Zenith Polymer Diffuse Reflectance Standards, Targets And . - Tokyo Inst

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Zenith Polymer Diffuse Reflectance Standards,Targets and MaterialsFOR USE OVER THE UV, VIS AND NIR SPECTRAL REGIONS. your Partner in Lighting Technology!

Properties of Zenith Polymer – optical PTFEAll SphereOptics GmbH Zenith Polymer products are made from ourmaterial available in Germany and throughout the production process,proprietary Zenith Polymer reflectance material. This highly reflecting,including pressing and sintering, the highest level of cleanness is main-PTFE-based material is resistant to harsh environments and exposurestained. All machines used to obtain the final product are reserved exclu-and its unique optical properties, when produced under strict clean con-sively for PTFE use to keep the high level of purity.ditions, makes it the ideal reflectance material for standards or targets.Manufactured in Germany under ISO/TS 16949 conditions, we act as aOur products are all produced using the highest purity PTFE powderreliable and qualified partner in the European industry.MECHANICAL/CHEMICAL PROPERTIES:OPTICAL PROPERTIES:»After sintering, material is easy to machine»»Usable temperature range: - 50 C to 250 C»Usable humidity range: 5 % to 95 %, but water absorption bandswill be visible»Standard pore sizes: 1 µm – 20 μm, average 6 μm»Atmospheric UV resistance»Surface roughness: 3 µm– 25 μm»Nearly ideal lambertian, diffuse reflectance»Density: 1.3 g/cm to 1.5 g/cm (depending on the product)»Nearly ideal diffuse transmittance»Non-polar, insulator»Uniform BRDF over all angles»Hydrophobic»No absorption bands in the range of 250 nm – 2450 nm»Chemically inert, exception: reacts with organic Lithium and»Laser damage threshold: 7 J/cm2Sodium compounds»Vacuum compatible to 10-6 Torr3Temperature Range( 3002002603003Thermal Linear Coefficient α10-5 (1/K)7.89.123.710.81422.939.312.715.418.4Effective spectral range: 260 nm – 2450 nmReflectance: 99 % from 350 nm – 1500 nm 95 % from 1500 nm – 2450 nmAbsorbance: 20 % above 2700 nmInputradiation(any angle)Output IO at ϴOEqual energy scattered atall angles over steradianswith 100% reflectanceOutput I IO · cos(ϴ)ϴTo an observer, IO seems to vary as tocosine of the angle ϴ. Intensity is afunction of the area of the targetpresented to the angle of the viewer.Zenith Polymer reflectance material provides the highest diffuse reflec-The surface and the porous structure of Zenith Polymer material exhi-tance of any known material over the UV-VIS-NIR region. The reflec-bits highly lambertian behavior. The material is extremely hydrophobictance is very flat and generally 99 % over a range from 400 nm toand shows no sign of optical or physical degradation after long-term1500 nm and 95 % from 250 nm to 2500 nm. Surface or subsurfaceimmersion testing in fresh water.contamination may lower the reflectance at the extreme upper and lowerends of the spectral range.NOTE:All our products can be purchased with a NIST or PTB traceable certificate over the range of 250 nm – 2450 nm.2 I Zenith Polymer Diffuse Reflectance Standards, Targets and Materials

