NUCLEAR PHYSICS - REVIEW

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NUCLEAR PHYSICS REVIEW

Atomic structure

Atomic structure

1808 - John Dalton – new idea – the matter is made of tiny solidindivisible spheres like billiard balls - atoms 1897 – J. J. Thomson found the first subatomic particle - the electronelectrons (the plums) Thomson’s “plum-pudding” modelthe atom was a positive sphere of matter andthe negative electrons were embedded in itpositive matter (the pudding) Scientists then set out to find the structureof the atom.

Ernest Rutherford got his students Geiger and Marsden to fire the fast moving α-particles atvery thin gold foil and observe how they were scattered.Most of the α-particles passed straight through the foil, some were slightly deflected, as expected,but to his surprise a few were scattered back towards the source.Rutherford’s conclusion (1911): a particle had a head-on collision with a heavier particle heavier particle had to be very small, since very fewa particles were bounced back. heavy particles must be positive (repulsion) Nuclear (planetary) model of the atomAtom contains a small but very massive positive corewhich he called nucleus, Orbiting around nucleus in circles are the electrons.(if they were not orbiting but at rest, they would move straight to the nucleus;instead centripetal force is provided by the electrostatic attraction betweenelectrons and nucleus.)no neutrons (AD 1911)The most suprising thing about this model is that the atom is mainly empty space! 1919 – Ernest Rutherford finally discovered proton

Problems with Rutherford’s model: According to Maxwell, any accelerating charge will generate an EM wave Electrons will radiate, slow down and eventually spiral into the nucleus.The end of the world as we know it. The solution was found in quantum theory.Bohr’s Model – atomic energy levelsBohr's atomic model is an updated version ofRutherford's model. The main differencebetween the two is that Bohr's model is based oftheories and lessons from quantum physics. Electrons occupy discrete energy levels only, called “stationary states.” Electrons in these stationary states do not emit EM waves as they orbit. Photon is emitted when an electron jumps from excited state to a lower energy state.Energy of that photon is equal to the energy difference between two states. Ephoton ΔE1932 – Chadwick discovered neutron

The modern modelThe model we now accept is that there is a nucleus at thecentre of the atom and the electrons do exist in certainenergy levels, but they don’t simply orbit the nucleus. Theprobability of finding electron somewhere is given by waveequations, resulting in some interesting patterns.The result of this theory can be again visualizedusing very simple model, this time only energylevel model. This model is not a picture of theatom but just represents possible energy ofelectrons.

Each element (atom/ion)produces a specific set ofabsorption (and emission) lines.We call this the "spectral signature"or “fingerprints” of an atom/ion.Emission SpectraAbsorption Spectra Allows the identificationof elements across thegalaxy and universe.(If we mapped it andcan recognize it)

1. A hot solid, liquid or gas at high pressure produces a continuousspectrum – all λ.2. A hot, low-density / low pressure gas produces anemission-line spectrum – energy only at specific λ.3. A continuous spectrum source viewed through a cool, low-densitygas produces an absorption-line spectrum – missing λ – dark lines.Thus, when we see a spectrumwe can tell what type of sourcewe are seeing.

r 1.2 10 15 m A1 3Nuclear Structure

NucleonThe name given to the particles of the nucleus. NuclideA particular combination of protons and neutrons that form anucleus. It is used to distinguish isotopes among nuclei. Nucleon number (mass number) - AThe number of protons and neutrons in the nucleus. Proton number - ZThe number of protons in the nucleus. Symbol for a nucleid IsotopesNuclei (atoms) with the same number ofprotons but different numbers of neutrons. Neutron number - N (N A – Z)The number of neutrons in the nucleus.AZX73Li

Isotopes – Nuclei (atoms) of the same number of protons butdifferent numbers of neutrons. The existence of isotopes is evidence for the existenceof neutrons, because there is no other way to explain themass difference of two isotopes of the same element. The same number of electrons – the same bonding the same chemical properties Different masses – different physical properties Many isotopes do not occur naturally, and the most massive238isotope found in nature is uranium isotope 92U the current largest atomic number element, with atomicnumber 118, survived for less than a thousandth of a second

The strong nuclear force

What holds the nucleus together?The mutual repulsion of the protons tends to push the nucleusapart. What then, holds the nucleus together?The strong nuclear force.Strong nuclear force has much shorter range than electric.It is the force which attracts protons to protons, neutrons to neutrons, and protonsand neutrons to each other. That force has a very short range, about 1.5 radii of aproton or neutron (1.5 x 10-14m) and is independent of charge and this is the reasonthe nucleus of an atom turns out to be so small.The strong nuclear force was first described by the Japanese physicist HidekiYukawa in 1935. It is the strongest force in the universe, 1038 times stronger thangravitational force and 100 times stronger than the electromagnetic force.

