Classification Report New Blue Toilet Fluid

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Product Created: 27/01/2016Jurisdiction: 0Report Created:28/01/2016Classification ReportNew Blue Toilet FluidCompany IdentificationSupplierBlue Diamond ProductsUnit 1 Brick Park,Bretfield Court,Bretton Street Industrial Estate,Dewsbury,WF12 9BY 44 (0)1924 455 313 44 (0)1924 450 551mick@blue-diamond-products.co.ukMixture IdentificationSDS No.4077Product nameNew Blue Toilet FluidHazard IdentificationPictogramSignal wordWarningHazard statementsH319 Causes serious eye irritation.Precautionary statementsP102 Keep out of reach of children.P264 Wash contaminated skin thoroughly after handling.P305 P351 P338 IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.P337 P313 If eye irritation persists: Get medical advice/attention.P501 Dispose of contents/container in accordance with national regulations.Supplementary precautionary P280 Wear protective gloves/protective clothing/eye protection/face protection.statementsChild-Resistant FasteningNoTactile Warning of DangerNo1/21

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidClassificationPhysical hazardsNot ClassifiedHealth hazardsEye Irrit. 2 - H319Environmental hazardsNot ClassifiedEntered FormulationSDS numberName3006AGMA Toilet Additive 1338 (3006)2914CERAVON BLUE V10 DC (2914)2922FORMALDEHYDE REODORANT ALTERNATIVE (2922)3Water (3)Constituent Chemicals1Content %19.0%0.05%0.6%80.05%Water (3)CAS number: 7732-18-580.05%EC number: 231-791-2Product number: —EU index number: —Physical hazardsHealth hazardsEnvironmental hazards2Not ClassifiedNot ClassifiedNot ClassifiedBronopol (INN) (2925)CAS number: 52-51-72.47%EC number: 200-143-0Product number: VIEU index number: 603-085-00-8Physical hazardsNot ClassifiedHealth hazards Acute Tox. 4 - H302,Acute Tox. 4 - H312,Skin Irrit. 2 - H315,Eye Dam. 1 H318,STOT SE 3 H335 Environmental hazardsAquatic Acute 1 - H40032-tert-Butylcyclohexyl acetate (1812)CAS number: 88-41-50.0417%EC number: 201-828-7Product number: —EU index number: —Physical hazardsHealth hazardsEnvironmental hazards4Not ClassifiedNot ClassifiedAquatic Chronic 2 - H4112,4-Dimethylcyclohex-3-ene-1-carbaldehyde (247)CAS number: 68039-49-60.03258%EC number: 268-264-1Product number: —EU index number: —Physical hazardsHealth hazardsEnvironmental hazardsNot ClassifiedSkin Irrit. 2 - H315,Eye Irrit. 2 - H319,Skin Sens. 1 - H317Aquatic Chronic 3 - H4122/21

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet l acetate (1617)number: 226-501-60.0246% CAS number: 5413-60-5 ECProduct number: —EU index number: —Physical hazardsHealth hazardsEnvironmental hazards6Undecan-4-olide (308)CAS number: 104-67-6Not ClassifiedNot ClassifiedAquatic Chronic 3 - H4120.02202%EC number: 203-225-4Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazardsNot ClassifiedEnvironmental hazardsAquatic Chronic 2 - H4117Diethyl malonate (2266)CAS number: 105-53-3EC number: 203-305-90.0147%Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazardsEye Irrit. 2 - H319Environmental hazardsNot Classified8p-Menth-1-en-8-ol (1006)CAS number: 98-55-5EC number: 202-680-60.0147%Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazardsSkin Irrit. 2 - H315,Eye Irrit. 2 - H319Environmental hazardsNot Classified9α-Hexylcinnamaldehyde (210)CAS number: 101-86-0EC number: 202-983-30.0123%Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazardsSkin Sens. 1 - H317Environmental hazardsAquatic Chronic 2 - H41110Methyl salicylate (541)CAS number: 119-36-8EC number: 204-317-70.01128%EU index number: —3/21Product number: —