Zenith Polymer Diffuse Reflectance StandardsSphereOptics' diffuse 99 % reflectance standard is used industry-widefor calibration of sphere systems, photometers, optical equipment, andspectrophotometers. The range of grey scale standards are generallyused to determine the linearity of optical detector systems used in colorimeters, spectrophotometers and densitometers.Standards are available in two sizes of 50 mm and 30 mm diameter withreflectance values ranging from 99 % (white) to a 2.5 % grey standard.Reflectance values include 99 %, 80 %, 60 %, 50 %, 25 %, 10 %, 5 %and 2.5 %. Standards are sold individually or in sets of two, four or eightstandards with a free choice of reflectance values. Each standard ispackaged in a durable holder with a protective cover and comes in astorage box.SphereOptics maintains a calibration laboratory in Germany and usesstandards traceable to both the National Institute of Standards andTechnology (NIST) and the Physikalisch-Technische Bundesanstalt(PTB). All standards come with a printed and signed certificate and measurement data in electronic form.Art.-No.ReflectivityDiameterSG 3051SG 3052SG 3055SG 3067SG 3068SG 3070SG 3071SG 3072SG 3073SG 3074SG 3082SG 3083SG 3075SG 3076SG 3046SG 3045SG 3086SG 3087SG 3088SG 3089SG 3044SG 3043 99 % 99 % 80 % 80 % 60 % 60 % 50 % 50 % 25 % 25 % 10 % 10 % 5% 5% 2.5 % 2.5 %Set of 2 2Set of 2 2Set of 4 2Set of 4 2Set of 8 2Set of 8 250 mm30 mm50 mm30 mm50 mm30 mm50 mm30 mm50 mm30 mm50 mm30 mm50 mm30 mm50 mm30 mm50 mm30 mm50 mm30 mm50 mm30 mmCalibration will be performed on a Perkin Elmer Lambda 950, data will be supplied electronicallyin 1 nm steps, 50 nm step printed documentation with NIST/PTB traceability with certificate forthe range from 250 nm - 2450 nm.2Within the sets, reflectivities are selectable.Typical Reflectance - Zenith Polymer Diffuse Reflectance Standard100%90%80%70%% 00175020002250Wavelength (nm)2,5% Standard25% Standard5% Standard50% Standard10% Standard60% StandardMixed Rare Earth Oxide Wavelength StandardThe NIST/PTB traceable wavelength calibration standard is a mixtureof three pure, rare earth oxides of Holmium, Erbium and Dysprosium,Typical Reflectance - Zenith Wavelength Standard100which provides a stable reference for validating the wavelength scale of90spectrophotometers and calibrating monochromators in the 250 nm toArt.-No.DescriptionSG 3333Wavelength standard, 50 mm diameterrare earth oxides mixed into Zenith PolymerSG 3334Wavelength standard, 30 mm diameterrare earth oxides mixed into Zenith Polymer80% Reflectance2450 nm 72269.62315.52361.42407.3mixed into Zenith Polymer , which exhibit distinct absorption peaks and250500750100012501500175020002250Wavelength (nm)Calibration will be performed on a Perkin Elmer Lambda 950, data will be supplied electronicallyin 0.1 nm steps, 50 nm step printed documentation with NIST/PTB traceability with certificate forthe range from 250 nm - 2450 nm.APPLICATIONS:Calibration of: Sphere Systems Photometers, Radiometers & Spectrophotometers Densitometers & Optical EquipmentTest Linearity of: Detector Systems Colorimeters, Densitometers & SpectrophotometersZenith Polymer Diffuse Reflectance Standards, Targets and Materials I 3

Zenith Lite Diffuse TargetsZenith Lite diffuse targets are made from our Zenith Polymer diffuse reflectance material, which provides nearly ideal diffuse lambertianreflectance over the wavelength range from 250 nm to 2450 nm. Zenith Lite targets are constructed using a 1 mm or 2 mm thick ZenithPolymer panel laminated with a special adhesive to a 10 mm - 20 mmthick aluminium honeycomb structured plate that serves as a solid, butlightweight backing. They are the ideal choice for both laboratory andfield applications since they are lightweight and can withstand harsh environments for long exposure periods. Due to their design, very flexiblemounting solutions are possible.The laminating technique used with Zenith Lite diffuse targets allowsfor multiple reflectance values in one target with almost no visible seams.Targets can be made to any size and combination of white or greyscalereflectance. The aluminium backing can be drilled to allow attachmentto a variety of mounting devices. Even with a 1 mm or 2 mm Zenith film,the diffuse optical properties are maintained.All targets can be provided with National Institute of Standards and Technology (NIST) / Physikalisch-Technische Bundesanstalt (PTB) traceablecalibration certificates from 250 nm to 2450 nm. For the targets biggerthan 300 mm x 300 mm a smaller reference target (witness sample) isprovided and the calibration is performed on the reference.Art.