Quartz Valley Indian Reservation - California

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Quartz Valley Indian ReservationQuality Assurance Project Plan2016 RevisionWater Quality Sampling and AnalysisCWA 106 grant identification # I-96927206-0Prepared byTribal Environmental Protection DepartmentQuartz Valley Indian Reservation13601 Quartz Valley RoadFort Jones, CA 96032

Quartz Valley Indian ReservationQuality Assurance Project PlanWater Quality Sampling and AnalysisCWA 106 Grant Identification # I-96927206-0Approval PageThis QAPP has been approved by:Date:Crystal RobinsonQVIR Environmental Director/QA ManagerDate:Harold BennettQVIR ChairmanFor EPA use:Approved by EPA Project Manager:Date:Loretta VanegasCWA 106 Project OfficerExpedited Review? YesNoReceived by QA Office:Date:Date:Reviewed by:Approved:Eugenia McNaughtonRegion 9 Quality Assurance ManagerDate:QVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 2 of 126

Table of ContentsDistribution List . 7Project Organization . 8Problem Definition/Background . 10Decline of the Fishery . 12Land Use Factors . 13Purpose of Water Quality Investigations . 18Principal data users/decision makers who will use the data to make decision . 18Brief Summary of existing information and recent water quality data collection . 19Project/Task Description and Schedule . 26Monitoring Locations, Methods and Timing of Samples . 27Sample Frequency and Parameters . 31Quality Objectives and Criteria for Measurement Data . 52Identify Data Needs and Establish Acceptance Criteria . 57Data Quality Indicators . 57Special Training Requirements/Certificates . 63Documents and Records . 63Data Generation . 69Sampling Design . 69Sampling Methods . 71Surface Water. 71Groundwater . 73Surface and Groundwater . 73Field Health and Safety Procedures . 75Decontamination Procedures . 75Disposal of Residual Materials . 76Sample Handling and Custody. 80Containers & Preservatives . 80Packaging and Shipping . 80Sample Custody . 81Sample Disposal. 82Analytical Methods . 82Laboratory Analyses Methods (Off-Site) . 82Quality Control Requirements . 83QVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 3 of 126

Field Sampling Quality Control . 83Laboratory Analyses Quality Control (Off-Site) . 85Background Samples . 87Instrument/Equipment Testing, Inspection, and Maintenance . 95Field Measurement Instruments/Equipment . 95Laboratory Analysis Instruments/Equipment (Off-Site) . 95Instrument/Equipment Calibration and Frequency . 95Inspection and Acceptance of Supplies and Consumables . 101ASSESSMENT AND OVERSIGHT . 102DATA REVIEW AND USABILITY . 106Data Review, Verification, and Validation Requirements. 106Reconciliation with User Requirements . 108References . 110Appendix . 112List of TablesTable 1: Lakes at Headwaters of Shackleford-Mill Creeks (Data from Klamath NationForest) . 12Table 2 Top-ten most commonly used pesticides in Shackleford and Scott BAsin during1990-2004 (Data Source: CA Pesticide Use Reporting Database) . 16Table 3 Top-five industrial practices for total pesticide use and the top five esticides usedin Siskiyou County 2010 (Data Source: CA Pesticide Use Reporting Database) . 17Table 4: Groundwater Analysis Results . 21Table 5: Surface Water Analysis Results. 23Table 6: Field Parameters at Surface Water Sample Locations . 23Table 7 Sites and Parameters . 34Table 8 Locations and Rationale for Site Selection . 43Table 9 Water Quality Parameters and Action Levels. 54Table 10 Precision of Sampling Equipment by the QVIR EPD . 61Table 11 Required Sample Containers, Volumes, Preservation Methods, Analysis Methodand Holding Times for Water Samples Requiring Lab Analysis . 78Table 12 Summary of Field and QC Samples . 89Table 13 Quality Control Samples, Data Quality Indicators, Frequency, Methods,Acceptance Criteria and Corrective Actions. 90Table 14 Field Equipment Calibration, Maintenance, Testing and Inspection. 97List of FiguresFigure 1 QVIR Water Quality Program Organizational Structure . 10QVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 4 of 126