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidPhysical hazardsNot ClassifiedHealth hazardsAcute Tox. 4 - H302Environmental hazardsNot Classified11Cineole (1626)CAS number: 470-82-6EC number: 207-431-50.01092%Product number: —EU index number: —Physical hazardsFlam. Liq. 3 - H226Health hazardsSkin Sens. 1 - H317Environmental hazardsNot Classified12Acid Violet 49 (2913)CAS number: 1694-09-3EC number: 216-901-90.00995%Product number: VIEU index number: 650-010-00-XPhysical hazardsNot ClassifiedHealth hazardsCarc. 2 - H351Environmental hazardsNot Classified13Bornan-2-one (1673)CAS number: 76-22-2EC number: 200-945-00.0078%Product number: —EU index number: —Physical hazardsFlam. Sol. 2 - H228Health hazardsAcute Tox. 4 - H302,Acute Tox. 4 - H332,STOT SE 2 - H371Environmental hazardsNot Classified14Hexyl salicylate (2915)CAS number: 6259-76-3EC number: 228-408-60.00732%Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazardsSkin Irrit. 2 - H315,Eye Irrit. 2 - H319,Skin Sens. 1 - H317Environmental hazardsAquatic Chronic 1 - H41015Ethyl 2,3-epoxy-3-phenylbutyrate (1817)EC number: 201-061-8CAS number: 77-83-8EU index number: —Physical hazardsNot ClassifiedHealth hazardsNot Classified4/210.00732%Product number: —

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidEnvironmental hazardsAquatic Chronic 2 - H411163,7-Dimethyloctan-3-ol (435)CAS number: 78-69-3EC number: 201-133-90.00732%Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazardsSkin Irrit. 2 - H315,Eye Irrit. 2 - H319Environmental hazardsNot -inden-6-yl propionate (2302)EC number: 241-514-7CAS number: 17511-60-30.00588%Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazardsNot ClassifiedEnvironmental hazardsAquatic Chronic 2 - H41118Allyl phenoxyacetate (2916)CAS number: 7493-74-50.0054%EC number: 231-335-2Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazards Acute Tox. 4 - H302,Acute Tox. 4 - H312,Skin Irrit. 2 - H315,Skin Sens. 1 - H317 Environmental hazardsNot Classified19Thymol (460)CAS number: 89-83-80.00492%EC number: 201-944-8Product number: —EU index number: 604-032-00-1Physical hazardsNot ClassifiedHealth hazards Acute Tox. 4 - H302,Skin Corr. 1B - H314,Eye Dam. 1 - H318 Environmental hazardsChronic 2 - H41120α,α,4-Trimethylcyclohexylmethyl acetate (2917)0.0027% CAS number: 80-25-1EC number: 201-264-1Product number: —EU index number: —Physical hazardsHealth hazardsEnvironmental hazardsFlam. Liq. 3 - H226Eye Irrit. 2 - H319,Skin Sens. 1 - H317,Asp. Tox. 1 - H304Aquatic Chronic 2 - H4115/21Aquatic

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet Fluid21Pin-2(10)-ene (220)CAS number: 127-91-30.00252%EC number: 204-872-5Product number: —EU index number: —Physical hazardsFlam. Liq. 3 - H226Health hazards Skin Irrit. 2 - H315,Skin Sens. 1 - H317,Asp. Tox. 1 - H304 Environmental hazardsClassified22Decan-1-ol (2918)CAS number: 112-30-1Not0.00246%EC number: 203-956-9Product number: —EU index number: —Physical hazardsHealth hazardsEnvironmental hazards23Not ClassifiedEye Irrit. 2 - H319Aquatic Chronic 2 - H411White mineral oil (petroleum), light (2912)CAS number: 92062-35-60.00245%EC number: 295-550-3Product number: —EU index number: —Physical hazardsHealth hazardsEnvironmental hazardsNot ClassifiedNot ClassifiedNot Classified24Ethyl 2-naphthyl ether (1629)CAS number: 93-18-5EC number: 202-226-70.0024%Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazardsSkin Irrit. 2 - H315,Eye Irrit. 2 - H319Environmental hazardsAquatic Chronic 2 - H41125Dodecanenitrile (2919)CAS number: 2437-25-4EC number: 219-440-10.00198%Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazardsSkin Irrit. 2 - H315Environmental hazardsAquatic Acute 1 - H400,Aquatic Chronic 1 - H41026( )-Pin-2(3)-ene (2920)CAS number: 7785-70-8EC number: 232-087-80.00048%EU index number: —6/21Product number: —

