Appendix E: This Appendix Presents Tables That Compare The .

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Wohlers Report 2014Appendix E: Material PropertiesAppendix E:Material propertiesThis appendix presents tables that compare the physical and mechanicalproperties of some of the most popular materials for additivemanufacturing. The first table provides common manufacturingmaterials for the purpose of comparison. These 57 pages are private andnot published elsewhere.by Juan Vargas, Lluvia Herrera, andJorge e)Nylon Tensile strength(ASTM 00-9,000(34-62)4,500-5,400(31-37)Tensile modulus(ASTM 0(1,172-1,724)Elongation % at break41.682.81103-1207-13Elongation % at yieldN/A10.7%6%N/AN/AImpact strength(notched Izod)ft-lb/in of notch(J/m)1.7-4.5(0.9 0.1)0.4-1.4(21-75)Hardness75-115Rockwell (R)93-122Rockwell (R)118-133Rockwell (R)70Shore (D)68-83Shore (D)Glass-transitiontemperature C(Heat-deflectiontemperature 107-121)Source: www.matweb.com and CADCAMNetNote: Ryan Wicker and David Espalin contributed to this appendix.COPYRIGHT 20141WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessMaterial extrusionManufacturerStratasys Ltd. (1 of polycarbonatefilamentpolyphenyl e styreneblend filamentType acrylonitrilestyrene filament butadiene styrenefilamentType an, Vantage S,Vantage SE,Titan TI,Vantage SE,Vantage S,Vantage SE,Vantage I, (when Titan, Vantage S,Vantage I, (whenVantage S,configured withVantage SE,Titan, Fortus 400mc,configured with Vantage I, (whenPC), FortusFortus 400mc,Fortus 900mcABS)configured with360mc, FortusFortus 900mcProdigy Plus,ABS) Prodigy400mc, FortusFortus 360mc,Plus, Fortus900mcFortus 400mc,400mc, Uprint,Uprint,Titan, Vantage S,Vantage SE, Fortus360mc, Fortus400mc, Fortus900mc, Mojodurable, strong,good heat andchemicalresistance;comes in colorsthis blend combinesthe most desirableproperties of bothmaterialsNotescan be sterilizedwith gammaradiationcomplies with ISOvery toughvery tough10993 and USPthermoplastic,thermoplastic,Class VI medicalcommonly usedcommonly used forclassifications forfor d on the following pageCOPYRIGHT 20142WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material onateISOPolyphenylsulfone(PPSF)PC-ABSPhysical propertiesTensilestrength(ASTM 7)8,000(55)5,900(41)Elasticmodulus(ASTM Elongation(ASTM D638)% at yield64.45436Impactstrength(notched Izodtest)ft-lb/in neral informationGlasstransitiontemperature CHeatdeflectiontemperature C@66 psi@264 96Source: Materials Sheets, Stratasysredeyeondemand.com/Materials FDM Thermoplastics.aspx, February 2014COPYRIGHT 20143WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessMaterial extrusionManufacturerStratasys Ltd. (2 of 2)MaterialABS-M30ABS-M30iABS PlusULTEM 9085ABS-ESD7FDM Nylon 12Type of materialABS withimprovedstrengthABS withimprovedstrength andbiocompatibilityABS roduction-gradethermoplasticType of machineFDM 400mc,Fortus 360mc,Fortus 400mc,Fortus 900mcFortus 400mc,Fortus 900mcFDM 200mc,Fortus 200mcFortus 400mc,Fortus 900mcFortus 400mc,Fortus 900mcFortus 900mc,Fortus 400 mc,Fortus 360 mcNotesgreater tensile, high strength, blend combinesimpact, andbiocompatiblethe mostflame retardant,flexural strength (ISO 10993desirablehigh strength tothan standardcertified), canproperties ofweight ratio, FSTABS filament,be gamma or both materials,rating, ideal for25-70%EtO sterilized,up to 40%the transportationimprovedgoodimprovedindustrystrength overmechanicalstrength overstandard ABSpropertiesstandard ABSstatic dissipativeoffers the bestproperties,z-lamination andprevents builduphighest impactof static electricity, strength of anyideal for electronic FDM thermoplastic,products with as well as excellentcircuit boards chemical resistancePhysical propertiesTensile strength(ASTM D638)2lb/in 36)7,000(48)Elastic modulus(ASTM D638)2lb/in ASTM D638)% at yield443636.5Impact strength(notched Izod test)ft-lb/in of ral informationGlass-transitiontemperature C108108108186108N/AHeat-deflectiontemperature C@66 psi@264 psi968296829682N/A15396827555Source: Materials Sheets, Stratasys, redeyeondemand.com/Materials FDM