The Estimation Of The Wastewater Generation And Pollution Load By The .

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IWG-Env, International Work Session on Water Statistics, Vienna, June 20-22 2005The Estimation of the Wastewater Generation and PollutionLoad by the Branches of IndustryByKaia Oras and Eda GrünerStatistical Office of EstoniaIntroductionStatistical Office of Estonia conducted a small study with the aim to improve thequality of the data delivered by the Joint OECD/Eurostat Questionnaire on InlandWaters from Estonia, and particularly on the table 7 and 3.2 on wastewater treatmentand also on discharged wastewater volumes and wastewater pollutant loads.As practically no information existed on wastewater loads generated by the branchesof industry in Estonia, the estimations of the wastewater generation on the level ofindustry groups were made. Factors based on economic indicators were developedand used for the estimation of missing data on wastewater discharge quantities.As a starting point, the data about wastewater generation were readily available onlyfor the enterprises that discharged wastewater directly to environment (and possesseddischarge consent). For others, which deliver their wastewater to wastewatertreatment plants, practically no relevant information existed. The survey was carriedout to enterprises, which deliver their wastewater to wastewater treatment plants withthe focus to identify their water consumption and discharge. As a result the detailedwater consumption data on enterprise level were obtained. Data obtained by thissurvey were used as a starting point for combining economic data with data on watermanagement.The estimation of pollution (P, N, BOD, suspended solids) of industrial wastewaterwas performed in two locations of the flow: generation and discharge to environment:GenerationDischarge to environmentWaste water loading schemePOINT SOURCES:AgricultureWW 5.2.2Ind ustrial Activities (WW 5)WW 5.2.1 Mining and quarrying Manufacturing Industry Prod./Distr. Electricity ConstructionIW WTPWW 5.2WW 6.2WW 7.2WW 5.1Domestic Sector (WW 4) Other activities HouseholdsWW 4.1Urban WasteWater CollectingSystemWW 6.1WW 7WW 6.3WW 4.2.2IndependenttreatmentNON-POINT SOURCES: Run-off rainwater AgricultureWW 7.1UWWTPWW 6WW 4.2.1Rainwater run-off from paved area, infiltrationand drainage into collecting system Atmospheric depositionDrainage from soils, direct transfers etc.IWWTP Industrial waste water treatment plantUWWTP Urban waste water treatment plant1WW 4.2INLANDWATERS

IWG-Env, International Work Session on Water Statistics, Vienna, June 20-22 2005The estimations for industry groups (NACE 2-digit grouping level) were made forfollowing parameters: volume, BOD, N, P, suspended solids. The estimations werebased on water use data and statistical databases available in Statistical Office(production statistics, environmental expenditure statistics) and Estonian EnvironmentInformation Centre of the Ministry of the Environment of Estonia (Wastewater inflowpart of the database of wastewater treatment plants reports).Wastewater factorsIn order to reach full coverage of industrial sector on NACE 2 digit level on water use(by purpose types) and wastewater generation the factors were developed. Wastewaterfactors should be understood as the ratio between the amount of generated wastewaterin m3 d and net sales in kroons for given branch.As a first step the quantity relationship between the water use and wastewatergeneration on NACE 2 digit level were figured out.Factors based on economic indicators were developed and used for the estimation ofwastewater discharge quantities. The estimation of wastewater discharge quantitieswas based on net sales values. Wastewater factors were calculated according to theformula:Fww Wt/SWhere:Fww — wastewater factorWt — total quantity of wastewater generatedS — total net saleOn the bases of data of enterprises included in Statistical Office survey, thewastewater factors for NACE categories on 2 or 3 digit levels were calculated.nnFww — Σ Wt,i/ Σ S,i,i 1i 1Where:Wt — total quantity of wastewater generated by i enterprise,Si — total net sale of i enterprise,N — number of enterprises in given NACE categoryFor each economic activity group wastewater quantities were summed from the threecategories of data: Wastewater quantities on the bases of EEIC database on water useand discharge, Statistical Office survey results and the estimations of missingwastewater quantities based on monetary factor. Details on total estimated quantitiesof wastewater generated in each NACE category in 2001 are presented in Table 1.2