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidPhysical hazardsFlam. Liq. 3 - H226Health hazardsSkin Irrit. 2 - H315,Skin Sens. 1 - H317,Asp. Tox. 1 - H304Environmental hazardsAquatic Acute 1 - H400,Aquatic Chronic 1 - H41027Tridec-2-enenitrile (1630)CAS number: 22629-49-8EC number: 245-142-60.00048%Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazardsNot ClassifiedEnvironmental hazardsAquatic Acute 1 - H400,Aquatic Chronic 1 - H41028Caryophyllene (2921)CAS number: 87-44-5EC number: 201-746-10.00012%Product number: —EU index number: —Physical hazardsNot ClassifiedHealth hazardsAsp. Tox. 1 - H304Environmental hazardsNot Classified29Limonene (1003)CAS number: 138-86-3EC number: 205-341-00.00006%Product number: VIEU index number: 601-029-00-7Physical hazardsFlam. Liq. 3 - H226Health hazardsSkin Irrit. 2 - H315,Skin Sens. 1 - H317Environmental hazardsAquatic Acute 1 - H400,Aquatic Chronic 1 - eneEC number: 204-622-5CAS number: 123-35-3EU index number: —Physical hazardsFlam. Liq. 3 - H226Health hazardsSkin Irrit. 2 - H315,Eye Irrit. 2 - H319,Asp. Tox. 1 - H304Environmental hazardsNot Classified31p-Cymene (285)CAS number: 99-87-6Product number: —0.000024%EC number: 202-796-7EU index number: —Physical hazardsFlam. Liq. 3 - H226Health hazardsAsp. Tox. 1 - H304Environmental hazardsAquatic Chronic 2 - H4117/21Product number: —

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidPhysical2.1 ExplosivesNot Classified2.2 Flammable GasesNot Classified2.3 AerosolsNot Classified2.4 Oxidising GasesNot Classified2.5 Pressurised GasNot Classified2.6 Flammable LiquidsNot Classified2.7 Flammable SolidsNot Classified2.8 Self Reactive Substances and MixturesNot Classified2.9 Pyrophoric LiquidsNot Classified2.10 Pyrophoric SolidsNot Classified2.11 Self Heating Substances and MixturesNot Classified2.12 Substances and Mixtures which in contact with water emit flammable gases Not Classified 2.13 Oxidising LiquidsNot Classified2.14 Oxidising SolidsNot Classified2.15 Organic peroxidesNot Classified2.16 Corrosive to MetalsNot ClassifiedHuman Health3.1.1 Acute Toxicity (Oral)Not ClassifiedCalculated ATEBronopol (INN)12348.178137652.47%8/21

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidAcute Tox. 4Calculated ATESubstance ATE Derivation MethodLD₅₀305.0Methyl salicylate%Acute Tox. 4Calculated ATESubstance ATE Derivation MethodLD₅₀-Bornan-2-one%Acute Tox. 4Calculated ATESubstance ATE Derivation MethodcATPE-Allyl phenoxyacetate%Acute Tox. 4Calculated ATESubstance ATE Derivation MethodcATPE-Thymol%Acute Tox. 4Calculated ATE--Substance ATE Derivation MethodLD₅₀Total of % unknowns0.0Unknowns calculation usedLow3.1.2 Acute Toxicity (Dermal)Not ClassifiedCalculated ATEBronopol (INN)44534.412955472.47%Acute Tox. 4Calculated ATESubstance ATE Derivation MethodcATPE1100.0Allyl phenoxyacetate%Acute Tox. 4Calculated ATESubstance ATE Derivation Method9/21

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidcATPE-Total of % unknowns0.0Unknowns calculation usedLow3.1.3 Acute Toxicity (Inhalation)Not ClassifiedBornan-2-one%Acute Tox. 4ATE (Dust/Mist):--ATE (Gases):ATE (Vapours):----Substance ATE DerivationMethodcATPE3.2 Skin Corrosion/IrritationNot ClassifiedBronopol (INN)2.47%Skin Irrit. 2Skin CorrosionSkin Irrit kin Irrit. 2Skin CorrosionSkin Irrit 2---p-Menth-1-en-8-ol%Skin Irrit. 2Skin CorrosionSkin Irrit 2---3,7-Dimethyloctan-3-ol%Skin Irrit. 2Skin Corrosion--Skin Irrit 2--10/21