Thermoplastics.aspx, February 2014COPYRIGHT 20144WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessMaterial jettingManufacturerStratasys Ltd. (1 of 3)MaterialFullCure 720FullCure 830Vero WhiteFullCure 840Vero BlueType ofmaterialType ofmachineNotesFullCure 870Vero BlackFullCure 970Tango BlackFullCure 950 FullCure 930Tango Gray Tango Plusphotopolymer resinEden 250/260/330/350/350V/500, Objet 24, Objet 30,Connex260, Connex350, Connex500generalpurposetransparentresingood impact strength and flexural moduluswith opaque colorsEden 330/350/350V/500, Objet 24,Connex260, Connex350, Connex500rubber-like flexible materials; black is slightlysofter; gray is harder but still flexiblePhysical propertiesTensilestrength(ASTM s(ASTM TM D638)% at yield20(at break)20(at break)20(at break)17.7(at break)47.7(at break)47.0(at break)218(at break)Impactstrength(notched Izodtest)ft-lb/in of N/AN/AN/AHardness(Shore Dscale)8383838361 (Shore A)75 (Shore A)27 (Shore A)-10.72.6-9.6General informationGlasstransitiontemperature C48.758.048.762.7Source: PolyJet Material Spec Sheet, http://www.stratasys.com/ aterialSpecs/PolyJet Materials Data Sheet.pdf, February 2014COPYRIGHT 20145WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessMaterial jettingManufacturerStratasys Ltd. (2 of 3)MaterialFullCure 630FullCure 655DurusWhiteFullCure 430FullCure 680FullCure 980Tango BlackFullCure 850 VeroGrayType of materialacrylate photopolymer resinphotopolymer resinType of machineEden 250/260/330/350/350V/500, Objet 24, Objet 30EdenEden330/350/350V/500, 250/260/330/350/35Objet 24,0V/500, Objet 24,Connex260Objet 30Noteshearing aidmaterial (clear)hearing aidmaterial(rose clear)hearing aidmaterial like flexiblegood impactmaterials; black isstrength andslightly softer than flexural modulusits grey counterpart with opaque colorsPhysical propertiesTensile strength(ASTM ,089(21.3)211 (1.45)8,700 (60)Elastic modulus(ASTM ngation(ASTM D638)% at break20201044.221815Impact strength(notched Izod test)ft-lb/in of N/A0.4(25)Hardness(ShoreD-scale)8383857627 (Shore A)8635.9-9.656.5General informationGlass-transitiontemperature C44.944.958.5Source: PolyJet Material Spec Sheet, http://www.stratasys.com/ aterialSpecs/PolyJet Materials Data Sheet.pdf, February 2014COPYRIGHT 20146WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessMaterial jettingManufacturerStratasys Ltd. (3 of 3)MaterialObjetFullCure mer resinType of materialNotesRGD 515/535 Objet VeroClear DM 8500 Seriesrigid, whitematerialgood impactstrength andflexuralmodulushightemperaturematerialABS-like digitalmaterialrigid, clear,transparentmaterialrigid, whitematerialrubber-likeflexible materials;black 64333,587(1,700-2,300)N/APhysical propertiesTensile strength(ASTM 0(50-65)Elastic modulus(ASTM )Elongation atbreak(ASTM D638)% at yield10-2510-2510-1525-4010-2515-2535-110Impact strength(notched Izodtest)ft-lb/in of 414-0.656(22-35)N/AHardness(Shore l informationGlass-transitiontemperature CN/A52-5462-6547-53Source: PolyJet Material Spec Sheet, http://www.stratasys.com/ aterialSpecs/PolyJet Materials Data Sheet.pdf, February 2014COPYRIGHT 20147WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessMaterial jettingManufacturerSolidscape, a subsidiary of Stratasys Ltd. (1 of 1)MaterialType of materialInduraCastcomposition:natural andthermoplasticsynthetic waxesand fatty esters3Z Modelorganiccompound3Z Support3Z LabCASTwax blendorganiccompound3Z Lab FillplusCASTwax blendsulphonamideand benzoatederivatives withpolyester resinT66 Benchtop System, T612 Benchtop System, R66 System, 3Z Pro, 3Z Studio, 3Z Lab, 3Z EduType of machineNotesInduraFillmelting point: melting point:203-230 F120-158 F(95-110 C);(49-70 C);coefficient of soluble in athermalmineral oilexpansionbath at 122negligible; no 131 F (50residue after55 C); noautoclavepost-dissolveprocess; nodry or cureshrinkage; time; no postnon-toxic;dissolvedistortionfinishing ordisintegrationtouch upat normalnecessary;temperaturesnon-toxicmeltingpoint: 221239 F (95115 C);non-toxic;registeredby TSCAlow meltingpoint:21-162 F(50-72 C)non-toxic;registered