The Strong Nuclear Force and the Stability of the NucleusAs nuclei get larger, more neutronsare required for stability.The neutrons act like glue withoutadding more repulsive force.The stable nuclides of the lighterelements have approximately equalnumbers of protons and neutrons?However, as Z increases the stabilityline' curves upwards.Heavier nuclei need more and moreneutrons to be stable. Why?It is the strong nuclear force that holds thenucleons together, but this is a very short range force.The repulsive electric force between the protons is a longer range force.So in a large nucleus all the protons repel each other, but each nucleonattracts only its nearest neighbours.More neutrons are needed to hold the nucleus together (although adding too many neutronscan also cause instability).There is an upper limit to the size of a stable nucleus; all the nuclides with Z higher than 83are unstable.

The Mass Deficit of theNucleus and NuclearBinding energy

Nucleus(small mass) Separated nucleons(greater mass)Bindingenergy Binding energy (BE) is energy required to separate the nucleus into itindividual free nucleons. Mass defect (Δm) is the difference between the mass of separated freenucleons and the mass of the nucleusbinding energy: mass deficit converted into energy(heat, light, higher energy states of the nucleus/atom or other forms of energy).BE (J) Δm(kg) c2BE (MeV) Δm(u) 931.5c 3x108 m/s1𝑢 931.5 𝑀𝑒𝑉Unified Atomic Mass Unit (amu abbreviated as u) 1/12 of the mass of one atom of carbon-12 (6p 6n 6e). 1 u 1.66053886 x 10-27 kg1 electron volt 1.60217646 10-19 joules

binding energy per nucleon - the binding energy ofa nucleus is divided by its mass number𝐵𝐸𝐴BE of pure Fe is 8.7 MeV/nucleon. It is maximum BE.If a nucleus has a large binding energy then it will require a lot of workto pull it apart – we say it is stable.The binding energy curveGraph of binding energy per nucleonBE varies with mass number;BE increase as the mass(nucleon) number increasesup to Fe.Fe is most stable.After that it slightlydecreases.In most cases it is about 8MeV

Radioactive Decay The most common types of radiation are called alpha (a), beta (b),and gamma (g) radiation. But there are several other varieties of radioactive decay. Unstable nucleus by emitting radioactiveparticle/energy becomes more stable.

Alpha radiation (decay) Alpha particles emitted by radioactive nuclei consist of 2 protons and 2neutrons bound together into a particle identical to a helium nucleus; henceis written as42He or 42a. When an unstable nucleus decays by emitting an a -particleit loses 4 nucleons, 2 of them being protons The nuclear equation is:22688Ra 22286Rn 24 HeAZX Y aA-4Z-242α decay occurs primarily among heavyelements because the nucleus has too manyprotons which cause excessive repulsion. In anattempt to reduce the repulsion, a heliumnucleus is emitted.

Beta radiation (decay) Beta particles are high energy electrons emmited from the nuclus. But there are no electrons in the nucleus. What happens is this: one of the neutrons changes into a proton (stays in the nucleus) and011electron (emitted as a b-particle).0𝑛 1𝑝 1𝑒 𝜈 This means that the proton number increases by 1,while the total nucleon number remains the same.The nuclear equation is:AZX Y e AZ 10-1(nu) antineutrinoNeutrinos are created as a result of “beta plus” decay in which proton isconverted via weak force to a neutron, a positron (antielectron) and a neutrino(nuclear fusion powering the sun and other stars.).

Gamma radiation (decay)Nucleus, just like the atom, possesses energy levels. In α and βdecay, the product of decay is often nuclide in an excited state. Thedaughter nuclide then drops to its ground state by emitting a photon.Gamma-emission does not change the structure of the nucleus, but itdoes make the nucleus more stable because it reduces the energy ofthe nucleus.Nuclear energy levels are of the order of MeV hence the high energyof the emitted photon, and the frequancies (f E/h) correspond togamma rays.125B 126 C * 0 1e 126 C g 0 1e

Energy released in a decay: A C Dspontaneous decay: M m1 m2 binding energy of the decayingnucleus binding energies of the product nuclei. The daughter ismore stable. This is why radioactive decay happens with heavyelements lying to the right of maximum in the binding energy curve.Energy released is in the form of kinetic energy of the products.22688Ra 22286Rn 42αM m1 m2 , buttotal energy on the left total energy on the rightMc 2 m1c 2 m2 c 2 KE1 KE2

Decay chainsA radioactive nuclide oftenproduces a radioactive daughternuclide. The daughter will alsodecay, and the process willcontinue until finally a stablenuclide is formed. This processis known as decay chain.