-No.ReflectivityDimensionsSG 3151SG 3152SG 3153SG 3154SG 3171SG 3155SG 3166SG 3167SG 3168SG 3169SG 3172SG 3170SG 3156SG 3157SG 3158SG 3159SG 3173SG 3160SG 3161SG 3162SG 3163SG 3164SG 3174SG 3165 95 % 90 % 50 % 20 % 10 % 5% 95 % 90 % 50 % 20 % 10 % 5% 95 % 90 % 50 % 20 % 10 % 5% 95 % 90 % 50 % 20 % 10 % 5%200x200x12 mm (approx. 8x8 inch)200x200x11 mm (approx. 8x8 inch)200x200x11 mm (approx. 8x8 inch)200x200x11 mm (approx. 8x8 inch)200x200x11 mm (approx. 8x8 inch)200x200x11 mm (approx. 8x8 inch)300x300x12 mm (approx. 12x12 inch)300x300x11 mm (approx. 12x12 inch)300x300x11 mm (approx. 12x12 inch)300x300x11 mm (approx. 12x12 inch)300x300x11 mm (approx. 12x12 inch)300x300x11 mm (approx. 12x12 inch)500x500x12 mm (approx. 20x20 inch)500x500x11 mm (approx. 20x20 inch)500x500x11 mm (approx. 20x20 inch)500x500x11 mm (approx. 20x20 inch)500x500x11 mm (approx. 20x20 inch)500x500x11 mm (approx. 20x20 inch)1000x1000x12 mm (approx. 40x40 inch)1000x1000x11 mm (approx. 40x40 inch)1000x1000x11 mm (approx. 40x40 inch)1000x1000x11 mm (approx. 40x40 inch)1000x1000x11 mm (approx. 40x40 inch)1000x1000x11 mm (approx. 40x40 inch)Calibration will be performed on a Perkin Elmer Lambda 950, data will be supplied electronicallyin 1 nm steps, 50 nm step printed documentation with NIST/PTB traceability with certificate forthe 250 nm – 2450 nm range.Typical Reflectance - Zenith Lite Diffuse Reflectance Targets100%90%80%70%% 00175020002250Wavelength (nm)5% Target10% Target20% Target50% Target90% Target95% TargetZenith Polymer Full Material TargetsAlthough the Zenith Lite diffuse targets cover a wide range of applications, in some cases, the purity of the material and volume reflection (bulk scattering) is required. For vacuum applications or use underspace conditions, only pure optical PTFE can be used. There is also theoption to vacuum bake the raw PTFE material before production. Weoffer a restricted choice of standard sizes, so for custom sizes, pleasecontact us directly.Art.-No.ReflectivityDimensionsSG 3105SG 3110SG 3120SG 3150 99 % 99 % 99 % 99 %50x50x10 mm (approx. 2x2 inch)100x100x10 mm (approx. 4x4 inch)200x200x10 mm (approx. 8x8 inch)500x500x10 mm (approx. 20x20 inch)Calibration will be performed on a Perkin Elmer Lambda 950, data will be supplied electronicallyin 1 nm steps, 50 nm step printed documentation with NIST/PTB traceability with certificate forthe 250 nm – 2450 nm range.APPLICATIONS:Remote Sensing Calibration Field Testing of Imaging Systems Environmental Test Targets Optical Reflectors Contrast Measurement for CameraApplications Illuminator Panels for QC of Projectors and Projector Lamps Reflectance Standard for Illumination Measurements and Calibration4 I Zenith Polymer Diffuse Reflectance Standards, Targets and Materials

Zenith Polymer White DiffuserLambertian transmission sheetsOur Zenith Polymer diffusers are made of the same material as ourreflectance standards with its unique, highly lambertian optical properties. Thin section Zenith Polymer sheets are used as cosine diffusersminimise angular dependency of the light reaching a photodetector orto create more even illumination from a light source. With a constant,lambertian throughput over the entire wavelength range of 250 nm to2450 nm, the Zenith Polymer diffuser finds application in a variety oflight scattering measurements and calibration set ups.Typical Transmission - Zenith Polymer White Diffuser7060% 002250Wavelength (nm)Thickness:0.1 mm0.25 mm0.5 mm1 mm2 mmArt.