Thermo Scientific Orion Star A111 Benchtop And Star A121 .

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Thermo Scientific Orion Star A111 Benchtop andStar A121 Portable pH MetersReference Guide

Ross and the COIL trade dress are trademarks of Thermo Fisher Scientific, Inc. andits subsidiaries.AQUAfast, AQUASensors, BOD AutoEZ, ionplus, KNIpHE, LogR, No Cal, ORION, perpHect,PerpHecT, pHISA, pHuture, Pure Water, Sage, ROSS, ROSS Ultra, Sure-Flow, Titrator PLUS, andTURBO2 are registered trademarks of Thermo Fisher Scientific, Inc. and its subsidiaries.A , All in One, Aplus, AUTO-BAR, AUTO-CAL, Auto-ID, AUTO-READ, AUTO-STIR,Auto-Test, AutoTration, CISA, digital LogR, DuraProbe, EZ Startup, ISEasy,Low Maintenance Triode, Minimum Stir Requirement, MSR, NISS, Optimum Results, Orion DualStar, Orion Star, SAOB, SMART AVERAGING, SMART STABILITY, Star LogR, Star Navigator 21,Stat Face, Triode are trademarks of Thermo Fisher Scientific, Inc. and its subsidiaries.Guaranteed Success and The Technical Edge are service marks of Thermo Fisher Scientific, Inc.and its subsidiaries. 2011 Thermo Fisher Scientific Inc. All rights reserved. All trademarks are the property ofThermo Fisher Scientific, Inc. and its subsidiaries.The specifications, descriptions, drawings, ordering information and part numbers within thisdocument are subject to change without notice.This publication supersedes all previous publications on this subject.

Thermo Scientific Orion Star A111 Benchtop and Star A121 Portable pH MetersTable of ContentsChapter 1Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1Chapter 2Meter Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3Connections . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Display Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Keypad Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Meter Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chapter 33455Meter Setup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7Navigating the Setup Menu . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7Setup Examples. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10Automatic pH Buffer Recognition Selection . . . . . . . . . . . .10Read Type Selection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10Reviewing pH Calibration Slope Data . . . . . . . . . . . . . . . . .10Chapter 4Calibration and Measurement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11pH Calibration and Measurement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11pH Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11pH Measurement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11mV Measurement and RmV & ORP Calibration and Measurement. . . . . . . . . . 12mV Measurement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12RmV and ORP Calibration . . . . . . . . . . . . . . . . . . . . . . . . . .12RmV and ORP Measurement . . . . . . . . . . . . . . . . . . . . . . .12Temperature Measurement and Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13Temperature Measurement. . . . . . . . . . . . . . . . . . . . . . . . .13Temperature Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . .13Chapter 5Data Storage and Review . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15Manual Datalog with Continuous Read Mode . . . . . . . . . . . . . . . . . . . . . . . . . . .Automatic Datalog with AUTO-READ Mode. . . . . . . . . . . . . . . . . . . . . . . . . . . .Viewing the Data from the Last Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Viewing Stored Readings (the Data Log) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chapter 6Customer Services . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17Meter Error Codes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Troubleshooting Guide. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Assistance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Warranty and Registration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .WEEE Compliance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Declaration of Conformity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Meter Specifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Ordering Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Chapter 7151516161718181818192021Appendix . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23Automatic pH Buffer Recognition Feature . . . . . . . . . . . . . .23Electrode Condition Icon . . . . . . . . . . . . . . . . . . . . . . . . . . .23Notes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24

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Chapter 1 IntroductionThank you for your purchase of the Orion Star A111 benchtop pH or Star A121 portable pH meter. These metersare capable of measure pH, raw millivolts (mV), relative millivolts (Rmv), oxidation-reduction potential (ORP) andtemperature.The Orion Star A111 benchtop pH meters are IP54-rated. The Orion Star A121 portable pH meters feature awaterproof, IP67-rating.Please read this reference guide thoroughly. Any use outside of these instructions may invalidate your warranty andcause permanent damage to the meter.Thermo Scientific Orion Star A111 Benchtop and Star A121 Portable pH Meters1