byTSCA.; postprinting, theresultingstructuredissolves in aliquid solutionprocessmelting point:221-239 F(95-115 C);non-toxic;registered byTSCAlow meltingpoint:21-162 F(50-72 C)non-toxic;registered byTSCA.; postprinting, theresultingstructuredissolves in aliquid solutionprocessmelting pointof 221-239 F(95-115 C);non-toxic;clean burnoutduring castingwith noresidual ashor shrinkage,and thermalpolyesterformulaproducesstrong moldsPhysical propertiesTensile strength(ASTM D638)2lb/in (MPa)Elastic modulus(ASTM D638)2lb/in (MPa)N/AElongation(ASTM D638)% at yieldImpact strength(notched Izod)ft-lb/in of AN/AN/AN/AGeneral N/ASource: Material Properties Sheet, Solidscape, Inc.COPYRIGHT 20148WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessMaterial jettingManufacturer3D Systems (1 of 4)MaterialVisiJetSR 200VisiJetHR 200VisiJetDP 200Type of materialmodel, acrylicplasticmodel, acrylicplasticmodelType of machineProJetSD, HD compatibleProJet HDcompatibleProJet DPcompatiblewhite, blue, or greycolored MJM modelmaterial, thermalmaterialapplication, UVcuring, providessuperior stiffness,utilizes VisiJetS100 white supportmaterialblue MJMmodel material,thermalmaterialapplication, UVcuring, highquality surfacefinish, utilizesVisiJet S100white etMXVisiJetEX200wax modeling wax modeling model, acrylic model, acrylicmaterialmaterialplasticplasticProJet CPXcompatibleideal materialfor high-quality,smooth surfacefinish dentalwax-ups,utilizes VisiJetS100 WhitesupportmaterialProJet CPcompatibleProJet5000dark bluelight bluemodelingmodelingmaterial,clear meltmaterialaway, easyaway, easyapplication,removal fromremoval fromUV curing,small andsmall andprovides fordelicate partdelicate partgreat flexuralfeatures,features,properties,utilizes VisiJetutilizes VisiJetgreat end partS200 whiteS200 D, HDclear material,thermalmaterialapplication,great surfacefinish characteristic, usesVisiJet S100white supportmaterialPhysical propertiesTensile strength(ASTM D638)2lb/in (MPa)3,800(26.2)Elastic modulus(ASTM D638)2lb/in (MPa)Elongation(ASTM D638)% at yield4,640(32)N/A6.1-8.97Impact strength(notched Izodtest)ft-lb/in of ore D-scale)General informationHeat deflectiontemperature at66 psi in C46N/ASource: 3-D Printer Modeling Materials, 3D Systems, 3dsystems.com/products/materials/index.asp, February 2014COPYRIGHT 20149WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessMaterial jettingManufacturer3D Systems (2 of 4)MaterialVisiJet SLFlexVisiJet SLToughVisiJet SLClearVisiJet SLBlackVisiJet SLImpactVisiJet SLHiTempType of materialUV curable plasticType of machineProJet 6000 & 7000 Printers (SD, HD, MP)Noteshumidity andchemicallyhighcrystal clear high strength tough andhigh flexibilityresistant withdurability and appearance, and good durable, idealand shapehigh rigidity,impactstiff anddimensional for functionalretentionlong tiesVisiJet SLe-StoneVisiJet SLJewelmodelsideal forrequiring highcrown anddetail,bridgeresolution,restorationsand accuracyPhysical propertiesTensile strength(ASTM D638)2lb/in (MPa)Elastic modulus(ASTM D638)2lb/in (MPa)Elongation(ASTM D638)% at yieldImpact strength(notched Izod test)ft-lb/in of notch(J/m)Hardness(Shore 491,678(3,390)236,411(1,630)277,022(1,910)6(% at break)17(% at break)12(% at break)16186514(% at break) (% at break) (% at break) (% at break) (% at break)22444647652622458086858680868072General informationHeat deflectiontemperature at 66 psiin CN/ASource: Product Data Sheets\ 3-D Printer Modeling Materials, 3D Systems, y 2014COPYRIGHT 201410WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessMaterial jettingManufacturer3D Systems (3 of 4)MaterialVisiJetCR-ClVisiJetCR-WTVisiJetCR-BKType of materialpolycarbonatelikeABS-likerubber-likeProJet 5500XType of machineVisiJetVisiJetC4 Spectrum FTX Greenheat-curedplasticcompositeUV MXUV-curable liquid plasticProJet 4500 ProJet 1200ProJet 5000NotesPhysical propertiesTensile strength(ASTM )4,351(30)5,715(39.4)4,757(32.8)4,496(31)Elastic modulus(ASTM (1,555)183,763(1,267)Elongation(ASTM D638)% at yield138.12933.6107.815.4(% at break) (% at break) (% at