August 16-19,1999 Seoul, Korea - GBV

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ProceedingsVol.3The 8th APCChE CongressAsian Pacific Confederation of Chemical EngineeringChallenges Facing Chemical Engineeringin the 21st CenturyAugust 16-19,1999Seoul, KorearAPCChE 9 9UB/TIB Hannover117 029 22X89The Korean Institute of Chemical EngineersThe Asian Pacific Confederation of Chemical EngineeringI

Thursday, August 19,1999ORAL SESSIONSSESSION 1F : Topics on Materials Science I9-1F-IL[Invited Lecture]Materials Processing for Electronics - From Growth Rate to MorphologyHiroshi Komiyama.The University of Tokyo, Japan14599-1F-01Growth Chemistry and Interface Characterization of Single CrystalSiC on Modified Si SurfaceKee Suk Nahm, Kwang Chul Kim, Chan II Park,Chonbuk National University, Korea14619-1F-02Study on the Gasification Behavior of Carbonaceous Materialby a Fixed-Point Observation with TEMTakayuki Takarada, Kayoko Morishita, Gunma University, Japan14659-1F-03Comparison of Tetrakis-Dimethyl-Amido-Titanium andTetrakis-Diethyl-Amido-Titanium and Remote Plasma TitaniumNitride (TiN) Metal-Organic Chemical Vapor Deposition (MOCVD)Ju-Young Yun, Shi-Woo Rhee,Pohang University of Science and Technology, Korea1469SESSION 1G : Topics on Materials Science II9-1G-IL[Invited Lecture]Toughening of the Thermoplastic Modified Thermosets HavingMorphology SpectrumY. S. Kim, H. S. Min, S. C. Kim, Korea Advanced Instituteof Science and Technology, Korea14739-1G-01Polymers Designed for Membrane SeparationHidetoshi Kita, Yamaguchi University, Japan14779-1G-02Surface Molecular Imprinted Polymers as a Novel Separation ToolMasahiro Goto, Kazuya Uezu, Shintaro Furusaki,Kyushu University, Japan1481(41)

SESSION 2F : Development of Catalytic Processes I9-2F-01Role of Water in the Catalytic Decomposition of ChlorinatedHydrocarbons over Cr-containing CatalystsDae-Chul Kim, Son-Ki Ihm,Korea Advanced Institute of Science and Technology, Korea14859-2F-02Liquid Phase Kinetics of Tertiary Butyl Alcohol Synthesis fromHydration of Isobutene over a Commercial Ion Exchange Resin CatalystM. R. Suboh, C. Zhang, A. A. Adesina, M. S. Wainwright,University of New South Wales, Australia14899-2F-03Oxygen Production Using BaO-BaO2 Reaction CycleChangchun Jin, Takashi Suehiro, Tetsuro Ikegami, Akio Kodama,Motonobu Goto, Tsutomu Hirose, Kumamoto University, Japan14939-2F-04The New Reaction Route for N-VINYL-2-Pyrrolidone overAcid-Base Bifunctional CatalystPine-Sci Kuo, Chu-Chang Dai,Industrial Technology Research Institute, Taiwan14979-2F-05Low-Temperature CO Oxidation over a Heterogenized WackerCatalyst: The Role of Copper Phase on Catalyst StabilityEun Duck Park, Jae Sung Lee,Pohang University of Science and Technology, Korea1501SESSION 2G : Development of Catalytic Processes II9-2G-01Study on the Reaction Variables in a Fixed-bed Reactor forOxidation of o-Xylene over V2O5/TiO2 CatalystsYeung Ho Park, Seung Jun Kim, Shin Choon Kang, Hanyang University, Korea15059-2G-02The Degradation of Polyvinyl Alcohol by Means of a Photo-FentonReactionD. C .M. Ho, Po Lock Yue, J. F. Porter,The Hong Kong University of Science and Technology, Hong Kong15099-2G-03The Design Principles of Pd-only Catalysts for the Purificationof Automobile Emis«(42)

