation for Cement Raw MaterialBlending Optimization . 117Theme 6: Chemical Process Simulation and Optimization . 1187
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016Parametric Optimization of an Externally Heat-Integrated DoubleDistillation Column (EHIDDiC) System . 119Analysis of Various Control Configurations of a Packed Bed ReactiveDistillation Column. 120Numerical Solution of Inverse Heat Problems . 121Kinetics Modelling and Mechanism of Pb (Ii) Sorption on ChemicallyModified Activated Carbon . 122Haar Wavelet Based Numerical Scheme to Solve Convection DiffusionEquations . 123Foaming surfactant formulation for CO2 mobility control for EORapplications . 124Theme 7: Modelling & Simulation . 125Numerical Solution of a System Of Reaction Diffusion Pdes Arising in ENPlasma . 126Biogeography Based Algorithm for Optimization Problems: PreliminaryExperimental Results . 127Numerical solution of Harry Dym Equation by Meshless Technique . 128On the Numerical Solution of Linear Multi-Term Fractional OrderDifferential Equations using Laplace Transform and Quadrature . 129A mesh Free Collocation Technique for the Numerical Solution of FisherEquation . 130Segmentation of Vector-Valued Texture Images using Adaptive ScaleLocal Variation . 131Theme 8: Green, Safe and Sustainable Production . 132Sustainable State-of-Practice in the Industrial Plant Business for MultiEthnic Organization . 133A Novel Approach—Modeling Vulnerability in Non-Invasive IndustrialInstrumentation for Luminescence Scanning Technology . 1358
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016Granex Power Cycle: Investigation of an Efficient Cycle for UtilizingWaste Heat . 137Structural, Magnetic, and Electric Properties of Sol-gel SynthesizedChromium-Gallium (Cr-Ga) Substituted M-type Hexagonal Ferrites forPractical Applications . 138ABSTRACTS . 139Rubber Toughened Polystyrene Silica Nanocomposites: Morphology,Thermal and Mechanical Behaviour . 140A weak formulation based meshless method with numerical integrationbased on Haar wavelets and hybrid functions for boundary valueproblems . 141Modified Strawberry Algorithm for Global Optimization problems . 142Experimental Study of Separation of CO2 from Natural Gas throughHollow fiber Membrane Contactors . 143Experimental Analysis of Pressure Retarded Osmosis from SalinityGradients Using Hollow Fiber Membrane Contactor . 144Electromagnetic Energy Harvesting from Gas Flow in Pipelines . 145Synthesis and Characterization of Zeolitic Imidazolate Framework (ZIF)71 based Mixed Matrix Membrane . 146Low Energy Process for Natural Gas Treatment by Using PolymericMembrane System . 147Parametric Optimization of an Internally Heat-Integrated DistillationColumn . 148Process Design for Bio-Ethanol Fermentation from Potato Peels Waste:Simultaneous Saccharification and Fermentation of Starch by Very HighGravity Process. 149Enhanced differential evolutionary algorithm for global optimizationproblems . 1509
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016Development of Carbon Fiber Reinforced Composite Pressure Vesseland Effect of Polar Winding Pattern in Mass Saving. 151Impact of Waste Marble Dust on the Sustainability of Cement SandMortar . 152MOF-5 based Mixed Matrix Membranes for Solvent ResistantNanofiltrtion. 153Studying the Effects of Design Parameters on the Performance ofRegenerator for Cryo-Cooler Applications. 154Efficient Quadrature Rules for Numerical Evaluation of Singular andHypersingular Integrals . 155Numerical Solution of Abel Integral Equation using Transforms andQuadrature. 156Retrofit of Pre-Heat Train of a Crude Distillation Unit. 157Meshless Procedure for Solution of the Elliptic Partial DifferentialEquations . 158Converging, Non-Converging Slotted Pores Membranes and Oil DropsDeformation . 159Non-Linear Time History Analysis of Reinforced Concrete SpecialMoment Resisting Frames for Loss Estimation. 160Exploring the Energy Output Using Bio Solar Cell . 161Characterization of Produced and Brackish Water. 162Study of Polymer Composite Membrane for Pervaporation . 163Geospray: Geopolymer Coating Material for Industrial Applications . 165Membrane Reactor for Biodiesel Production from Waste Cooking Oil 166Static Adsorption Behaviour of Newly Developed Foaming Surfactants, AComparative Study. 167CO2Mobility Control by Using Surfactants for EOR Applications . 168Crime Mapping the Best Option for Criminology: A Review . 16910
