GHS - OSHA HCS Comparison Comparison Of Hazard .

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GHS - OSHA HCS ComparisonComparison of Hazard Communication Requirements

Comparison of Hazard Communication RequirementsTABLE OF CONTENTSI.IntroductionxGeneral Provisions ard determination/classificationLabelsWorkplace labelingUpdating labelsMSDS/SDSMSDS/SDS component disclosureUpdating MSDS/SDSInformation & TrainingTrade secrets /CBIMultiple hazards/PrecedenceHazard determination/classification provisionsII.Health Hazard ComparisonII-1Acute ToxicitySkin corrosion/irritationSerious eye damage/eye irritationRespiratory or skin sensitizationGerm cell mutagenicityCarcinogenicityToxic to reproductionTarget organ toxicity - - single exposureTarget organ toxicity - - repeated exposureIIIPhysical Hazard ComparisoniiIII-1

Comparison of Hazard Communication Requirements.IVExplosivesFlammable gasesFlammable AerosolsOxidizing gasesGases under pressureFlammable liquidsFlammable solidsSelf-reactive substancesPyrophoric liquidsPyrophoric solidsSelf-heating substancesSubstances which on Contact with Water emitsFlammable GasesOxidizing liquidsOxidizing solidsOrganic peroxidesCorrosive to metalsLabel ComparisonIV-1Comparison of HCS & GHS label elementsGHS & transport pictogramsLabel examples: GHS, ANSI/OSHA (HCS)VMSDS ComparisonIV-2IV-5IV-8V-1By 16 section formatBy MSDS elementVICompetent Authority Allowances & Building BlockDecisionsIntroductioniiiVI-1

Comparison of Hazard Communication Requirements1.1.1 Purpose, Scope & Application Of The GHS1.1.3.1.1 Application1.1.3.1.4 Consumer sector1.1.3.1.5.1 Building blocks1.3 Classification Of Hazardous Substances &Mixtures1.3.2.4.9.5 Single positive study1.3.3.2.2 Lower generic cut-off1.3.3.2.3 Higher generic cut-off1.3.3.2.4 Document cut-off variations1.4 Hazard Communication: Labeling1.4.1.5 UNCETDG signal word/hazard statement1.4.6.3.1 Supplemental information1.4.6.3.2 Supplemental hazard information1.4.7.2.2 Updating information1.4.7.2.3 Review label/MSDS1.4.8.2 CBI1.4.9 Training1.4.10.4.2.3 domestic & transport pictograms1.4.10.5.2 GHS label (c) Precautionary statements andpictograms1.4.10.5.2 GHS label (d) Product identifier(ii)1.4.10.5. GHS label (d) Product identifier (iii)1.4.10.5.3.1 Precedence for the allocation of symbols1.4.10.5.3.3 Precedence for allocation of hazardstatements1.4.10.5.4.1Location of GHS information on the label1.4.10.5.4.2Supplemental information: option &location1.4.10.5.4.3 Use of colour outside pictograms1.4.10.5.5 Special labelling arrangements1.4.10.5.5.1 Workplace labelling1.4.10.5.5.2 Consumer product labelling based on thelikelihood of injury1.4.10.5.5.3 Tactile warnings1.5 Hazard Communication: Safety Data Sheets1.5.2 Criteria for determining whether an SDS should beproduced1.5.3.1.2 Alternate cut-offs & MSDSiv

Comparison of Hazard Communication Requirements1.5.3.1.3 Acute/aquatic toxicity/ based on components at1%1.5.3.1.4 Building blocks/MSDS1.5.3.3.1 Additional information on MSDSTable 1.5.2 SDS Section 2.: graphics/pictogramsTable 1.5.2 SDS Section 3. concentration/rangesTable 1.5.2 SDS Section 16. Other information2.1 Explosives2.1.2.2 Hazard categories/classification2.1.2.2 Wetted with water or alcohols2.1.3 Hazard Communication2.2 Flammable Gases2.2.2 Hazard categories/classification2.2.2 NOTE 1: Ammonia and methyl bromide2.2.3 Hazard Communication2.2.4.2 Alternative test methods2.3 Flammable Aerosols2.3.2.2 Hazard categories/classification2.3.3 Hazard Communication2.4 Oxidizing Gases2.4.2 Classification NOTE: Artificial air2.4.3 Hazard Communication2.5 Gases Under Pressure2.5.2 Classification/groups2.5.4.2 Complex calculation2.5.3 Hazard Communication2.6 Flammable Liquid2.6.2 Classification/hazard categories2.6.1 Table NOTE 1: Gas oils, diesel and light heatingoilsNOTE 3: Viscous flammable liquids such as paints,enamels, lacquers, varnishes, adhesives and polishes2.6.3 Hazard Communication2.7 Flammable Solids2.7.2 Classification/hazard categoriesv