-No.TransmissionSG 3201 50 %SG 3202 50 %SG 3203 25 %SG 3204 25 %SG 3205 16 %SG 3206 16 %SG 3210 8%SG 3211 8%SG 3212 8%SG 3213 4%SG 3214 4%SG 3215 4%DescriptionDiffuser 100 μm thickness200x200 mm (approx. 8x8 inch)Diffuser 100 μm thickness500x500 mm (approx. 20x20 inch)Diffuser 250 μm thickness200x200 mm (approx. 8x8 inch)Diffuser 250 μm thickness500x500 mm (approx. 20x20 inch)Diffuser 500 μm thickness200x200 mm (approx. 8x8 inch)Diffuser 500 μm thickness500x500 mm (approx. 20x20 inch)Diffuser 1mm thickness200x200 mm (approx. 8x8 inch)Diffuser 1mm thickness500x500 mm (approx. 20x20 inch)Diffuser 1mm thickness1000x1000 mm (approx. 40x40 inch)Diffuser, 2 mm thickness200x200 mm (approx. 8x8 inch)Diffuser, 2 mm thickness500x500 mm (approx. 20x20 inch)Diffuser, 2 mm thickness1000x1000 mm (approx. 40x40 inch)Only general transmission data available!Zenith Polymer Greyscale DiffuserLambertian reflectance sheetsFor some applications in quality control or production processes, theflat surface of the reflectance targets and standards are not usable andcustom curvature or shape is required. To realise optical and processstability, often Zenith Polymer greyscale diffuser sheets are used as anoptical baseline reference. To enable the customer to adapt the opticalstandard to his or her needs, we offer the greyscale Zenith Polymer as 1 mm thick sheets, optionally with the proper gluing agent applied,so engineers and quality control personnel can fit the standard to theirneeds.Art.-No.ReflectivitySG 3224 50 %SG 3223 50 %SG 3222 50 %SG 3221 20 %SG 3200 20 %SG 3219 20 %SG 3225 10 %SG 3226 10 %SG 3227 10 %SG 3218 5%SG 3217 5%SG 3216 5%DescriptionDiffuser, 1 mm thickness1000x1000 mm (approx. 40x40 inch)Diffuser, 1 mm thickness500x500 mm (approx. 20x20 inch)Diffuser, 1 mm thickness200x200 mm (approx. 8x8 inch)Diffuser, 1 mm thickness1000x1000 mm (approx. 40x40 inch)Diffuser, 1 mm thickness500x500 mm (approx. 20x20 inch)Diffuser, 1 mm thickness200x200 mm (approx. 8x8 inch)Diffuser, 1 mm thickness1000x1000 mm (approx. 40x40 inch)Diffuser, 1 mm thickness500x500 mm (approx. 20x20 inch)Diffuser, 1 mm thickness200x200 mm (approx. 8x8 inch)Diffuser 1mm thickness1000x1000 mm (approx. 40x40 inch)Diffuser 1mm thickness500x500 mm (approx. 20x20 inch)Diffuser 1mm thickness200x200 mm (approx. 8x8 inch)APPLICATIONS:Industry Quality Control Refinement of Detectors Custom Research Applications Remote Sensing CalibrationZenith Polymer Diffuse Reflectance Standards, Targets and Materials I 5

Calibration ServiceSphereOptics can provide a service for the measurement for our standards and targets, as well as for samples, that are provided by the cus-Art.-No.DescriptionSG 3401One-point-calibration (Ø 10 mm measurementsurface): 1-2 pieceSG 3401-3One-point-calibration (Ø 10 mm measurementsurface): Quantity discount from 3 to 5 pieceswith an integrating sphere. Following applications are possible:SG 3401-6One-point-calibration (Ø 10 mm measurementsurface): Quantity discount from 6 - 10 pieces»(Re)calibration of optical standards and reflecting materialsSG 3401-xx»Verification of wavelength standards»Deviation of color valuesOne-point-calibration (Ø 10 mm measurementsurface): Quantity discount for 11 and more pieces – on request»Determination of transmission properties of glassSG 3411»Customer specific measurement service on requestOne-point-calibration (Ø 10 mm measurementsurface), wavelength standards or non-standardmeasurement range / resolution: 1 piecetomer. The reflectance and transmittance measurements in the rangefrom 250 nm to 2450 nm