DuPont Renewably Sourced (RS) Engineering Polymers
DuPont Renewably Sourced (RS)Engineering Polymers
2206 Years of Innovation and Success A Dynamic Science Company 60,000 employees in over 70 Countries 30 Billion in global revenues 6 Billion sold into the automotive segment 1 Billion in bio-based revenue expected in 2015 A World Leader in Renewable MaterialsOne of The Top Rated Green Companies of the World (Ceres, Business Week, Fortune)
3DuPont Mission: Sustainable GrowthThe creation of shareholder and societal value while wereduce the environmental footprint along the value chainsin which we operate.
4Terminology RENEWABLY SOURCED and BIO-BASED define the same thing. Itrefers to a material that contains carbon originating from a renewableplant source. DuPont Renewably Sourced materials contain aminimum of 20% renewably sourced ingredients by weight. RENEWABLY SOURCED can include BIODEGRADABLE products thatcan be broken down by living organisms like bacteria. It also includesdurable goods that are designed for long life. Products discussed in this presentation are for durable good typeapplications and recyclable.
5responsible innovation nowresponsible – 208 years of trusted solutions renewably sourced materials light-weighting safer, sustainable worldinnovation - pushing the edge of creativity in material science expert application development customer collaboration and integrationnow - sense of urgency global presence, local deliveryaccessible: Dial DuPont, self-serve WEB contentunderstand the “new reality”matching delivery to customer needs
6Next Generation Materials and Fuels from BiomassAutomotive OEMs around the world are developing cars to be more environmentally friendlyBiomass to ProductsGreen Chemistry &EngineeringWide range of productscommercially available andunder development.Deliver renewably sourced materials made from biomass instead ofpetroleum with uncompromised product performance
7DuPont’s 2015 Sustainability GoalsDuPont is one of the first companies to developenvironmental metrics nearly 18 years agoReduce Greenhouse Gas Emissions by another 15% Reduced 72% since 1990Water Conservation by 30%Fleet Fuel Efficiency: 100% fleet with better fuel efficiencyReduce Air Carcinogens emissions another 50%: Reduced 92% air carcinogenic emissions since 1990Double Revenue from Non-depletable Resources to 8Billion
8What’s at Stake Economic, Environmental, Social Challenges Global population growth Increasing global demand for energy Depleting oil reserves Rising greenhouse gas levels Need for energy independence Energy security/National security Consumer awareness of environmental optionsDriving the need for Renewable Energy and Materials
9DuPont Renewably Sourced MaterialsOur goal is to provide performanceand functionality equivalent to orbetter than today’s fully petroleumbased materials while reducing theenvironmental footprint.www.renewable.dupont.com
10DuPont Renewably Sourced MaterialsCurrent Portfolio for Engineering PolymersSorona EP Thermoplastic Polymer DuPont Sorona EP thermoplastic polymer is similar to the highperformance characteristics of current PBT materials.Hytrel RS Thermoplastic Elastomer DuPont Hytrel RS offers the flexibility and elastic recovery of rubbers,the strength of plastics and ease of processing by conventionalthermoplastic methods.Polymers Based on Sebacic Acid made from Castor Oil Zytel RS 6,10 and 10,10 polyamides Castor oil based polyamides with high strength and toughness
11DuPont Sorona Polymer1,3-propanediolBio-PDO O-(-C DMT / TPA Unique polymer withversatile propertiesCatalyst 37% renewably sourcedingredients, by weight(Sb-free) Antimony free catalystOC-OCH2CH2CH2O)-Sorona renewablysourced polymern
12Renewable sourcing for long chainpolyamidesCastor OilPalm orCoconut OilPetrochemicalsSebacic acidLauric icacidPA1010PA610PA612100% Renewable Carbon62% Renewable CarbonPotentially 66% RenewableCarbon
13Renewable Materials from DuPontSorona for interior textilesHytrel RS thermoplasticelastomer for injection andextrusionCerenol for polyurethane partsZytel RS polyamidesfor injection andextrusionBioFuelsSorona EPPTT polyester for molded partsSorona for carpets and mats
14Sorona Life Cycle AnalysisSorona vs nylon 6 Life Cycle Analysis (Cradle to gate) per ISO standards 37% renewable content 63% less green house gas emissions 30% less energy and 21% less process water.Major ISO 14000-series documents: ISO-14040 ISO-14044 ISO-14047ISO-14042Environmental management- Life cycle assessment- Principles and frameworkEnvironmental management- Life cycle assessment- Requirements and guidelinesEnvironmental management- Life cycle impact assessment- Examples of application of ISO-14048 ISO-14049Environmental management- Life cycle assessment- Data documentation formatEnvironmental management- Life cycle assessment- Examples of application of ISO14041 to goal and scope definition and inventory analysisHolistic Approach:Evaluate the impact of all upstream and downstream products and processes.LCA data for common petroleum based polymers can be found atwww.lca.plasticseurope.org as one of several public forums that use ISO.
15DuPont Sorona Fibers Carpets, fabrics, automotive interiors– all commercial applications.Available at most carpet outlets. 37% renewable content 63% less green house gas emissions,30% less energy vs nylon 6If only 20% of the residential carpet soldin the U.S. were made from Sorona , theenergy equivalent of approximately 50million gallons of gasoline would besaved per year.