SESSION 2H : Development of Catalytic Processes III9-2H-IL[Invited Lecture]Catalyst Preparation with New Mesoporous Molecular SievesRyong Ryoo, Shinae Jun, Sang Hun Joo,Korea Advanced Institute of Science and Technology, Korea15219-2H-01Kinetics of Methanol Steam Reforming over Cu-Zn CatalystsMee Sook Lim, Dong Hyun Kim,Kyungpook National University, Korea15259-2H-02A Novel Method for Improving the Performance of Porous MembraneReactor Fed with Pure ReactantAzis Trianto, Takashi Fukushima, Takao Kokugan,Tokyo University of Agriculture and Technology, Japan15299-2H-03Urea from Underground Coal GasChristopher J. Williamson, University of Canterbury, New Zealand Functionalization and Grafting of Syndiotactic-Styrene/4-MethylStyrene CopolymerShu-Hua Chan, Huai-Mei Chou, Sheng-Te Yang, Li-Jiun Chen,Chi-Lan Li, Industrial Technology Research Institute, Taiwan15339-2H-041537SESSION 3F : Waste Treatment and Utilization III9-3F-01Development of Bubble Column for Treatment of WastewaterIncluding OilYoshiyuki Bando, Takayuki Tanaka, Keiji Yasuda, Masaaki Nakamura,Nagoya University, Japan15419-3F-02Lubricating Oil Sludge and its DemulsificationGuohua Chen, Po Lock Yue, Hong Kong University of Scienceand Technology, Hong KongGaohong He, Dalian University of Technology, Hong Kong15459-3F-03Pretreated Biomass of Marine Macroalgae as Low Cost High EfficiencyAdsorbent for Heavy Metal IonsQiming Yu, Pairat Kaewsarn, Jose T. Matheickal, Weitung Ma,Griffith University, Australia15499-3F-04Development of Biological Treatment Process for Heavy Metal Containing 1553Industrial Wastewater Using Sulfate Reducing Bacterial ActivityJi-Won Yang, Sang-Pil Yeom,Korea Advanced Institute of Science and Technology, Korea9-3F-05Catalytic Dechlorination of PCBs at Low TemperatureDong-Keun Lee, Eun-Suk Byun, Gyeongsang National University, KoreaIn-Cheol Cho, Kyoung Sang Nam-Do Provincial Government, KoreaSung-Woo Kim, Sam Hyeob Resource Development Co., Ltd., Korea(43)1557

SESSION 3G : Waste Treatment and Utilization IV9-3G-01Biosorption of Copper(ll) from Aqueous Solutions by Pre-treatedBiomass of Marine Alga Padina SP.Qiming Yu, Pairat Kaewsarn, Griffith University, Australia15619-3G-02Environmental Crystallization in the Wastewater TreatmentIzumi Hirasawa, Waseda University, Japan15659-3G-03Influence of Growth Rate on Biosorption of Heavy Metals by NocardiaAmaraeDong Wook Kim, Korea Institute of Science and Technology, KoreaDaniel K. Cha, University of Delaware, USAYunchul Chung, Korea Institute of Science and Technology, Korea15699-3G-04Production of Lime from Sludge in Water Treatment PlantsIbrahim S. Al-Mutaz, King Saud University, Saudi ArabiaSami O. A. Al-Yousef, Riyadh Water & Sewage Authority,Saudi Arabia1573SESSION 3H : Waste Treatment and Utilization V9-3H-IL[Invited Lecture]Energy-efficient Catalysis in Renewable and Non-renewableFeedstocksV. P. Shiralkar, National Chemical Laboratory (CSIR), India15779-3H-01Effect of Structure Change on Drying Characteristics of MunicipalSolid WasteYuji Tatemoto, Yoshiyuki Bando, Keiji Yasuda, Masaaki Nakamura,Nagoya University, JapanMuneo Azegami, Prand Research Institute, Japan15839-3H-02Oil Recovery and Raw Material Recycle-Technologiesby the Pyrolysis of Was*(44)