Ionising Properties Radiation ionises molecules by knocking' electrons off of them. As it does so, energy is transferred from the radiation to the material. To knock an electron out of an atom requires about 10 eVα-particleSince the α-particle is massive, relatively slow-moving particle (up to 0.1 c) witha charge of 2e, it interacts strongly with matter.Alpha particles have energies of about 5 MeV so α-particle can ionize a lot ofatoms before they loose all their KE, passing through just a few cm of airThey cannot penetrate paper.Can be very harmful since ionizing atoms of human tissue cause demage to thecells similar to burning.β-particleThe b-particle is a much lighter particle than the a-particle and although theytravel much faster (up to 0.9 c) they cause less intense ionisation than the a-particle. They have a charge of only – e so they are less reactive. The b particle travels about 1 m in air before it is absorbed.It can be stopped by a few mm of Al or other metal

g - photonA g - photon moving at the speed of light interacts weakly with matter because itis uncharged and therefore it is difficult to stop.very penetrating: never completely stopped, though lead (Pb) and thick concretewill reduce intensity.The high energy also means that if they are absorbed by atomic electrons, theygive electrons enough energy to leave the atom. So they are ionizing.As they pass easily through human tissue, gamma rays have many medicalapplications.

Properties 2The diagram shows how the different types areaffected by a magnetic field.The alpha beam is a flow of positively ( ) chargedparticles, so it is equivalent to an electric current.It is deflected in a direction given by right-handrule - the rule used for working out the direction ofthe force on a current-carrying wire in a magneticfield.Beta particles are much lighter than the alphaparticles and have a negative charge, so they aredeflected more, and in the opposite direction.Being uncharged, the gamma rays are not deflectedby the field.

Half - life

Number of nuclei remainingDefinitionN0Half-life (T1/2) is the time taken for one half ofthe nuclei present in any given radioactivesample to decay. . . . . . .N0 2 .N0 4N0 8.t½t½t½.t½time

Activity and half-life It is much easier to measure the radiation than number of undecayed nucleiin a sample. Activity (becquerel - Bq)of a radioactive sample is the average number ofdisintegrations per second. 100 Bq means that 100 nuclei are disintegrating/sec.Activity of a sample of I -131.T1/2 8 daysSince the rate of decay isproportional to the number ofnuclei, a graph of the rate ofparticle emission againsttime will have the sameshape.activity / BqAs the activity is alwaysproportional to the number ofundecayed nuclei, it toohalves every 8 days.original activity 40 etime / days

activityRadioactive decay is a randomprocess. So, in practice, the curve isa ‘best fit’ of points which varyirregularly like this.time

nT2Example:sample containing N radioactive atoms, grams, kilogram, moles, after T1/2 N/2 decayedafter T1/2 N/2/2 decayedafter T1/2 N/2/2/2 decayed after time nT1/2 onlyNn survived2N N N . N2 2 2 232ntransmutatedNNfor example, after 4T1/2 there is still 4 16 atoms2in the sample (survived)N N N N 15 Nand 2 4 8 16transmutated16

Example:Cobalt–60 decays by beta emission and has a half-life of aproximately 5years. If a sample of cobalt–60 emits 40 beta particles per second, howmany will the same sample be emitting in 15 years time?After 5 years activity will be 20/sec (number of decays/sec).After another 5 years it will be 10/sec.Finally after a further 5 years it will emit 5 particles/sec.