16Sorona EP Polymers Excellent surface appearance. Caneliminate painting even with glassreinforced grades. This provides costsavings and further environmental benefitsby eliminating paint. Stronger and stiffer than PBT Lower shrink for less warpageApplications Electrical and electronic parts Automotive components Industrial and consumer products Appliance and power tools Office furniture & sporting goodsPBT, 30%GRSoronaØ, 30%GRHDT (1.8 MPa)1.5Specific Gravity1Shrinkage0.50Flex Mod (150C)Flexural ModulusTensile StrengthElongationPTTISO Recycle DesignationCompatible with PET
17Comparative Properties – Glass Reinforced12000Sorona 3030GPBT10000Tensile Modulus, MPa80004000PA6DAMPA6650%RHSorona A650%RH2000013-15% GlassDatasheets at www.plastics.dupont.comContact Rick Bell for detailed product comparisons30% Glass
18DuPont Automotive – Renewably Sourced MaterialsToyota SAI launched DecemberSustainable compact luxury car60 percent of the interior fabrics useDuPont Sorona renewablysourced fiber headliner sun visor other fabric covered surfaces floor mats. (Also on Prius).
19Automotive Carpet made with DuPont Sorona Commercial Automotive Applications Rapidly Growing Greater design flexibilitywithout fear of staininglighter colors Reduction in warrantyclaims for stain damagedcarpet No surface treatmentsrequired for soil resistance Superior softness whiledelivering wear resistancecomparable to nylon Dries faster than nylon andis therefore more resistantto mold and mildew.
20Hytrel RSProperties identical to standard Hytrel Excellent elasticity &low temperatureflexibility Excellent flex fatigueand cut growth lifeIn Hytrel RS, petroleum sourced polyetherglycols in the soft segments are replaced byRenewably Sourced polyether glycols madefrom non-food biomass. Good chemical & oilresistance High tear strength,toughness, resilience,impact resistance% renewable content7060504030201003040506070shore D hardnessThe renewably sourced content of Hytrel RS varies withthe hardness of the grade
21Hytrel RS – Potential ApplicationsProperties similar as regular Hytrel TPECVJ bootABD Covers(Driver)Air ductOvermolded parts(Door latches)Hose & tubing(vacuum hoses)CVJ, shifter boot, seat shiftdust coversAir brake hoseAnythermoplasticelastomer, softtouchapplication
22DuPont Hytrel RS ConceptElastomeric Suspension FabricFor Automotive SeatingWeight, space, design, comfort, utility, durabilityExamples of woven filament design
23Specialty Polyamides Based onRenewable FeedstockDeveloping specialty polyamides from renewable feed stocks.Sebacic acid, is derived from a renewable resource and is used inpreparing PA 6,10 & PA10,10.Sebacic acid Good mechanical, RF & Impact Resistance to polar fluids Low moisture absorption Good paintability, extrudability Up to 100% bio-sourced Non-food crop sourced¾ Fuel linesPA10,10PA 6,10¾ Pneumatic tubes¾ Air brake tubes¾ Handheld device
24Comparative properties of base polymersTENSILE 5000Mechanical Properties ( dry as moulded )Yield Stress (Mpa)Yield Strain (%)Strain at Break (%)Tensile Modulus (MPa)Unnotched Charpy Impact Strength -50C (kJ/m2)Notched Charpy Impact Strength -50C (kJ/m2)PA61062 502250NB2.4PA612614.3 502100NB3.5PA1010504.6 501550NB6.3PA11435 501350NBPA12455.2 501400NB5.2
25Zytel RS Long Chain Polyamides Based on biofeedstock derived fromcastor plant. Includes various grades ofPA10,10 (100% biobased) and PA6,10 (60%biobased). Commercial in monofilaments, consumerproducts, sporting goods, hand helddevices, automotive.Radiator end-tanks High performance polyamides that providehigh flexibility, toughness and thermalproperties with superior chemical andhydrolysis resistance Provides competitive cost options vsnylon 11 and 12.Pneumatic tubesFuel ConnectorsFuel lines and tubingCoolant pipes
26Radiator End-Tanks - DensoCommercial example of better performance at lowercost while reducing carbon footprint Zytel RS (PA 610) commercial inradiator end tanks First use of this renewably sourcedplastic in a mechanical componentexposed to the hot, chemicallyaggressive underhood environment DuPont won Denso's "InnovativeTechnology of the Year" award and SPE2009 automotive award “Most InnovativeUse of Plastics for the Environment”Lower cost vs PA11, PA12 or PA6,12
27Positioning of Various PolyamidesHydrocarbons resistanceBarrier Properties (fuel, CO2)Chain lengthPA12PA11PA1010PA612PA610PA66Polar Fluids resistanceFlexibilityMoisture resistanceHydrolysis resistanceStress Cracking resistance
28Hytrel RS responsible innovation now!Does not reduce our food stocksSupports the planet for future generationsBetter carbon footprint than petrochemical-based productsEquivalent product performance to traditional materialsFrom DuPont a name that you can trust for more than 200 years andhas delivered and is continuing to deliver sustainable solutions
29Sorona RS responsible innovation now!Made with renewable plant materialsSupports the planet for future generationsBetter carbon footprint than petrochemical-based productsEquivalent or better product performance to traditional materialsExcellent surface quality, lower warpage, better laser weldability, andbetter strength and stiffness than PBT.From DuPont a name that you can trust for more than 200 years andhas delivered and is continuing to deliver sustainable solutions
30Summary DuPont Renewably Sourced Materials supports corporatetransformation and sustainability goals. DuPont is leading the way towards the creation of arenewable economy. We have the broadest productportfolio for engineering polymers. Renewably Sourced Materials offer uncompromisedproduct performance and a reduced environmentalfootprint. Product data sheets and commercially sourced productsare available for engineering resins applications in Auto,EE, Industrial, and Consumer markets.
31DuPont Renewably Sourced Materialsvisit www.renewable.dupont.com
32OBRIGADO !!!
The renewably sourced content of Hytrel RS varies with the hardness of the grade Excellent elasticity & low temperature flexibility Excellent flex fatigue and cut growth life Good chemical & oil resistance High tear strength,
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