Atomic Theory Scientists

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Atomic Theory ScientistsThe history of the atom.

HISTORY OF THE ATOM- Democritus460 BCDemocritus develops the idea of atomsHe pounded up materials in his pestle andmortar until he had reduced them to smallerand smaller particles which he called ATOMOS (greek for indivisible) This is where we get the word “atoms”

History of the Atom- Aristotle Aristotle said there were four elements:– Earth– Air– Water– Fire

Boyle Boyle rejected the idea that there were 4 elements– Impossible to combine the 4 elements to form a substance– Impossible to extract these elements from a substance Boyle defined an element as any substance that cannotbe decomposed into a simpler substance

HISTORY OF THE ATOM- DaltonJohn Dalton1808Dalton's Atomic Theory1) All matter is made of atoms. Atoms are indivisibleand indestructible.2) All atoms of a given element are identical in massand properties3) Compounds are formed by a combination of two ormore different kinds of atoms.4) A chemical reaction is a rearrangement of atoms.Dalton’s “Billiard Ball Model”:Atoms are the smallest type of matter and theyare entirely solid like a billiard ball

HISTORY OF THE ATOM- ThomsonJoseph John Thomson Found the electron using the cathode ray tube because ofits negative charge He found that atoms could sometimes eject a far smallernegative particle which he called an ELECTRON . Also developed the Plum Pudding Model of the atom

Thomson’s Plum Pudding ModelThompson develops the idea that an atom was made up ofelectrons scattered unevenly within an elastic sphere surroundedby a soup of positive charge to balance the electron's chargelike plums surrounded by pudding.PLUM PUDDINGMODEL

History of the Atom- MillikanRobert Millikan Discovered the charge and mass of anelectron by his famous oil dropexperiment– The experiment entailed observing tinycharged droplets of oil between two horizontalmetal electrodes. This enabled him to measurethe charge of an electron– calculated the mass of an electron, which is 9.1 1031 kg

What’s next? Two inferences:– Something had to account for the mass of the atom since the electrondoesn’t contribute to it– Since the charge on an atom is neutral, there must be a positivelycharged area to balance out the negative charge of the electron

HISTORY OF THE ATOM- RutherfordErnest Rutherford–He used his Gold Foil experiment to prove Thomson’s plumpudding model wrong, discovered protons, and developed theidea of a nucleus–He passed particles through gold foil, and realized noteverything passed through, so there must be something otherthan just a negative charge–He developed the Nuclear Atom model or the Planetary modelof the atom–Most of the mass of the atom is in the nucleus and electronsorbit the nucleus like planets orbit the sun

HISTORY OF THE ATOMhelium nucleigold foilhelium nucleiThey found that while most of the helium nuclei passedthrough the foil, a small number were deflected and, to theirsurprise, some helium nuclei bounced straight back.

History of the Atom- ChadwickJames Chadwick Chadwick took Rutherford’s researchfurther and found the neutron The problem was the atomic number was less than theatomic mass (average mass of the atom). For example,a helium atom has an atomic mass of 4, but an atomicnumber (or positive charge) of 2.Since electrons have almost no mass, it seemedthat something besides the protons in the nucleuswere adding to the mass. One leading explanation wasthat there were electrons and additional protons inthe nucleus as well -- the protons still contributedtheir mass but their positive charge was canceled outby the negatively charged electrons. idea that therecould be a particle with mass but no charge. He calledit a neutron, and imagined it as a paired proton andelectron.

Niels BohrNiels Bohr1913Bohr refined Rutherford's idea by addingthat the electrons were in orbits. Likeplanets orbiting the sun. With each orbitonly able to contain a set number ofelectrons. This is called Bohr model orQuantum model of the atom.

SchrodingerBohr’s model only fits hydrogen and was provenincorrect by Schrodinger.Schrodinger suggested that orbits were notalways circular, but in a pattern. He called themorbitals.Schrodinger’s model is called the QuantumMechanical Model of the atom

HeisenbergWerner Heisenberg The Heisenberg uncertainty principle states that itis impossible to know simultaneously the exactposition and momentum of a particle. That is, the more exactly the position is determined,the less known the momentum, and vice versa.

History of the Atom- Chadwick Chadwick took Rutherford’s research further and found the neutron The problem was the atomic number was less than the atomic mass (average mass of the atom). For example, a helium atom has an atomic mass of 4, but an atomic number (or positive charge) of 2. Since electrons have almost no mass, it seemed

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