Page 1/11 Safety Data Sheet Acc. To OSHA HCS

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51.0.2Page 1/11Safety Data Sheetacc. to OSHA HCSPrinting date 07/20/2020Reviewed on 07/20/20201 Identification· Product identifier· Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE· Article number: 12660, 12660-500g, 12660-SPECIAL· Application of the substance / the mixture Laboratory chemicals· Details of the supplier of the safety data sheet· Manufacturer/Supplier:Electron Microscopy Sciences1560 Industry RoadUSA-Hatfield, PA 19440Tel: 215-412-8400 Fax: 215-412-8450email: sgkcck@aol.comwww.emsdiasum.com· Information department: Product safety department· Emergency telephone number:ChemTrec 1-800-424-9300 Contract CCN76611-703-527-38872 Hazard(s) identification· Classification of the substance or mixtureGHS02 FlameFlam. Liq. 2 H225 Highly flammable liquid and vapor.GHS06 Skull and crossbonesAcute Tox. 3 H331 Toxic if inhaled.GHS05 CorrosionEye Dam. 1 H318 Causes serious eye damage.GHS07Skin Irrit. 2 H315 Causes skin irritation.STOT SE 3 H336 May cause drowsiness or dizziness.· Label elements· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).· Hazard pictogramsGHS02GHS05GHS06GHS07· Signal word Danger(Contd. on page 2)US

51.0.2Page 2/11Safety Data Sheetacc. to OSHA HCSPrinting date 07/20/2020Reviewed on 07/20/2020Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE(Contd. of page 1)· Hazard-determining components of labeling:Graphiten-Butyl Alcoholpropan-2-ol1-methoxy-2-propanol· Hazard statementsHighly flammable liquid and vapor.Toxic if inhaled.Causes skin irritation.Causes serious eye damage.May cause drowsiness or dizziness.· Precautionary statementsKeep away from heat/sparks/open flames/hot surfaces. - No smoking.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/equipment.Use only non-sparking tools.Take precautionary measures against static discharge.Avoid breathing dust/fume/gas/mist/vapors/sprayWash thoroughly after handling.Use only outdoors or in a well-ventilated area.Wear protective gloves/protective clothing/eye protection/face protection.If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.IF INHALED: Remove person to fresh air and keep comfortable for breathing.If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.Immediately call a poison center/doctor.Specific treatment (see on this label).Take off contaminated clothing and wash it before reuse.If skin irritation occurs: Get medical advice/attention.In case of fire: Use for extinction: CO2, powder or water spray.Store in a well-ventilated place. Keep container tightly closed.Store in a well-ventilated place. Keep cool.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.· Classification system:· NFPA ratings (scale 0 - 4)Health 2Fire 2Reactivity 0220· HMIS-ratings (scale 0 - 4)HEALTH2FIRE2REACTIVITY 0Health 2Fire 2Reactivity 0· Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.US(Contd. on page 3)

51.0.2Page 3/11Safety Data Sheetacc. to OSHA HCSPrinting date 07/20/2020Reviewed on 07/20/2020Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE(Contd. of page 2)3 Composition/information on ingredients· Chemical characterization: Mixtures· Description: Mixture of the substances listed below with nonhazardous additions.· Dangerous components:67-63-0 propan-2-ol7782-42-5 Graphite71-36-3 n-Butyl Alcohol107-98-2 1-methoxy-2-propanol 50- 100% 10- 25% 2.5- 10% 2.5- 10%4 First-aid measures· Description of first aid measures· General information:Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hoursafter the accident.· After inhalation:Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.In case of unconsciousness place patient stably in side position for transportation.· After skin contact: Immediately wash with water and soap and rinse thoroughly.· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.· After swallowing: If symptoms persist consult doctor.· Information for doctor:· Most important symptoms and effects, both acute and delayed No further relevant information available.· Indication of any immediate medical attention and special treatment neededNo further relevant information available.5 Fire-fighting measures· Extinguishing media· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.· For safety reasons unsuitable extinguishing agents: Water with full jet· Special hazards arising from the substance or mixture No further relevant information available.· Advice for firefighters· Protective equipment: Mouth respiratory protective device.6 Accidental release measures· Personal precautions, protective equipment and emergency proceduresWear protective equipment. Keep unprotected persons away.· Environmental precautions: Do not allow to enter sewers/ surface or ground water.· Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Dispose contaminated material as waste according to item 13.Ensure adequate ventilation.Do not flush with water or aqueous cleansing agents· Reference to other sectionsSee Section 7 for information on safe handling.See Section 8 for information on personal protection equipment.See Section 13 for disposal information.(Contd. on page 4)US