Nuclear Reactions,Transmutations,Fission and Fusion

Natural transmutation (radioactivity)Till now we have discussed only transmutations of onenuclei to another by emmiting radioactive particle thatoccur only naturally.Induced (artificial) transmutationThis change of one element to another through thebombardment of a nucleus is known as artificialtransmutation.Induced transmutation doesn’t mean it can not happen naturally– it means bombarment onlyexample: production of nitrogen from carbon in atmosphere orartificially induced in the lab147N 01n 146 C 11 p

Alpha particle, neutrons, protons, and deuterons . canbe used to produce artificial nuclear reactions. The key to understanding these reactions and makingpredictions about the products of such reactions is beingable to balance nuclear equations. For the nuclear equation : A C D or A B C D nucleon and proton numbers must balanceon each side of the equation. conservation of total energy (energy mass)must be satisfiedEnergy released in nuclear reaction or decay is found the sameway as binding energy: first find mass differenceΔm LHS – RHS in uand then E Δm x 931.5 (MeV)

Energy released in a nuclear reaction/artificial transmutationNuclear reactions A B C D can either1. release energyifΔm (mA mB) – (mC mD) 0The total amount of energy released will be E Δmc2 in the form ofkinetic energy of products. If there was initial kinetic energy, that willbe added up to released energy.2. or requires energy inputNitrogen-14 will decay only if energy is supplied to it –collision with fast moving α particle:14718.0057 u 18.0070 uN 24a 178 O 11 pΔm (m) –Rutherford’s(mC mD) induced 0A mB1.Famoustransmutation: bombarding nitrogen gasα particle must have enough kinetic withenergyto makeup , and to provide for kinetic energy of products. This energy issuplied by a particle accelerator used to accelerate the helium nucleus.

Fission Fission means splitting up alarge nucleus (A 200) intotwo smaller nuclei. the total BE would increasewhich means that thedaughters are more stablethan parent. The excess energy isreleased by the reaction.

Spontaneous fission is very rare. Uranium is the largestnucleus found on Earth. Its isotopes will sometimes fissionnaturally. But half-life for U-235 is 7.04x108 years Bombarding the nucleus with neutrons can trigger a fissionreaction. For exampleThe strong forces thathold the nucleus together onlyact over a very short distance.When a uranium nucleusabsorbs a neutron itknocks the nucleus out of shape. If the nucleus deforms enough, theelectrostatic repulsion between the protons in each half becomes greater thanthe strong force. It then splits in two.The nuclei splits randomly.In the diagram, the fission fragments are shown as isotopes of Ba and Kr.This is just one of the many possible combinations.Fission of a uranium nucleus gives out about 200 MeV of energy.

Chain Reactions When the uranium nucleus splits, a number of neutronsare also ejected. If each ejected neutron causes another uranium nucleusto undergo fission, we get a chain reaction The number of fissions increases rapidly and a hugeamount of energy is released. Uncontrolled chain reactions are used in nuclear bombs The energy they unleash is devastating. Nuclear power stations use the heat released in carefullycontrolled fission reactions to generate electricity. They use control rods to absorb some of the neutrons.

Fusion Fusion means joining up twosmall nuclei to form a biggernucleus. When two small nuclei theproduct of fusion would havemore BE per nucleon. The increases in bindingenergy per nucleon aremuch larger for fusion thanfor fission reactions,because the graph increasesmore steeply for light nuclei. So fusion gives out more energy per nucleoninvolved in the reaction than fission.

Fusion has a number of advantages over fission:greater power output per kilogram,the raw materials are cheap and readily available,no radioactive elements are produced directly,irradiation by the neutrons leads to radioactivity in the reactormaterials but these have relatively short half lives and onlyneed to be stored safely for a short time. So why don't we use fusion in nuclear power stations? The JET (Joint European Torus) project was set up to carry outresearch into fusion power. It has yet to generate a self-sustaining fusion reaction. The main problem is getting two nuclei close enough for longenough for them to fuse.

Each small nucleus has a positive charge so they will repel eachother. To make the nuclei come close enough for the strong force topull them together, they must be thrown together with very igh velocity.For this to take place, the matter must either be heated totemperatures as high as the core of the sun (about 13 million Kelvin)or the particles must be thrown together in a particle accelerator) At this temperature all matter exists as an ionised gas or plasma. Problem: containment. What can you use to hold something this hot? JET (and Princeton) uses magnetic fields in a doughnutshapedchamber called a torus to keep the plasma away from the containerwalls. Unfortunately generating high temperatures and strong magneticfields uses up more energy than the fusion reaction produces! The same problem is with accelerators, the path taken by Japan. We are still some years off a fusion power station.

NUCLEAR PHYSICS - REVIEW . Atomic structure. . Bohr's atomic model is an updated version of Rutherford's model. The main difference between the two is that Bohr's model is based of Bohr’s Model – atomic energy levels theories and lessons from quantum

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