Green Engineering Textbook Chapter 3

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Chapter 3. Environmental Law and Regulations: From End-of-Pipe to PollutionPreventionbyDavid R. ShonnardChemical engineers practice a profession and must obey rules governing theirprofessional conduct. One important set of rules that all chemical engineers should beaware of is environmental statutes, which are laws enacted by Congress. Regulations arepromulgated by administrative agencies based on authority conferred by the statute. TheEnvironmental statutes are designed to protect human health and the environment byplacing limits on the quantity and chemical make-up of waste streams that are releasedfrom manufacturing processes. For example, one statute places restrictions on howhazardous waste from industry is stored, transported, and tr eated. Another statute placesstrict liability on the generators of hazardous waste, requiring responsible parties to cleanup disposal sites that fail to protect the environment. For manufacturers of newchemicals, there are regulatory requirements that required filing of a premanufacturenotice (PMN) before introducing a new chemical into the marketplace. While manycompanies have Health, Safety, and Environment (HS&E) staff that can help the engineerinterpret and implement environmental requirements, it is nevertheless important thatchemical engineers be aware of prominent federal environmental laws, and adhere to therequirements of these statutes.The purpose of this chapter is to provide an overview of environmental regulation. Muchof the ma terial on regulations in this chapter has been adapted from an excellent reviewof environmental law by Lynch (1995). More comprehensive sources on this topicinclude the United States Code (U.S.C.), and the Code of Federal Regulations (C.F.R.),which are sets of environmental statutes and regulations, respectively; they are availableonline at the sited maintained by the federal government printing office. TheEnvironmental Law Handbook (Sullivan and Adams, 1997) and West’s EnvironmentalLaw Statutes (We st Publishing Co.) are compendia of existing statutes. Most of thesesources can be found online.There are approximately 20 federal statutes, hundreds of state and local ordinances,thousands of federal and state regulations, and even more federal and state court casesand administrative adjudications, etc., that deal with environmental issues. Takentogether, they make up the field of environmental law, which has seen explosive growthin the last 30 years, as shown in Figure 3.1-1. Chemical engineers should be familiarwith environmental laws and regulations because they affect the operation of chemicalprocesses and the professional responsibilities of chemical engineers. Environmentalregulations and the common law system of environmental law requir e actions by affectedentities. For example, the Clean Water Act (an environmental statute) requires facilitiesthat discharge pollutants from a point source into navigable waters in the United States toapply for a national pollutant discharge elimination system (NPDES) permit. In manyfirms, chemical engineers are responsible for applying for and obtaining these permits.The common law created by judicial decision also encourages chemical engineers to act

Figure 3.1-1 Cumulative growth in the federal environmental laws and amendments.responsibly when performing their professional duties because environmental laws andregulation do not cover every conceivable environmental wrong. Chemical engineersneed to be aware of the potential legal liability resulting from violation of environmentallaws and regulations to protect their company and themselves from legal andadministrative actions.The sources of environmental laws and regulations are legislatures, administrativeagencies, and the courts. When drafting environmental laws, federal and statelegislatures often use broad language to describe the objectives, regulatory programs, andenforcement provisions of the statute. Often, legislators do not have the time or resourcesto implement the stat ute and therefore leave the detailed development of regulations toadministrative agencies. Administrative agencies, such as the Environmental ProtectionAgency, give meaning to statutory provisions through a procedure know as rule making.Federal rule m aking consists of giving notice of proposed new regulations by publicationin the Federal Register , providing an opportunity for public comment, altering theproposed rule, where appropriate, to incorporate the comments received, and publishingfinal regul ations in the Federal Register. Final rules have the force of law. As such,administrative agencies fulfill a legislative function delegated to them by Congress.Administrative agencies can be created by the executive or legislative branches ofgovernment. In 1970, President Nixon established the United States Environmental