51.0.2Page 4/11Safety Data Sheetacc. to OSHA HCSPrinting date 07/20/2020Reviewed on 07/20/2020Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE(Contd. of page 3)· Protective Action Criteria for Chemicals· PAC-1:67-63-0 propan-2-ol71-36-3 n-Butyl Alcohol107-98-2 1-methoxy-2-propanol400 ppm60 ppm100 ppm· PAC-2:67-63-0 propan-2-ol71-36-3 n-Butyl Alcohol107-98-2 1-methoxy-2-propanol2000* ppm800 ppm160 ppm· PAC-3:67-63-0 propan-2-ol71-36-3 n-Butyl Alcohol107-98-2 1-methoxy-2-propanol12000** ppm8000** ppm660 ppm7 Handling and storage· Handling:· Precautions for safe handlingEnsure good ventilation/exhaustion at the workplace.Prevent formation of aerosols.· Information about protection against explosions and fires:Keep ignition sources away - Do not smoke.Protect from heat.Protect against electrostatic charges.· Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles: Store in a cool location.· Information about storage in one common storage facility: Not required.· Further information about storage conditions:Keep receptacle tightly sealed.Store in cool, dry conditions in well sealed receptacles.Protect from heat and direct sunlight.· Specific end use(s) No further relevant information available.8 Exposure controls/personal protection· Additional information about design of technical systems: No further data; see item 7.· Control parameters· Components with limit values that require monitoring at the workplace:The following constituents are the only constituents of the product which have a PEL, TLV or other recommendedexposure limit.At this time, the remaining constituent has no known exposure limits.67-63-0 propan-2-olPEL Long-term value: 980 mg/m³, 400 ppm(Contd. on page 5)US

51.0.2Page 5/11Safety Data Sheetacc. to OSHA HCSPrinting date 07/20/2020Reviewed on 07/20/2020Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE(Contd. of page 4)REL Short-term value: 1225 mg/m³, 500 ppmLong-term value: 980 mg/m³, 400 ppmTLV Short-term value: 984 mg/m³, 400 ppmLong-term value: 492 mg/m³, 200 ppmBEI71-36-3 n-Butyl AlcoholPEL Long-term value: 300 mg/m³, 100 ppmREL Ceiling limit value: 150 mg/m³, 50 ppmSkinTLV Long-term value: 61 mg/m³, 20 ppm107-98-2 1-methoxy-2-propanolREL Short-term value: 540 mg/m³, 150 ppmLong-term value: 360 mg/m³, 100 ppmTLV Short-term value: 369 mg/m³, 100 ppmLong-term value: 184 mg/m³, 50 ppm· Ingredients with biological limit values:67-63-0 propan-2-olBEI 40 mg/LMedium: urineTime: end of shift at end of workweekParameter: Acetone (background, nonspecific)· Additional information: The lists that were valid during the creation were used as basis.· Exposure controls· Personal protective equipment:· General protective and hygienic measures:Keep away from foodstuffs, beverages and feed.Immediately remove all soiled and contaminated clothing.Wash hands before breaks and at the end of work.Avoid contact with the skin.Avoid contact with the eyes and skin.· Breathing equipment:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure userespiratory protective device that is independent of circulating air.· Protection of hands:Protective glovesThe glove material has to be impermeable and resistant to the product/ the substance/ the preparation.Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ thechemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marks of quality andvaries from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance ofthe glove material can not be calculated in advance and has therefore to be checked prior to the application.· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to beobserved.(Contd. on page 6)US

51.0.2Page 6/11Safety Data Sheetacc. to OSHA HCSPrinting date 07/20/2020Reviewed on 07/20/2020Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE(Contd. of page 5)· Eye protection:Tightly sealed goggles9 Physical and chemical properties· Information on basic physical and chemical properties· General Information· Appearance:FluidForm:BlackColor:Characteristic· Odor:Not determined.· Odor threshold:· pH-value:Not determined.· Change in conditionMelting point/Melting range:Boiling point/Boiling range:-88.8 C (-127.8 F)82 C (179.6 F)· Flash point:11 C (51.8 F)· Flammability (solid, gaseous):Not flammable.· Ignition temperature:270 C (518 F)· Decomposition temperature:Not determined.· Auto igniting:Product is not selfigniting.· Danger of explosion:Product is not explosive. However, formation of explosive air/vapormixtures are possible.· Explosion limits:Lower:Upper:1.5 Vol %20 Vol %· Vapor pressure at 20 C (68 F):43 hPa (32.3 mm Hg)· Density:· Relative density· Vapor density· Evaporation rateNot determined.Not determined.Not determined.Not determined.· Solubility in / Miscibility withWater:Not miscible or difficult to mix.· Partition coefficient (n-octanol/water): Not determined.· Viscosity:Dynamic:Kinematic:· Solvent content:Organic solvents:VOC content:Not determined.Not determined.80.0 %80.00 %800.0 g/l / 6.68 lb/gal(Contd. on page 7)US

