Water - Its Properties And Role In The Environment

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Water - Its Properties and Role in the EnvironmentOutline: Role in early history and science Unique chemistry Hydrologic cycle - redistribution, climate effects Ocean circulation - basic wind & thermohaline

Chemically uniqueExists in all three phases at atmospheric temperatures & pressures(high melting and boiling points compared to molecules of similarsize It is the only substance that does this!

Chemically and Physically unique High heat capacity (4.2 J/g/K). It stores a lot of heat energy whichmakes it a good medium for spreading the planet’s heat High heat of fusion (solid to liquid 335 J/g/K) and vaporization(liquid to gas 2400 J/g/K) so more effectively transfers heat whenchanging phase in atmosphere/ocean

Physically Unique Water is physicallyunique because it is lessdense as a solid (ice) thanas a liquid. The maximum density ofliquid water occurs at 4ºC

Chemically andBiologicallyUnique High surface tension so it forms drops & helps make good cellmembranes Dissolve other compounds very easily and so can transportchemicals (e.g., NaCl, nutrients) Mediates or facilitates most chemical reactions in living systems(e.g., takes water to photosynthesize) - neutral pH

Covalent and Ionic Bonds

Hydrogen Bonds - 10 x stronger than normalintermolecular (van der Waals)forces.

Distribution of waterWater volume, incubic milesPercent oftotalwater317,000,00097.24%Icecaps, Glaciers7,000,0002.14%Ground water2,000,0000.61%Fresh-water lakes30,0000.009%Inland seas25,0000.008%Soil %Water sourceOceansRiversTotal watervolume326,000,000100%

Hydrologic Cycle (in 103 km3)

Quantitative Hydrological Cycle

Period of RenewalWater of HydrospherePeriod of renewalWorld Ocean2500 yearsGround water1400 yearsPolar ice9700 yearsMountain glaciers1600 yearsGround ice of the permafrost zone10000 yearsLakes17 yearsBogs5 yearsSoil moisture1 yearsChannel network16 daysAtmospheric moisture8 daysBiological waterseveral cle.htm

Aquifers

Freshwater ResourcesRiversGroundwaterVolume(cubic miles)Residence Time30020000016 days1400 yrsFlux(cubic miles / year)7000140

Atmospheric circulation

Equatorial Hadley 0/Image56.gif

PrecipitationTo see the animated version go tohttp://geography.uoregon.edu/envchange/clim animations/gifs/prate web.gif

Rain shadow

Effects of global warming on water cycleGlobal warming(temperature increase)Speeds up globalwater cycleMore extreme weather events Droughts Storms Floods

Projected Changes in Annual Precipitation for the 2050sThe projected change is compared to the present day with a 1% increase per year in equivalent CO2Source: The Met Office. Hadley Center for Climate Prediction and Research

Global Precipitation Trends(% per decade) 1900 - 1994Green increasing, Brown decreasingSource: Watson 2001

U.S. Precipitation Trends: 1901 to 1998Green increasing, Brown decreasingAll stations/trends displayed regardless of statistical significanceSource: National Climatic Data Center/NESDIS/NOAA

Extreme Precipitation Events in the U.S.Source: Karl, et.al. 1996.

Rivers 300 0.0001% Atmosphere 3,100 0.001% Soil moisture 16,000 0.005% Inland seas 25,000 0.008% Fresh-water lakes 30,000 0.009% Ground water 2,000,000 0.61% Icecaps, Glaciers 7,000,000 2.14% Oceans 317,000,000 97.24% Percent of total water Water volume, in cubic miles Water source Distribution of water

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