Alcohol 190 Proof USP MSDS - Qualityexcipients

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Alcohol 190 Proof USP MSDS

SAFETY DATA SHEETPreparation Date: 9/12/2013Revision Date: 4/15/2015Revision Number: G4Product identifierProduct code:Product Name:Other means of identificationSynonyms:CAS #:RTECS #CI#:ET108ALCOHOL, 190 PROOF, USPAlcool ethylique 190 proof (French)Ethanol 190 proofEthanol, undenatured 190 proof64-17-5KQ6300000Not availableRecommended use of the chemical and restrictions on useSolvent. Perfuming agent. In pharmaceuticals. Inks. In organic synthesis. InRecommended use:beverages.Uses advised againstNo information availableSupplier:Order Online At:Spectrum Chemicals and Laboratory Products, Inc.14422 South San Pedro St.Gardena, CA 90248(310) 516-8000https://www.spectrumchemical.comEmergency telephone numberChemtrec 1-800-424-9300Contact Person:Contact Person:Martin LaBenz (West Coast)Ibad Tirmiz (East Coast)2. HAZARDS IDENTIFICATIONClassificationThis chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)Serious eye damage/eye irritationReproductive toxicitySpecific target organ toxicity (single exposure)Specific target organ toxicity (repeated exposure)Flammable liquidsCategory 2Category 1ACategory 3Category 1Category 2Label elementsProduct code: ET108Product name: ALCOHOL, 190PROOF, USP1 / 13

DangerHazard statementsCauses serious eye irritationMay damage fertility or the unborn childMay cause respiratory irritation. May cause drowsiness or dizzinessCauses damage to organs through prolonged or repeated exposureHighly flammable liquid and vaporHazards not otherwise classified (HNOC)Not ApplicableOther hazardsCauses mild skin irritationCan burn with an invisible flamePrecautionary Statements - PreventionObtain special instructions before useDo not handle until all safety precautions have been read and understoodWash face, hands and any exposed skin thoroughly after handlingWear protective gloves/protective clothing/eye protection/face protectionDo not breathe dust/fume/gas/mist/vapors/sprayDo not eat, drink or smoke when using this productUse only outdoors or in a well-ventilated areaKeep away from heat/sparks/open flames/hot surfaces. — No smokingKeep container tightly closedGround/bond container and receiving equipmentUse explosion-proof electrical/ventilating/lighting/ .? /equipmentUse only non-sparking toolsTake precautionary measures against static dischargeKeep coolPrecautionary Statements - ResponseIF exposed or concerned: Get medical advice/attentionIn case of fire: Use CO2, dry chemical, or foam to extinguish.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eyeirritation persists: Get medical advice/attention.If skin irritation occurs: Get medical advice/attentionIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.Precautionary Statements - StorageStore locked upStore in a well-ventilated place. Keep container tightly closedPrecautionary Statements - DisposalDispose of contents/container to an approved waste disposal plantProduct code: ET108Product name: ALCOHOL, 190PROOF, USP2 / 13

3. COMPOSITION/INFORMATION ON INGREDIENTSComponentsEthyl Alcohol 200 proof64-17-5Water7732-18-5CAS-No.64-17-5Weight %95Trade Secret*7732-18-55*4. FIRST AID MEASURESFirst aid measuresGeneral Advice:Poison information centers in each State capital city can provide additionalassistance for scheduled poisons (13 1126)Skin Contact:Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention. If skin irritation persists, call a physician.Eye Contact:Flush eye with water for 15 minutes. Get medical attention.Inhalation:Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.Get medical attention.Ingestion:Do not induce vomiting without medical advice. Never give anything by mouth to anunconscious person. Consult a physician if necessary.Most important symptoms and effects, both acute and delayedCauses eye irritation. May cause skin irritation. May cause irritation of respiratory tract.SymptomsDyspnea (Difficulty breathing and shortness of breath). Central nervous system effects.Dizziness. Drowsiness. Headache. Ataxia. Staggering gait. Nausea. Vomiting. May causecardiovascular effects.Indication of any immediate medical attention and special treatment neededTreat symptomaticallyNotes to Physician:Protection of first-aidersFirst-Aid Providers: Avoid exposure to blood or body fluids. Wear gloves and other necessary protective clothing. Dispose ofcontaminated clothing and equipment as bio-hazardous waste5. FIRE-FIGHTING MEASURESExtinguishing MediaSuitable Extinguishing Media:Carbon dioxide (CO2). Dry chemical. Alcohol-resistant foam.Water spray.Unsuitable Extinguishing Media:Do not use a solid (straight) water stream as it may scatterand spread fire.Specific hazards arising from the chemicalHazardous Combustion Products:Product code: ET108Carbon monoxide; Carbon dioxideProduct name: ALCOHOL, 190PROOF, USP3 / 13