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Chapter 2 Meter OverviewConnections1. Power source:a.Power adapter (included with Orion Star A111 benchtop pH meters, sold separately for Star A121portable pH meters) – Select the appropriate wall socket plug. Slide off the clear plastic cover, and slideon the plug plate into the groove on the back of the adapter.b.Batteries (included with and factory installed on Star A121 portable meters, sold separately for StarA111 benchtop meters) – Select four AA batteries. Confirm that the meter is off and remove the batterycompartment cover.To remove the battery compartment cover:i. Loosen the screws.ii. Release the top portion of the battery compartment from the meter (using a coinor your finger.)iii. Release the bottom portion of the battery compartment (using a coinor your finger).Insert batteries as shown in the battery compartment housing.Orion Star A111 BenchtopOrion Star A121 PortableRemove screwsPush down on tab and lift thebattery cover2. Prepare the pH electrode according tothe electrode instructions.3. Connect the appropriate items aslabeled on the meter and as shown infigure 1.Figure 1Thermo Scientific Orion Star A111 Benchtop and Star A121 Portable pH Meters3

Display InformationDisplay IconDescriptionMEASIndicates that the meter is in the measurement mode.SETUPIndicates that the meter is in setup mode.CALIndicates that the meter is the calibration mode.MANShown when a manual calibration is being done and complete.AUTOShown when using automatic buffer calibration (default setting) and has been completed.Shows the battery status (more bars more power remaining).Blinks when power is low and the battery needs to be changed.Batteries included with and factory installed in the Orion Star A121 portable pH meter.)Shown when the meter is running on AC power.(Adapter included with the Orion Star A111 benchtop pH meter.)Shown when the meter is on AUTO-READ mode. Default setting. AR and unit of measurement will blink until thereading is stable. When the reading is stable it is held on the screen and AR is lit. Pressto take anew reading.READY2,4,7,9,10,12Unit of measurement will blink until the reading is stable. When the reading is stable, READY is lit.Buffer points that have been calibrated are displayed as follows:Displayed Buffer Value24791012Calibrated USA Buffer Value (at 25 C)1.684.017.00-10.0112.46Calibrated DIN Buffer Value (at 25 C)1.684.016.869.18--Appears after a complete calibration.Shows the electrode condition. If the icon has a slash through it, the electrode condition is bad. Consult theelectrode user guide.Displayed when a reading is stored into the memory.Displayed when viewing stored readings.SecondarydisplayShows temperature reading in measurement mode and setup menu in setup mode.Primary displayLarger, lower display shows measured value in selected mode.InstructionsLocated below the primary display. These phrases aid in the setup menu and calibration modes.4Thermo Scientific Orion Star A111 Benchtop and Star A121 Portable pH Meters

Keypad InformationIn the measurement screen: Press to take a measurement.In the setup screen: Press to escape the setup menu.In the calibration screen: Press to abort calibration.Press to turn the meter on or off.In the measurement screen:Press to switch between modes.In the setup screen:Press to confirm the selection.Press to enter the calibration mode.Press to enter the setup mode.In the measurement screen:Press to store the data on the screen in continuousread mode and with data logging on.In the setup screen:Press to scroll up in the list of options.In the measurement screen:Press to see the stored data.In the setup screen:Press to scroll down in the list of options.Meter MaintenanceFor routine meter maintenance, dust and wipe the meter with a damp cloth. If necessary, warm water or a mild waterbased detergent can be used. Meter maintenance can be performed on a daily, weekly or monthly basis, as required bythe environment in which the meter is operated. Immediately remove any spilled substance from the meter using theproper cleaning procedure for the type of spill.Thermo Scientific Orion Star A111 Benchtop and Star A121 Portable pH Meters5

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Chapter 3 Meter SetupPressingwill take you to the setup menu.Navigating the Setup MenuA complete chart showing the main setup levels and submenus is shown after these steps.1. In the setup menu, press2. Pressoruntil the desired main setup level is shown on the top line.to enter into the submenu options.3. For main setup options with more than one submenu:1.0 Configuration3.0 Temperature Settings6.0 Calibration Dataa.Pressorb.Pressto enter into the submenu.c.Pressord.Pressto save your selection.until the desired submenu is shown.until the desired option is shown.For main setup options with one submenu:2.0 General Meter Setup4.0 Read Type5.0 Datalog Clear7.0 Factory Reseta.Pressorb.Pressto save your selection.4. Pressuntil the desired option is shown.to exit the setup menu and return to measurement mode.Thermo Scientific Orion Star A111 Benchtop and Star A121 Portable pH Meters7