SESSION 40F : Biomaterials and Bioprocesseslll9-40F-01The Effects of Surfactants on Chalcopyrite Bioleaching: PreliminaryResultsJinyu Tang, Ha Ming Ang, Curtin University of Technology, AustraliaHelen R. Watling, Belinda J. Clark, CSIRO Minerals, Australia15999-40F-02E. Coli Oxygen-Dependent nar Promoter System in the Fed-BatchCultures for the Production of Recombinant (3 -galactosidaseHo Nam Chang, Se Jong Han,Korea Advanced Institute of Science and Technology, KoreaJong Won Lee, Catholic University of Taegu-Hyosung, Korea16039-40F-03Effects of the Toxic Compounds in Flue Gas on Growth of Highly CO21607Tolerant MicroalgaeJu-No Lee, Jin-Suk Lee, Chul-Seung Shin, Soon-Chul Park, KIER, KoreaSeung-Wook Kim, Korea University, Korea9-40F-05Hydrodynamic Behavior in an External-Loop Inverse FluidizationAirlift Bioreactor'Shejiao Han, Reginald B. H. Tan, K. C. Loh, National Universityof Singapore, Singapore1611SESSION 40H : Applications of Biotechnology9-40H-IL[Invited Lecture]Engineering for GMP Biopharmaceutical PlantsByong Hyock Choi, Wayne Process Engineering, Ltd., Korea16159-40H-01Repression of Baculovirus-lnduced Insect Cell Apoptosis UsingSilkworm HemolymphWon Jong Rhee, Eun Jeong Kim, Tai Hyun Park,Seoul National University, Korea1619ii9-40H-02Recombinant Insect Larval Production Process is Optimized byGenerating Fusions with Green Fluorescent ProteinHyung Joon Cha, William E. Bentley, University of Maryland, USA16239-40H-03Hydrolysis of Olive Oil in a Batch Reactor: Additive Effects onLipase ActivityHuanfei Jia, H. M. Ang, P. Padmanabhan,Curtin University of Technology, Australia16279-40H-04Refolding of Denatured and Reduced Lysozyme with Cysteine/CystineRed/Ox Solution in DiafiltrationHidefumi Yoshii, Takeshi Furuta, Takahiro Yonehara, Daisuke Ito,Tottori University, JapanPekka Linko, Helsinki University of Technology, Japan1631(45)

SESSION 50F : Topics in Fluid Mechanics III9-50F-01Hydrodynamics during the Deposition of Langmuir-Blodgett FilmsLiyan Zhang, M. P. Srinivasan,National University of Singapore, Singapore16359-50F-02Microstructure and Rheological Properties of Aqueous CationicSurfactant Solution in the presence of Structure-Enhancing AdditivesWon-Jong Kim, Seung-Man Yang,Korea Advanced Institute of Science and Technology, Korea16399-50F-03Diffusion and Partition Coefficients of Substrates in AOTMicroemulsion-based OrganogelsKazuhito Nagayama, Akio Ueta,Kochi National College of Technology, JapanMasanao Imai, Toshifusa Doi, Nihon University, Japan16439-50F-04Computational Fluid Dynamics for Predicting Mixing Behaviorof Bakers' Yeast FermentorThongchai Srinophakun, Kasetsart University, ThailandJessada J. Jitjaroenchai, KMUTT, Thailand16479-50F-05Hydrodynamic Study of Mixing in the Combustion Chamber of aSecondary Reformer Using Acid-Alkali Cold ModelHerri Susanto, Suhartono, ITB, Indonesia'1651SESSION 50G : Heat and Mass Transfer9-50G-01Dissolution of CO2 from CO2 Drops Suspended in a CounterFlow of Water at High Pressure, Low Temperature Region- Effect of Hydrate Film on the Mass TransferKeiichi Ogasawara, Ho Teng, Akihiro Yamasaki,National Institute of Materials and Chemical Research, Japan16559-50G-02On the Use of Open Boundary Condition Method in the NumericalSimulation of Nonisothermal Viscoelastic FlowSeung Joon Park, Seung Jong Lee, Seoul National University, Korea16599-50G-03Unsteady Forced Convection Heat Transfer in Porous MediumWen-Tung Cheng, National Chung Hsing University, TaiwanHasiao-Tsung Lin, National Central University, Taiwan16639-50G-04Design of a New Heterogeneous Reactor for Kinetic Studies ofSemiconductor Photocatalysis using CFDVidya Niwas Khetawat, Ajay K. Ray,National University of Singapore, Singapore1667(46)