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016Optimal Route Guide by GIS for Fire Cases at Public Use Buildings . 170Environmental and Safety Issues of Forte Ceramics. 171Gas Sweetening and Sulfur Recovery by Claus Process . 172Investigation of Turbidity using Statistical Experimental Design. 173Production of Magnesium Sulphate from Dolomite Ore Deposits In KP. 174Recycling used Automobile Oil by Thermal Cracking. 175Waste Heat Recovery System for Kohat Cement . 176Treatment of Formaldehyde from Industrial Waste Water . 177Desulfurization of Fuels by Adsorption Through Hydroxy Appetite . 178Production of Biodiesel from Animal Fat . 179Boiler Designing for Waste Heat Recovery Plant for a Cement Industry. 180Effect of Desulfurization on Viscosity of Pyrolytic Oils . 181Extraction of Edible Oil from Rice Husks . 182Extraction of Sweetener from Leaves of Stevia . 183Factors Effecting Rheological Properties of Polyurethane Composites184Effect of Varying R-Values on Mechanical Properties of Polyurethane 185Preparation of Biodiesel from Waste Cooking Oil Using MagneticallySeparable Silica Supported Heterogeneous Acid Catalyst . 186Production of Potassium Chromate By Green Metallurgical Processing. 187Process Design for Production Of Sodium Chromate . 188Treatment of Tannery Waste Water Using Iron Chloride . 189Optimizing Viscosity of Urea-Formaldehyde Resin Using StatisticalExperimental Design . 190Production of Fuel by Pyrolysis of Waste Plastics. 19111
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016Simulation and Optimization of Membrane-Thermal ConcentrationProcess for Concentration of Thin Sugar Juice . 192Techno-economical Comparison of Parabolic Trough Solar ThermalPower Plant with Quaid-e-Azam Solar Photovoltaic Power Plant . 193Energy audit of Askari Cement, Nizampur . 194Video Streaming data estimation and management for efficientbandwidth utilization using Probabilistic Models . 195Derivative Based Hybrid Genetic Algorithm: A Preliminary ExperimentalResults . 196Mineralogical Characterization and Evaluation of Phosphate Ore fromGarhi Habib Ullah, District Mansehra, Khyber Pakhtunkwa, Pakistan. 197Extaction of Niobium from Ore Deposits Occurring In KPK . 198Numerical Simulation of Hollow Fiber Membrane Contactors for CO2Separation from Natural Gas . 199Energetic and Exergetic Analysis of 2.97 MW Rice Husk Fired SteamTurbine Power Plant in an Existing Fertilizer Industry by Using AspenHYSYS V8.8 . 200Experimental Study of Dispersion of Pollutants in the Atmosphere . 20112
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016EDITORIAL BOARDDr. Mohammad YounasDr. Saeed GulDr. Jamil AhmedDr. Muhammad Imran AhmadDr. Naseer Ahmed KhanDr. Asmat UllahEngr. Amir Muhammad13
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016ORGANIZING COMMITTEEPatron-in-ChiefProf. Dr. Iftikhar HussainVice Chancellor, UET PeshawarConference AdvisorProf. Dr. Noor Muhammad KhanDean, Faculty of Engineering, UET PeshawarConference ChairDr. Mohammad YounasChairman, Department of Chemical EngineeringConference Co-ChairDr. Saeed GulDirector ORIC/Associate Professor, Department of ChemicalEngineeringConference SecretaryEngr. Amir MuhammadLecturer, Department of Chemical Engineering14
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016Protocol and Registration CommitteeDr. Nehar UllahEngr. Unsia HabibEngr. Abdul HaiEngr. Amjad AliEngr. Qazi SohaibEngr. Uzair TariqMedia and Publications CommitteeDr. Muhammad Imran AhmadDr. Asmat UllahDr. Naseer Ahmed KhanMs Ghazala Ali KhanBoarding and Lodging CommitteeEngr. Imran Khan SwatiEngr. Amad Ullah KhanEngr. Wajid AliEngr. Muhammad TariqEngr. Shafi Ullah MarwatEngr. Yahya Gul15
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016Food and Entertainment CommitteeEngr. Imran Khan SwatiEngr. Wajid AliEngr. Amir NaveedEngr. Aimal KhanEngr. Arshad HussainEngr. Syed Zakria BachaConference Hall and Stage CommitteeDr. Muddasar HabibEngr. Amad Ullah KhanEngr. Murtaza KhanEngr. Micaiah Cyril DasEngr. Sidrat ul MuntehaEngr. Sarfaraz Khan16
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016SCIENTIFIC EXPERT COMMITTEEProf. Dr. Naveed Ramzan (UET Lahore)Prof. Dr. Zafar Noon (UET Lahore)Prof. Dr. Mehmood Saleem (ICET PU Lahore)Prof. Dr. Muhammad Tayyeb Javed (PIEAS Islamabad)Prof. Dr. Shahid Raza Malik (NFC IEFR Faisalabad)Prof. Dr. Sohail A Soomro (MUET Jamshoro)Prof. Dr. Arshad Hussain (NUST Islamabad)Prof. Dr. Suleman Tahir (University of Gujrat)Dr. Asim Laeeq Khan (COMSATS CIIT Lahore)Dr. Waqar Ali Khan (NFC IEFR Faisalabad)Prof. Dr. Rizwan A. Gul (PCAS-E UET Peshawar)Prof. Dr. Sahar Noor (UET Peshawar)Dr. Afzal Khan (UET Peshawar)Prof. Dr. Siraj Ul Islam (UET Peshawar)Prof. Dr. Daulat Khan (UET Peshawar)Dr. Gul Muhammad Khan (UET Peshawar)Dr. Mohammad Younas (UET Peshawar)Dr. Farid Ullah (UET Peshawar)Dr. Saeed Gul (UET Peshawar)17
