Electronic Supplementary Information All-inkjet-printed .
Electronic Supplementary Material (ESI) for Energy & Environmental Science.This journal is The Royal Society of Chemistry 2016Electronic Supplementary InformationAll-inkjet-printed, solid-state flexible supercapacitors on paperKeun-Ho Choi,a JongTae Yoo,ab Chang Kee Leec and Sang-Young Leea*aDepartmentof Energy Engineering, School of Energy and Chemical Engineering, UlsanNational Institute of Science and Technology (UNIST), Ulsan, 689-798, South Korea. E-mail:syleek@unist.ac.kr; Tel: 82-52-217-2948bSchoolof Energy and Chemical Engineering, Ulsan National Institute of Science andTechnology (UNIST), Ulsan, 689-798, South Korea.cKoreaPackaging Center, Korea Institute of Industrial Technology, Bucheon, Gyeonggi-do,421-742, South Korea.1
Fig. S1. Schematics and SEM images of the stepwise fabrication procedure of the CNFnanomat-based primer layer: (a) A4 paper, (b) inkjet-printed (wet-state) CNF layer depositedon A4 paper, (c) inkjet-printed CNF nanomat deposited onto A4 paper. The highly developednanoporous structure was generated after the solvent exchange between ethanol/acetonemixture and water.Fig. S2. 3D laser scanning microscope images of: (a) A4 paper (wetting substrate, Ra(surface roughness) 4.8 m) and (b) PET film (non-wetting substrate, Ra 0.2 m).Fig. S3. Viscosity of the electrode (SWNT/AC) inks as a function of shear rate, before/aftercentrifugation (at 10,000 rpm for 1 h).Fig. S4. SEM images of the Ag NWs: (a) before and (b) after sonication-driven scission.Fig. S5. Viscosity of Ag NW inks (containing short NWs, after sonication-driven scission) asa function of shear rate.Fig. S6. SEM images of a control sample (Ag NWs without SWNTs): (a) before and (b) afterUV irradiation.Fig. S7. FT-IR spectra showing the change of characteristic peaks assigned to C C doublebonds of ETPTA, before/after the UV crosslinking reaction.2
Fig. S8. Linear sweep voltammetry (LSV) profile of [BMIM][BF4]/ETPTA mixture (afterremoval of the residual water).Fig. S9. TGA profile (dynamic mode, heating rate 10 oC min-1 under nitrogen atmosphere)of the inkjet-printed ([BMIM][BF4]/ETPTA) solid-state electrolyte.Fig. S10. Effect of scan rates ( 1 - 200 mV s-1) on: (a) CV profiles and (b) coulombicefficiency of the inkjet-printed SC.Fig. S11. Ragone plot (i.e., specific energy density [Wh kg-1] vs. specific power density [Wkg-1]) of the inkjet-printed SC.Fig. S12. (a) Galvanostatic charge-discharge (GCD) profiles (at current density 0.2 mA cm2)of the inkjet-printed SCs showing IR drop. Galvanostatic GCD profiles (at current densities 1.0 – 10.0 mA cm-2) of the inkjet-printed SCs (b) with Ag NWs and (c) without Ag NWs.Fig. S13. Schematics and photographs of the inkjet-printed SCs: (a) 5 cells connected inseries and (b) 5 cells connected in parallel.Fig. S14. (a) Schematic of the inkjet-printed, letter (“BATTERY”)-shaped SC that wasseamlessly connected with the inkjet-printed electrical circuit. (b) Charge/discharge profilesof the inkjet-printed, letter (“BATTERY”)-shaped SC.Fig. S15. (a) Schematic of the inkjet-printed, traditional Korean “Taegeuk” symbol-like SCthat was aesthetically unitized with inkjet-printed electric circuit and other patterns. (b)Charge/discharge profiles of the inkjet-printed, “Taegeuk” symbol-like SC.3
Fig. S16. A schematic of the inkjet-printed SCs that were seamlessly connected via theinkjet-printed electric circuits to LED lamps in the inkjet-printed Korea map.Fig. S17. Photographs of the (a) temperature sensor and (b) Arduino board.Fig. S18. Video clips showing the operation of: (a) a blue LED lamp in the smart cup (forcold water ( 10 oC)) and (b) a red LED lamp in the smart cup (for hot water ( 80 oC)).4
Fig. S1. Schematics and SEM images of the stepwise fabrication procedure of the CNFnanomat-based primer layer: (a) A4 paper, (b) inkjet-printed (wet-state) CNF layer depositedon A4 paper, (c) inkjet-printed CNF nanomat deposited onto A4 paper. The highly developednanoporous structure was generated after the solvent exchange between ethanol/acetonemixture and water.5
Fig. S2. 3D laser scanning microscope images of: (a) A4 paper (wetting substrate, Ra(surface roughness) 4.8 m) and (b) PET film (non-wetting substrate, Ra 0.2 m).6
80Before CentrifugationAfter CentrifugationViscosity (cP)604020012345678910Shear Rate (s-1)Fig. S3. Viscosity of the electrode (SWNT/AC) inks as a function of shear rate, before/aftercentrifugation (at 10,000 rpm for 1 h).7
Fig. S4. SEM images of the Ag NWs: (a) before and (b) after sonication-driven scission.8
Viscosity (cP)102Ag NW Ink10110010-112345678910Shear Rate (s-1)Fig. S5. Viscosity of Ag NW inks (containing short NWs, after sonication-driven scission) asa function of shear rate.9
Fig. S6. SEM images of a control sample (Ag NWs without SWNTs): (a) before and (b) afterUV irradiation.10
Fig. S7. FT-IR spectra showing the change of characteristic peaks assigned to C C doublebonds of ETPTA, before/after UV crosslinking reaction.11
