OFF! DEEP WOODS INSECT REPELLENT V

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200OFF! DEEP WOODS INSECT REPELLENT VVersion 1.1Print Date 03/04/2015Revision Date 02/23/2015SDS Number 3500000048071. PRODUCT AND COMPANY IDENTIFICATIONProduct informationProduct name:OFF! DEEP WOODS INSECT REPELLENT VRecommended use:Insect RepellentManufacturer, importer,supplier:S.C. Johnson & Son, Inc.1525 Howe StreetRacine WI 53403-2236TelephoneEmergency telephonenumber:: 1800558525224 Hour Medical Emergency Phone: (866)231-540624 Hour International Emergency Phone: (703)527-388724 Hour Transport Emergency Phone: (800)424-93002. HAZARDS IDENTIFICATIONClassification of the substance or mixtureGlobally Harmonized System (GHS) ClassificationHazard classificationHazard categoryAerosolCategory 1Gases under pressureLiquefied gasHazards identificationExtremely flammable aerosol.Contains gas under pressure;may explode if heated.LabellingHazard symbolsFlameGas cylinderSignal wordDangerHazard statementsExtremely flammable aerosol.Contains gas under pressure; may explode if heated.Precautionary statementsProtect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F.Protect from sunlight. Store in a well-ventilated place.Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Do not spray on an open flame or other ignition source.Do not pierce or burn, even after use.1/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200OFF! DEEP WOODS INSECT REPELLENT VVersion 1.1Print Date 03/04/2015Revision Date 02/23/2015SDS Number 350000004807Other hazards:None identified3. COMPOSITION/INFORMATION ON INGREDIENTSChemical NameCAS-No.Weight percentEthyl alcohol64-17-530.00 - 60.00N,N-Diethyl-m-toluamide134-62-310.00 - 30.00Butane106-97-81.00 - 5.00Propane74-98-61.00 - 5.00Isobutane75-28-51.00 - 5.00The specific chemical identity and/or exact percentage (concentration) of this composition has beenwithheld as a trade secret.For additional information on product ingredients, see www.whatsinsidescjohnson.com.4. FIRST AID MEASURESEye contact:No special requirementsSkin contact:If you suspect a reaction to this product, discontinue use andremove contaminated clothing.Inhalation:No special requirements.Ingestion:No special requirementsSuitable extinguishingmedia:Use water spray, alcohol-resistant foam, dry chemical orcarbon dioxide.Specific hazards duringfirefighting:Aerosol Product - Containers may rocket or explode in heat offire. Do not allow run-off from fire fighting to enter drains orwater courses.Further information:Fight fire from maximum distance or protected area. Cool anduse caution when approaching or handling fire-exposedcontainers. Wear full protective clothing and positive pressure5. FIREFIGHTING MEASURES2/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200OFF! DEEP WOODS INSECT REPELLENT VVersion 1.1Print Date 03/04/2015Revision Date 02/23/2015SDS Number 350000004807self-contained breathing apparatus. In case of fire and/orexplosion do not breathe fumes.NFPA Classification:NFPA Level 2 Aerosol6. ACCIDENTAL RELEASE MEASURESPersonal precautions:Remove all sources of ignition.Wear personal protective equipment.Wash thoroughly after handling.Environmentalprecautions:Do not flush into surface water or sanitary sewer system.Use appropriate containment to avoid environmentalcontamination.Outside of normal use, avoid release to the environment.Methods and materialsfor containment andcleaning up:If damage occurs to aerosol can:Contain spillage, soak up with non-combustible absorbentmaterial, (e.g. sand, earth, diatomaceous earth, vermiculite)and transfer to a container for disposal according to local /national regulations (see section 13).Use only non-sparking equipment.Dike large spills.Clean residue from spill site.Precautions for safehandling:Avoid contact with eyes and lips.For personal protection see section 8.Use only as directed.KEEP OUT OF REACH OF CHILDREN AND PETS.Pressurized container.Do not pierce or burn, even after use.Advice on protectionagainst fire and explosion:Keep away from sources of ignition - No smoking.Do not spray on an open flame or other ignition source.:Protect from sunlight. Do not expose to temperaturesexceeding 50 C/ 122 F.7. HANDLING AND STORAGEHandlingStorageRequirements for storageareas and containers3/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200OFF! DEEP WOODS INSECT REPELLENT VVersion 1.1Print Date 03/04/2015Revision Date 02/23/2015SDS Number 350000004807Keep away from food, drink and animal feedingstuffs.Keep in a dry, cool and well-ventilated place.Other data:Stable under recommended storage conditions.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONOccupational Exposure LimitsComponentsCAS-No.mg/m3ppmEthyl alcohol64-17-51,900 mg/m31,000 ppmNonstandardunits-BasisEthyl alcohol64-17-5-1,000 ppm-ACGIHSTELButane106-97-8-1,000 ppm-ACGIHSTELPropane74-98-6-1,000 ppm-ACGIHTWAPropane74-98-61,800 mg/m31,000 ppm-OSHA TWAIsobutane75-28-5-1,000 ppm-ACGIHSTELOSHA TWAPersonal protective equipmentRespiratory protection:Do not spray in enclosed areas.Hand protection:No special requirements.Eye protection:No special requirements.Skin and body protection:No special requirements.Hygiene measures:Handle in accordance with good industrial hygiene and safetypractice. Wash thoroughly after handling.9. PHYSICAL AND CHEMICAL PROPERTIES4/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200OFF! DEEP WOODS INSECT REPELLENT VVersion 1.1Print Date 03/04/2015Revision Date 02/23/2015SDS Number 350000004807Form:aerosolForm:Compressed gasColor:clearOdor:Alcohol OdorOdour Threshold: No data availablepH: No data availableMelting point/freezing point: No data availableInitial boiling point andboiling range: No data availableFlash point: -7 C19.4 FEvaporation rate: No data availableFlammability (solid, gas): No data availableUpper/lower flammability orexplosive limits: No data availableVapour pressure: No data availableVapour density: No data availableRelative density: 0.84 g/ml at 21 CSolubility(ies): slightly soluble5/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200OFF! DEEP WOODS INSECT REPELLENT VVersion 1.1Print Date 03/04/2015Revision Date 02/23/2015SDS Number 350000004807Partition coefficient: noctanol/water: No data availableAuto-ignition temperature: No data availableDecomposition temperature: No data availableViscosity, dynamic: No data availableViscosity, kinematic: No data availableOxidizing properties: No data availableVolatile OrganicCompoundsTotal VOC (wt. %)*:Other information: None identified64.2 %- additional exemptions may apply*as defined by US Federal and State Consumer ProductRegulations10. STABILITY AND REACTIVITYPossibility of hazardousreactions: Stable under recommended storage conditions.Conditions to avoid: Heat, flames and sparks.Incompatible materials: Strong oxidizing agentsHazardous decompositionproducts: Thermal decomposition can lead to release of irritating gasesand vapours.11. TOXICOLOGICAL INFORMATION6/13:

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200OFF! DEEP WOODS INSECT REPELLENT VVersion 1.1Print Date 03/04/2015Revision Date 02/23/2015SDS Number 350000004807Emergency Overview:DangerAcute oral toxicityAcute inhalation toxicity::No data availableNo data availableAcute dermal toxicityGHS PropertiesAcute toxicity: No data availableClassificationNo classification proposedSkin corrosion/irritationNo classification proposed-Serious eyedamage/eye irritationSkin sensitisationNo classification proposed-No classification proposed-RespiratorysensitisationGerm cell mutagenicityNo classification proposed-No classification proposed-CarcinogenicityNo classification proposed-Reproductive toxicityNo classification proposed-Specific target organtoxicity - singleexposureSpecific target organtoxicity - repeatedexposureAspiration hazardNo classification proposed-No classification proposed-No classification proposed-Aggravated MedicalCondition:Routes of entry-Do not apply to cuts or irritated skin.12. ECOLOGICAL INFORMATIONProduct : The product itself has not been tested.ToxicityThe ingredients in this formula have been reviewed and no adverse impact to the environment isexpected when used according to label directions.Toxicity to fish7/13

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200OFF! DEEP WOODS INSECT REPELLENT VVersion 1.1Print Date 03/04/2015Revision Date 02/23/2015SDS Number 350000004807ComponentsEnd pointSpeciesValueExposuretime96 hEthyl alcoholflowthroughtest LC50Pimephales promelas(fathead minnow)14,200mg/lN,N-Diethyl-m-toluamidestatic testLC50Oncorhynchus mykiss(rainbow trout)71.25 mg/l96 hButaneNo dataavailablePropaneLC50Fish27.98 mg/l96 hIsobutaneLC50Fish27.98 mg/l96 hValueExposuretime48 hToxicity to aquatic invertebratesComponentsEnd pointSpeciesEthyl alcoholstatic testEC50Daphnia magna (Waterflea)2 mg/lNOECN,N-Diethyl-m-toluamideNo dataavailableButaneNo dataDaphnia magna8/139.6 mg/l9d

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200OFF! DEEP WOODS INSECT REPELLENT VVersion 1.1Print Date 03/04/2015Revision Date 02/23/2015SDS Number 350000004807availablePropaneLC50Daphnid14.22 mg/l48 hIsobutaneLC50Daphnid16.33 mg/l48 hToxicity to aquatic plantsComponentsEnd pointSpeciesValueEthyl alcoholStaticEC50Chlorella vulgaris (Freshwater algae)275 mg/lExposuretime72 hN,N-Diethyl-m-toluamideNo dataavailableNo dataavailableNo dataavailableEC50Green algea8.57 mg/l96 hButanePropaneIsobutanePersistence and degradabilityComponentBiodegradationEthyl alcohol97 %Exposuretime28 dSummaryN,N-Diethyl-m-toluamideButaneNo data available100 %385.5 hReadily biodegradablePropane70 % 10 dReadily biodegradableIsobutane70 % 10 dReadily biodegradableReadily biodegradableBioaccumulative potentialComponentBioconcentration9/13Partition Coefficient n-

Safety Data Sheetaccording to Hazard Communication Standard; 29 CFR 1910.1200OFF! DEEP WOODS INSECT REPELLENT VVersion 1.1Print Date 03/04/2015Revision Date 02/23/2015SDS Number 350000004807Ethyl alcoholN,N-Diethyl-m-toluamidefactor (BCF)3.2 estimatedNo data availableOctanol/water (log)-0.35 MeasuredNo data availableButanePropaneIsobutaneNo data availableNo data available1.57 - 1.972.892.362.8ComponentEnd pointValueEthyl neNo data availableNo data availableNo data availableNo data availableNo data availableMobilityPBT and vPvB assessmentComponentEthyl alcoholResultsNot fulfilling PBT and vPvB criteriaN,N-Diethyl-m-toluamideNot fulfilling PBT and vPvB criteriaButaneNot fulfilling PBT and vPvB criteriaPropaneNot fulfilling PBT and vPvB criteriaIsobutaneNot fulfilling PBT and vPvB criteriaOther adverse effects:None known.13. DISPOSAL CONSIDERATIONSPESTICIDAL WASTE:For disposal information, please read and follow Disposalinstructions on the pesticide label.Consumer may discard empty container in trash, or recyclewhere facilities exist.10/13