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016PREFACESustainability means “to maintain or endure.” According to thework of the UN Brundtland Commission, sustainability in thecontext of development is to “meet the needs of the presentwithout compromising the ability of future generations to meettheir own needs”. Sustainability in process industries is globallyknown since last few decades. Sustainable development containssocial, cultural, environmental and economic aspects.Pakistan is facing various problems and energy is one of the mainissues today. There are many reasons behind energy crisis inPakistan, inefficient processes are one of the major factors amongstthem. It is high time to address sustainability, link it to the processindustries, and to contribute to sustainable development in order toovercome the energy crisis in Pakistan.The Chemical Engineering Department of University ofEngineering and Technology, Peshawar plays a vital role inresearch areas of national interest. Our faculty is actively involvedin applied research at both national and international level.The 1st conference on “Sustainability in Process Industries (SPI2012), held at UET, Peshawar on March 28, 2012, attractedprominent researchers from all over Pakistan which created alinkage and presented approaches for the application ofsustainability in the process industry.The Department of Chemical Engineering had again takeninitiative to hold a 2nd conference on “Sustainability in ProcessIndustry(SPI-2014)”, on May 22, 2014 in collaboration withPASTIC and NAYS. Continuing this tradition, the 3rd conferencein this series, i.e. “Sustainability in Process Industry (SPI2016)” October 19-20, 2016 is organized with the support ofHigher Education Commission (HEC) in collaboration withPASTIC.18
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016The mission of this conference is to identify new directions forresearch and development on “Sustainability in ProcessIndustry” and share success stories regarding applied research andindustrial case studies on R&D.We hope that you will find this 3rd conference on “Sustainabilityin Process Industry (SPI 2016)” interesting and that theconference will provide you with a valuable opportunity to shareideas with other researchers and industrial practitioners.Dr. Mohammad YounasChair19
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016ACKNOWLEDGEMENTIt is our great pleasure to welcome you to the SPI-2016 3rdconference of this series, i.e. “Sustainability in Process Industry(SPI-2016)”.Putting together SPI-2016 was a team effort. We firstthank the authors for providing the content of the program in theform of oral and poster presentations and all other participants. Weare also grateful to the key note speakers from academia andvarious industries. These valuable talks can and will guide us to abetter understanding of “Sustainability in Process Industry”.We also thank the host organization, UET, Peshawar, and ourgenerous sponsors HEC, PASTIC, NAYS, Technology Links (Pvt)Ltd, Rizvi and Co. (Pvt) Ltd, and Meditron (Pvt) Ltd, without theirsupport it would not be possible to hold this conference.We are grateful to all organizers, who worked hard in order tomake this conference successful.20
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 201621
3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016ABOUT PASTICPakistanScientificandTechnological Information Centre(PASTIC) formerly known asPakistan National Scientific andTechnical Documentation Centre(PANSDOC) was establishedunder auspices of Pakistan Councilof Scientific and IndustrialResearch (PCSIR) with thetechnical assistance of UNESCO.PANSDOC was later transferredto Pakistan Science Foundation, an autonomous organization ofMinistry of Science & Technology and was renamed as PakistanScientific and Technological Information Centre (PASTIC). Atpresent PASTIC is functioning under administrative control ofPakistan Science Foundation, Ministry of Science and Technology.PASTIC is the premier organization in the field of scientific andtechnological information dissemination serving thousand ofresearchers and R&D workers in the country. PASTIC mission toserve as a Gateway for S&T information for research anddevelopment community by catering to their information needsthrough its anticipatory and responsive scientific informationservices. PASTIC col
Synthesis of Zeolite from Coal Power Plant Ash.47 . 3rd Conference on Sustainability in Process Industry (SPI 2016) 19-20th Oct 2016 4 Mixed Matrix Membranes comprising of fluorinated and sulfonated . Increase of Aluminium Particles in the Environment due to Chemtrails durin
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