Safety Data Sheet BIODIESEL B100 - Hero Bx

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Safety Data SheetBIODIESEL B100 – HBX 3000SDS Revision Date: 07/18/20171. Identification of the substance/mixture and of the company/undertaking1.1. Product identifierProduct IdentityBIODIESEL B100, HBX 3000Alternate NamesFatty Acid Methyl Ester1.2. Relevant identified uses of the substance or mixture and uses advised againstIntended useSee Technical Data Sheet.Application MethodSee Technical Data Sheet.1.3. Details of the supplier of the safety data sheetCompany NameLake Erie Biofuels, LLC d/b/a Hero BX1540 East Lake Road. Suite 300Erie, PA 16511Emergency24 hour Emergency Telephone No.Customer Service: Lake Erie Biofuels, LLC d/b/aHero BX(814) 528-9222(814) 528-92002. Hazard identification of the product2.1. Classification of the substance or mixtureNo applicable GHS categories.2.2. Label elementsUsing the Toxicity Data listed in section 11 and 12 the product is labeled as follows:No applicable GHS categories.[Prevention]:No GHS prevention statements[Response]:No GHS response statements[Storage]:No GHS storage statements[Disposal]:No GHS disposal statementsPage 1 of 9

Safety Data SheetBIODIESEL B100 – HBX 3000SDS Revision Date: 07/18/20173. Composition/information on ingredientsThis product contains the following substances that present a hazard within the meaning of the relevant State andFederal Hazardous Substances regulations.Ingredient/Chemical DesignationsWeight %Fatty Acid , Me esterCAS Number: 0061788-61-2GHS Classification100[1] Substance classified with a health or environmental hazard.[2] Substance with a workplace exposure limit.Notes[1][3] PBT-substance or vPvB-substance.*The full texts of the phrases are shown in Section 16.4. First aid measures4.1. Description of first aid measuresGeneralInhalationEyesSkinIngestionIn all cases of doubt, or when symptoms persist, seek medical attention.Never give anything by mouth to an unconscious person.Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, giveartificial respiration. If unconscious place in the recovery position and obtain immediatemedical attention. Give nothing by mouth.Irrigate copiously with clean fresh water for at least 15 minutes, holding the eyelids apartand seek medical attention.Remove contaminated clothing. Wash skin thoroughly with soap and water or use arecognized skin cleanser.If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT inducevomiting.4.2. Most important symptoms and effects, both acute and delayedOverviewNo specific symptom data available. See section 2 for further details.5. Fire-fighting measures5.1. Extinguishing mediaRecommended extinguishing media; alcohol resistant foam, CO 2, powder, water spray.Do not use; water jet.5.2. Special hazards arising from the substance or mixtureOil soaked rags can cause spontaneous combustion if not handled properly. Wash rags with soap and water beforedisposal.Hazardous decomposition: Combustion produces carbon monoxide, carbon dioxide, and thick smoke.5.3. Advice for fire-fightersCool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants fromfire fighting to enter drains or water coursesERG Guide No.----Page 2 of 9

Safety Data SheetBIODIESEL B100 – HBX 3000SDS Revision Date: 07/18/20176. Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresRemove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In case of a major spill orspillage in a confined space evacuate the area and check that solvent vapor levels are below the Lower ExplosiveLimit before re-entering.Oil soaked rags can cause spontaneous combustion if not handled properly. Wash rags with soap and water beforedisposal.6.2. Environmental precautionsDo not allow spills to enter drains or watercourses.Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly removesoiled clothing and wash thoroughly before reuse.6.3. Methods and material for containment and cleaning upOil soaked rags can cause spontaneous combustion if not handled properly. Wash rags with soap and water beforedisposal.Take the personal protective measures listed in section 8.Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed containersoutside buildings and dispose of according to the Waste Regulations. (See section 13).Do not allow spills to enter drains or watercourses.If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the case ofcontamination of rivers, streams or lakes the Environmental Protection Agency should also be informed.7. Handling and storage7.1. Precautions for safe handlingSee section 2 for further details. - [Prevention]:7.2. Conditions for safe storage, including any incompatibilitiesStore in closed containers between 50F and 120FIncompatible materials: Strong oxidizing agentsSee section 2 for further details. - [Storage]:7.3. Specific end use(s)No data available.Page 3 of 9

