The Significance Of Coal Beyond Electricity Generation

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THE SIGNIFICANCE OF COALBEYOND ELECTRICITY GENERATIONFFF Carbon Conference, Middelburg1 April 2022Prof Nikki Wagnernwagner@uj.ac.za

OVERVIEW Understanding coal Coal and global significance The significance beyond electricity generationCoal is critical to our world, through its use inproviding much-needed affordable electricityand also in building our societies through itsuse in steel and cement. 37% of the world’selectricity and over 70% of the world’s steel isproduced using coal (World Coal Association,2020)Coal plays a significantrole in the construction ofrenewable energyinfrastructure andsupporting these fuels onthe grid.AS A SOCIETY, WE NEED TO ENSURE THE SUSTAINABLE,ENVIRONMENTALLY RESPONSIBLE USE OF COAL. AND THISBEGINS BY UNDERSTANDING THE GEOLOGICAL RESOURCE

COAL: “that dirty black stuff”?“mineral of fossilized carbon”combustible sedimentary rock containing 50% by weight and 70% by volume carbonaceous material formed fromcompaction of variously altered plant remains.Composed of carbon, with variable hydrogen, sulphur, oxygen,nitrogen, and many other elements.Rocks are comprised on mineral assemblages.Coal is comprised of organic and inorganic (mineral) assemblages.Organic building blocks are termed macerals.

Understanding coal Geologist: how did coal form? (coal diagenesis) Geologist: where is coal? (coal exploration) Mining engineers: how can the coal be extracted? (mining) Process engineers: : how can the coal quality be upgraded? (beneficiation) Chemical engineers: how can the energy and carbon be harnessed?(conversion &advanced applications) Metallurgists: how can the properties be manipulated for ore reduction? (coking andreductant properties) Mineralogist: what can be recovered from coal discard and ash? (ash properties) Mechanical Engineers: how to improve efficiencies? (CCT) Environmentalist: what are the pollutants? (CCT) Accountants / CFO’s / COO’s: how can we make more money? (coal-value chain) Civil society: do we understand coal? (CCT, advanced applications)ORGANIC PETROLOGY FINDS RELEVANCE IN GEOLOGY, METALLURGY, CHEMICALENGINEERING, COAL SUSTAINABILITY ACROSS THE COAL VALUE-CHAIN

Basic understanding of coal .Petrographic aspects Type - lithotypes / macerals Grade – minerals / ash Rank – maturity (lignite,bituminous, bituminous, anthracite) Condition – weathering /oxidationGrade (inorganic matter)Type(organic matter)Chemical aspects Proximate analysisUltimate analysisCVAsh oxideMineralogyIncreasing rank(maturity)

Three MainOrganic MaceralGroups Vitrinite group Inertinite group Liptinite group

GLOBALSIGNIFICANCE 1.06 trillion tonnes of provencoal reserves worldwide(World Coal Association) Equates to close to 132 yearsof future supply at currentrates of production Distributed more evenly thanother fossil fuels Accounts for 28% of globalprimary energy

SA COAL FACTSSouth Africa is the–7th largest producer of coal–5th largest exporter of coal–8% of world coal reservesCoal in South Africa accounts for–1st / 2nd highest foreign exchange earnings in the country–2nd largest mining income-earning commodity, beating gold– 70% of SA primary energy production– 90% of carbon reductants in the metallurgical industry– 40% of petrol and diesel requirements– 200 major chemicals for 1000s of carbon-based products

Coal demand by region and scenario, 2018-2040Last updated 21 Nov 2019; IEA Asia Pacific Eurasia Middle East Africa Europe Central and SouthAmerica North AmericaIEA, Coal demand by region and scenario, 2018-2040, IEA, Paris l-demand-by-region-andscenario-2018-2040 IEA. All Rights Reserved

e-ideas-vs-reality/materials-throughput-energy

INDUSTRIAL USES OF COALThe significance of coal in the transport sector.1Liquid fuelHybrid vehiclesHydrogen2AluminiumCarbon fibersThe significance of coal in the infrastructure sector.3SteelCement4BricksThe significance of coal in the clean energy sector.Materials of constructionCRM and REE5

