PROPYLENE GLYCOL 99% SAFETY DATA SHEET 2017 SECTION

PROPYLENE GLYCOL 99%SAFETY DATA SHEET2017SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct Name:Propylene Glycol – 99%General or Generic ID:Manufacturer’s Name:(same as Supplier)Recommended Use:Propane 1,2-diol; 1,2-dihydroxypropane; methyl-ethylene glycol; mono-propylene glycolInland Technologies International Ltd.P.O. Box 253, 14 Queen StreetTruro, Nova ScotiaB2N 5C1 CanadaPhone: 1-877-633-5263De-icing/Anti-icing applications, antifreeze agents, mining chemicals.Restricted Use:There are no uses advised against.Emergency Telephone:CANUTEC: 613-996-6666 or *666 on a cellular phoneSECTION 2. HAZARDS IDENTIFICATIONHazard ClassificationHealth Hazards:Hazard statement:Health0Flammability1Physical Hazard0This material is NOT HAZARDOUS by OSHA Hazard Communication definition.Propylene Glycol is a slightly combustible liquid. Do not handle near heat, sparks or openflame. May cause eye irritation. High aerosol concentrations may cause mild irritation ofthe nose and throat as well as central nervous system depression. Not expected to causeskin irritation. Not expected to be a sensitizer.Other hazards which donot result in GHSclassification:None.SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTSChemical IdentityCommon name and synonymsCAS numberContent in Percent (%)PROPYLENE GLYCOLGlycol, 1,2 - propandiol57-55-699 – 100%1

SECTION 4. FIRST AID MEASURESGeneral information:Ingestion:Inhalation:Skin contact:Eye contact:Get medical advice/attention if you feel unwell. Show this safety data sheet to the doctorin advance.Call a physician or poison control center immediately. Do not induce vomiting withoutadvice from poison control center. Never give liquid to an unconscious person. If vomitingoccurs, keep head low so that stomach content doesn’t get into lungs.Move to fresh air. Treat symptomatically. Get medical attention if symptoms persist.Wash skin thoroughly with soap and water. Get medical attention if irritation persistsafter washing.Immediately flush with plenty of water for at least 15 minutes. If easy to do, removecontact lenses. Get medical attention.Most important symptoms/effects, acute and delayed:Symptoms:May irritate eyes. Harmful if swallowed.Indication of immediate medical attention and special treatment needed:Treatment:Treat symptomatically. Symptoms may be delayed.SECTION 5. FIRE FIGHTING MEASURESGeneral fire hazards:Suitable and unsuitableextinguishing media:Specific hazards of arising fromchemical:Special protective equipmentand precautions for firefighters:In case of fire and/or explosion, do not breathe fumes.Suitable extinguishing media: Water spray, foam, dry powder or carbon dioxide.Unsuitable extinguishing media: Direct water spray will spread fire.Fire may produce irritating, corrosive and/or toxic gases.Special firefighting procedures: Move containers from fire area if you can do sowithout risk. Use water spray to keep fire-exposed containers cool. Cool containersexposed to flames with water until well after the fire is out.Special protective equipment for firefighters: Firefighters must use standardprotective equipment including flame retardant coat, helmet with face shield,gloves, rubber boots, and in enclosed spaces, SCBA.SECTION 6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protectiveequipment and emergencyprocedures:Methods and material forcontainment and cleaning:Notification procedures:Environmental precautions:Use personal protective equipment. Keep unauthorized personnel away. Keep upwind. Ventiliate closed spaces before entering them.Absorb spill with vermiculite or other inert material, then place in a container forchemical waste. Clean surface thoroughly to remove residual contamination. Dikefar ahead of larger spill for later recovery and disposal.Dike for later disposal. Prevent entry into waterways, sewers, basements orconfined areas. Stop the flow of material, if this is without risk. Inform authorities iflarge amounts are involved.Do not contaminate water sources or sewer. Prevent further leakage or spillage ifsafe to do so. Avoid discharge into drains, watercourses or onto the ground.2