SESSION 500H : Powder Technology9-500H-IL[Invited Lecture]Particulate Design for Drug Delivery System with SphericalCrystallization TechniqueYoshiaki Kawashima, Gifu Pharmaceutical University, Japan16719-500H-01The Ultra-fine Grinding Mechanism of Inorganic Powders and Surface1675Modification in a Stirred Grinding Media Mill: Simulation on the MotionBalls in a Stirred MillHyun Soo Kim, Woo Sik Choi, Pusan National University, KoreaToshihiko Umekage, Shinichi Yuu, Kyushu Institute of Technology, Japan9-500H-02A Simple Method to Increase the Efficiency of Reverse Flow CycloneLiu Qi, Madhumita Bhowmick Ray,National University of Singapore, Singapore9-500H-03Synthesis of Ultra-fine TiO2 Powder Using Thermal Plasma1683Seung-Min Oh, Jeong-Gu Gong, Dong-Wha Park, Inha Univeristy, Korea9-500H-04The Measurement of Crystal Size Distribution by MultiphasicObservation Using a Real-time, High-speed Image ProcessingSystem in a Stirred-type CrystallizerKazuhiko Nishi, Mitsuo Kamiwano, Meguru Kaminoyama,Yokohama National University, Japan16791687SESSION 60F : Fundamentals of Fluidization Engineering9-60F-01Flow Regime Transition in Three-Phase Fluidized Beds—An OverviewSang Done Kim, Korea Advanced Institute of Science and TechnologyYong Kang, Chungnam National University, KoreaDong Hyun Lee, University of British Columbia, Canada16919-60F-02Transient Fluid Flow in the Surgical Cavity of Brain TumorsChee Seng Teo, Madhusudana Rao Suryadevara, Timothy Lee,Chi-Hwa Wang, National University of Singapore, Singapore16959-60F-03Models for Minimum Liquid Fluidization Velocity of Gas-LiquidFluidized BedsD. H. Lee, N. Epstein, J. R. Grace,University of British Columbia, Canada16999-60F-04Effect of Particle Size Distribution on Particle Entrainment Ratein a Gas Fluidized BedJeong-Hoo Choi, Joon-Min Suh, Konkuk University, Korea17039-60F-05Stochastic Analysis of Gas-Liquid-Solid Flow in Three-Phase CirculatingFluidized BedsYong J. Cho, P. S. Song, Sung H. Kim, Yong Kang,Chungnam National University, KoreaSang D. Kim,Korea Advanced Institute of Science and Technology, Korea1707(47)

SESSION 60G : Applications of Fluidization Engineering I9-60G-01Nonlinear Modeling of the Chaotic Dynamics in a CirculatingFluidized Bed by an Artificial Neural NetworkY Nakajima, R. Kikuchi, K. Kuramoto A. Tsutsumi,University of Tokyo, JapanK. Otawara, Kureha Techno Eng. Co., Japan17119-60G-02Particle Hold-up in the Two-Fluidized Reactor System withTwo LoopsealsChang-Keun Yi, Sung-Ho Cho, Dal-Hee Bae, Dowon Shun,Gyoung-Tae Jin, Jae-Ek Son,Korea Institute of Energy Research, Korea17159-60G-03Efficiency and Agglomeration of Powder Coatingof Fluidizing Particles in Circulating Fluidized BedHiroyuki Kage, Mitsunaga Dohzaki, Hironao Ogura, Yoshizo Matsuno,Kyushu Institute of Technology, Japan17199-60G-04A Cold Model Experiment for Developing a New Type MovingBed Coal Gasifier with Circulating Thermal MediumYasuo Hatate, Kazuya Ijichi, Yoshimitsu Uemura, Desmond F. King,Kagoshima University, Japan1723SESSION 60H : Applications of Fluidization Engineering II9-60H-IL[Invited Lecture]Fluidization of Cohesive PowdersMasayuki Horio, Tokyo University of Agriculture & Technology, Japan17279-60H-01Fluidised Bed Production of High Quality Hot Briquetted Ironfor SteelmakingAllon D. Brent, BHP HBI, AustraliaPeter L. J. Mayfield, Thomas A. Honeyands, BHP CMRP, Australia17339-60H-02The Sedimentation of an Aggregate and a Fractal FloeHeng-Kwong Tsao, C.-Y. Tseng, S.-C. Wang,National Central University Taiwan, Taiwan17379-60H-03Effects of Particle Properties on Hydrodynamic Behaviorsand Heat Transfer Characteristics in Pulsated Fluidized BedAkira Nishimura, Seiichi Deguchi, Hitoki Matsuda, Noriyuki Kobayashi,Masanobu Hasatani, Nagoya University, JapanArun S. Mujumdar, McGill University, Canada17419-60H-04Effects of Pressure on Combustion Characteristics of CoalYongseung Yun, Gae Bong Lee,Institute for Advanced Engineering, Korea1745(48)