Comparison of Hazard Communication Requirements2.7.2.4 NOTE: tests on solid substances or mixtures2.7.3 Hazard Communication2.8 Self-Reactive Substances2.8.2.2 Classification/hazard categories2.8.4.1 Testing/methods2.8.3 Hazard Communication2.9 Pyrophoric Liquids2.9.2 Classification2.9.3 Hazard Communication2.10 Pyrophoric Solids2.10.2 Classification2.10.3 Hazard Communication2.11 Self-Heating Substances2.11.2.2 Classification/hazard categories2.11.2.2 NOTE 1: tests on solid substances or mixtures2.11.3 Hazard Communication2.12 Substances Which, In Contact With Water,Emit Flammable Gas2.12.2 Classification/hazard categories2.11.2.1 NOTE 2: tests on solid substances or mixtures2.12.3 Hazard Communication2.13 Oxidizing Liquids2.13.2 Classification/hazard categories2.13.4.1 Test method2.13.3 Hazard Communication2.14 Oxidizing Solids2.14.2 Classification/hazard categories2.14.4.1 Test method2.14.3 Hazard Communication2.15 Organic Peroxides2.15.2.2 Classification/hazard categories2.15.4.1 Test series2.15.3 Hazard Communicationvi

Comparison of Hazard Communication Requirements2.16 Corrosive To Metals2.16.2 Classification2.16.3 Hazard Communication3.1 Acute Toxicity3.1.2 Classification/hazard categories/building blocks3.1.4 Hazard Communication3.2 Skin Corrosion/Irritation3.2.2.4.2 Corrosion: classification/hazardcategories/building blocks3.2.2.5 Irritation: classification/hazard categories/buildingblocks3.2.4 Hazard Communication3.3 Serious Eye Damage/Eye Irritation3.3.2.9 Reversible eye effects: classification/hazardcategories/building blocks3.3.4 Hazard Communication3.4 Respiratory or Skin Sensitization3.4.3.3 Skin Sensitizer Classification criteria formixtures: MSDS/labels (note 1)3.4.3.3 Respiratory Sensitizer Classification criteria formixtures (liquid/solid): MSDS/labels (note 3)3.4.3.3 Respiratory Sensitizer Classification criteria formixtures (gaseous): MSDS/labels (note 5)3.4.4 Hazard Communication3.5 Germ Cell Mutagenicity3.5.2.1 Classification/hazard categories/building blocks3.5.3.1 Test data for mixtures3.5.4 Hazard Communication3.6 Carcinogenicity3.6.2.1 Route specific classification3.6.2.6 One positive study3.6.3.1 Test data for mixtures3.6.3.3 Carcinogen Classification criteria for mixtures:MSDS/labels (note 1)3.6.4 Hazard Communicationvii

Comparison of Hazard Communication Requirements3.7 Reproductive Toxicity3.7.2.3.1 One positive study3.7.3.1 Test data for mixtures3.7.3.3 Category 1 reproductive toxicant Classificationcriteria for mixtures: MSDS/labels (note 1)3.7.3.3 Category 2 Classification criteria for mixtures:MSDS/labels (note 3)3.7.4 Hazard Communication3.8 Specific Target Organ Systemic Toxicity –Single Exposure3.8.2.1 Classification/hazard categories/building blocks3.8.2.10.4 Saturated vapour concentration3.8.2 Category 1 target organ/systemic toxicantClassification criteria for mixtures: MSDS/labels (note 1)3.8.2 Category 1 target organ/systemic toxicantClassification criteria for mixtures: MSDS/labels (note 3)3.8.2 Category 2 target organ/systemic toxicantClassification criteria for mixtures: MSDS/labels (note 4)3.8.4 Hazard Communication3.9 Specific Target Organ Systemic Toxicity –Repeat Exposure3.9.2.1 Classification/hazard categories/building blocks3.9.2.10.4 Saturated vapour concentration3.9.3 Category 1 target organ/systemic toxicantClassification criteria for mixtures: MSDS/labels (note 1)3.9.3 Category 1 target organ/systemic toxicantClassification criteria for mixtures: MSDS/labels (note 3)3.9.3 Category 2 target organ/systemic toxicantClassification criteria for mixtures: MSDS/labels (note 4)3.9.4 Hazard Communicationviii

Comparison of Hazard Communication RequirementsComparison of Hazard Communication RequirementsOSHA Hazard Communication Standard 29CFR1910.12001 (HCS)Globally Harmonized System2 (GHS)ix