Protection Agency by executive order to consolidate federal programs for regulating airand water pollution, radiation, pesticides, and solid waste disposal. However,administrative agencies are most often established by statue(for example, theOccupational Safety and Health Act established the Occupational Safety and HealthAdministration), and in these cases, the agency powers are derived from their enablinglegislation. Administrative agencies also have the authority to resolve disputes that arisefrom the exercise of their administrative powers. Regulated entities have the right toappeal decisions made by administrative agencies to an administrative law judge, who isappointed by the agency. Thus administrative agencies have a judicial function inaddition to a legislative function.Courts are a third government actor that helps to define the field of environmental law.The role of the courts in environmental law is:1. To det ermine the coverage of environmental statutes (which entities arecovered by regulations);2. To review administrative rules and decisions (ensuring that regulations arepromulgated following proper procedures and within the limits ofstatutorily delegate authority); and3. To develop the common law (a record of individual court cases anddecisions that set a precedent for future judicial decisions).Section 3.2 provides a brief description of the most important features of nine federalenvironmental statutes that most significantly affect chemical engineers and the chemicalindustry. This brief survey is meant to be representative, not comprehensive, and thefocus will be on federal laws because they have national scope and often serve as modelsfor state environmental statutes. We begin with three statutes that regulate the creation,use, and manufacture of chemical substances. Next, we cover the key provisions of threestatutes that seek to control the discharge of pollutants to specific environmental media —air, water, and soil. Next, a statute that initiated a clean-up program for the many sites ofsoil and groundwater contamination is discussed. The final two statutes involve thereporting of toxic substance releases and a voluntary program for preventing pollutiongeneration and release at industrial facilities. Section 3.3 describes the evolution inenvironmental regulation from end-of-pipe pollution control to more proactive pollutionprevention approaches. Section 3.4 presents the key features of pollution prevention,including its position in the hierarchy of environmental management alternatives, a shortreview of terminology, and examples of pollution prevention strategies and applications.

Chapter 3 Example TableTable 3.1 Summary Table for Environmental LawsEnvironmental StatuteDateBackgroundEnactedRegulation of ChemicalManufacturingThe Toxic SubstancesControl Act (TSCA)The Federal Insecticide,Fungicide, and RodenticideAct (FIFRA)The Occupational Safety andHealth Act (OSH Act)Key Provisions1976Highly toxic substances, such aspolychlorinated biphenyls (PCBs), beganappearing in the environment and in foodsupplies. This prompted the federalgovernment to create a program to assess therisks of chemicals before they are introducedinto commerce.Chemical manufacturers, importers, orprocessors, must submit a report detailingchemical and processing information for eachchemical. Extensive testing by companiesmay be required for chemicals of concern.For newly created chemicals, aPremanufacturing Notice must be submitted.Enacted,1947Amended,1972Because all pesticides are toxic to plants andanimals, they may pose an unacceptable riskto human health and the environment.FIFRA is a federal regulatory programwhose purpose is to assess the risks ofpesticides and to control their usage so thatany exposure that my result poses anacceptable level of risk.Before any pesticide can be distributed orsold in the U.S., it must be registered withthe EPA. The data is difficult and expensiveto develop and must prove that the chemicalis effective and safe to humans and theenvironment. Labels must be placed onpesticide products that indicate approveduses and restrictions.1970The agency that oversees the implementationof the OSH Act is the Occupational Safetyand Health Administration (OSHA). Allprivate facilities having more than 10employees must comply with the OSH Actrequirements.Companies must adhere to all OSHA healthstandards (exposure limits to chemicals) andsafety standards (physical hazards fromequipment). The OSH Act’s HazardCommunication Standard requires companiesto develop hazard assessment data (materialsafety data sheet (MSDS), label chemicalsubstances, and inform and train employeesin the safe use of chemicals.