Flammable. May be ignited by heat, sparks or flames.Material can burn with invisible flame. Vapor may travelconsiderable distance to source of ignition and flash back.Vapors may form explosive mixtures with air. Most vaporsare heavier than air. They will spread along the ground andcollect in low or confined areas (sewers, basements, tanks).Container explosion may occur under fire conditions or whenheated. Fire may produce irritating, corrosive and/or toxicgases.Specific hazards:Special Protective Actions for FirefightersSpecific Methods:Water mist may be used to cool closed containers. Forlarger fires, use water spray or fog. Cool containers withflooding quantities of water until well after fire is out.Special Protective Equipment for Firefighters:As in any fire, wear self-contained breathing apparatuspressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency proceduresPersonal Precautions:Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid contactwith skin, eyes and clothing. Use personal protective equipment. Remove all sources ofignition. Pay attention to flashback. Take precautionary measures against static discharges. Allequipment used when handling the product must be grounded. Use spark-proof tools andexplosion-proof equipment. In case of large spill, water spray or vapor suppressing foam maybe used to reduce vapors, but may not prevent ignition in closed spaces.Environmental precautionsPrevent further leakage or spillage if safe to do so. Prevent product from enteringdrains. Prevent entry into waterways, sewers, basements or confined areas.Methods and material for containment and cleaning upMethods for containmentStop leak if you can do it without risk. Absorb spill with inert material (e.g. vermiculite,dry sand or earth), then place in a suitable chemical waste container. In case of largespill, dike if needed. Dike far ahead of liquid spill for later disposal.Methods for cleaning upUse appropriate tools to put the spilled material in a suitable chemical waste disposalcontainer. Use only non-sparking tools. Clean contaminated surface thoroughly.7. HANDLING AND STORAGEPrecautions for safe handlingTechnical Measures/Precautions:Provide sufficient air exchange and/or exhaust in work rooms. Remove all sources of ignition. To avoid ignition ofvapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep away fromincompatible materials.Safe Handling Advice:Wear personal protective equipment. Use only in well-ventilated areas. Avoid contact with skin, eyes and clothing.Keep away from heat and sources of ignition. Do not breathe vapors or spray mist. Do not ingest. When using donot smoke. Handle in accordance with good industrial hygiene and safety practice.Conditions for safe storage, including any incompatibilitiesProduct code: ET108Product name: ALCOHOL, 190PROOF, USP4 / 13