Current Density (mA cm-2)0.20.10.0-0.1-0.2-4-3-2-10123Voltage (V vs. Pt/Pt )Fig. S8. Linear sweep voltammetry (LSV) profile of [BMIM][BF4]/ETPTA mixture (afterremoval of the residual water).12
Fig. S9. TGA profile (dynamic mode, heating rate 10 oC min-1 under nitrogen atmosphere)of the inkjet-printed ([BMIM][BF4]/ETPTA) solid-state electrolyte.13
Fig. S10. Effect of scan rates ( 1 - 200 mV s-1) on: (a) CV profiles and (b) coulombicefficiency of the inkjet-printed SC.14
Specific Energy (Wh kg-1)103102Inkjet-printed supercapacitor (this work)Thin-film supercapacitor (Ref. 34)Thin-film supercapacitor (Ref. 37)10110010-1 110102103104105Specific Power (W kg-1)Fig. S11. Ragone plot (i.e., specific energy density [Wh kg-1] vs. specific power density [Wkg-1]) of the inkjet-printed SC.15
Fig. S12. (a) Galvanostatic charge-discharge (GCD) profiles (at current density 0.2 mA cm2) of the inkjet-printed SCs showing IR drop. Galvanostatic GCD profiles (at current densities 1.0 – 10.0 mA cm-2) of the inkjet-printed SCs (b) with Ag NWs and (c) without Ag NWs.16
Fig. S13. Schematics and photographs of the inkjet-printed SCs: (a) 5 cells connected inseries and (b) 5 cells connected in parallel.17
Fig. S14. (a) Schematic of the inkjet-printed, letter (“BATTERY”)-shaped SC that wasseamlessly connected with the inkjet-printed electrical circuit. (b) Charge/discharge profilesof the inkjet-printed, letter (“BATTERY”)-shaped SC.18
Fig. S15. (a) Schematic of the inkjet-printed, traditional Korean “Taegeuk” symbol-like SCthat was aesthetically unitized with the inkjet-printed electric circuit and other patterns. (b)Charge/discharge profiles of the inkjet-printed, “Taegeuk” symbol-like SC.19
Fig. S16. Schematic of the inkjet-printed SCs that were seamlessly connected via the inkjetprinted electric circuits to LED lamps in the inkjet-printed Korea map.20
Fig. S17. Photographs of the (a) temperature sensor and (b) Arduino board.21
Fig. S18. Video clips showing the operation of: (a) a blue LED lamp in the smart cup (forcold water ( 10 oC)) and (b) a red LED lamp in the smart cup (for hot water ( 80 oC)).22
inkjet-printed electric circuits to LED lamps in the inkjet-printed Korea map. Fig. S17. Photographs of the (a) temperature sensor and (b) Arduino board. Fig. S18. Video clips showing the operation of: (a) a blue LED lamp in the smart cup (for cold water ( 10 oC)) and (b) a red LED lamp in the smart cup (for hot water ( 80 oC)).
VERSATILE PRINTER FOR A LARGE VARIETY OF PROCESSES INKJET PRINTER The SUSS LP50 is a desktop R&D inkjet printer for func-tional printing applications. It is designed for research and development of inkjet processes and applications, as well as evaluation and development of inkjet mate-rials. The LP50 platform is an open, accurate, flexible,
provided that the "ink" satisfies certain fluid requirements. Table I summarizes some common types of inkjet fluids and their applications. 1.1 Printing process overview The two main modes of inkjet printing are continuous inkjet (CIJ) mode and drop-on-demand (DOD) mode, as illustrated in Figure 2(a) and (b).Inbothmethods,the
inkjet printing, which in our opinion, offer the greatest advance in their respective fields in recent years, and most promise for forthcoming work of a significant nature. 2. Inkjet Printing Process Inkjet printing is a material-conserving deposition technique used for liquid phase materials. These materials, or inks, consist
Due to its ability to print on a wide variety of substrates, inkjet technology is also increasingly being used in industrial printing and in the package printing industry. Together with laser printing, inkjet printing is the fastest growing area of the printing industry [1]. Most inkjet inks have a low viscosity and a low surface tension, which put
Established in the year 1977, we Asian Reprographics Pvt.Ltd., was taken over by new management of S.Devraj Jain Family in 1994 for consolidating the strength, skills and . u r P r o d u c t s. DIGITAL IMAGING MEDIA 200 Micron Inkjet Blue X Ray Film Inkjet Blue X-Ray Film Inkjet RC Photo Luster Paper Samkit Inkjet Blue X Ray Film O u r P r o .
INDEX Purex fume extraction systems Inkjet 10-11 For continuous inkjet printers. Inkjet Extractor (Standard) 10 Inkjet Extractor (Digital) 11 Laserex 14-27 For laser engraving, marking, welding and cutting. Laserex Alpha 200 & 400 14 Laserex Alpha 400i 15 Laserex Digital 210 & 210i 16 Laserex Digital 400 & 400i 17 Laserex Digital 800i 18
that piezoelectric DOD polymer inkjet printing could be a powerful, solid-freeform, fabrication technology to create a controlled 3D architecture. Keywords: inkjet printing, direct writing, 3D construction, micro-patterning, viscosity, surface tension. Introduction An inkjet printer is a familiar piece of equipment used in both the home and office.
NORTH LANARKSHIRE COUNCIL AGmA REPORT 1 1 I I 1 1 IFROM: QR8FSocWWoRK PERlQD Ollff109 - 16mm I I SoClAtWoRK DATE : 16 SEPTEMBER1896 Ref. : EMch I I 1 1. introduction This report compares actual expenditure and income against estimates both for the year to date and the prc@cted &-turn. Explanations are provided for the major &-turn variance.