IWG-Env, International Work Session on Water Statistics, Vienna, June 20-22 2005Why the factors could not be developed from the basis of enterpriseswith pollution permissionFor comparison wastewater factors on economic activity level were also calculatedjust on the basis of the data of enterprise who possessed a discharge consent. Thenumber of such enterprises is low: in several economic activities only few enterpriseswere possessing pollution consents and some economic activities were notrepresented at all.Wastewater factors of enterprises with water permits are 10 times higher than the oneswithout water permits inside the same economic activity. So, the wastewaterquantities could have been heavily overestimated if the factors of the permit ownerswould have been used for the wastewater generation estimation. So, the reliability ofthe factors developed from the basis of the data of enterprises having water permits islower.Another reason is that quite often these enterprises have unique production type insideNACE category and the estimations based on these enterprises data cannot be appliedon other enterprises in this economic category.For example inside economic activity production of paper and products of paper(NACE category 21), only 2 enterprises produce paper from pulp or recycled paper.These are also the only 2 enterprises with water permits. Other enterprises in the sameeconomic activity (NACE category 21) do not possess water permits and they havecompletely different production profile as they are producing paper products out ofpaper. So, the factors derived from the data of the paper mills are not suitable for theestimation of the wastewater production of the paper products fabricators.Another economic activity with big variability is production of chemicals andchemical products (NACE 24), where one enterprise (big wastewater generation andlow net sales) is distorting the picture. The majority of enterprises does not have waterpermits and produce mainly cosmetics and other domestic chemicals.Comparison of wastewater factors derived from the data of enterprises with andwithout water permits is outlined in Table 2.The estimation of the pollution load reaching the environment bysource industry groupsNo factors for pollution loads (BOD, N, P, suspended solids) were calculated oneconomic activities level, because pollution load estimations were based on thequantities of generated wastewater. In fact they would have been the same factorsmultiplied with average pollution load of wastewater.The “upside down” approach (i.e. the estimation of the share of every economicactivity in total number) was used for the estimation of the share of different NACEcategories in the pollution load (N, P, BOD, suspended solids) released intoenvironment by wastewaterThe following presumptions were made:3

IWG-Env, International Work Session on Water Statistics, Vienna, June 20-22 20051. All wastewater discharged into environment has the same (average) load ofpollutants.2. Share of pollutants originated from different NACE categories is proportionalto the quantity of generated wastewater.Load of the following pollutants in wastewater was estimated: BOD7, suspendedsolids, total N and total P. These are the most common pollutants for which data werecollected and total quantities of these pollutant released into environment withwastewater was known.Quantities of pollutants in wastewater originating from different NACE categories arepresented in Table 3.The estimation of the pollution load generated by industry groupsEstimations were made on the basis of the influents flows to WWTP. In order to findout the industry wastewater, wastewater generated by households was subtracted fromthe total wastewater. The basis for the calculation was the expert opinion that inEstonia 1 inhabitant uses as average 127 litres water per day and produces the samequantity of wastewater.The assumption was made that the nutrients load of households and industrywastewater does not differ drastically and thus the quantities of pollutants weredivided between population and industry proportionally to the quantity of treatedwastewater.There are two types of WWTP-s which show different characteristics: URBAN-typeWWTP and all other types (including industrial) of WWTP.For the both types of WWTP’s the average concentrations of pollution loads of theinflow were found. Next, the division between the quantities of pollutants in influentflow originating from industry and households was found. The estimated quantities ofpollutants and wastewater volumes treated by both types of WWTP were summed.Next table outlines in right side the average pollution load of wastewater fromindustry and on the left side the division of total pollution between population andindustry.Quantities of pollutants in influentPollutantTotalinfluentFrompopulationFrom industryBOD7, tons37 104Suspended solids, tons 31 324Total N, tons7 3561 527Total P, tons14 02812 2332 85858923 07619 0904 497937Wastewater treated, m346 558 34972 561 2044Average pollutionload of wastewater fromindustry per cubic metre3182636213

IWG-Env, International Work Session on Water Statistics, Vienna, June 20-22 2005Estimation of the pollution generation by NACE categoriesIn order to estimate the pollution load of wastewater generated by NACE categoriesthe total estimated quantities of pollutants originated from industry were divided byNACE categories proportionally to the quantity of generated wastewater.Following presumption was made:1) Wastewater from all industry branches (NACE categories) has the same pollutionload (estimated as described above)2) Cooling wastewater wherever it is generated has the same pollution load (averageconcentration according to the inflow data of WWTP)3) Sanitary wastewater from of all enterprises has the same pollution load (which wasequalized to average concentration of the pollution load of URBAN-type of WWTPinfluent):In the Table 4 the pollution load by the sources and categories of wastewater areoutlined for the year 2001. Next, the pollution loads by categories of wastewater weresummed in order to get the pollution loads by economical sectors. Table 5 outlines theresults.ConclusionsData about wastewater generation were available only for the enterprises, whichdischarged wastewater directly to environment (and were possessing a dischargeconsent). For other enterprises, which deliver their wastewater to wastewatertreatment plants, practically no information existed on the quantities of wastewatergeneration and pollutions loads.The estimations on the wastewater generation by industry on the NACE 2-digitgrouping level were made for following parameters: volume, BOD, N, P, suspendedsolids. The estimations were based on water use data and statistical databasesavailable in Statistical Office (production statistics, environmental expenditurestatistics) and environmental Ministry (database of wastewater treatment facilities).In order to reach full coverage of industrial sector on NACE 2digit level on water use(by purpose types) and wastewater generation the wastewater factors were developed.Wastewater factors were based on statistical survey data and connected amount ofgenerated wastewater with economical data (net sales) of enterprises.In addition the estimation of pollution load (P, N, BOD, suspended solids) ofindustrial wastewater by industry on the NACE 2-digit grouping level in two locationsof the flow — generation and discharge to environment — was performed. Thepollution loads estimations were made on bases of data from database of wastewatertreatment facilities and estimated wastewater generation on the NACE 2-digitgrouping level.The result of the study could also provide the tool for forecasting of water supplydemand based on industrial statistics and forecasting.5