Technical Measures/Storage Conditions:Hygroscopic. Keep container tightly closed in a dry and well-ventilated place. Store at room temperature in theoriginal container. Sensitive to light. Store in light-resistant containers. Keep away from heat and sources ofignition. Store in a segrated and approved area. Store away from incompatible materials.Incompatible Materials:Oxidizing agents. Acids. Alkali Metals. Halogens. caustics. isocyanates. Metals. Bases. Acid anhydrides. Acidchlorides. Hydrazine.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parametersNational occupational exposure limitsUnited StatesComponentsEthyl Alcohol 200 proof - 64-17-5OSHA1000 ppm TWA1900 mg/m3 TWANoneNIOSH1000 ppm TWA1900 mg/m3 TWANoneACGIH1000 ppm STELAIHA WHEELNoneNoneNoneWater - 7732-18-5CanadaComponentsEthyl Alcohol 200 proof - 64-17-5Alberta1000 ppm TWA1880 mg/m3 TWANoneBritish Columbia1000 ppm STELOntario1000 ppm STELNoneNoneQuebec1000 ppm TWAEV1880 mg/m3 TWAEVNoneWater - 7732-18-5Australia and MexicoComponentsEthyl Alcohol 200 proof64-17-5Water7732-18-5Australia1000 ppm TWA1880 mg/m3 TWANoneMexico1000 ppm TWA1900 mg/m3 TWANoneAppropriate engineering controlsEngineering measures to reduce exposure:Ensure adequate ventilation. Provide exhaust ventilation orother engineering controls to keep the airborneconcentrations of vapors and mist below their respectivethreshold limit value.Individual protection measures, such as personal protective equipmentPersonal Protective EquipmentEye protection:Goggles. Safety glasses with side-shields.Skin and body protection:Chemical resistant apron. Long sleeved clothing. Gloves.Respiratory protection:Vapor respirator. Be sure to use an approved/certified respirator or equivalent.Hygiene measures:Avoid contact with skin, eyes and clothing. When using, do not eat, drink or smoke.Wash hands before breaks and immediately after handling the product.9. PHYSICAL AND CHEMICAL PROPERTIESProduct code: ET108Product name: ALCOHOL, 190PROOF, USP5 / 13

9. PHYSICAL AND CHEMICAL PROPERTIESPhysical state:Liquid.Appearance:No information availableTasteOdor:Pleasant. Alcoholic. Mild. Ethereal. Like Pungent. Burning.wine or whiskey.Color:Clear. Colorless.Molecular/Formula weight:46.07Formula:C2-H5-OHFlash point ( C):17Flashpoint ( C/ F):17 C/63 FFlash Point Tested according to:Closed cupLower Explosion Limit (%):3.3%Upper Explosion Limit (%):19%Autoignition Temperature ( C/ F):363 C/685.4 FpH:No information availableMelting point/range( C/ F):-114.1-117.3 C/-173.38-179.14 FBoiling point/range( C/ F):79 C/174.2 FDecomposition temperature( C/ F):No information availableBulk density:No information availableSpecific gravity:0.8 @ 20 CVapor pressure @ 20 C (kPa):5.93Density (g/cm3):No information availableEvaporation rate:No information availableVapor density:1.59VOC content (g/L):789Odor threshold (ppm):5-10 (recognition)84 (tolerance)Partition coefficient(n-octanol/water):No information availableViscosity:No information availableMiscibility:Miscible with waterMiscible with AcetoneMiscible with EtherMiscible with BenzeneMiscible with glacial Acetic AcidMiscible with many organic solventsSolubility:Very soluble in water10. STABILITY AND REACTIVITYReactivityIt can react vigorously, violently or explosively with oxidizersWhen Ethanol comes in contact with Platinum or Sodium, it liberates flammable hydrogen gasIt can react vigorously or explosively with acid hydrides or acid chloridesIt reacts with alkali metals to liberate flammable hydrogen gasIt reacts with ammona silver nitrate to form silver nitride and silver fulminateIt reacts with acetyl bromide to evolve hydrogen bromideEthyl alcohol can react with freshly cut/etched/scratched aluminum with the evolution of heat and release of hydrogen gas. The Ethylalcohol has to be on the aluminum surface as it is being cut/scratched/etchedChemical stabilityStability:Stable under recommended storage conditionsPossibility of Hazardous Reactions: Hazardous polymerization does not occurConditions to avoid:Heat. Ignition sources. Incompatible materials.Incompatible Materials:Oxidizing agents. Acids. Alkali Metals. Halogens. caustics. isocyanates. Metals.Bases. Acid anhydrides. Acid chlorides. Hydrazine.Product code: ET108Product name: ALCOHOL, 190PROOF, USP6 / 13

