3. CHEMICAL AND PHYSICAL INFORMATION 3.1 CHEMICAL IDENTITY

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FUEL OILS1053. CHEMICAL AND PHYSICAL INFORMATION3.1 CHEMICAL IDENTITYInformation regarding the chemical identity of fuel oils is located in Table 3-l. Information on thecomposition of selected fuel oils, specifically fuel oil no. 2 and kerosene, is presented in Table 3-2.All of the fuel oil classes discussed in this Profile are refined from crude petroleum and may becategorized as either a distillate fuel or a residual fuel depending on the method of production. Fueloils no. 1 and no. 2 are distillate fuels which consist of distilled process streams. Residual fuel oilssuch as fuel oil no. 4 are residues remaining after distillation or cracking, or blends of such residueswith distillates (IARC 1989). Diesel fuels are approximately similar to fuel oils used for heating (fueloils no. 1, no. 2, and no. 4). All fuel oils consist of complex mixtures of aliphatic and aromatichydrocarbons. The aliphatic alkanes (paraffins) and cycloalkanes (naphthenes) are hydrogen saturatedand compose approximately 80-90% of the fuel oils. Aromatics (e.g., benzene) and olefins (e.g.,styrene and indene) compose 10-20% and l%, respectively, of the fuel oils. Fuel oil no. 1 (straightrunkerosene) is a light distillate which consists primarily of hydrocarbons in the C9—C16 range; fuel oilno. 2 is a heavier, usually blended, distillate with hydrocarbons in the C11-C20 range. Straight-rundistillates may also be used to produce fuel oil no. 1 and diesel fuel oil no. 1. Diesel fuel no. 1 andno. 2 are similar in chemical composition to fuel oil no. 1 and fuel oil no. 2, respectively, with theexception of the additives. Diesel fuels predominantly contain a mixture of C10 through C19hydrocarbons, which include approximately 64% aliphatic hydrocarbons, l-2% olefinic hydrocarbons,and 35% aromatic hydrocarbons (Air Force 1989). Jet fuels are based primarily on straight-runkerosene, as well as additives. All of the above fuel oils contain less than 5% polycyclic aromatichydrocarbons. Fuel no. 4 (marine diesel fuel) is less volatile than diesel fuel no. 2 and may contain upto 15% residual process streams, in addition to more than 5% polycyclic aromatic hydrocarbons (IARC1989). Residual fuel oils are generally more complex in composition and impurities than distillate fueloils; therefore, a specific composition cannot be determined (Air Force 1989). Sulfur content inresidual fuel oils has been reported to be from 0.18% to 4.36% by weight.

FUEL OILS108CHEMICAL AND PHYSICAL INFORMATION3.2 PHYSICAL AND CHEMICAL PROPERTIESInformation regarding the physical and chemical properties of fuel oils is located in Table 3-3.

CHEMICAL AND PHYSICAL INFORMATION 3.1 CHEMICAL IDENTITY Information regarding the chemical identity of fuel oils is located in Table 3-l. Information on the composition of selected fuel oils, specifically fuel oil no. 2 and kerosene, is presented in Table 3-2.

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