Safety Data SheetBIODIESEL B100 – HBX 3000SDS Revision Date: 07/18/20178. Exposure controls and personal protection8.1. Control parametersExposureCAS No.0067784-80-9IngredientSourceSoybean oil, Me esterValueOSHANo Established LimitACGIHNo Established LimitNIOSHNo Established LimitSupplierNo Established LimitCarcinogen DataCAS No.0067784-80-9IngredientSoybean oil, Me esterSourceValueOSHASelect Carcinogen: NoNTPKnown: No; Suspected: NoIARCGroup 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;8.2. Exposure controlsRespiratoryIf workers are exposed to concentrations above the exposure limit they must use theappropriate, certified respirators.EyesWear safety eyewear, e.g. safety spectacles, goggles or visors to protect against thesplash of liquids.SkinOveralls which cover the body, arms and legs should be worn. Skin should not be exposed.All parts of the body should be washed after contact.Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by theuse of local exhaust ventilation and good general extraction. If these are not sufficient tomaintain concentrations of particulates and any vapor below occupational exposure limitssuitable respiratory protection must be worn.Other Work Practices Use good personal hygiene practices. Wash hands before eating, drinking, smoking orusing toilet. Promptly remove soiled clothing and wash thoroughly before reuse.See section 2 for further details. - [Prevention]:Page 4 of 9

Safety Data SheetBIODIESEL B100 – HBX 3000SDS Revision Date: 07/18/20179. Physical and chemical propertiesAppearanceOdorOdor thresholdpH Not DeterminedMelting point / freezing pointInitial boiling point and boiling rangeFlash PointEvaporation rate (Ether 1)Flammability (solid, gas)Upper/lower flammability or explosive limitsPale Yellow LiquidMildNot MeasuredNot MeasuredNot Measured200C at 101.3 kPa (760 mmHg)130C (ASTM 93)Greater than Butyl AcetateNot ApplicableLower Explosive Limit: Not MeasuredUpper Explosive Limit: Not MeasuredVapor pressure (Pa)Vapor DensitySpecific GravitySolubility in WaterPartition coefficient n-octanol/water (Log Kow)Auto-ignition temperatureDecomposition temperatureViscosity (cSt)VOC %9.2. Other informationGreater than Air0.88InsolubleNot MeasuredNot MeasuredNot MeasuredNot MeasuredNot MeasuredNo other relevant information.10. Stability and reactivity10.1. ReactivityHazardous Polymerization will not occur.10.2. Chemical stabilityStable under normal circumstances.10.3. Possibility of hazardous reactionsNo data available.10.4. Conditions to avoidKeep away from oxidizing agents, excessive heat, and ignition sources.10.5. Incompatible materialsStrong oxidizing agents10.6. Hazardous decomposition productsCombustion produces carbon monoxide, carbon dioxide, and thick smokePage 5 of 9

Safety Data SheetBIODIESEL B100 – HBX 3000SDS Revision Date: 07/18/201711. Toxicological informationAcute toxicityIngredientSoybean oil, Me ester - (67784-80-9)Oral LD50,mg/kgSkin LD50,mg/kgNo dataavailableNo dataavailableInhalationVapor LD50,mg/L/4hrNo dataavailableInhalationDust/Mist LD50,mg/L/4hrNo dataavailableInhalationGas LD50,ppmNo dataavailableNote: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimatewas used in the calculation of the product's ATE (Acute Toxicity Estimate).ClassificationCategoryHazard DescriptionAcute toxicity (oral)---Not ApplicableAcute toxicity (dermal)---Not ApplicableAcute toxicity (inhalation)---Not ApplicableSkin corrosion/irritation---Not ApplicableSerious eye damage/irritation---Not ApplicableRespiratory sensitization---Not ApplicableSkin sensitization---Not ApplicableGerm cell mutagenicity---Not ApplicableCarcinogenicity---Not ApplicableReproductive toxicity---Not ApplicableSTOT-single exposure---Not ApplicableSTOT-repeated exposure---Not ApplicableAspiration hazard---Not ApplicablePage 6 of 9

