In-situ Experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisIn-situ experimentsby Nuclear Forward ScatteringV. Procházka, V. VrbaFinancováno z projektu: IGA PrF 2014017V. Procházka, V. VrbaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisOutline1Introduction2In-situ observation of chemical reactions3In-situ crystallization of amorphous metals4Data analysisV. Vrba, V. ProcházkaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisOutline1Introduction2In-situ observation of chemical reactions3In-situ crystallization of amorphous metals4Data analysisV. Vrba, V. ProcházkaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisPalacky University in Olomouc, Czech Republic(Vrba, Procházka)Slovak Technical University in Bratislava(Miglierini)V. Vrba, V. ProcházkaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisOutline1Introduction2In-situ observation of chemical reactions3In-situ crystallization of amorphous metals4Data analysisV. Vrba, V. ProcházkaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisHigh valence (VI) iron decompositionCleaning of contaminated water and waste waterFind mechanism of the decompositionObservation of possible intermediate state57Fe to 75% enriched powder of K2 FeVI O4sample holder - capillaryT 200 C, 220 C, 235 C and 250 CCharacteristic time of decomposition is tens ofminutesTime NFS spectrum accumulation - 1 min.P01, DESY, HamburgV. Vrba, V. ProcházkaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisResults, isothermal decomposition at 235 Camplitude (a.u.)20 min.V. Vrba, V. Procházka70 min.140 min.18016014012010080604020140 min.104(b)70 min.20 min.103102101100204060In-situ experiments80 100 120 140 160time (ns)amplitude (a.u.)AnalysisBulding physical model(spectral components)Fitting of HyperfineparametersCONUSSannealing time (min)Precursor paramagneticProduct magnetic(a)
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysis1.1W1 WIII0.90.80.70.60.50.40.30.20.104080 120 160 200annealing time (min.)V. Vrba, V. ProcházkaWIIIWIVWV0.10.080.060.040.0204080 120 160 200annealing time (min.)In-situ experimentsamount of component III, IV, Vamount of component I and IIResults,isothermal process, T 235 C
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisOutline1Introduction2In-situ observation of chemical reactions3In-situ crystallization of amorphous metals4Data analysisV. Vrba, V. ProcházkaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisAmorphous metals crystallizationAmorphous metals (metalic glasses), composition Fe90 Zr7 B3Interesting magnetic propertiesIts properties are determined by microstructural orderingPreparation - fast wheel quenching, disorder of melting iffrozenIncreased temperature caused growing of small grains in theamorphous matterV. Vrba, V. ProcházkaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisCrystallizationID18, GrenobleIsothermal heatingNFS data were accumulated during 1 min.Analysis5E3120 min(a)120 min(b)log10 amplitude (a.u.)annealing time (min)1201008040 min6040 min402015 min15 min2E37E23E27E13E17E03E01E0020406080100 120 140 160time (ns)V. Vrba, V. Procházka20406080100 120 140 160time (ns)In-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisResults of NFS experimentshyperfine field (T)Three different areas were identifiedAmorphous, crystal grains and grains interface28crystalline2624interface(a)22relative face0.00153045607590 105 120 135time of annealing (min)V. Vrba, V. ProcházkaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisOutline1Introduction2In-situ observation of chemical reactions3In-situ crystallization of amorphous metals4Data analysisV. Vrba, V. ProcházkaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisSequential fitting procedureCONUSSIn-situ experiments contain around 100interferograms.Neighbors differ only slightly.Fitted parameters of N-th interferogram are inputvalues for N 1-th interferogramSequence of fitting is neededHUBERT - interface software for CONUSSV. Vrba, V. ProcházkaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisHUBERT - interface software for CONUSSInterface software - CONUSS run behindTransform data from .fio (Hamburg) and .mca(Grenoble) format to 3column structureRun CONUSS,Sequential fitting procedureWritten in QtCreatorUsing "gnuplot"as a plotting toolIt is FREE and offerd for anyonee-mail: v.prochazka@upol.cz,willywillow@seznam.czV. Vrba, V. ProcházkaIn-situ experiments
OutlineIntroductionIn-situ observation of chemical reactionsIn-situ crystallization of amorphous metalsData analysisHUBERT - interface software for CONUSSV. Vrba, V. ProcházkaIn-situ experiments
In-situ observation of chemical reactions In-situ crystallization of amorphous metals Data analysis Outline 1 Introduction 2 In-situ observation of chemical reactions 3 In-situ crystallization of amorphous metals 4 Data analysis V
In situ continuous process gas analysis SITRANS SL In situ O2 gas analyzer 2 The field design of the SITRANS SL in-situ gas analyzer consists of a transmitter unit and a detector unit. The light which is not ab-sorbed by the sample is detected in the receiver. The concentra-tion of the gas component is determined from the absorption. SITRANS SL 2 2
College London (UCL) to investigate the potential uses of experiments in understanding consumer behaviour, and to develop a better understanding of the potential benefits of experiments if used in Ofcom's work. 1.2 The potential uses of experiments . Experiments test the actual behaviour of individuals under different conditions. In an
treatment e ects, and propose a novel experimental design in this setting. Our paper adds to both the literature on single-wave and multiple-wave experiments. In the context of single-wave (or two-wave) experiments, existing network experiments include clustered experiments (Eckles et al.,2017;Ugander et al.,2013;Karrer et al.,2021) and satu-
4 Sensor Experiments 4.1 Search & Rescue Experiments Experiments were conducted on February 11, 2005 at the Lakehurst Naval Air Base, NJ as part of the New Jersey Task Force 1 search and rescue train-ing exercise. The purpose of the experiments was to validate the utility of sensor networks for mapping, to characterize the ambient conditions of .
IN SITU The term in situ spectroscopy is well established and widely used in the catalysis literature. First part Etymology Etymologically, the term in situ has no temporal discrimination. Advanced techniques for characterization of heterogeneous catalysts.
11:50 – 12:10 Synchrotron-based in situ mechanical testing of nanocrystalline metals and alloys Patric A. Gruber, Karlsruhe Institute of Technology, Germany 12:10 – 12:30 Ex-situ and in-situ study of the plastic deformation of InSb micropillars under
tube, (2) in-situ and impedance eduction method tests in a grazing flow impedance tube, and (3) in-situ testing in a full scale engine nacelle during ground tests. The first of these tests were essentially risk mitigation steps. Lab tests were intended to provide insight and guidance for accurately measuring the impedance of the liner housed in the
Tank Gauge) API 2350 categorizes storage tanks by the extent to which personnel are in attendance during receiving operations. The overfill prevention methodology is based upon the tank catagory. Category 1 Fully Attended Personnel must always be on site during the receipt of product, must monitor the receipt continuously during the first and last hours, and must verify receipt each hour .