Hazardous decomposition products: Carbon monoxide. Carbon dioxide. When heated to decomposition it emits acrid smoke andirritating fumes.Other InformationCorrosivity:No information availableSpecial Remarks on Corrosivity: No information available11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposurePrincipal Routes of Exposure:Ingestion. Skin. Eyes. Inhalation.Acute ToxicityThe following values are calculated based on chapter 3.1 of the GHS document .7432mg/kgATEmix (oral)131.26mg/lATEmix (inhalation-vapor)Component InformationEthyl Alcohol 200 proof - 64-17-5LD50/oral/rat 7060 mg/kg Oral LD50 RatLD50/oral/mouse 3450 mg/kgLD50/dermal/rabbit No information availableLD50/dermal/rat No information availableLC50/inhalation/rat 124.7 mg/L Inhalation LC50 Rat 4 hLC50/inhalation/mouse 39000 mg/m34 hOther LD50 or LC50information 60000 ppm Inhalation LC50 Mouse 1 h5900 mg/m3Inhalation LC50 Rat 6 h20000 ppm Inhalation LC50 Rat 10 h5560 mg/kg Oral LD50 Guinea Pig6300 mg/kg Oral LD50 RabbitWater - 7732-18-5LD50/oral/rat 90 mL/kg Oral LD50 RatLD50/oral/mouse No information availableLD50/dermal/rabbit No information availableLD50/dermal/rat No information availableLC50/inhalation/rat No information availableLC50/inhalation/mouse No infomation availableOther LD50 or LC50information No information availableProduct InformationLD50/oral/rat VALUE- Acute Tox Oral No information availableLD50/oral/mouse Value - Acute Tox Oral No information availableLD50/dermal/rabbitVALUE-Acute Tox Dermal No information availableProduct code: ET108Product name: ALCOHOL, 190PROOF, USP7 / 13

LD50/dermal/ratVALUE -Acute Tox Dermal No information availableLC50/inhalation/ratVALUE-Vapor No information availableVALUE-Gas No information availableVALUE-Dust/Mist No information availableLC50/Inhalation/mouseVALUE-Vapor No information availableVALUE - Gas No information availableVALUE - Dust/Mist No information availableSymptomsSkin Contact:Mildly to moderately irritating to the skin.Eye Contact:Causes serious eye irritation.InhalationMay cause irritation of respiratory tract. Symptoms may include coughing andshortness of breath. May cause nausea, and headache. It may affectbehavior/central nervous system (ataxia, general anesthetic, drowsiness). May affectrespiration (respiratory depression). Inhalation of high concentrations of vapor maycause anesthetic effects. Inhalation of high concentrations of vapors may causedizziness or suffocation. May affect the brain.Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Maycause gastritis. May cause loss of appetite. May cause flushed skin. May affect thecardiovascular system (change in heart rate). May affect the cardiovascular system(hypotension or hypertension, tachycardia, dysrhythmias). It may affectbehavior/central nervous system (excitation, mild euphoria, excessive talking,fatigue, headache, dizziness, drowsiness, staggaring gait, ataxia, hallucinations,slurred speech, amnesia, confusion, release of inhibitions, agressive behavior,convulsions, coma). May affect respiration (dyspnea, respiratory depression). It mayaffect the brain. May affect liver . May affect the blood. May affect the endocrinesystem. It may affect the spleen. May affect urinary system (kidneys).IngestionAspiration hazardNo information availableDelayed and immediate effects as well as chronic effects from short and long-term exposureChronic ToxicityProlonged or repeated skin contact may cause dermatitis, and dryness and crackingof the skin. Prolonged or repeated ingestion may affect behavior/central nervoussystem. Prolonged or repeated ingestion may affect metabolism (cause anorexia,weight loss). Prolonged or repeated ingestion may affect the liver (fatty liverdegeneration, cirrhosis of the liver. Prolonged or repeated ingestion may affect thecardiovascular system.Sensitization:No information availableMutagenic Effects:May affect genetic materialExperiments with bacteria and/or yeast have shown mutagenic effectsCarcinogenic effects:May cause cancer based on animal test data. Equivocal tumorigenic agent byRTECS criteria.Product code: ET108Product name: ALCOHOL, 190PROOF, USP8 / 13