1. SIGNIFICANCE OF COAL IN TRANSPORTFUELSCTL in South Africa20% SA transport fuel7.5% SA jet fuel

Sasol gasification CTL process

2. SIGNIFICANCE OF COAL & CARBON IN THEALUMINIUM INDUSTRY

0.2kg carbon for every2.2 kg aluminiumproducedEnergy – coal can be replacedCathodes – no current alternative tocoalAnodes – no current alternative tocoal

3. SIGNIFICANCE OF COAL IN THE STEEL steel.php

IMPACT OF ORGANIC MATTER COMPOSITION ON INDUSTRIAL PLANT- METALLURGICAL PROCESSES A CHANGE IN THE PROPORTION OF ORGANIC MATTERCOMPOSITION IN COAL CAN AFFECT: REACTIVITY –RATE OF CARBON CONSUMPTION RESISTIVITY POROSITY AND PERMEABILITY STRENGTHCokes for metallurgical applications in ferrochrome production / steel manufacture

Blast furnaces:770kg coal 1400kg iron ore 150kglimestone 120kg recycled steel 1 ton crude steelElectric arc furnaces:880kg recycled steel 150kg coal 43kglimestone 1 ton crude steel(World Coal Association, 2020)80% of all the materials in a single wind turbine are steel

4. SIGNIFICANCE OF COAL IN THE CEMENTCALCINED ANTHRACITEINDUSTRY200kg coal 1 ton cement300-400kg cement for1m3 concrete3 Gorges Dam, China28 million m3 of concrete almost 2 million tons of coal(World Coal Association, 2020)

CONSIDER ASH AS A RAW MATERIALSIZE, AND RECOVER CHAR AND OTHERMINERALS, OR USE ASH AS IS Largest use of ash is in cement andconcrete. Also used in mine reclamation,roads, infilling voids Gypsum used in wallboardmanufacture Cenospheres are recovered andused in electromagnetics (fillers incomposite materials and paints)

5. SIGNIFICANCE OF COAL IN THE CLEAN ENERGYINDUSTRY: CRITICAL RAW MATERIALSWhat do we need to go 473/30/tab-figures-data

CRITICAL RAW MATERIALS .SO, HOW DO WE FIND THESE VIP RAW aw-materials-is-out/

Coal as an alternative source of graphiteERA-MIN CHARPHITE projectChar concentrateGraphitised charNatural graphite

USA Rare Earth Element Advanced Coal Technology Act (2019)Annual budget of 23 million to 2027Department of Energy and the National Energy Laboratory (NETL)

Input of REY into coal: Examples from Fire Clay coalBasal bench TonsteinOrganic interactions withminerals and REY-bearingfluids throughout depositionalhistory of Fire Clay coalTop benchTuffaceous:Volcanic ashfallTerrigenous influencescontinuedthrough time of ration fromAsh-fall tonsteinInfiltration fromAsh-fall tonsteinTerrigenous:Monazite, zircon, etc.Infiltration fromunderclayHydrothermal:Fluids related toemplacementof Pine Mountain thrust

Many additional uses:Paper manufactureBrick manufactureSmall scale industriesAmmonia gas from coke ovensActivated carbonsSilicon metalCarbon nanotubesHydrogenLight weight composite materialsUnderground coal gasificationCARBON FIBRES: STRONG, LIGHT WEIGHT COMPOSITE MATERIALS

SUMMARY Coal is primarily used for coal combustion – pf combustion Multitude of coal utilization options beyond electricity generation Transport sector: liquid fuels; vehicles; infrastructure Clean energy: infrastructure; CRM Coal utilization is related to the type, grade, and rank of coal, as well as the chemicalcomposition of macerals Coal properties are a result of coal origin and formation, & subsequent processes Coal petrography enhances the understanding of coal deposits and coal utilizationCoal is significant in ourdaily livesAnd should be used in asocially responsible manner

Dr Klaus Brendow (World Energy Council): Coal’s globalimage does not reflect the realities of the industry

Coal is comprised of organic and inorganic (mineral) assemblages. . do we understand coal? (CCT, advanced applications) ORGANIC PETROLOGY FINDS RELEVANCE IN GEOLOGY, METALLURGY, CHEMICAL ENGINEERING, COAL SUSTAINABILITY ACROSS THE COAL VALUE-CHAIN . LIGHT WEIGHT COMPOSITE MATERIALS Underground coal gasification Many additional uses: Paper .

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