SECTION 7. HANDLING AND STORAGEPrecautions for safe handling:Conditions for safe storage:(including any incompatibilities)Use personal protective equipment as required. Do not breathe mist or vapour.Avoid contact with eyes, skin and clothing. Do not taste or swallow. Wash handsthoroughly after handling. Do not handleuntil all safety precautions have been readand understood. Obtain special instructions before use.Keep container tightly closed. Store in well-ventilated place. Store in a dry place.Store in a locked or controlled access area.SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl Parameters:Occupational Exposure Limits:Chemical IdentityTypeExposure Limit ValuesPROPYLENE GLYCOLCeiling50 PPMPROPYLENE GLYCOL - AerosolCeilingEngineering Controls:Source125mg/m3US. OSHA VPEL100mg/m3ACGIH TLVMaintain sufficient mechanical (general and/or local exhaust) ventilation tomaintain exposure below TLVs.Individual protection measures, such as personal protective equipment:General information:Good general ventilation (typically 10 air exchanges per hour) should be used.Ventilation rates should be matched to conditions. If applicable, use processenclosures, local exhust ventilation, or other engineering controls to maintainairborne levels below recommended exposure limts. If exposure limits have notbeen established, maintain airborne levels to an acceptabel level. An eye wash andsafety shower must be avilable in the immediate work area.Eye/face protection:Wear safety glasses with side sheilds (or goggles).Skin Protection:Respiratory protection:Hygiene measures:Hand: Chemical resistant gloves.Other: Wear suitable protective clothingIn case of inadequate ventilation use suitable respirator. Chemical respirator withorganic vapour cartridge, full facepiece, dust and mist filter.Provide eyewash station and safety shower. Always observe good personal hygienemeasures, such as washing after handling the material and before eating, drinking,and/or smoking. Routinely wash work clothing and protective equipment toremove contaminants. Avoid contact with eyes, skin and clothing.SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESAppearance:Odour:Physical State: LiquidForm: LiquidColour: Clear (colourless)OdourlessOdour threshold:No data availablepH:6-8Melting point/freezing point:-76 F (-60 C)Initial boiling point and boiling range: 368 F ( 187 C)Flash point: 212 F (100 C) – Closed CupEvaporation rate:0.013

Flammability (solid/gas):Upper/lower limit on flammability orexplosive limits:Vapour pressure:No data availableFlammability limit – upper (%): 12.6 %(V)Flammability limit – lower (%): 2.6 %(V)Explosive limit – upper (%): No data availableExplosive limit – lower (%): No data available0.13mmHg @ 20 CVapour density:2.62 AIR 1Relative density:SolubilityPartition coefficient (n-octanol/water)1.03 (20 C)Solubility in water: Miscible with waterSolubility (other): No data availableNo data availableAuto-ignition temperature:752 F (400 C)Decomposition temperature:No data availableViscosity:Other information:45 mPa.s at 20 CMinimum ignition temperature: 752 F (400 C)Molecular weight: 76.10 g/mol (C3H8O2)SECTION 10. STABILITY AND REACTIVITYReactivity:No dangerous reactions known under conditions of normal use.Chemical stability:HygroscopicPossibility of hazardous reactions:Conditions to avoid:Incompatible materials:Hazardous polymerization does not occur.Excessive heat. Contact with incompatible materials. Exposure to moist air orwater.Strong oxidizing agents. Acids.Hazardous decomposition products:Thermal decomposition may release oxides of carbon.SECTION 11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure:Ingestion:Harmful if swallowed.Inhalation:Spray mist may irritate the respiratory system.Skin contact:May cause irritation.Eye contact:Causes serious eye irritation.Information on toxicological effects:Acute ToxicityOral:LD50 (Rat): 2,000mg/kgDermal:LD50 (Rabbit): 20,800mg/kgInhalation:No data available.Repeated dose toxicity:No data available.Skin corrosion/irritation:Defatting, drying and cracking of skin.Serious eye damage/eye irritation:May irritate eyes.Respiratory or skin sensitization:Not a skin sensitizer.Carcinogenicity:This substance has no evidence of carcinogenic properties.Germ cell mutagenicity:In Vitro: No mutagenic components identified.In Vivo: No mutagenic components identified.4