are performed by using a high end spectrometer, Perkin Elmer Lambda 950 or Lambda 19, which are both equippedThe measurement of reflectance is done in the 8 geometry. Using thisRecalibration will be performed on a Perkin Elmer Lambda 19, data will be supplied electronically in 1 nm steps, 50 nm step printed documentation with NIST/PTB traceability with certificatefor the 250 nm - 2450 nm range.setup, the sample is mounted at the port of the sphere with an angle of8 , which shifts the specular reflection of the sample toward the sphereswall. Optional, it is possible to have a light trap at this 8 position of theSphere, to get also the diffuse and specular parts of the total reflection.To obtain the right reflectance values a reference standard is used,which was certified by the Physikalisch-Technische Bundesanstalt(PTB). The wavelength accuracy of the spectrometer is checked periodically by using a SRM-2036 standard of the National Institute of Standards & Technology (NIST).In cooperation with Labsphere Inc.; SphereOptics provides ISO 17025(NVLAP) accredited calibrations.Handling & Care Instructions for Zenith Polymer MaterialsCharacteristics, handling, storage & transport, cleaning, disposalZenith Polymer (Polytetrafluorethylen) is a thermoplastic material usedStorage and Transportin a variety of different shapes as diffuse reflection material in opticalZenith Polymer products should be stored such as other high qualitysystems. However, during treatment it shows many characteristics si-optical components in a clean laboratory environment. We recommendmilar to a Duroplast. The material has a hardness comparable to poly-to store the highly pure optical PTFE dry, covered, dust free and at roomethylene.temperature. After exposure to extreme temperature and humidity conranges from - 260 Cditions for instance during transport, the reflection material should beto 260 C even up to 300 C in short term use. The long-run-treatmentallowed to adapt to the laboratory environment for 2 hours, before it istemperatures however depend on the prevailing strain. It is chemicallyused for measurements. Storage necessarily has to be hydrocarbon-inert to all but the most powerful bases such as sodium or lithium com-free.pounds.Recommended max. longterm temperature range: - 50 C to 150 CThe porous network of thermoplastic produces multiple reflections inRecommended max. longterm moisture range: 5 % to 95 %The thermic carrying capacity of Zenith Polymer the first few tenths of a millimeter. This “open structure” readily absorbsnonpolar solvents, greases and oils. Also intensive contact with cigaretteDisposalsmoke affect the optical properties. Zenith PolymerIf the Zenith Polymer material still does not show the required reflectivi- is nonpolar andty, even after the appropriate rework has been made, we recommend tohydrophobic.replace them. For correct exploitation of the old, contaminated materialsGeneral Handlingeither send them back to your supplier or depose them according to theZenith Polymerrespective government regulations for organic polymer. as an optical reference material should be stored andhandled like other optical components and reflectance standards. Toavoid impact on optical characteristics it is recommended to wear unpowdered latex or vinyl gloves while handling.APPLICATIONS:SateliteTargets SpaceofBasedPlatforms Spectrophotometers, Radiance CalibrationSpectrofluorometersStandards Uniform Light Source Spheres» TestingCalibrationof wavelengthaccuracySpectrometers,» Industrial standards for Biomedicine, Pharmaceutical-, Textile- and Paper industry6 I Zenith Polymer Diffuse Reflectance Standards, Targets and Materials