Meter SetupSetupMenuLevelSecondary Primary figurationSelect measurement resolution and buffer setSubmenu RES0.1, 0.01MeasurementResolution0.01 is the default.Submenu CALAUTO, MANTo select AUTO orMANUAL calibrationNote: If CAL AUTO is selected, then go to BUF submenu.Submenu BUFUSA, DINBuffer Set forAutomatic pH BufferRecognitionUSA buffers are: 1.68, 4.01, 7.00, 10.01 & 12.46. DINbuffers are 1.68, 4.01, 6.86 & 9.18. USA buffers are thedefault.MainGENGeneral Meter SetupAutomatic meter shut-offSubmenu AUTOON, OFFAutomatic MeterShut-OffTo save battery life, the meter will turn off after 15minutes without any key presses. On is the defaultsetting.MainTEMPTemperature SettingsSelect temperature units and the temperature used formanual temperature compensationSubmenu UNITDEGC, DEGFTemperature UnitThe default setting is for temperature readout to bedisplayed in C.Submenu DEGC orDEGF-5.0 to 105.0Manual TemperatureCompensation ValueThis value is used when there is no ATC probeconnected, and can be set with the meter’s temperatureranges. The temperature unit for this value will matchthe temperature unit already selected. The defaultsetting is 25.0 C.Submenu READAUTO, CONTAUTO is for AUTOREAD. CONT is forcontinuous read.In AUTO-READ mode, the meter will display themeasurement as it stabilizes and lock and hold theto take ameasurement when it is stable. Pressnew measurement.2.03.0In Continuous read mode, the meter will continuouslymeasure and update the display. The unit of measure willflash. When the reading has been stable, “READY” willstop flashing. The default setting is AUTO-READ.Main5.0LOGDatalog ClearSubmenu DATAON, OFFTo enable data storage The default is off.Submenu DELNO, LAST, ALLClears any storedreadings in thedatalog.The default is no."NO" does not delete any readings."LAST" deletes only the last reading."ALL" deletes all of the logged data.MainCALCalibration DataAllows for review and clearing of saved data.80.0 to 120.0Slope InformationThis is the slope data from the last calibration.SLP.2 and SLP.A (average slope) will only showif 3 points are calibrated.6.0Submenu SLP.1,SLP.2,SLP.APress8andto scroll between them.Thermo Scientific Orion Star A111 Benchtop and Star A121 Portable pH Meters

Meter Setup (continued)SetupMenuLevelSecondary Primary DisplayDisplaySubmenu BUF.1,BUF.2,Varies according tobuffers used.DescriptionInformationCalibrated pH BufferValuesShows the buffer values used in the last calibration.Press theandarrows to scroll betweenthem.BUF.3Note: It will only show the values used. For example,if there was only one calibrated value, BUF.2 andBUF.3 will not show.Submenu CLRNO, YESClears thecalibration data.MainRSTFactory ResetNO, YESReturns all metersettings to thefactory defaults anddeletes all storeddata (calibration anddatalog).7.0Submenu RSTThe default is no.The default is no. Before selecting yes, please makesure any data that you would like to keep has beenrecorded.Thermo Scientific Orion Star A111 Benchtop and Star A121 Portable pH Meters9

Setup ExamplesAutomatic pH Buffer Recognition Selection1. In pH measurement mode, press.2. Presstwice.3. Pressto select automatic buffer recognition (AUTO) or manual calibration (MAN).4. If automatic buffer recognition was chosen, press. Pressto select USA or DIN buffer setfor automatic buffer recognition.5. Pressto save configuration andto return measurement mode.Read Type Selection1. In measurement mode, press2. PressPress3. Press.in setup until “4.0” is shown on the top line and “READ” is shown on the lower line.orto select the measurement mode:CONT ContinuousAUTO AUTO-READ 4. Pressto save selection. Press thekey to return to measurement mode.Note: In AUTO-READ mode, the meter will display the measurement as it stabilizes and lock and hold themeasurement when it is stable. AR and unit of measure will blink until the reading is stable. When thereading is stable it is held on the screen and AR is lit. Pressto take a new measurement.In Continuous read mode, the meter will continuously measure and update the display. The unit ofmeasure will flash. When the reading is stable, “READY” will appear. This read type is useful whenperforming an experiment that requires continuous measurements to be taken, regardless of themeasurement stability.Reviewing pH Calibration Slope Data1. In pH measurement mode, press. Pressfive times so that "6.0" is on the top, secondarydisplay and "CAL" is on the larger, primary display.2. Pressto view slope. If a 3-point calibration was done, presssegment, and3. Press10to view the second slopeagain to display the average slope (SLP.A).to return to measurement mode.Thermo Scientific Orion Star A111 Benchtop and Star A121 Portable pH Meters