ComponentsACGIH CarcinogensIARCEthyl Alcohol 200 proofA3 ConfirmedAnimal Carcinogenwith UnknownRelevance toHumansWaterNot listedNTPGroup 1 Not listedMonograph100E [2012] inalcoholicbeveragesMonograph 96[2010] inalcoholicbeveragesNot listedNot listedOSHA HCS CarcinogensPresentAustralia - Prohibited Australia - ncesNot listedNot listedNot listedNot listedNot listedACGIH (American Conference of Governmental Industrial Hygienists)IARC (International Agency for Research on Cancer)NTP (National Toxicology Program)OSHA (Occupational Safety and Health Administration of the US Department of Labor)Reproductive toxicityMay damage fertility or the unborn childReproductive Effects:Developmental Effects:Causes adverse reproductive effects.May cause adverse developmental effectsMay cause harm to the unborn childCauses birth defects (teratogenic effects)Teratogenic Effects:Specific Target Organ ToxicitySTOT - single exposureSTOT - repeated exposureTarget Organs:respiratory system. central nervous system.Causes damage to organs through prolonged or repeated exposure.Skin. Liver. Central nervous system. Nervous system. Heart.12. ECOLOGICAL INFORMATIONEcotoxicityEcotoxicity effects:Ethyl Alcohol 200 proof - 64-17-5Freshwater Fish Species Data:Water Flea Data:Aquatic environment.12.0 - 16.0 mL/L LC50 Oncorhynchus mykiss 96 h static 113400 - 15100 mg/L LC50 Pimephales promelas 96 h flow-through 1100 mg/L LC50 Pimephales promelas 96 h static 19268 - 14221 mg/L LC50 Daphnia magna 48 h10800 mg/L EC50 Daphnia magna 24 h2 mg/L EC50 Daphnia magna 48 hPersistence and degradability:No information availableBioaccumulative potential:No information availableMobility:No information available13. DISPOSAL CONSIDERATIONSDisposal MethodsProduct code: ET108Product name: ALCOHOL, 190PROOF, USP9 / 13

13. DISPOSAL CONSIDERATIONSWaste from residues / unused products:Waste must be disposed of in accordance with Federal, State and Local regulation.Contaminated packaging:Empty containers should be taken for local recycling, recovery or waste disposalComponentsEthyl Alcohol 200 proofWaterRCRA - F SeriesWastesNoneNoneRCRA - K SeriesWastesNoneNoneRCRA - PSeriesWastesNoneNoneRCRA - U Series WastesNoneNone14. TRANSPORT INFORMATIONDOTUN-No:Proper Shipping Name:Hazard Class:Subsidiary Risk:Packing Group:ERG No:Marine PollutantDOT RQ (lbs):UN1170Ethanol3Not applicableII127No data availableNo information availableTDG (Canada)UN-No:Proper Shipping Name:Hazard Class:Subsidiary Risk:Packing Group:Description:UN1170Ethanol3No information availableIINo information availableADRUN-No:Proper Shipping Name:Hazard Class:Packing Group:Subsidiary Risk:Classification Code:Description:CEFIC Tremcard No:UN1170Ethanol (Ethyl alcohol)3IINo information availableNo information availableNo information availableNo information availableIMO / IMDGUN-No:Proper Shipping Name:Hazard Class:Subsidiary Risk:Packing Group:Description:IMDG Page:Marine PollutantEMS:MFAG:Maximum Quantity:UN1170Ethanol (Ethyl alcohol)3No information availableIINo information availableNo information availableNo information availableF-ENo information availableNo information availableRIDProduct code: ET108Product name: ALCOHOL, 190PROOF, USP10 / 13