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidHexyl salicylate%Skin Irrit. 2Skin CorrosionSkin Irrit 2---Allyl phenoxyacetate%Skin Irrit. 2Skin CorrosionSkin Irrit 2---Thymol%Skin Corr. 1BSkin CorrosionSkin Irrit 2---Pin-2(10)-ene%Skin Irrit. 2Skin CorrosionSkin Irrit 2---Ethyl 2-naphthyl ether%Skin Irrit. 2Skin CorrosionSkin Irrit 2---Dodecanenitrile%Skin Irrit. 2Skin CorrosionSkin Irrit 2---( )-Pin-2(3)-ene%Skin Irrit. 2Skin CorrosionSkin Irrit 2---Limonene%Skin Irrit. 2Skin CorrosionSkin Irrit 2---7-Methyl-3-methyleneocta-1,6-diene11/21

Skin Irrit. 2Skin Corrosion-Skin CorrosionSkin Irrit 2-0Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidSkin Irrit 20.2473.3 Serious Eye Damage/Eye IrritationEye Irrit. 2 - H319Causes serious eye irritation.Bronopol (INN)2.47%Eye Dam. 1Eye Dam 10.82333333Eye Irrit 22.472,4-Dimethylcyclohex-3-ene-1-carbaldehyde%Eye Irrit. 2Eye Dam 1--Eye Irrit 2--Diethyl malonate%Eye Irrit. 2Eye Dam 1--Eye Irrit 2--p-Menth-1-en-8-ol%Eye Irrit. 2Eye Dam 1--Eye Irrit 2--3,7-Dimethyloctan-3-ol%Eye Irrit. 2Eye Dam 1--Eye Irrit 2-%12/21

Hexyl salicylate%Eye Irrit. 2Eye Dam 1Eye Irrit 2---Thymol%Eye Dam. 1Eye Dam 1Eye Irrit 2---α,α,4-Trimethylcyclohexylmethyl acetate%Eye Irrit. 2Eye Dam 1--Eye Irrit 2--Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidDecan-1-ol%Eye Irrit. 2Eye Dam 1Eye Irrit 2---Ethyl 2-naphthyl ether%Eye Irrit. 2Eye Dam 1Eye Irrit 2---7-Methyl-3-methyleneocta-1,6-diene%Eye Irrit. 2Eye Dam 1Eye Irrit 2---Calculation methodAdditiveEye Dam 10.82333333Eye Irrit 22.473.4.1 Respiratory SensitisationNot Classified3.4.2 Skin SensitisationNot e%13/21

Skin Sens. 1Skin Sens--Elicit Sens--α-Hexylcinnamaldehyde%Skin Sens. 1Skin Sens--Elicit Sens--Cineole%Skin Sens. 1Skin Sens--Elicit Sens--Hexyl salicylateSkin Sens. 1Skin Sens-Acid Violet 49Elicit Sens-%Carc. 2Route of Entry (GHSNot specificCarc 1A Carc 1B Carc 2 calculation)-----%14/21

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidAllyl phenoxyacetate%Skin Sens. 1Skin SensElicit Sens---α,α,4-Trimethylcyclohexylmethyl acetate%Skin Sens. 1Skin SensElicit Sens---Pin-2(10)-ene%Skin Sens. 1Skin SensElicit Sens---( )-Pin-2(3)-ene%Skin Sens. 1Skin SensElicit Sens---Limonene%Skin Sens. 1Skin SensElicit Sens---Skin SensElicit Sens003.5 Germ Cell MutagenicityNot Classified3.6 CarcinogenicityNot ClassifiedCarc 1A0Carc 1B0Carc 203.7 Reproductive ToxicityNot Classified15/21

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet Fluid3.7.1 Reproductive Toxicity (Lactation)Not Classified3.8.1 Specific Target Organ Toxicity - Single ExposureNot ClassifiedBornan-2-one%STOT SE 2Route of Entry (GHS calculation)STOT SE 1Not specific--STOT SE 10STOT SE 20STOT SE 2--3.8.2 Specific Target Organ Toxicity - Single Exposure (H335 & H336)Not ClassifiedBronopol (INN)2.47%STOT SE 3STOT SE 3 H335STOT SE 3 H336--0.1235STOT SE 3 H3350.1235STOT SE 3 H33603.9 Specific Target Organ Toxicity - Repeated ExposureNot Classified3.10 Aspiration HazardNot Classifiedα,α,4-Trimethylcyclohexylmethyl acetate%Asp. Tox. 1Asp. Tox 1-Pin-2(10)-ene%Asp. Tox. 1Asp. Tox 1-%16/21