51.0.2Page 7/11Safety Data Sheetacc. to OSHA HCSPrinting date 07/20/2020Reviewed on 07/20/2020Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE(Contd. of page 6)Solids content:· Other information0.0 %No further relevant information available.10 Stability and reactivity· Reactivity No further relevant information available.· Chemical stability· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.· Possibility of hazardous reactions No dangerous reactions known.· Conditions to avoid No further relevant information available.· Incompatible materials: No further relevant information available.· Hazardous decomposition products: No dangerous decomposition products known.11 Toxicological information· Information on toxicological effects· Acute toxicity:· LD/LC50 values that are relevant for classification:67-63-0 propan-2-olOralLD505,045 mg/kg (rat)DermalLD5012,800 mg/kg (rabbit)Inhalative LC50/4 h 30 mg/l (rat)· Primary irritant effect:· on the skin: Irritant to skin and mucous membranes.· on the eye: Strong irritant with the danger of severe eye injury.· Sensitization: No sensitizing effects known.· Additional toxicological information:The product shows the following dangers according to internally approved calculation methods for preparations:HarmfulIrritant· Carcinogenic categories· IARC (International Agency for Research on Cancer)67-63-0 propan-2-ol3· NTP (National Toxicology Program)None of the ingredients is listed.· OSHA-Ca (Occupational Safety Health Administration)None of the ingredients is listed.12 Ecological information· Toxicity· Aquatic toxicity: No further relevant information available.· Persistence and degradability No further relevant information available.· Behavior in environmental systems:· Bioaccumulative potential No further relevant information available.· Mobility in soil No further relevant information available.(Contd. on page 8)US

51.0.2Page 8/11Safety Data Sheetacc. to OSHA HCSPrinting date 07/20/2020Reviewed on 07/20/2020Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE(Contd. of page 7)· Additional ecological information:· General notes:Water hazard class 1 (Self-assessment): slightly hazardous for waterDo not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.· Other adverse effects No further relevant information available.13 Disposal considerations· Waste treatment methods· Recommendation:Must not be disposed of together with household garbage. Do not allow product to reach sewage system.· Uncleaned packagings:· Recommendation: Disposal must be made according to official regulations.14 Transport information· UN-Number· DOT, ADR, IMDG, IATAUN1263· UN proper shipping name· DOT· ADR· IMDG, IATAPaint1263 PAINTPAINT· Transport hazard class(es)· DOT· Class· Label3 Flammable liquids3· ADR, IMDG, IATA· Class· Label3 Flammable liquids3· Packing group· DOT, ADR, IMDG, IATAII· Environmental hazards:Not applicable.Warning: Flammable liquids· Special precautions for user· Hazard identification number (Kemler code): 33F-E,S-E· EMS Number:(Contd. on page 9)US

51.0.2Page 9/11Safety Data Sheetacc. to OSHA HCSPrinting date 07/20/2020Reviewed on 07/20/2020Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE(Contd. of page 8)· Stowage CategoryB· Transport in bulk according to Annex II ofMARPOL73/78 and the IBC CodeNot applicable.· Transport/Additional information:· DOT· Quantity limitations· ADR· Excepted quantities (EQ)· IMDG· Limited quantities (LQ)· Excepted quantities (EQ)· UN "Model Regulation":On passenger aircraft/rail: 5 LOn cargo aircraft only: 60 LCode: E2Maximum net quantity per inner packaging: 30 mlMaximum net quantity per outer packaging: 500 ml1LCode: E2Maximum net quantity per inner packaging: 30 mlMaximum net quantity per outer packaging: 500 mlUN 1263 PAINT, 3, II15 Regulatory information· Safety, health and environmental regulations/legislation specific for the substance or mixture· Sara· Section 355 (extremely hazardous substances):None of the ingredients is listed.· Section 313 (Specific toxic chemical listings):67-63-0 propan-2-ol71-36-3 n-Butyl Alcohol· TSCA (Toxic Substances Control Act):All components have the value ACTIVE.· Hazardous Air PollutantsNone of the ingredients is listed.· Proposition 65· Chemicals known to cause cancer:None of the ingredients is listed.· Chemicals known to cause reproductive toxicity for females:None of the ingredients is listed.· Chemicals known to cause reproductive toxicity for males:None of the ingredients is listed.· Chemicals known to cause developmental toxicity:None of the ingredients is listed.· Carcinogenic categories· EPA (Environmental Protection Agency)71-36-3 n-Butyl AlcoholD(Contd. on page 10)US