14. TRANSPORT INFORMATIONUN-No:Proper Shipping Name:Hazard Class:Subsidiary Risk:Packing Group:Classification Code:Description:UN1170Ethanol (Ethyl alcohol)33IINo information availableNo information availableUN-No:Proper Shipping Name:Hazard Class:Subsidiary Risk:Packing Group:Description:UN1170Ethanol3No information availableIINo information availableUN-No:Proper Shipping Name:Hazard Class:Subsidiary Risk:Packing Group:ERG Code:Description:UN1170Ethanol3No information availableII3LNo information availableICAOIATA15. REGULATORY INFORMATIONInternational InventoriesComponentsEthyl Alcohol 200 proofWaterU.S. TSCA KOREA KECL sent KEPresent35400Japan ENCSCHINA(2)-202Not EINECS-No.Present 200-578-6Present 231-791-2U.S. RegulationsEthyl Alcohol 200 proofMassachusetts RTK: PresentNew Jersey RTK Hazardous Substance List: PresentPennsylvania RTK: PresentMinnesota - Hazardous Substance List: PresentLouisana Reportable Quantity List for Pollutants: Present (listed as Volatile Organic Compounds)California Directors List of Hazardous Substances: PresentFDA - Food Additives Generally Recognized as Safe (GRAS): 21 CFR 184.1293California Prop. 65: Safe Drinking Water and Toxic Enforcement Act of 1986.Chemicals Known to the State of California to Cause Cancer:This product does not contain a chemical requiring a warning under California Prop. 65. (See table below)Chemicals Known to the State of California to Cause Reproductive Toxicity:WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm (See table below)ComponentsCarcinogenDevelopmental ToxicityEthyl Alcohol 200 proofcarcinogen (listed asAlcoholic beverages whenassociated with alcoholabuse)Not Listeddevelopmental toxicity(Ethyl alcohol in alcoholicbeverages)WaterProduct code: ET108Not ListedMale ReproductiveToxicityNot ListedFemale ReproductiveToxicity:Not ListedNot ListedNot ListedProduct name: ALCOHOL, 190PROOF, USP11 / 13

CERCLA/SARAComponentsEthyl Alcohol 200 proofWaterCERCLA - Hazardous Section 302 Extremely Section 302 ExtremelySection 313 Section 313 - Reportingde minimisSubstances and theirHazardousHazardousChemical CategoryReportable Quantities Substances and TPQs Substances and RQsNoneNoneNoneNoneNoneNoneNoneNoneNoneNoneU.S. TSCAComponentsEthyl Alcohol 200 proofWaterTSCA Section 5(a)2 - Chemicals With SignificantNew Use Rules (SNURS)Not ApplicableNot ApplicableTSCA 8(d) -Health and Safety ReportingNot ApplicableNot ApplicableCanadaWHMIS hazard class:B2 Flammable liquidD2B Toxic materialsEthyl Alcohol 200 proofB2 D2BWaterUncontrolled product according to WHMIS classification criteriaCanada Controlled Products Regulation:This product has been classified according to the hazard criteria of the CPR (Controlled Products Regulation) and the MSDS containsall of the information required by the CPR.ComponentsEthyl Alcohol 200 proofWHMIS Ingredient Disclosure List 0.1 %InventoryComponentsEthyl Alcohol 200 proofWaterCanada (DSL)PresentPresentCanada (NDSL)Not ListedNot ListedComponentsCEPA Schedule I - Toxic SubstancesEthyl Alcohol 200 proofWaterNot listedNot listedCEPA - 2010 Greenhouse Gases Subject to ManditoryReportingNot listedNot listedEU ClassificationR-phrase(s)R11 - Highly flammable.S -phrase(s)S 7 - Keep container tightly closed.S16 - Keep away from sources of ignition - No smoking.Product code: ET108Product name: ALCOHOL, 190PROOF, USP12 / 13