Table 3.1 Continued; Summary Table for Environmental LawsEnvironmental StatuteDateBackgroundKey ProvisionsRegulation of Discharges tothe Air, Water, and SoilClean Air Act (CAA)1970The CAA is intended to control the dischargeof air pollution by establishing uniformambient air quality standards that are insome instances health-based and in others,technology-based. The CAA also addressesspecific air pollution problems such ashazardous air pollutants, stratospheric ozonedepletion, and acid rain.The CAA established the National Ambient AirQuality Standards (NAAQS) for maximumconcentrations in ambient air of CO, Pb, NO2, O3,particulate matter, and SO 2. States must developsource-specific emission limits to achieve theNAAQS. States issue air emission permits tofacilities. Stricter requirements established forhazardous air pollutants (HAPs) and for newsources.Clean Water Act (CWA)1972The Clean Water Act (CWA) is the firstcomprehensive federal program designed toreduce pollutant discharges into the nation’swaterways (“zero discharge” goal). Anothergoal of the CWA is to make water bodiessafe for swimming, fishing, and other formsof recreation (“swimmable” goal). This actis considered largely successful becausesignificant improvements have been made inthe quality of the nation’s waterways sinceits enactment.The CWA established the National PollutantDischarge Elimination System (NPDES) permitprogram that requires any point source ofpollution to obtain a permit. Permits contain eithereffluent limits or require the installation ofspecific pollutant treatment. Permit holders mustmonitor discharges, collect data, and keep recordsof the pollutant levels of their effluents. Industrialsources that discharge into sewers must complywith EPA pretreatment standards by applying thebest available control technology (BACT).Resource Conservation andRecovery Act (RCRA)1976The Resource Conservation and RecoveryAct was enacted to regulate the “cradle-tograve” generation, transport, and disposal ofboth non-hazardous and hazardous wastes toland, encourage recycling, and promote thedevelopment of alternative energy sourcesGenerators must maintain records of the quantityof hazardous waste generated, where the wastewas sent for treatment, storage, or disposal, andfile this data in biennial reports to the EPA.Transporters and disposal facilities must adhere tosimilar requirements for record keeping as well asfor monitoring the environment.

based on solid waste materials.Table 3.1 Continued; Summary Table for Environmental LawsEnvironmental StatuteDateBackgroundEnactedClean-Up, EmergencyPanning, and PollutionPreventionThe ComprehensiveEnvironmental Response,Compensation, andLiability Act (CERCLA)1980The Emergency Planningand Community Right toKnow Act (EPCRA)1986Pollution Prevention Act(PPA)1990CERCLA began a process of identifying andcleaning up the many sites of uncontrolledhazardous waste disposal at abandoned sites,industrial complexes, and federal facilities.EPA is responsible for creating a list of themost hazardous sites of contamination, whichis termed the National Priority List (NPL). Itwas amended by the Superfund Amendmentsand Reauthorization Act (SARA) of 1986.Title III of (SARA) contains a separate pieceof legislation called the (EPCRA). There aretwo main goals of EPCRA; 1) to have statescreate local emergency units that mustdevelop plans to respond to chemical releaseemergencies, and 2) to require EPA tocompile an inventory of toxic chemicalreleases to the air, water, and soil frommanufacturing facilities.The act established pollution prevention asthe nation’s primary pollution managementstrategy with emphasis on source reduction.Established a Pollution PreventionInformation Clearinghouse whose goal is tocompile source reduction information andmake it available to the public.Key ProvisionsAfter a site is listed in the NPL, EPA identifiespotentially responsible parties (PRPs) and notifiesthem of their potential CERCLA liability, whichis strict, joint and several, and retroactive. PRPsare 1) present or 2) past owners of hazardouswaste disposal facilities, 3) generators ofhazardous waste, and 4) transporters of hazardouswaste.Facilities must work with state and local entitiesto develop emergency response plans in case of anaccidental release. Affected facilities must reportannually to EPA data on the maximum amount ofthe toxic substance on-site in the previous year,the treatment and disposal methods used, and theamounts released to the environment ortransferred off-site for treatment and/or disposal.The only mandatory provisions of the PPArequires owners and operators of facilities that arerequired to file a Form R under the SARA TitleIII to report to the EPA information regarding thesource reduction and recycling efforts that thefacility has undertaken during the previous year.

Chapter 3 Sample Homework Problem1. Categorize the following solvent recovery operation in terms of the waste managementhierarchy. Discuss the pollution prevention features of this process. Determine whetherthis process is pollution prevention or not. Use both the federal definition and also theexpanded definition adopted in this text.Process Description: The automotive industry uses robots to paint automobile bodiesbefore attaching them to the chassis, and installing other components such as the drivetrain, lights, trim, and upholstery. In order to accommodate different colors, the paintlines must be flushed with a solvent and then re-charged with the new color paint. In thepast, this solvent and paint residue was disposed of as hazardous waste or incinerated.The current process of spray painting automobiles uses a closed-loop solvent recoveryprocess as outlined in the diagram below (Gage Products, Ferndale, MI).

Environmental Law Handbook (Sullivan and Adams, 1997) and West’s Environmental Law Statutes (West Publishing Co.) are compendia of existing statutes. Most of these sources can be found online. There are approximately 20 federal statutes, hundreds of state and local ordinances,

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