( )-Pin-2(3)-eneAsp. Tox. 1Asp. Tox 1-Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet FluidCaryophyllene%Asp. Tox. 1Asp. Tox 1-7-Methyl-3-methyleneocta-1,6-diene%Asp. Tox. 1Asp. Tox 1-p-Cymene%Asp. Tox. 1Asp. Tox 1-Environmental4.1.1 Hazardous to the Aquatic Environment (Acute)Not ClassifiedBronopol (INN)2.47%Aquatic Acute 1M-FactorAquatic Acute 10.98810Dodecanenitrile%Aquatic Acute 1M-FactorAquatic Acute 1--10( )-Pin-2(3)-ene%Aquatic Acute 1M-FactorAquatic Acute 1--1Tridec-2-enenitrile%Aquatic Acute 1M-FactorAquatic Acute 117/21

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet Fluid10--Limonene%Aquatic Acute 1M-Factor1Aquatic Acute 1--Aquatic Acute 10.9884.1.2 Hazardous to the Aquatic Environment (Chronic)Not Classified2-tert-Butylcyclohexyl acetate%Aquatic Chronic 2DegradabilityM-Factor----Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic c Chronic 4-%Aquatic Chronic 3DegradabilityM-Factor----Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--3a,4,5,6,7,7a-Hexahydro-4,7-methanoinden-6-yl acetateAquatic Chronic 4-%Aquatic Chronic 3DegradabilityM-Factor----Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--Undecan-4-olideAquatic Chronic 4-%Aquatic Chronic 2DegradabilityM-Factor----Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--α-HexylcinnamaldehydeAquatic Chronic 4-%Aquatic Chronic 2DegradabilityM-Factor----Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--Ethyl 2,3-epoxy-3-phenylbutyrateAquatic Chronic 4-%Aquatic Chronic 2DegradabilityM-Factor----Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--Hexyl salicylateAquatic Chronic 4-%Aquatic Chronic 1DegradabilityM-Factor--1Aquatic Chronic 1--18/21Aquatic Chronic 2--Aquatic Chronic 3--Aquatic Chronic 4--

3a,4,5,6,7,7a-Hexahydro-4,7-methano-1H-inden-6-yl propionate%Aquatic Chronic 2DegradabilityM-FactorAquatic Chronic 1------Aquatic Chronic 2--Aquatic Chronic 3--Aquatic Chronic 4--Thymol%Aquatic Chronic 2Degradability--M-Factor--Aquatic Chronic 1--19/21Aquatic Chronic 2--Aquatic Chronic 3--Aquatic Chronic 4--

Product Created: 27/01/2016Jurisdiction: 0Report Created: 28/01/2016New Blue Toilet Fluidα,α,4-Trimethylcyclohexylmethyl acetate%Aquatic Chronic 2DegradabilityM-Factor----Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--Aquatic Chronic 4--Decan-1-ol%Aquatic Chronic 2DegradabilityM-Factor----Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--Aquatic Chronic 4--Ethyl 2-naphthyl ether%Aquatic Chronic 2Degradability--M-Factor--Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--Aquatic Chronic 4--Dodecanenitrile%Aquatic Chronic 1Degradability--M-Factor1Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--Aquatic Chronic 4--( )-Pin-2(3)-ene%Aquatic Chronic 1Degradability--M-Factor1Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--Aquatic Chronic 4--Tridec-2-enenitrile%Aquatic Chronic 1Degradability--M-Factor10Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--Aquatic Chronic 4--Limonene%Aquatic Chronic 1Degradability--M-Factor1Aquatic Chronic 1--Aquatic Chronic 2--Aquatic Chronic 3--Aquatic Chronic 4--p-Cymene%Aquatic Chronic 2Degradability--M-Factor--Aquatic Chronic 1--Aquatic Chronic 10Aquatic Chronic 20Aquatic Chronic 3020/21Aquatic Chronic 2--Aquatic Chronic 3--Aquatic Chronic 4--

Product Created: 27/01/2016Jurisdiction: 0New Blue Toilet FluidAquatic Chronic 405.1 Hazardous to the ozone layerNot Classified21/21Report Created: 28/01/2016

3006 AGMA Toilet Additive 1338 (3006) 19.0% 2914 CERAVON BLUE V10 DC (2914) 0.05% 2922 FORMALDEHYDE REODORANT ALTERNATIVE (2922) 0.6% 3 Water (3) 80.05% Constituent Chemicals 1 Water (3) 80.05% CAS number: 7732-18-5 EC number: 231-791-2 Product number: — EU index number: — Physical hazards Not Classified Health hazards Not Classified Environmental hazards Not Classified 2 Bronopol (INN .

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