break) (% at break) (% at break) (% at break) (% at break)Impact strength(notched Izod test)ft-lb/in of notch(J/m)Hardness(Shore D-scale)20(% at break)N/A8383N/A79N/AGeneral informationHeat deflectiontemperature at 66 psiin CN/ASource: Product Data Sheets\ 3-D Printer Modeling Materials, 3D Systems, y 2014COPYRIGHT 201411WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessMaterial jettingManufacturer3D Systems (4 of 4)MaterialVisiJetM3 XVisiJetM3 BlackVisiJetVisiJetM3 Crystal M3 PropastVisiJetM3 NavyVisiJet M3TechplastVisiJet M3Procastwax supportmaterialUV curable plasticType of materialVisiJetS300Type of machineProJet 3510 (SD, HD, HD Plus) & 3500 HD MaxNotestough, high temperature resistant, durable, stable, watertight, biocompatible, castablePhysical propertiesTensile strength(ASTM 00(26.2)2.973(20.5)3,205(22.1)4,641(32)Elastic modulus(ASTM 044(1,724)Elongation(ASTM D638)% at yield8.3(at break)19.7(at break)6.83(at break)8.97(at break)8(at break)6.1(at break)12.3(at break)808680Impact strength(notched Izod test)ft-lb/in of notch(J/m)Hardness(Shore D-scale)N/AN/A80868586General informationHeat deflectiontemperature at 66 psiin CN/ASource: Product Data Sheets\ 3-D Printer Modeling Materials, 3D Systems, y 2014COPYRIGHT 201412WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessBinder jettingManufacturerExOne Company (1 of 1)Material nameS3S4 (non-annealed)S4 (annealed)milky white matte glassMaterial (alloyfamily)316 stainless steel andbronze420 stainless steel andbronze420 stainless steel andbronzeglassNotesused in digital mold andcore-making systemused in digital mold andcore-making systemused in digital mold andcore-making systemglass material systemsare best used for artsculptures; material isporous, opaque, fragilePhysical propertiesUltimate tensilestrength ld stress dness60 HRB20-25 HRC305.5-7.0Mohr hardnessModulus 4)Elongation(%)8.02.37.0N/ASource: Material Data Sheets from ExOne Company, exone.com/eng/technology/x1-prometal/materials prometal.html,February 2014. Information regarding other materials, including but not limited to copper, tungsten, and nickel, available uponrequest from ExOne.COPYRIGHT 201413WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessBinder jettingManufacturer3D Systems (1 of 1)MaterialZP 131ZP 150Type of materialhigh-performancecomposite powderType of machineZPrinter 150/250/350/450/650Spectrum Z510NotesZPrinters “print” parts by jetting binder onto a base powder; after fabrication, a part may beinfiltrated for added strength; making colored parts is possible by using colored water-based binder;ZCast parts are not infiltratedPhysical propertiesTensile strength(ASTM D638)2lb/in(MPa)3,480(24)Elastic modulus(ASTM D638)2lb/in(MPa)1,566,408(10,800)Elongation(ASTM D638)% at yieldN/AImpact strength(notched Izod test)ft-lb/in of notch(J/m)N/AHardness(Shore D-scale)87N/AGeneral informationHeat deflectiontemperature at 66psi in C115N/ASource: Product Data Sheets, Z Corporation, 3-D Printer Modeling Materials, 3D , February 2014COPYRIGHT 201414WOHLERS ASSOCIATES, INC.

Wohlers Report 2014Appendix E: Material PropertiesProcessSheet laminationManufacturerFabrisonic LLC (1 of loy/temper1100 T03003 T03003 H186061 T0101, 100 annealedType ofmachineFORMation, SonicLayer R200, 4000, 7200General propertiesDensity3(g/cm )2.712.732.732.708.96Material1100 T03003 T03003 H186061 T0copperPhysical propertiesUltimatetensile strength(Rm)2lb/in(MPa)89.6110200124210Yield strength(Rp 0.2)2lb/in(MPa)34.541.418655.233Elongation(ASTM D638)% at break353042570Hardness(Brinell scale)2328553090Modulus ofelasticity(GPa)68.9110Source: Product Data Sheets, Fabrisonic, http://www.fabrisonic.com/materials.html, February 2014COPYRIGHT 201415WOHL

(ASTM D638) % at yield 4 4 3 6 3 6.5 Impact strength (notched Izod test) ft-lb/in of notch (J/m) 2.6 (139) 2.6 (139) 2.0 (106) 2.0 (106) 2.1 (111) 3.74 Hardness (Rockwell) 109.5 109.5 N/A N/A 109.5 N/A General information Glass-transition temperature C 108 108 108 186 108 N/A Heat-deflection .

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