SESSION 7F : Solid-Fluid Separation II9-7F-01Optical Resolution of Amino Acids By Ultrafiltration UsingModified CyclodextrinsM. Arif Yudiarto, Yukiko Yoshizawa, Takao Kokugan,Tokyo University of Agriculture and Technology, Japan17499-7F-02Numerical Simulation of a Kinetically Controlled PSA Bulk SeparationProcess based on a Bidisperse Pore Diffusion ModelR. Gupta, S. Farooq, National University of Singapore, Singapore17539-7F-03Optimization of Start-up Operating Conditions in RPSADaeho Ko, II Moon, Yonsei University, KoreaMin Oh, Taejon National University of Technology, Korea17579-7F-04Characterization of Ethanol-Pulp from Oil-Palm Empty Fruit BunchesHerri Susanto, ITB, IndonesiaWieke Pratiwi,Institute for Research and Development of Cellulose Industry, Indonesia17619-7F-05Effect of Salt on Temperature-Swing Adsorption of Nonionic Surfactantwith PVMEGKazuaki Yamagiwa, Masanori Yoshida, Akira Ohkawa,Niigata University, JapanHisao Ichijo,National Institute of Materials and Chemical Research, Japan1765SESSION 7G : Solid-Fluid Separation III9-7G-01Deposition of Colloidal Particles in Randomly Packed Fibrous MediaYongcheng Li, C.-W. Park, University of Florida, USA17699-7G-02Collection Performance of Medium Performance Air Filter Consistingof Binary Fibers under Dust Loaded ConditionT. Sakano, N. Namiki, H. Emi, Y. Otani, Kanazawa University, Japan17739-7G-03Adsorbents for Light Alkane/Alkene SeparationSang-Sup Han, Jong-Nam Kim, Soon-Haeng Cho,Korea Institute of Energy Research, KoreaN. V. Choudary, Prakash Kumar, S.G.T. Bhat,Indian Petrochemicals Corporation Ltd., India17779-7G-04A Theoretical Study on Interaction between AgNO3-Silica Gel andAdsorbed Molecules by Using AB Initio MO MethodTetsuo Suzuki, Hajime Tamon, Morio Okazaki,Kyoto University, Japan1781(49)

SESSION 7H : Solid-Fluid Separation IV9-7H-IL[Invited Lecture]Recent EOS-based Equilibrium Models for Separation ProcessesChul Soo Lee, B.H. Park, J. W. Kang, Korea University, KoreaK. P. Yoo, Sogang University, Korea17859-7H-01Sorption Kinetics for the Removal of Copper and Zinc from EffluentsUsing Bone CharC. W. Cheung, J. F. Porter, G. McKay,Hong Kong University of Science and Technology, Hong Kong17899-7H-02Adsorption of Maltooligosaccharides from Aqueous Solution ontoActivated CarbonJae Wook Lee, Heung Joe Jung, Seonam University, KoreaII Shik Moon, Sunchon National University, KoreaHee Moon, Chonnam National University, Korea17939-7H-03Adsorption Kinetics of Hydrocarbons in a Large HeterogeneousMicroporous ParticleShizhang Qiao, Xijun Hu, Hong Kong University of Scienceand Technology, Hong Kong17979-7H-04Separation of The Ni2 and Cr6 Ions with Application of the Zeolitefrom Type NaABlagica Cekova, Maria Curie-Sklodovska, Macedonia1801(50)