Figure 2 Scott River Basin, Siskiyou County California . 11Figure 3 Surface Water Sampling Loactions . 29Figure 4 Static Groundwater Monitoring Locations . 30Figure 5 Domestic Groundwater Monitoring Locations . 31Figure 6 Schedule for Implementation . 51List of AppendicesAppendix A: Shackleford Creek Limiting FactorsAppendix B: ECORP WQ Study DocumentsAppendix B1: Prior groundwater test results before ECORP BWAAppendix B2: ECORPs SAPAppendix B3: CLS Lab QA informationAppendix B4: Habitat unit characterization from ECORPAppendix B5: Flow Measurement from ECORPAppendix C: Laboratory DocumentsAppendix C1: Sample Labels from LabsAppendix C2: Sample Chain of Custody and Custody SealsAppendix C3: Labs’ & Consultant QA informationAppendix C3-1: Jon Lee ConsultingAppendix C3-2: North Coast LaboratoriesAppendix C3-3: Aquatic AnalystsAppendix C3-4: IEH Analytical Lab CertificationAppendix C3-5: QVIR Microbiology LabAppendix C3-6: IEH Analytical Lab QA ManualAppendix D: QVIR Water Quality Checklists and WorksheetsAppendix D1: Field Activities Review ChecklistAppendix D2: Laboratory Data Review ChecklistAppendix D3: Field Water Quality Data SheetsAppendix E: Field Equipment Manuals and InstructionsAppendix E1: Garmin Rino 650 GPSQVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 5 of 126

Appendix E2: SonTek Flow TrackerAppendix E3: HOBO Water Temp Pro LoggersAppendix E4: Van Dorn Sample Bottle InstructionsAppendix E5: YSI 556 MultiProbe System ManualAppendix E6: YSI 6600 EDS MultiProbe System ManualAppendix E7: Model WQ770 Turbidity MeterAppendix E8: HOBO U20 Water Level Logger ManualAppendix F: Sampling ProtocolsAppendix F1: Rapid Bioassessment ProtocolAppendix F2: NCWAP Methods ManualAppendix F3: SWAMP ProtocolAppendix F4: Ground Water SOPAppendix F5: Surface Water SOPAppendix F6: Discharge Measurements SOPAppendix F7: Grazing Allottment SOPAppendix F8: HOBO Temperature ProtocolAppendix G: Water Quality StandardsAppendix G1: Basin Plan MCL TablesAppendix G2: EPA National Guidance WQ StandardsQVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 6 of 126

Distribution ListThe following is a list of individuals who will receive copies of the approvedQAPP and any subsequent revisions or changes.Crystal RobinsonQVIR Environmental DirectorQuartz Valley Indian Reservation13601 Quartz Valley RoadFort Jones, CA 96032Ph: 530-468-5907 Fax: 530-468-5908crystal.robinson@qvir-nsn.govQVIR Environmental Department StaffQuartz Valley Indian Reservation13601 Quartz Valley RoadFort Jones, CA 96032Ph: 530-468-5907 Fax: 530-468-5908Tim WilhiteGAP Project OfficerUSEPA c/o Klamath Nat’l Forest1711 South Main StreetYreka, CA 96097-9549Ph: 530-841-4577 Fax: 530841-4571Wilhite.Timothy@epa.govEugenia McNaughton, ManagerRegion 9 Quality Assurance OfficeU.S. EPA Region 975 Hawthorne StreetMail Code: EMD-3-2San Francisco, CA 94105Ph.(415) 972-3411mcnaugton.eugenia@epa.govQVIR Tribal CouncilQuartz Valley Indian Reservation13601 Quartz Valley RoadFort Jones, CA 96032Ph.: 530-468-5907 Fax: 530-468-5908Loretta VanegasCWA 106 Project OfficerUSEPA REGION 975 Hawthorne StreetMail Code: WTR-10San Francisco, CA 94105Ph.: 415-972-3517vanegas.loretta@epa.gov

Project OrganizationTitle/ResponsibilityNamePhone NumberEPA Project ManagerLoretta VanegasCWA 106 Project OfficerCrystal RobinsonQVIR EnvironmentalDirectorSarah SchaeferFisheries/Water QualityCoordinatorIEH AnalyticalLaboratoriesDamien GadomskiJim SweetAquatic Analysts(415) 972-3433North Coast LaboratoriesLtd.(707) 822-4649Jon LeeJon Lee Consulting(707) 441-9347QVIR Project ManagerQuality Assurance ManagerQVIRLab - OrganicsLab- PhytoplanktonLab- PesticidesLab – MacroinvertebratesLab - BacteriaQVIR Field TechniciansCrystal RobinsonLab DirectorQVIR Microbiology LabAlex Case Field TechIsaiah Williams FieldTech(530) 468-5907(530) 468-5907(206) 632-2715(503) 869-5032(530) 468-5907(530) 468-5907The Quartz Valley Indian Reservation’s Environmental Department (QVIRED)is completing this QAPP to define how quality control (QC) procedures areimplemented and to define how the QVIRED and its staff will work together onquality assurance (QA) to insure that data are properly collected and analyzed,managed and stored for on-going use, and results published in a timely fashion.Because of the systematic planning process documented in this QAPP, theQVIRED Water Quality Monitoring Program will supply quality assured data formanagement decisions related to the aquatic environment within QVIRjurisdiction and the Scott River watershed.QVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 8 of 126

The QVIR Water Quality Monitoring Program is organized as shown in Figure 1.The QVIR Environmental Director has ultimate control over and responsibilityfor the WQ program. The QVIR Environmental Director is responsible forprogram coordination, schedule and budget management, technical oversight,report preparation, and overall program quality.The QA Manager will have responsibility and authority for: Ongoing review of monitoring methods and equipment calibration, Auditing field notebooks, databases, chain of custody forms, and Insuring adherence to field and laboratory QA/QC programs. Assist with report preparation Run preliminary analysis of data, and provide charts for reportsIn short, the QA Manager will insure that QC procedures developed in this QAPPare carried out.The Field Technicians will work under the supervision of the QA Manager andfollow procedures as defined in this QAPP. The Field Technicians will: Collect field samples Fill out forms to record results and field conditions, Care for and calibrate equipment, Properly fix and ship samples needing laboratory analysis, Transfer results from the field or laboratory into databases, Properly store data and archive to insure against loss,Any time there are problems perceived by the Data Manager or the WQTechnician with any part of the WQ Monitoring Program, they are to notify theQVIR Project Manager so they can work collaboratively on resolving them. TheQA Manager will also periodically conduct audits to detect QA/QC problems ordeficiencies.If any tests of surface or groundwater exceed action levels, the QVIREnvironmental Director will be notified so that she can inform the QVIR TribalCouncil. Following notification of the Tribal Council, the QVIR EPD would theninform the North Coast Regional Water Quality Control Board staff and workcooperatively with that agency for abatement of problems.QVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 9 of 126

The QVIR EPD will send water quality samples for nutrient analysis to IEHAnalytical. Water samples tested for pesticides will be sent to North CoastLaboratories, Ltd. A benthic macro-invertebrate consulting firm, Jon LeeConsulting, will provide technical assistance in the sampling and identification ofaquatic macro-invertebrates. Phytoplankton and algae samples will be sent to JimSweet Aquatic Analyst, to be processed and analyzed. Bacteria samples will beanalyzed for E. coli, fecal, and total coliforms in house by QVIR’s EnvironmentalLab Accredidation Program (ELAP) certified bacteria laboratory.Figure 1 QVIR Water Quality Program Organizational StructureQVIR Program Environmental Director/QVIR Data ManagerConsultantQVIR FieldTechniciansIEH Analytical,North Coast Laboratories, Aquatic Analysts,Jon Lee Consulting,QVIR Microbiology LabProblem Definition/BackgroundThe Quartz Valley Indian Reservation lies in a rural, sparsely populated areawithin the Scott River watershed in the Klamath Mountain Province. The ScottRiver is one of four major tributaries of the Klamath River (Figure 2),contributing about 5% of the entire Klamath’s runoff (yearly average of 615,000acre feet). The Scott River watershed is a large area with substantial variation ingeology, geomorphology, and climatology. The watershed drains approximately520,617 acres (812.2 mi2 or 2,107 km2). Major tributaries to the 58 mile longScott River in the Scott Valley include: Shackleford, Kidder, Etna, French, andMoffett Creeks, and also the South and East Forks (SRWC SAP 2005).QuartzValley Indian Reservation has several streams on tribal land. Shackleford, Mill,and Sniktaw Creeks all run through the original reservation boundaries.The headwaters of the largest creeks, Shackleford and Mill lie in the Marble MountainWilderness Area. Campbell, Cliff, and Summit Lakes comprise the headwaters ofQVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 10 of 126

Shackleford Creek. The headwaters of Mill Creek consist of the two Mill Creek ponds.The size, elevation and depth of each lake are listed in Table 1. The Tribe has interest inthe health of these aquatic ecosystems because of their role in producing cold water fishand other culturally significant flora and fauna. Chinook and coho salmon as well assteelhead trout return to these creeks to spawn and rely on a healthy Scott River forjuvenile rearing and adult migration.Figure 2 Scott River Basin, Siskiyou County CaliforniaQVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 11 of 126

Table 1: Lakes at Headwaters of Shackleford-Mill Creeks (Data from Klamath Nation �Cliff6100’52175’Summit6050’515’Summit Meadow6050’1.34’Mill Creek (West)6450’4.58’Mill Creek (East)6350’1.515’The Scott River was listed as sediment and temperature impaired under Section 303(d) ofthe Clean Water Act by the North Coast Regional Water Quality Control Board and theU.S. Environmental Protection Agency (EPA) in 1997. Total Maximum Daily Loads(TMDL’s) were approved by the Regional Water Board (December 2005), the StateWater Board (June 2006) and the US EPA (September 2006). Water quality conditions(low flow, high temperatures, altered sediment supplies, and highly fluctuating waterchemistry during summer months) are considered to have adversely affected the habitatof anadromous salmonid populations in the Scott River watershed. Coho salmon in theregion were listed as threatened under the Federal Endangered Species Act (ESA) in1997 by the National Marine Fisheries Service (NMFS) and by the California Fish andGame Commission in 2002. Additionally, the Klamath River in the section downstreamof the confluence with the Scott is also listed for nutrients and organic enrichment/lowdissolved oxygen; the Klamath TMDL was approved by the EPA in 2010.Decline of the FisheryAll runs of anadromous fish have declined over time in the Scott basin. Historically,spring-run Chinook salmon were the most abundant salmon in the rivers of the KlamathBasin, and outnumbered the fall Chinook run (Hume in Snyder 1931). “Salmon ascendthe river in large numbers, before the waters subside in the spring,” remarked Gibbs in1851 (SRWC SAP 2005). Fall Chinook, winter steelhead, and summer steelhead werealso widespread in the Scott River Basin (Maria, personal communication in SRWC SAP2005). Today, the spring Chinook run and the summer steelhead run are virtuallynonexistent in the Scott River (KRBFTF, 1991. p. 2-87, 2-99, and 4-15; USFS, 2000b,p.3-9; USFS, 2000a). The fall Chinook population of the Scott River basin is thought tohave declined since at least the 1960’s (Hardy and Addley, 2001, p.12). The Scott RiverQVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 12 of 126