51.0.2Page 10/11Safety Data Sheetacc. to OSHA HCSPrinting date 07/20/2020Reviewed on 07/20/2020Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE(Contd. of page 9)· TLV (Threshold Limit Value established by ACGIH)67-63-0 propan-2-olA4· NIOSH-Ca (National Institute for Occupational Safety and Health)None of the ingredients is listed.· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).· Hazard pictogramsGHS02GHS05GHS06GHS07· Signal word Danger· Hazard-determining components of labeling:Graphiten-Butyl Alcoholpropan-2-ol1-methoxy-2-propanol· Hazard statementsHighly flammable liquid and vapor.Toxic if inhaled.Causes skin irritation.Causes serious eye damage.May cause drowsiness or dizziness.· Precautionary statementsKeep away from heat/sparks/open flames/hot surfaces. - No smoking.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/equipment.Use only non-sparking tools.Take precautionary measures against static discharge.Avoid breathing dust/fume/gas/mist/vapors/sprayWash thoroughly after handling.Use only outdoors or in a well-ventilated area.Wear protective gloves/protective clothing/eye protection/face protection.If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.IF INHALED: Remove person to fresh air and keep comfortable for breathing.If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.Immediately call a poison center/doctor.Specific treatment (see on this label).Take off contaminated clothing and wash it before reuse.If skin irritation occurs: Get medical advice/attention.In case of fire: Use for extinction: CO2, powder or water spray.Store in a well-ventilated place. Keep container tightly closed.Store in a well-ventilated place. Keep cool.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.US(Contd. on page 11)

51.0.2Page 11/11Safety Data Sheetacc. to OSHA HCSPrinting date 07/20/2020Reviewed on 07/20/2020Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE(Contd. of page 10)16 Other informationThis information is based on our present knowledge. However, this shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship.· Date of preparation / last revision 07/20/2020 / · Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the InternationalCarriage of Dangerous Goods by Road)IMDG: International Maritime Code for Dangerous GoodsDOT: US Department of TransportationIATA: International Air Transport AssociationACGIH: American Conference of Governmental Industrial HygienistsEINECS: European Inventory of Existing Commercial Chemical SubstancesELINCS: European List of Notified Chemical SubstancesCAS: Chemical Abstracts Service (division of the American Chemical Society)NFPA: National Fire Protection Association (USA)HMIS: Hazardous Materials Identification System (USA)VOC: Volatile Organic Compounds (USA, EU)LC50: Lethal concentration, 50 percentLD50: Lethal dose, 50 percentPBT: Persistent, Bioaccumulative and ToxicvPvB: very Persistent and very BioaccumulativeNIOSH: National Institute for Occupational SafetyOSHA: Occupational Safety HealthTLV: Threshold Limit ValuePEL: Permissible Exposure LimitREL: Recommended Exposure LimitBEI: Biological Exposure LimitFlam. Liq. 2: Flammable liquids – Category 2Acute Tox. 3: Acute toxicity – Category 3Skin Irrit. 2: Skin corrosion/irritation – Category 2Eye Dam. 1: Serious eye damage/eye irritation – Category 1STOT SE 3: Specific target organ toxicity (single exposure) – Category 3US

51.0.2Page 1/9Safety Data Sheetaccording to WHS RegulationsPrinting date 20.07.2020Revision: 20.07.20201 Identification· Product identifier· Trade name: COLLO

Page 1/11 Safety Data Sheet acc. to OSHA HCS Printing date 07/20/2020 Reviewed on 07/20/2020 51.0.2 1 Identification · Product identifier · Trade name: COLLOIDAL GRAPHITE, ALCOHOL BASE · Article number: 12660, 12660-500g, 12660-SPECIAL · Application of the substance / the mixture Laboratory chemicals · Details of the supplier of the safety data sheet · Manufacturer/Supplier:

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