ComponentsEthyl Alcohol 200 proofClassificationF; R11Concentration Limits:No informationNo informationWaterSafety PhrasesS7 S16The product is classified in accordance with Annex VI to Directive 67/548/EECIndication of danger:F - Highly flammable.16. OTHER INFORMATIONPreparation Date:Revision Date:Prepared by:9/12/20134/15/2015Sonia OwenDisclaimer:All chemicals may pose unknown hazards and should be used with caution. ThisSafety Data Sheet (SDS) applies only to the material as packaged. If this product iscombined with other materials, deteriorates, or becomes contaminated, it may posehazards not mentioned in this SDS. The physical properties reported in this SDS areobtained from the literature and do not constitute product specifications. Informationcontained herein does not constitute a warranty, whether expressed or implied, as tothe safety, merchantability or fitness of the goods for a particular purpose. SpectrumChemicals & Laboratory Products, Inc. assumes no responsibility for results obtainedor for incidental or consequential damages, including lost profits, arising from the useof these data. No warranty against infringement of any patent, copyright or trademarkis made or implied. It shall be the user's responsibility to develop proper methods ofhandling and personal protection based on the actual conditions of use. While thisSDS is based on technical data judged to be reliable, Spectrum assumes noresponsibility for the completeness or accuracy of the information contained herein.End of Safety Data SheetProduct code: ET108Product name: ALCOHOL, 190PROOF, USP13 / 13

MATERIAL SAFETY DATA SHEETNFPAHMISPersonal Protective EquipmentSee Section 8.1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct code:Product Name:Chemical Name:Synonyms:Recommended use:CAS #:RTECS #Formula:CI#:Supplier:Order Online At:Emergency Telephone Number:Contact Person:Contact Person:ET108ALCOHOL, 190 PROOF, USPNo information availableAlcool ethylique 190 proof (French)Ethanol 190 proofEthanol, undenatured 190 proofSolvent. Perfuming agent. In pharmaceuticals. Inks. In organic synthesis. Inbeverages.64-17-5KQ6300000C2-H5-OHNot availableSpectrum Chemicals and Laboratory Products, Inc.14422 South San Pedro St.Gardena, CA 90248(310) 516-8000https://www.spectrumchemical.comCHEMTREC: 1-800-424-9300Regina Wachenheim (East Coast)Martin LaBenz (West Coast)2. HAZARDS IDENTIFICATIONProduct code: ET108Product name: ALCOHOL, 190PROOF, USP1 / 12

2. HAZARDS IDENTIFICATIONEMERGENCY OVERVIEWDANGER FLAMMABLE!Can burn with an invisible flameWARNING! IRRITANTIrritating to eyesIrritating to skinOdor:Pleasant. Alcoholic. Mild.Ethereal. Like wine or whiskey.Physical state:Liquid.Appearance:No information availableColor:Clear. Colorless.This material is considered hazardous by the OSHA Hazard CommunicationStandard (29 CFR 1910.1200)OSHA Regulatory StatusPOTENTIAL HEALTH EFFECTSPrincipal Routes of Exposure:Ingestion. Skin. Eyes. Inhalation.Acute Potential Health Effects:Skin Contact:Mildly to moderately irritating to the skin.Eye Contact:Causes serious eye irritation.Inhalation:May cause irritation of respiratory tract. May cause central nervous system effects. It may affect the blood. It may affectthe brain. Inhalation of vapors may cause dizziness or suffocation.Ingestion:Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhoea. May cause central nervous systemeffects. May affect respiration. May affect the blood. May affect the liver. It may affect the kidneys. May affect thecardiovascular system. It may affect the brain.Chronic Potential Health Effects:ComponentEthyl Alcohol 200 proof64-17-5 (95)Water7732-18-5 (5)Carcinogen Status:A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans by ACGIHGroup 1 - Carcinogenic to Humans by IARC (for Ethyl alcohol in alcoholic beverages)Present by OSHANot applicableTarget Organs:Skin. Liver. Central nervous system. Nervous system. Heart.Mutagenic Effects:May affect genetic materialExperiments with bacteria and/or yeast have shown mutagenic effectsTeratogenic Effects:Causes birth defects (teratogenic effects)Aggravated Medical Conditions: No information availableSee Section 11 for additional Toxicological InformationProduct code: ET108Product name: ALCOHOL, 190PROOF, USP2 / 12