Cleaning Service -Rework and cleaning of optical PTFE materialIn case your standard or target become contaminated, dirty or mechani-Art.-No.cally damaged we offer a cleaning and repair service.DescriptionSG CLEAN-STMechanical rework and cleaning of optical PTFEmaterialArea sizes: Ø 30 - 90 mm /50 x 50 mm - 90 x 90 mm (or similar size)SG CLEAN-TA1Mechanical rework and cleaning of optical PTFEmaterialArea sizes: Ø 100 - 190 mm /100 x 100 mm - 190 x 190 mm (or similar size)SG CLEAN-TA2Mechanical rework and cleaning of optical PTFEmaterialArea sizes: Ø 200 - 290 mm /200 x 200 mm - 290 x 290 mm (or similar size)SG CLEAN-TA3Mechanical rework and cleaning of optical PTFEmaterialArea sizes: Ø 300 - 390 mm /300 x 300 mm - 390 x 390 mm (or similar size)Gladly you can send your standards to us and our experienced laboratory stuff will give advices regarding the need or in extreme cases thegeneral possibility of cleaning.If the Zenith Polymer material still does not show the required reflectivity, even after the appropriate rework has been made, we recommend toreplace them. For correct exploitation of the old, contaminated materialseither send them back to your supplier or depose them according to therespective government regulations for organic polymer.Custom and OEM Parts made out of Zenith Polymer We welcome enquiries for the custom fabrication of Zenith Polymer With Zenith Polymer 99 % reflectance standards or Zenith Polymer parts such as small OEM integrating spheres, laser cavities, lampoptical greyscale standards, you obtain an optical standard which with-housings, illumination or diffuser panels and custom calibration targets.stands harsh environments, is chemically inert, stable against mostOur engineers can work directly from your print or drawing.acids, resists temperatures up to 250 C and offers you a constant, highdiffuse reflectivity over the broad range of UV-VIS and NIR.Zenith Polymer Space Grade MaterialZenith Polymer space grade is the material of choice for vacuum appli-material and manufacturing processes have been qualified by ESA con-cations and space based platforms or satellites. Our customers are thetractors for several satellite space projects.main European space agencies.The material exhibits reflectance values of more than 98 % over theOur space qualified material is produced using highly advanced manu-wavelength range of 300 nm to 1800 nm. It is resistant to heat, humidityfacturing processes that virtually eliminate potential contamination thatand exposure to high levels of radiation, making it the optimal materialcan lead to UV degradation under space conditions. Zenith Polymer for use in space.NOTE:We advise to get the mechanical rework and cleaning done by experts.Zenith Polymer Diffuse Reflectance Standards, Targets and Materials I 7

Zenith Polymer is a registered trademark. All other trademarks mentioned in this document are the property of their respective owners. Aspart of our continuing product improvement program, SphereOptics reserves the right to change specifications without notice.SphereOptics GmbHGewerbestrasse 13 82211 Herrsching GermanyFon 49 8152 983 78-90 Fax 49 8152 983 78-91info@sphereoptics.de www.sphereoptics.deImages: Defense Ministry Norsk Elektro Optikk AS PerkinElmer SphereOptics 2016 SphereOptics GmbH. All rights reserved.ISO 9001

reflectance values ranging from 99 % (white) to a 2.5 % grey standard. Reflectance values include 99%, 80 %, 60 %, 50 %, 25 %, 10 %, 5 % and 2.5 %. Standards are sold individually or in sets of two, four or eight standards with a free choice of reflectance values. Each standard is packaged in a durable holder with a protective cover and comes in a

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