POSTER SESSIONSThin Solid Films/Novel Materials/Topics on Materials Science(9-P3-1 -9-P3-51)9-P3-1Preparation of Sodium Silicate from ClayMi Sun Cha, Kyun Young Park, Kongju National University, Korea18059-P3-2Flame Synthesis of Silica Nanoparticles from Tetraethoxysilane VaporHee Dong Jang, Korea Institute of Geology, Mining and Materials, Korea18099-P3-3Dynamics of Hydrogen Trapped in Diamond Lattice - A DirectMolecular Orbital Dynamics ApproachAkira Shimizu, Micho Inagaki, Hiroto Tachikawa,Hokkaido University, Japan18139-P3-4Enhancement of Hydrophobicity by PECVD Thin Film Coating onMetal SurfacesHyun So, Young Chai Kim, Hanyang University, Korea18179-P3-5Preparation of Epoxy Resin/Acrylic Composite Latices byMiniemulsion Polymerization MethodH. Kawahara, T. Gotoh, K. Ohnishi,Dainippon Ink & Chemicals Inc., JapanH. Kage, Y. Matsuno, Kyushu Institute of Technology, Japan18219-P3-6Phase Behavior and Properties of Cationic/Anionic MixedSurfactant SystemsvKye-Hong Kang, Kyung-Hee Lim, Chung-Ang University, Korea18259-P3-7Structural and Optical Characterization of Thick GaN Film Grownby a Direct Reaction of Metal Ga with NH 3 in CVD ReactorKee Suk Nahm, Seung Hyun Yang, Sang Hyun Ahn,Chonbuk National University, Korea18299-P3-8Synthesis and Characterization of LiMn2 O4 Cathode Materialsby Adiphic Acid-Assisted Sol-Gel MethodKee Suk Nahm, Sang Ho Park, Yun Sung Lee,Chonbuk National University, KoreaYeong Seok Yang, Woo Suk University, Korea18339-P3-9Effect of Liquid Mixing on Decomposition Performance by UltrasoundKeiji Yasuda, Misako Tachi, Ryo Tanigawara, Yoshiyuki Bando,Masaaki Nakamura, Nagoya University, Japan1837(51:

9-P3-10Performance of Silica Slurries with Silica Particles Grownby Sol-Gel MethodSun Hyuck Bae, Do Hyun Kim,Korea Advanced Institute of Science and Technology, Korea18419-P3-11Simulation of an Inductively Coupled Ar-Plasma UsingTwo-Dimensional Continuum ModelDong Ho Kim, Do Hyun Kim,Korea Advanced Institute of Science and Technology, KoreaWon Young Chung, Samsung Electronics Co., LTD., Korea18459-P3-12Temperature Control of an RTP System Using a Model PredictiveControl Technique with Iterative LearningKwang Soon Lee, Jinho Lee, Insik Chin, Jinhoon Choi,Sogang University, Korea18499-P3-13Effect of Ultrasound on Recrystallization of Nitro CompoundHo-Yeon Lee, Kee-Kahb Koo, Sogang University, KoreaGio-Bin Lim, The University of Suwon, KoreaWon-Bok Jeong, Sun-Hwan Kim, Hanwha Corporation, KoreaHyoun-Soo Kim, Bang-Sam Park,Agency for Defence Development, Korea18539-P3-14Crystal Growth of Calcium Sulfate Dihydrate on Enamel SurfaceHee-Chun Eun, Kee-Kahb Koo, Sogang University, KoreaHo-Nam Lim, Kyung-Hee University, Korea18579-P3-15Application of Quaternary Ammonium Salts in the Synthesis ofPolymers Containing SiliconeJeong-Yeol Moon, Han-Jin Jang, Kyung-Hoon Kim, Sek-Eun Na,Dae Won Park, Jin-Kook Lee, Pusan National University, Korea18619-P3-16Electrochemical Surface Treatment of Carbon Fibersto Enhance Interfacial AdhesionMun-Han Kim, Soo-Jin Park, Jae-Rock Lee,Korea Research Institute of Chemical Technology, Korea9-P3-17Properties of Carbon-Carbon Composites Produc

Nitride (TiN) Metal-Organic Chemical Vapor Deposition (MOCVD) Ju-Young Yun, Shi-Woo Rhee, Pohang University of Science and Technology, Korea SESSION 1G : Topics on Materials Science II 9-1G-IL [Invited Lecture] 1473 Toughening of the Thermoplastic Modified Thermosets Having Morphology Spectrum Y. S. Kim, H. S. Min, S. C. Kim, Korea Advanced .

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