IWG-Env, International Work Session on Water Statistics, Vienna, June 20-22 2005Table 1. Generation of wastewater by NACE categories and by enterprise 3233343536TotalEnterprises havingwater permits5 951 1872 204 552371 62555 8701 198 8408 034 99800529 5001 779 73915 662981 228020 05949 23700036 417074 800421 21921 724 935Statistical Office survey39938953 126108 95747 992108 99018 1188 19651 8272 022 92534 66166 8947 092221 00684 56765929 137106 05885 77233 7424 18676 8703 570 1646Estimation accordingto Statistical Officesurvey17 7238 05211 9961 75814 1641019 868103 427068 6461 8772 3881 37624 2879 76245012 7426 76912 4462353 14017 968329 176TOTAL6 368 2992 265 730492 578105 6201 321 9948 053 21818 064155 254529 5003 871 31052 2001 050 5108 468265 352143 5671 10941 879112 827134 63633 97782 126516 05725 624 275

IWG-Env, International Work Session on Water Statistics, Vienna, June 20-22 2005Table 2. Wastewater factors derived from the data of enterprises with and withoutwater permitsEnterprises without water 3343536Number of enterprises Wastewater factor 1087Enterprises with water permitsNACENumber of ter factor 3910.0662.3280.0420.3231.2050.3940.295NACE

IWG-Env, International Work Session on Water Statistics, Vienna, June 20-22 2005Table 3. Quantities of pollutants in wastewater originating from different NACEcategories, tonsNACEBOD7Suspended ingtotal2.704 95 182.774Industrialandsanitary11.145cooling Total0.024 720.0006.2727.8860.0007.8860.4820.0000.48222.897 217.078290.354365.051 14.498 379.54922.320194.18179.184 369.53880.708 23.029

IWG-Env, International Work Session on Water Statistics, Vienna, June 20-22 2005Table 4. Pollution load of wastewater generated, by NACE categories, estimations for2001Quantity of wastewaterWastewater from industry (excl cooling water)industryCooling water SanitarycoolingBOD7Suspended solids Total N957 6791 655.5101 369.573322.66867.2721 174 788346.948287.02367.62214.0980298 70661.65651.00712.0172.505099 6491.8991.5710.3700.077346 2370975 757110.11291.09421.4614.4748 053 2181 939 7422 177 9873 935 489616.888510.340120.23525.06718 064998017 0660.3180.2630.0620.013222155 254113 65313 48028 12036.14529.9027.0451.46923529 500529 50000168.395139.31032.8216.843243 871 310274 0223 262 832334 45787.14672.09416.9853.5412552 2003 0594 85544 2860.9730.8050.1900.040261 050 510112 787293 023644 70035.86929.6746.9911.458278 4682 5461405 7830.8100.6700.1580.03328265 352159 97211 73693 64450.87542.0889.9162.06729143 56739 0552 813101 69912.42010.2752.4210.505301 109001 1090.0000.0000.0000.0003141 8791 4007 50332 9760.4450.3680.0870.01832112 82747 19512 65352 98015.00912.4172.9250.61033134 636116 065018 57136.91230.5367.1941.5003433 97714 2624 57515 1404.5363.7520.8840.1843582 1262 0996 69073 3370.6680.5520.1300.02736516 057225 2000290 85771.62059.25013.9592.910Total25 624 27510 424 1576 003 3259 196 7933 315.1532 742.565646.141134.711NACETotalFrom(excl.water)156 368 2995 205 582205 038172 265 7301 090 942018492 578193 87219105 6205 971201 321 99421221Total PContinues Wastewater from sanitaryCooling waterBOD7Suspended Total NsolidsTotal PBOD7Suspended solids Total NTotal 62263.02114.1030.0000.0000.0000.000211 652.8701 2.15785.13918.7864.2040.0000.0000.0000.000Total3 862.5702 692.067593.993132.92122.89779.18414.4980.7089

IWG-Env, International Work Session on Water Statistics, Vienna, June 20-22 2005Table 5. Pollution loads of BOD7, suspended solids, total N and total P by economicalsectors, tonsNACEBOD7Suspended solidsTotal NTotal P152 058.5091 20519.922376.71684.48318.5772182.2042 278.0651 932.7457.1147 200.6205 513.8151 254.633268.34110

Information Centre of the Ministry of the Environment of Estonia (Wastewater inflow part of the database of wastewater treatment plants reports). Wastewater factors In order to reach full coverage of industrial sector on NACE 2 digit level on water use (by purpose types) and wastewater generation the factors were developed. Wastewater

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