Comparison of Hazard Communication RequirementsComparison of Hazard Communication RequirementsIntroductionThe Globally Harmonized System (GHS) is not in itself a regulation or a model regulation. It is aframework from which competent authorities may select the appropriate harmonizedclassification & communication elements. Competent authorities will decide how to apply thevarious elements of the GHS within their systems based on their needs and the target audience.The GHS includes the following elements:(a)(b)harmonized criteria for classifying substances and mixtures according to theirhealth, environmental and physical hazards; andharmonized hazard communication elements, including requirements forlabeling and material safety data sheets.The harmonized elements of the GHS may be seen as a collection of building blocks from whichto form a regulatory approach. While the full range is available to everyone, and should be used ifa country or organization chooses to cover a certain effect when it adopts the GHS, the full rangedoes not have to be adopted. This constitutes the GHS building block approach.Competent authorities, such as OSHA, will determine how to implement the elements of the GHSwithin their systems. This document compares the GHS elements to the OSHA HazardCommunication Standard (HCS) elements. The competent authority allowances/decision pointsand the selection of building blocks are addressed in Section VI.This Comparison of Hazard Communication Requirements document includes the followingsegments: I. General provisions comparisonII. Health hazard comparisonIII. Physical hazard comparisonIV. Label comparison GHS & transport pictograms Label examplesV. MSDS comparisonVI. GHS Competent Authority Allowances & Building Block Discussion.x

Comparison of Hazard Communication RequirementsI. General Provisions ComparisonI-1

Comparison of Hazard Communication RequirementsPurposeComparisonThe purpose of the HCS and GHS are consistent. The HCS is one of the major existing systems which was to beharmonized by the GHS. While the intent of the GHS in international harmonization, it will also addressharmonization of sectors and regulations within countries.OSHA HCS 29CFR1910.12001GHS229 CFR 1910.1200 (a)(1) PurposeThe purpose of this section is to ensure that the hazards of allchemicals produced or imported are evaluated, and thatinformation concerning their hazards is transmitted toemployers and employees. This transmittal of information isto be accomplished by means of comprehensive hazardcommunication programs, which are to include containerlabeling and other forms of warning, material safety datasheets and employee training.(a)(2)This occupational safety and health standard is intended toaddress comprehensively the issue of evaluating the potentialhazards of chemicals, and communicating informationconcerning hazards and appropriate protective measures toemployees, and to preempt any legal requirements of a state,or political subdivision of a state, pertaining to this subject.Evaluating the potential hazards of chemicals, andcommunicating information concerning hazards andappropriate protective measures to employees, may include,for example, but is not limited to, provisions for: developingand maintaining a written hazard communication program forthe workplace, including lists of hazardous chemicals present;labeling of containers of chemicals in the workplace, as wellas of containers of chemicals being shipped to otherworkplaces; preparation and distribution of material safetydata sheets to employees and downstream employers; anddevelopment and implementation of employee trainingprograms regarding hazards of chemicals and protectivemeasures. Under section 18 of the Act, no state or politicalsubdivision of a state may adopt or enforce, through any courtor agency, any requirement relating to the issue addressed bythis Federal standard, except pursuant to a Federally-approvedstate plan.1.1.1 Purpose1.1.1.1. The use of chemical products to enhance andimprove life is a widespread practice worldwide. Butalongside the benefits of these products, there is also thepotential for adverse effects to people or the environment.As a result, a number of countries or organizations havedeveloped laws or regulations over the years that requireinformation to be prepared and transmitted to those usingchemicals, through labels or Safety Data Sheets (SDS).Given the large number of chemical products available,individual regulation of all of them is simply not possiblefor any entity. Provision of information gives those usingchemicals the identities and hazards of these chemicals, andallows the appropriate protective measures to beimplemented in the local use settings.I-21.1.1.2 While these existing laws or regulations are similarin many respects, their differences are significant enough toresult in different labels or SDS for the same product indifferent countries. Through variations in definitions ofhazards, a chemical may be considered flammable in onecountry, but not another. Or it may be considered to causecancer in one country, but not another. Decisions on whenor how to communicate hazards on a label or SDS thusvary around the world, and companies wishing to beinvolved in international trade must have large staffs ofexperts who can follow the changes in these laws andregulations and prepare different labels and SDS. Inaddition, given the complexity of developing andmaintaining a comprehensive system for classifying andlabelling chemicals, many countries have no system at all.1.1.1.3 Given the reality of the extensive global trade inchemicals, and the need to develop national programs toensure their safe use, transport, and disposal, it wasrecognised that an internationally-harmonized approach toclassification and labelling would provide the foundationfor such programs. Once countries have consistent andappropriate information on the chemicals they import orproduce in their own countries, the infrastructure to controlchemical exposures and protect people and the environmentcan be established in a comprehensive manner.