produces approximately 9.2 % of the natural fall Chinook salmon in the Klamath Riverbasin (SRWC, 2004, p.6-1).Historically, coho salmon would have flourished in the numerous ponds createdby beavers throughout the valley and in both forks of the Scott River (SRWC SAP2005 & Belchik, personal communication). Brown et al. (1994) state thatCalifornia coho populations are probably less than 6 % of what they were in the1940’s, and there has been at least a 70 % decline since the 1960s. Coho salmonoccupy only 61 % of the SONCC Coho ESU streams that were previouslyidentified as historical coho salmon streams (CDFG, 2002, p.2)Land Use FactorsFactors that limit salmon and steelhead production affect water quality and constrainattainment of other beneficial uses in Shackleford and Mill Creeks are inter-related.There are some over-arching factors, such as flow depletion, that cause secondary waterquality problems (e.g., transit time increases and stagnation of water can occur).Limiting factors are most often linked to land use activities, including logging,agriculture, rural urbanization, channelization, road building/use and mining.Historically, gold was mined in the Quartz Valley area, both in the valley itself and in thenearby Scott and Oro Fino valleys. The prominent type of mining performed in NorthernCalifornia during the late 1800’s was hydraulic mining. Surface and groundwater in theQuartz Valley could potentially be contaminated with heavy metals that naturally occurin association with gold but are discarded in tailings, such as arsenic and mercury.Dredge tailings from hydraulic mining can also serve as a long-term source of sedimentand can create long-term physical alterations to channels and substrate.Much of the land in Siskiyou County was logged, beginning in the latter half of the 19thcentury. Erosion due to land-slides associated with clear-cutting or failures of loggingroads still used or abandoned are thought to be sources of sediment to the ShacklefordCreek and Scott River system. Bank destabilization from agricultural practices alsocontributes to sediment deposits.Beginning around 1850, ranching became the most prevalent use of land around theQuartz Valley. Grazing of cattle is still performed by many landowners on the valleyfloors in the Scott River watershed, which could contribute to accelerated bank erosionalong streams and increased bacterial levels of surface waters when cattle are permitteduncontrolled access to streams. Land around the upper reaches of Shackleford Creek hasQVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 13 of 126

historically been used for cattle grazing during the summers, which have been shown tobe associated with increased levels of fecal coliforms to the surface water. Land in theQuartz Valley floor is also used for commercial agriculture, which includes use ofpesticides, nitrates, and phosphates which can find their way to the surface water.Private industrial timber lands border the Reservation and Shackleford Creek. Modernforestry practices often use herbicides, pesticides, and fertilizers and can be additionalsources of chemical inputs to surface and ground waters. Fruit Growers Company, one ofthe largest owners of private land in Siskiyou County, has been unwilling to share data orstudies they have conducted pertaining to Shackleford Creek. They have since sold theirwest side Scott River holdings to Timbervest. QVIR Environmental staff has beenmeeting with Timbervest representatives as of 2006 and have established a positiveworking relationship which includes data sharing and property access.On Reservation trust land, no grazing or agriculture is performed, however agricultureand grazing does occur within the original Reservation boundary on lands no longerowned by the QVIR. The area around Shackleford Creek and the Reservation doescontain paved roads and has vehicle traffic. Oils and other contaminants likely to comefrom automotive traffic are potential sources of chemicals to surface and ground waters.No heavy industry is present in the area, and chemical inputs from such industrialapplications do not currently occur. However, there are large scale agriculturaloperations in the larger Scott River watershed that use fertilizers and pesticides and posea concern to the Tribe.Logging and Roads: Upland areas within the Shackleford Creek watershed have beenextensively logged and currently have high road densities (see Appendix A).Compaction of soils and changes in routing of storm water on logged areas and loggingroads have been shown to have the following affects: increased peak stream discharge (Montgomery and Buffington, 1993; Jones andGrant, 1996),increased sediment yield (Hagans et al., 1986, de la Fuente and Elder, 1998), andreduced large wood for recruitment to streams (Reeves et al., 1993; SchuettHames et al., 1999).QVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 14 of 126

These potential effects to aquatic conditions related to logging and road type disturbancesare each described in greater detail below. Also the description of conditions inShackleford Creek uplands based on GIS and other data is presented in Appendix A.Increased peak stream flows can winnow out smaller sediment particles such as sand andgravels and leave the streambed with larger cobbles and boulders. This larger diameterdistribution of the substrate can end up being greater than optimal for salmonid use suchas spawning, or providing macro invertebrate habitat. The increased peak flows canwash out large wood and trigger bank failures and increased channel scour. Channelchanges can include decreased pool frequency and depth (Buffington and Montgomery,1993). Wider and shallower channels also are more subject to solar warming. Althoughless well studied, hydrologic changes associated with compaction of soil and loss ofinfiltration capacity over a watershed can also lead to decreased summer base flows.Increased sediment yield is a problem in the Scott River watershed (NCRWQCB, 2003;2005). Fine sediment comes primarily from surface or gully erosion. (Sommarstrom etal. (1990) identified erosion from road cuts and road fills on decomposed granitic soils asa major source of fines in the Scott River watershed.Increased sediment yield can affect watershed in two ways. One is by creating elevatedlevels of sand and fine sediment in transport that can settle downstream and fill interstitialspaces in normally sorted stream gravels, and cause decreased salmonid egg and alevinsurvival and reduced quality of aquatic insect habitat. Decreased aquatic invertebrateproduction diminishes food resources for juvenile salmonids. Smaller sediment particles,being highly mobile, fill pools thus reducing salmonid juvenile carrying capacity andadult salmonid holding habitat. Another way increased sediment yield can affectwatersheds is via elevated mass wasting. The coarse and fine sediment yielded to streamchannels by increased rates of mass wasting typically cause channel aggradation, loss ofpool habitat, changes in median particle size, decreased spawning gravel quality andchannel adjustments that facilitate stream warming.Large wood depletion and changes in riparian conditions can increase ambient airtemperature over streams and reduce relative humidity, thus leading to stream warming(Bartholow, 1989; Pool and Berman, 2001). Pools are often formed by large wood debrisand these have been shown to be extremely important nursery areas for coho salmonjuveniles (Reeves et al., 1988) as they must rear for one year in fresh water beforemigrating to the ocean. Large wood depletion is associated with diminished aquatichabitat complexity, reduced pool frequency and lower carrying capacity for juvenileQVIR QAPP Water Quality Sampling and AnalysisVersion Date: March 2016Page 15 of 126

coho. Large coniferous trees in riparian zones take decades or centuries to grow tosufficient size to be useful in buffering air temperatures and providing wood of sufficientsize to provide lasting habitat value (Shuett-Hames et al., 1999).Agricultural Water Diversion: Flow depletion in Shackleford Creek caused by waterextraction for agriculture contributes to stream warming. Water volume is directlyrelated to maintaining thermal mass and therefore reduced volumes will warm morereadily. Also water cools itself via hyporheric exchange with ground water and loss ofsurface flow will reduce this rate of exchange. Decreasing flows also causes riffles toshallow and will contribute to the formation of isolated and disconnected pools.Shackleford Creek on the QVIR flows subsurface in sections in late summer until the fallrains restore the stream flow. This drying of the channel causes stranding of salmonidsand other aquatic organisms. As flows decrease, the ability to scour substrate decreasesallowing increased growth of periphyton. High rates of photosynthesis are often the resultas a function of increased temperatures and slower flows. The photosynthesis andrespiration of the algae in low-flow conditions can cause large nocturnal and diurnalfluctuations in pH and dissolved oxygen.Pesticides: Many of the leading pesticides used in Scott Valley and the ShacklefordCreek drainage are chemicals that have no recognized levels of exposure for humanhealth risk as set by the U.S. Environmental Protection Agency or the State of California(EDW, 2005). However, two pesticides used in Scott Valley were acknowledged to beharmful to salmonids on July 2006, by the US EPA. Table 2 show the pesticides mostused in the Shackleford and Scott River basins with those h

Appendix C3-6: IEH Analytical Lab QA Manual Appendix D: QVIR Water Quality Checklists and Worksheets Appendix D1: Field Activities Review Checklist Appendix D2: Laboratory Data Review Checklist Appendix D3: Field Water Quality Data Sheets Appendix E: Field Equipment Manuals and Instr

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