Safety Data SheetBIODIESEL B100 – HBX 3000SDS Revision Date: 07/18/201712. Ecological information12.1. ToxicityNo additional information provided for this product. See Section 3 for chemical specific data.Aquatic EcotoxicityIngredientSoybean oil, Me ester - (67784-80-9)96 hr LC50 fish,mg/l48 hr EC50 crustacea,mg/lNot AvailableNot AvailableErC50 algae,mg/lNot Available12.2. Persistence and degradabilityThere is no data available on the preparation itself.12.3. Bioaccumulative potentialNot Measured12.4. Mobility in soilNo data available.12.5. Results of PBT and vPvB assessmentThis product contains no PBT/vPvB chemicals.12.6. Other adverse effectsNo data available.13. Disposal considerations13.1. Waste treatment methodsDo not allow into drains or water courses. Wastes and emptied containers should be disposed of in accordance withregulations made under the Control of Pollution Act and the Environmental Protection Act. Using information providedin this data sheet advice should be obtained from the Waste Regulation Authority, whether the special wasteregulations apply.14. Transport informationDOT14.1. UN numberNot Applicable14.2. UN proper ship. nameNot Regulated14.3. Transport hazard class(es) DOT Hazard Class: N/ADOT Label: --14.4. Packing groupNot ApplicableIMO/IMDGNot ApplicableNot RegulatedIMDG: Not ApplicableSub Class: Not ApplicableNot Applicable14.5. Environmental hazardsIMDGMarine Pollutant: No14.6. Special precautions for userNo further information14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC CodeNot ApplicablePage 7 of 9ICAO/IATANot ApplicableNot RegulatedAir Class: Not ApplicableNot Applicable

Safety Data SheetBIODIESEL B100 – HBX 3000SDS Revision Date: 07/18/201715. Regulatory informationRegulatory OverviewWHMIS ClassificationUS EPA Tier II HazardsThe regulatory data in Section 15 is not intended to be all-inclusive, only selectedregulations are represented. All ingredients of this product are listed on the TSCA (ToxicSubstance Control Act) Inventory or are not required to be listed on the TSCA Inventory.Not RegulatedFire:Sudden Release of Pressure:Reactive:Immediate (Acute):Delayed (Chronic):EPCRA 311/312 Chemicals and RQs:(No Product Ingredients Listed)EPCRA 302 Extremely Hazardous :(No Product Ingredients Listed)EPCRA 313 Toxic Chemicals:(No Product Ingredients Listed)Proposition 65 - Carcinogens ( 0.0%):(No Product Ingredients Listed)Proposition 65 - Developmental Toxins ( 0.0%):(No Product Ingredients Listed)Proposition 65 - Female Repro Toxins ( 0.0%):(No Product Ingredients Listed)Proposition 65 - Male Repro Toxins ( 0.0%):(No Product Ingredients Listed)N.J. RTK Substances ( 1%) :(No Product Ingredients Listed)Penn RTK Substances ( 1%) :(No Product Ingredients Listed)Page 8 of 9NoNoNoNoNo

Safety Data SheetBIODIESEL B100 – HBX 3000SDS Revision Date: 07/18/201716. Other informationThe information and recommendations contained herein are based upon data believed to be correct. However, noguarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to ourproducts. Customers/users of this product must comply with all applicable health and safety laws, regulations, andorders.The full text of the phrases appearing in section 3 is:Not applicableThis is the first version in the GHS SDS format. Listings of changes from previous versions in other formatsare not applicable.This information relates only to the specific material designated and may not be valid for such material used incombination with any other materials or in any other process. Such information is to the best of the company’sknowledge and believed accurate and reliable as of the date indicated. However, no representation, warranty orguarantee of any kind, express or implied, is made as to its accuracy, reliability or completeness and we assume noresponsibility for any loss, damage or expense, direct or consequential, arising out of use. It is the user’sresponsibility to satisfy himself as to the suitableness and completeness of such information for his own particularuse.End of DocumentPage 9 of 9

Soybean oil, Me ester - (67784-80-9) No data available No data available No data available No data available No data available Note: When no route specific LD50 data is available for an acute toxin, the converted acute tox

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