Comparison of Hazard Communication Requirements1.1.1.4 Thus the reasons for setting the objective ofharmonization were many. It is anticipated that, whenimplemented, the GHS will:(a) enhance the protection of human health and theenvironment by providing an internationallycomprehensible system for hazard communication;(b) provide a recognized framework for those countrieswithout an existing system;(c) reduce the need for testing and evaluation of chemicals;and(d) facilitate international trade in chemicals whose hazardshave been properly assessed and identified on aninternational basis.1.1.1.5 The work began with examination of existingsystems, and determination of the scope of the work. Whilemany countries had some requirements, the followingsystems were deemed to be the “major” existing systemsand were used as the primary basis for the elaboration ofthe GHS:Requirements of systems in the United States of Americafor the workplace, consumers and pesticides;(b) Requirements of Canada for the workplace, consumersand pesticides;(c) European Union directives for classification andlabelling of substances and preparations;(d) The United Nations Recommendations on theTransport of Dangerous Goods.1.1.1.6 The requirements of other countries were alsoexamined as the work developed, but the primary task wasto find ways to adopt the best aspects of these existingsystems and develop a harmonized approach. This workwas done based on agreed principles of harmonization thatwere adopted early in the process:(a) the level of protection offered to workers, consumers,the general public and the environment should not bereduced as a result of harmonizing the classification andlabelling systems;(b) the hazard classification process refers principally tothe hazards arising from the intrinsic properties of chemicalelements and compounds and mixtures thereof, whethernatural or synthetic;(c) harmonization means establishing a common andcoherent basis for chemical hazard classification andcommunication, from which the appropriate elementsrelevant to means of transport, consumer, worker andenvironment protection can be selected;(d) the scope of harmonization includes both hazardclassification criteria and hazard communication tools, e.g.labelling and chemical safety data sheets, taking intoaccount especially the four existing systems identified inthe ILO report;(e) changes in all these systems will be required to achievea single globally harmonized system; transitional measuresshould be included in the process of moving to the newsystem;I-3

Comparison of Hazard Communication Requirements(f) the involvement of concerned internationalorganizations of employers, workers, consumers, and otherrelevant organizations in the process of harmonizationshould be ensured;(g) the comprehension of chemical hazard information, bythe target audience, e.g. workers, consumers and thegeneral public should be addressed;(h)validated data already generated for the classification ofchemicals under the existing systems should be acceptedwhen reclassifying these chemicals under the harmonizedsystem;(i) a new harmonized classification system may requireadaptation of existing methods for testing of chemicals;(j) in relation to chemical hazard communication, the safetyand health of workers, consumers and the public in general,as well as the protection of the environment, should beensured while protecting confidential business information,as prescribed by the competent authorities.I-4

Comparison of Hazard Communication RequirementsScopeComparisonThe GHS scope clarification is consistent with the HCS exemptions and labeling exceptions. Consumer productsand pharmaceuticals are specifically addressed in the GHS scope. The HCS includes laboratories, sealedcontainers and distributors while as a framework for systems the GHS does not include these specific issues.The GHS addresses testing in the scope section. The HCS addresses testing under hazard determination. TheGHS and HCS do not require testing for health hazards. All the physical hazards in the HCS are not linked tospecific test methods (as is the case in the GHS) and testing for physical hazards is not required.OSHA HCS 29CFR1910.1200129 CFR 1910.1200 (b) Scope and application(b)(1)This section requires chemical manufacturers or importers toassess the hazards of chemicals which they produce or import,and all employers to provide information to their employeesabout the hazardous chemicals to which they are exposed, bymeans of a hazard communication program, labels and otherforms of warning, material safety data sheets, and informationand training. In addition, this section requires distributors totransmit the required information to employers. (Employerswho do not produce or import chemicals need only focus onthose parts of this rule that deal with establishing a workplaceprogram and communicating information to their workers.Appendix E of this section is a general guide for suchemployers to help them determine their complianceobligations under the rule.)GHS21.1.2 Scope1.1.2.1 The GHS includes the following elements:(a) harmonized criteria for classifying substances andmixtures according to their health, environmental andphysical hazards; and(b) harmonized hazard communication elements, includingrequirements for labelling and safety data sheets.1.1.2.2 This document describes the classification criteriaand the hazard communication elements by type of hazard(e.g. acute toxicity; flammability). In addition, decisionlogics for each hazard have been developed. Someexamples of classification of chemicals in the text, as wellas in Annex 7, illustrate how to apply the criteria. There isalso some discussion about issues that were raised duringthe development of the system where additional guidancewas thought to be necessary to implement the system.1.1.2.3 The scope of the GHS is based on the mandatefrom the 1992 United Nations Conference on Environmentand Development (UNCED)for development of such asystem as stated in paragraphs 26 and 27 of the Agenda 21,Chapt

(b) harmonized hazard communication elements, including requirements for labelling and safety data sheets. 1.1.2.2 This document describes the classification criteria and the hazard communication elements by type of hazard (e.g. acute toxicity; flammability). In addition, decision logics for each hazard have been developed. Some

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