POTENTIAL ENVIRONMENTAL EFFECTSNo information available3. COMPOSITION/INFORMATION ON INGREDIENTSComponentsCAS-No.Ethyl Alcohol 200 proofWater64-17-57732-18-5Weight %9554. FIRST AID MEASURESGeneral Advice:Poison information centres in each State capital city can provide additionalassistance for scheduled poisons (13 1126)Skin Contact:Wash off immediately with soap and plenty of water removing all contaminatedclothes and shoes. Get medical attention. If skin irritation persists, call a physician.Eye Contact:Flush eye with water for 15 minutes. Get medical attention.Inhalation:Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificialrespiration. Get medical attention.Ingestion:Do not induce vomiting without medical advice. Never give anything by mouth to anunconscious person. Consult a physician if necessary.Notes to Physician:Treat symptomatically5. FIRE-FIGHTING MEASURESFlammable PropertiesFlashpoint ( C/ F):17 C/63 FFlash Point Tested according to:Closed cupLower Explosion Limit (%):Upper Explosion Limit (%):3.3%19%Autoignition Temperature ( C/ F): 363 C/685.4 FSuitable Extinguishing Media:Carbon dioxide (CO2). Dry chemical. Alcohol-resistant foam.Water spray.Unsuitable Extinguishing Media:Do not use a solid (straight) water stream as it may scatterand spread fire.Hazardous Combustion Products:Carbon monoxide; Carbon dioxideProduct code: ET108Product name: ALCOHOL, 190PROOF, USP3 / 12

Specific hazards:FlammableMay be ignited by heat, sparks or flamesMaterial can burn with invisible flameVapor may travel considerable distance to source of ignitionand flash backVapors may form explosive mixtures with airMost vapors are heavier than air. They will spread along theground and collect in low or confined areas (sewers,basements, tanks)Container explosion may occur under fire conditions or whenheatedFire may produce irritating, corrosive and/or toxic gasesSpecial Protective Equipment for Firefighters:As in any fire, wear self-contained breathing apparatuspressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gearSpecific Methods:Water mist may be used to cool closed containers. Forlarger fires, use water spray or fog. Cool containers withflooding quantities of water until well after fire is out.6.

Alcohol 190 Proof USP MSDS. SAFETY DATA SHEET Product identifier Product code: ET108 Product Name: ALCOHOL, 190 PROOF, USP Other means of identification Synonyms: Alcool ethylique 190 proof (French) . Ethyl Alcohol 200 proof 64-17-5 64-17-5 95 * Water 7732-18-5

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USP Reference Standards for USP or NF. section, under Quantitative determinations, the text is revised as follows: ”For the USP Reference Standards where an International Standard (IS) established by the WHO exists, the reference standards documentation will indicate when the USP RS has been established by

Y-site compatible with several IV bag fluids, including: — Water for Injection, USP — 0.9% Sodium Chloride Injection, USP — Lactated Ringer’s Injection, USP — 10% Amino Acid — 5% Dextrose Injection, USP — 5% Dextrose in 0.9% Sodium Chloride Injection, USP — 5% Dextrose in Lactated Ringer’s Injection, USP Titrate DOSE .

2154 PROOF MARKS: GERMAN PROOF MARKS, cont. PROOF MARK CIRCA PROOF HOUSE TYPE OF PROOF AND GUN since 1950 E. German, Suhl repair proof since 1950 E. German, Suhl 1st black powder proof for smooth bored barrels since 1950 E. German, Suhl inspection mark since 1950 E. German, Suhl choke-bore barrel mark PROOF MARKS: GERMAN PROOF MARKS, cont.

toute la chaîne alimentaire, depuis la production primaire jusqu’à l’assiette du consommateur. La Commission du Codex Alimentarius – un lieu de débat où traiter des questions nouvelles et difficiles Après 45 ans d'activité, la Commission du Codex Alimentarius conserve toute son actualité et il serait difficile d'envisager un monde sans elle. La Commission est toujours prête à .