Chapter 4 Calibration and MeasurementpH Calibration and MeasurementpH Calibration1. Pressto display pH for pH measurement mode.2. Select fresh pH buffers. If calibrating more than one point (highly recommended), select pH buffers that bracket theexpected sample pH and are at least one pH unit apart.3. Press. Rinse the electrode (and ATC probe, if separate) with distilled water, blot dry and place into the buffer.4. Wait for “READY” to appear.a.With automatic buffer recognition (default, AUTO CAL appears at the top of the display): to calibrateadditional points, repeat steps 3 and 4a.b.With manual calibration (MAN CAL appears at the top of the display): pressorto set value.To calibrate additional points repeats steps 3 and 4b.5. When finished, pressa.to save and end calibration.For one-point calibration, pressorto edit the slope and press the enter key to save andreturn to measurement mode.b.For two- or three-point calibration, the slope will be displayed and the meter will automatically proceedto measurement mode.pH Measurement1. Prepare the pH electrode according to the electrode instructions. Pressto display pH for pH measurement mode.2. Rinse the electrode (and ATC probe, if separate) with distilled water, blot dry and place into the sample.3. If the meter is in AUTO-READ mode (meter default) press. If the meter is in continuous read mode, the meterwill immediately start taking readings. Record the pH and temperature of the sample when “READY” is displayed and“pH” stops blinking.Note: If in AUTO-READ mode and memory storage is enabled, the reading will automatically be stored when the “AR”appears. If in continuous read mode and memory storage is enabled, pressto store into the meter’s memory.4. Remove the electrode (and ATC probe, if separate) from the sample, rinse with distilled water, and blot dry. To continuetaking measurements , place electrode (and ATC probe, if separate) into the next sample and repeat steps 3 and 4.5. When finished measuring all samples, store electrode according to electrode instructions.Thermo Scientific Orion Star A111 Benchtop and Star A121 Portable pH Meters11

mV Measurement and RmV & ORP Calibration and MeasurementmV Measurement1. In the measurement mode, pressto display mV.2. Rinse the electrode (and ATC probe, if separate) with distilled water, blot dry and place into the sample.3. If the meter is is AUTO-READ mode (meter default), press.If the meter is in continuous read mode, the meter will immediately start taking readings.Record the mV reading and temperature of the sample when “READY” is displayed and “mV” stops blinking.Note: If in AUTO-READ mode and memory storage is enabled, the reading will automatically be stored when the"AR" icon appears. If in continuous read mode and memory storage is enabled, pressto store the readinginto the meter's memory.4. Remove the electrode (and ATC probe, if separate) from the sample, rinse with distilled water, blot dry. To continuetaking measurements repeat steps 2 through 4.5. When finished measuring all samples, store electrode according to electrode instructions.RmV and ORP Calibration1. In the measurement mode, pressto display RmV.2. When the electrode(s) are ready, press.blot dry and place into the standard.Rinse the electrode (and ATC probe, if separate) with distilled water,3. Wait for “READY” to stop flashing. Press4. When finished, pressorkeys to set the value.to save and end calibration.RmV and ORP Measurement1. In the measurement mode, pressto display RmV.2. Rinse the electrode (and ATC probe, if separate) with distilled water, blot dry

4 Thermo Scientific Orion Star A111 Benchtop and Star A121 Portable pH Meters Display Information Display Icon Description MEAS Indicates that the meter is in the measurement mode. SETUP Indicates that the meter is in setup mode. CAL Indicates that the meter is the calibration mode. MAN Shown when a manual calibration is being done and complete. AUTO Shown when using automatic buffer .

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