Reproductive toxicity:Specific target organ toxicity:(single exposure)Specific target organ toxicity:(repeated exposure)Aspiration hazard:May damage fertility or the unborn child.Other effects:None known.Central nervous system. Kidneys.Kidney, spleen, blood.Not classified.SECTION 12. ECOLOGICAL INFORMATIONEcotoxicity:Acute hazards to the aquatic environment: PROPYLENE GLYCOLFish:LC50 (Bluegill, 96 h): 51,400 mg/L MortalityLC50 (Fathead minnow, 96 h): 51,600 mg/L MortalityAquatic Invertebrates:EC50 (Water Flea, 48 h): 1000 mg/LChronic hazards to the aquatic environment:Fish:No data availableAquatic Invertebrates:No data availableToxicity to Aquatic Plants:No data availablePersistence and degradability:Biodegradation:BOD/COD Ratio:Mobility in soil:Other adverse effects:This product is expected to be biodegradableNo data availableThe product is water-soluble and may spread in water systems.The product components are not classified as environmentally hazardous.However, this does not exclude the possibility that large or frequent spills canhave a harmful or damaging effect on the environment.SECTION 13. DISPOSAL CONSIDERATIONDisposal Instructions:Contaminated packaging:Discharge, treatment, or disposal may be subject to national, state, or local laws.Since emptied containers retain product residue, follow label warnings even aftercontainer is emptied.SECTION 14. TRANSPORT INFORMATIONCanadian Transportation of Dangerous Goods Act:US DOT:IMDG:IATA:Not regulatedNot regulatedNot regulatedNot regulatedSECTION 15. REGULATORY INFORMATIONCanadian Regulations:This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and theSDS contains all of the information required by those regulations.WHMIS Classification – Propylene Glycol:D2B - Poisonous/Infectious material- Immediate/Serious effects5

- ToxicUnited States Federal Regulations:TSCA (Toxic Substances Control Act) Status:The intentional ingredients of this product are listed.CERCLA RQ – 40 CFR 302.4(a):Not applicableCERCLA RQ – 40 CFR 302.4(b):Not applicableSARA 313 Components – 40 CFR 355 Appendix A:NoneSection 311/312 Hazard Class – 40 CFR 370.2:XImmediateXDelayedFireReactivePressure GeneratingSARA 313 Components – 40 CFR 372.65:Section 313 Component(s):CAS Number:Percent (%):PROPYLENE GLYCOL57-55-699 – 100 %State and Local Regulations:California Proposition 65:NoneNew Jersey RTK Label Information:1,2-Propylene Glycol – 57-55-6Pennsylvania RTK Label Information:1,2-Propylene Glycol – 57-55-6Massachusetts RTK Label Information:1,2-Propylene Glycol – 57-55-6International Regulations:Inventory Status:Not determinedSECTION 16. OTHER INFORMATIONThe information accumulated herein is believed to be accurate but is not warranted to be whether originating with thecompany or not. Recipients are advised to confirm in advance of need that the information is current, applicable, andsuitable to their circumstances.Issue date: 09-15-2015Revision Date: 06-09-2017Version #: 1.4Further Information: No data available6

4 Flammability (solid/gas): No data available Upper/lower limit on flammability or explosive limits: Flammability limit – upper (%): 12.6 %(V) Flammability limit – lower (%): 2.6 %(V) Explosive limit – upper (%): No data available Explosive limit – lower (%): No data available Vapour pressure: 0.13mmHg @ 20 C Vapour density: