Barrier Paper

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www.mitsubishi-paper.comHiTec Paper.Barrier Paperfor Food Packaging

Mitsubishi HiTec PaperPassion for First Class HiTec PapersAs a leading international supplier of direct thermal, inkjet, carbonless, label and barrier papers,we produce first class coated speciality papers for many applications and printing technologies.Our HiTec papers combine decades of know-how with state-of-the-art coating technology andprofessional converting equipment.The responsible handling of resources is particularly important to us. We manufacturein the framework of an integrated management system (DIN EN ISO 9001, 14001 and50001 as well as DIN EN 15593). Our locations in Bielefeld and Flensburg are FSC and PEFC certified.We are a flexible medium sized enterprise within the international MitsubishiGroup. Consistent research and development is the foundation for greatinnovation. We develop individual, customized solutions for our customers.We offer the best global sales network and technical service to ourcustomers all over the world.› Huge experience and competence in paper making› State-of-the-art coating technologies and formulations› German-Japanese Research & Development› Wide range of products› Excellent Technical Service› Worldwide Sales Network› High innovative power› Made in Germany Qualitypaper is the foundation.Incomparable added value is createdby excellent coating. This is ourpassion: First class HiTec Paper.2

B A RRIER PA PERProtected.Foods, consumers and the environment sustainably protectedAT A GLANCE:In the food industry, packaging is no longerraw materials that are not in competitionjust about the protection of foods, its storagewith food production. Whether as primaryAll barricote barrier papers are characteri-or the smooth transport. The focus is on to-or secondary packaging - all barricotezed by the following features:pics such as waste prevention, replacementproducts are fully recyclable and thereforeof plastic packaging as well as using moreideally suited for the circular economy.sustainable materials.Environmentally friendly, sustainable and› Paper products made from virgin fibers› Water-based coatings for combinablebarrier functions againstsafe. water vapourIn short: innovative solutions that, in additionto the efficient protection of packagedInnovations such as barricote are possible grease / oilgoods, also take into account aspects suchbecause of our many years of experience in oxygen / aromaas environmental responsibility and sustain-coating various speciality papers. We have mineral oil migrationability. Solutions that protect consumerssix different coating technologies at ourand the environment. Solutions, such asdisposal for the application of many differentour barricote barrier papers for flexible foodfunctional, protective and barrier coatings,packaging.including multiple and double-sided coatings.Our curtain coater technology enables us toAs a sustainable high-tech material, paper isapply coatings in an extremely uniform andthe ideal basis for many food packaging.highly effective way, safely and accurately.At Mitsubishi HiTec Paper, we use renewable› 100 % free of p lastic films, aluminum, extrudedpolymers, varnishes or laminates fluorocarbons c hlorinated hydrocarbons (PVDC free) optical brighteners (OBA free)› High content of biodegradableingredients› Fully recyclable› Reverse side offset and flexo printablefullyrecyclableCurtain coater technologyPotential threats for ns: food and non-food packagingmineraloilsgrease /oilfoodstuffcurtainpaper webaromaoxygenAll barricote barrier papers featurethefollowing certifications:Zusätzlich› direct food contact (e. g. BfR XXXVI)› ISO 9001, ISO 14001, ISO 50001› INREKA DIN EN 15593› FSC Mix or PEFC B A RRIER PA PER3

BAG WG / BAG WGOMbarricote BAGHeat-sealed bags – food permanently protectedOur barrier paper barricote BAG WG* offers an excellent combined barrier against grease and oil as wellas against water vapour. In addition, BAG WGOM** with its oxygen and aroma barrier ensures a long shelflife of the packaged food. The integrated barrier against mineral oil migration reliably protects against MOSH/ MOAH impurities - the migration is below current legislation on the protection of packaged food. Anotherfeature of this particularly universal barrier paper is the certified seawater decomposability.Due to the very good heat-sealability, both papers are particularly suitable for bag packaging and are intelligent alternatives to film packaging made of PE, PP or BOPP film. Environmentally friendly and sustainable.BAG WG:Special features› Durable combined barrier against water vapour grease / oil› Very good heat-sealabilityGeneral features› Paper product made from virgin fibers› 100 % free of p lastic films, aluminum, extruded polymers,varnishes or laminates fluorocarbons chlorinated hydrocarbons (PVDC free)fullycre yclable optical brighteners (OBA free)› High content of biodegradable ingredients› Reverse side offset and flexo printableApplications: h eat-sealed bags for dry andgreasy foods and non-foodsHS BAG WGHeat seal strength (sealing duration 1 s)Seal strength [N/15 mm]765432104B A RRIER PA PER6080100120140160Temperature [ C]180200

BAG WG / BAG WGOMBAG WGOM:Special features› Durable combined barrier against water vapour grease / oil oxygen / aroma mineral oil migration› Very good heat-sealability› Particularly high proportion of renewable raw materials› Certified seawater decomposabilityfullycre yclableGeneral features› Paper product made from virgin fibers› 100 % free of p lastic films, aluminum, extruded polymers,varnishes or laminates fluorocarbons chlorinated hydrocarbons (PVDC free) optical brighteners (OBA free)› High content of biodegradable ingredients› Reverse side offset and flexo printableHS BAG WGOMHeat seal strengthApplications: heat-sealed bags for dry and(sealing duration 1 s, 150 C, 500 kPa)7Seal strength [N/15 mm]greasy foods and non-foods65432106080100120140160Temperature [ C]180200barricote BAGGradeSubstanceThicknessWater absorptionWater vapourpermeability(Cobb 300, EN ISO 535)(DIN 53122-1, 38 C / 90 % r. H.)BAG WG87 g/m²90 µm 1 g/m²70 g/(m²*d) 1800 sLevel 1BAG WGOM89 g/m²91 µm15 g/m²70 g/(m²*d) 1800 sLevel 1Grease resistanceTurpentine test Palm kernel oil(according to T454) (DIN 53116)OTRHeat-sealability(1 sec., 150 C, 500 kPa)6.5 N / 15 mm 100 cc/(m²*d)6 N / 15 mmInformation about test procedures can be found in the technical data sheets.* WG: W – water vapour barrier, G – grease and oil barrier** WGOM: W – water vapour barrier, G – grease and oil barrier, O - oxygen and aroma barrier, M – mineral oil barrierB A RRIER PA PER5

WR AP WG / WR AP WG UNIbarricote WRAP WGWrapped, glued or heat sealed – Everything stays where it belongsWhether wrapped or glued, the speciality paper barricote WRAP WG* is the ideal wrappingpaper for the food industry. The reliable barrier against water vapour and against grease oroil is complemented by a very good release effect. Barricote WRAP WG contains a particularlyhigh proportion of renewable raw materials and protects dry and greasy foods in an optimalway. Safe and highly sustainable.The barrier paper barricote WRAP WG uni* excels as a combined barrier against water vapourand grease / oil with very good heat-sealability. WRAP WG uni is the ideal alternative to PEwrapping materials. For dry and greasy food. Everything stays in shape and fresh.Well protected.WRAP WG:Special features› Combined barrier against water vapour grease / oil› Excellent freshness effect› Barrier side hot melt glueable› Particularly high proportion of renewable raw materials› Excellent release effect› Certified seawater decomposabilityGeneral features› Paper product made from virgin fibers› 100 % free of p lastic films, aluminum, extruded polymers,varnishes or laminates fluorocarbons chlorinated hydrocarbons (PVDC free) optical brighteners (OBA free)› High content of biodegradable ingredients› Reverse side offset and flexo printableApplications: wrapping papers fordry and greasy foods6B A RRIER PA PERfullycre yclable

fullyrecyclableWRAP WG uni:Special features› Combined barrier against water vapour grease / oil› Excellent freshness effect› Barrier side hot melt glueable› Very good heat-sealability› Certified seawater decomposabilityWRAP WG UNIHeat seal strength(sealing duration 1 s, 150 C, 500 kPa)Seal strength [N/15 mm]7General features› Paper product made from virgin fibers› 100 % free of p lastic films, aluminum, extruded polymers,varnishes or laminates654321 fluorocarbons0 chlorinated hydrocarbons (PVDC free)6080100120140160Temperature [ C]180200 optical brighteners (OBA free)› High content of biodegradable ingredients› Reverse side offset and flexo printableGrease barrier test (coloured oil)barricote WRAP WG uniWrapping paper without barrierNo leakageTurpentine oil seeps throughApplications: wrapping papers as well as heat-sealedsachets for dry and greasy foodsCONTROL SHEETSbarricote WRAP WGGrease resistanceGradeSubstanceThicknessWater absorptionWater vapour permeability(Cobb 300, EN ISO 535)(DIN 53122-1, 38 C / 90 % r. H.)Turpentine test(according to T454)Palm kernel oil(DIN 53116)WRAP WG44 g/m²53 µm3 g/m²250 g/(m²*d) 1800 sLevel 1-WRAP WGuni44 g/m²53 µm3 g/m²250 g/(m²*d) 1800 sLevel 14 N / 15 mmHeat-sealability(1 sec., 150 C, 500 kPa)Information about test procedures can be found in the technical data sheets.* WG: W – water vapour barrier, G – grease and oil barrierB A RRIER PA PER7

LINER MGbarricote LINER MGGlued or laminated – No chance for mineral oil migrationcorrugated cardboardLaminated or glued packaging made from our barrier paper barricote LINER MG* provides an optimaland secure barrier against the migration of mineral oils and similar substances. The migration isdemonstrably lower than current draft legislation to protect packaged foods. Another advantage ofthe water-based coating is the barrier against grease and oil.foodstuffLINER MG is the ideal basis for safe packaging of dry and greasy food such as pasta, oat flakes,cereals, coffee and other bulk food. The special barrier function is of course maintained during allmineral oilsfurther processing steps such as printing, folding, creasing, etc. Natural and safe.Liner MGLINER MG:Special features› Combined barrier against mineral oil migration grease / oil› Protective function not reduced by further processingGeneral features› Paper products made from virgin fibers› 100 % free of p lastic films, aluminum, extruded polymers,fullyrecyclablevarnishes or laminates fluorocarbonsMineralölmigration (MOAH) in mg pro kg Lebensmittel chlorinated hydrocarbons (PVDC free)Mineral Oil Migration (MOAH) optical brighteners (OBA free)Mineral oil migration (MOAH) [mg/kg]› High content of biodegradable ingredients› Reverse side offset and flexo printableApplications: lining paper for recycled cardboard and corrugatedcardboard, bags for dry and greasy foods0,70,6Guideline value „Mineralölverordnung“***0,50,40,30,20,10LINER MG (50 g)LINER MG (85 g)barricote LINER MGGradeLINER MGSubstance50 g/m²85 g/m²Thickness58 µm100 µmMineral oil migration (Tenax method, DIN EN 14338**)MOSH (C 20 –C 35 )MOAH (C 16 –C 35 )7%5%20 %10 %Grease resistance(according to T559) 12 12Information about test procedures can be found in the technical data sheets.* MG: M – mineral oil barrier, G – grease and oil barrier** laminated on carrier with MOSH 759 mg/kg and MOAH 277 mg/kg*** The guideline value of the draft regulation of the German “Mineralölverordnung” (4th draft of the BMEL of March 7, 2017) indicates a maximum transition of 0.5 mg / kg C16-C35 MOAH to foodstuffs.

GR ADE OVERVIEWGrade overview barricoteBAG WGBAG WGOMWRAP WGWRAP WG uniSubstance87 g/m²89 g/m²44 g/m²44 g/m²50 g/m²85 g/m²Thickness90 μm91 μm53 μm53 μm58 μm100 μm 1 g/m²15 g/m²3 g/m²3 g/m²2 g/m²30 g/m²15 g/m²15 g/m² 10 g/(m²*d)15 g/(m²*d)110 g/(m²*d)110 g/(m²*d)70 g/(m²*d)70 g/(m²*d)250 g/(m²*d)250 g/(m²*d)KIT-Value12121212 12Turpentine 1800 s 1800 s 1800 s 1800 s 1800 slevel 1level 1level 1level 1level 1Cobb 300WATER VAPOUR(EN ISO 535)Cobb1800(EN ISO 535)WVTR(23 C/85 % r. h.)WVTRGREASE & OIL(38 C/90 % r. h.)MINERAL OILSOXYGENPalm kernel oilOTR 100 cc/(m²*d)Hexanes25–50 g/(m²*d)5–10 g/(m²*d)MOSHMOAHHeat-sealability(1 sec., 150 C, 500 kPa)0.4 mg/kg6.5 N / 15 mm6 N / 15 mm7%5%20 %10 %4 N / 15 mmdirect contact with food (e.g. BfR XXXVI)ISO 9001, ISO 14001, ISO 50001INREKA DIN EN 15593FSC Mix or PEFC CertificationsSea waterdecomposabilityApplicationsLINER MGHeat-sealed bags for dry,moist and greasy foodsand non-foods Heat-sealed bags for dryand greasy foods andnon-foodsWrapping papers for dryand greasy foodsWrapping papers andheat-sealed sachets for dryand greasy foodLaminated paper forrecycled cardboard andcorrugated cardboard,bags for dry and greasyfoods

As a responsible manufacturer, we strive to produce and processour products in the most environmentally friendly way and to thehighest standards of quality. We take our social responsibilityseriously and are active in various environmental associationsand organizations. Complying with and conforming to rules andregulations goes without saying. Social commitment is an importantpart of our corporate culture.Certifications:› FSC Chain-of-Custody› PEFC Chain-of-Custody› DIN EN ISO 9001:2015› DIN EN ISO 14001:2015› DIN EN ISO 50001:2011› INREKA DIN EN 15593:2008 Memberships:› B.A.U.M.› ChePap Rhein-Ruhr› Klimapakt Flensburg› Ökoprofit Klub OWL› Two Sides› Wirtschaft pro Klima0 8 2 0 19 Mitsubishi HiTec Paper Europe GmbHNiedernholz 23 33699 Bielefeld DeutschlandTel: 49 521 2091-682 m

** WGOM: W – water vapour barrier, G – grease and oil barrier, O - oxygen and aroma barrier, M – mineral oil barrier Grade Sub-stance Thick-ness Water absorption Water vapour permeability (DIN 53122-1, 38 C / 90 % r. H.) Grease resistance OTR Heat-sealability (Cobb 300, EN ISO 535) Turpentine test (according to T454) Palm kernel oil

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