Energy: The Next Frontier NYS Advanced Energy Research And .

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Energy: The Next FrontierNYS Advanced Energy Researchand Technology CenterDr. Yacov ShamashVice President for Economic Development and Dean, College ofEngineering and Applied Sciences, Stony Brook UniversityGen5 Ceramic Consortium 2006Garden City, Long Island, N.Y.September 7, 2006

The mission of this Center willbe to forge partnerships betweenuniversities, industries, andnational laboratories in order todevelop reliable, economical, andplentiful sources of energy thatwill ensure sustained economicdevelopment of the region withoutimpairing the natural environment.

Objectives Establish a broad based interdisciplinary research program whichintegrates fundamental science, nanotechnology, and engineering to designnext generation advanced energy systems - renewable energy sources,molecularly engineered traditional fuels, cutting edge fuel cell technology.Build full scale demonstration and testing units which will evaluate newtechnologies; solar, biomass, hydrates, and cogeneration with traditional fuels.Design a working “green” power plant that incorporates wireless technologywith fundamental research to evaluate the economic factors of zero emissionspower generation and establish standards for safety and environmental impact.Develop accurate simulation models of the power grid to optimize thedistribution network, provide alternatives in case of local failures, and provideearly warning of sabotage, leaks, or terrorist infringement.Explain energy policy and emerging technologies to the public. this includessponsorship of national and international conferences for experts on energyrelated research, workshops to inform the public of energy issues, outreach toschools through special programs designed for k-12 teachers and their students

AERTC Participating InstitutionsAcademicInstitutionsSCC, NYIT, Hofstra, SUNY-Westbury, SUNY-MMALaboratoriesInvisionIndustriesAnoradEnergy research will be driven by an alliance of universities, laboratories, andcompanies.

Improving the present: continuing education programswith SUNY MaritimeLNG terminal and depot in LouisianaSUNY Maritime trains 98% ofthe ship captains that deliverLNG’s into East Coastterminals.Cadets at SUNY Maritime in basictraining. The Empire State training shipis above.

Ensuring the future: Energy EducationPlatinumNanoparticles: FromHydrogen Storage toCancer Treatment66th Annual STS (2006-2007)FinalistsDaniel Scott KatzErgerie Eugenie, Uniondale High School, Uniondale, New YorkDaniel Katz, HAFTR High School, Cedarhurst New York experiment withfuel cell design during a summer high school research program at StonyBrook University.

AERTCOrganization of the Energy Center OverviewStony Brook UniversityWhoWhatWhyAcademic institutionsNational mentLeveraging existing capabilities and partnerships, the energy center will promoteclean and economical energy through research, application, and outreach efforts.AERTC-Proposal-DM-200608Page 7

Organizational OverviewAdvisory BoardDirectorAdmin. ctTeamSupport nsAssociate Director ofResearch and EngineeringAssociate DirectorEconomic Development andOutreach, EducationSecretaryA director, with the counsel of the advisory board, will oversee the center’s initiatives.Associate directors, one for outreach, education, and economic development andanother for research, technology and engineering, will interface with the fivefocus groupsAERTC-Proposal-DM-200608Page 8

Establishment of AdvisoryCommitteesMergedPanel Final report Natural OverlapsAdviseonBuildingsand tyOutreach

Fundamental Research : SummaryMembers: *Doon Gibbs (BNL) *Fu Pen Chiang (USB) Clare Grey(USB) Emilio Mendez(USB/BNl) Kosta Likharev (USB) Ben Chu (USB) Peter Kahn(USB) Grigory Belenki (USB) Harry Gafney (QC-CUNY) Existing strengths:NanotechnologyDefine distinct focus areasfor fundamental researchwithin AERTC.Biofuels, photovoltaics,portable energy,optimizationconventional fuels,catalysis,cogeneration, processmodeling and simulation.Identify existing majorinstrumentation: BNLNanocenter (CNF),SupercomputerSuggest new facilities:Nanofabrication facility andtechnology testing center.

EngineeringInitiatives SummaryMembers: *Ralph James (BNL) *Serge Luryi (USB) Jon Longtin (USB) Hazem Tawfik(Farmingdale) Steve Eber (Keyspan) Cindy Lee(MSRC) Kalle Levon (Poly) Fritz Henn (BNL) Focus areas for engineeringresearch: EmployNanotechnologies: Bio-fuels and Bio-Inspired Energygeneration systems, hydrogenstorage, portable energy, CO2sequestration, optimization of fossiland coal fuels, catalysis, modelingand remote sensing.Identify major new facilities tobe constructed in the newAERTC building : NewTechnology Testing Facility,Biofuel Reactor Enclosure,Organic Synthesis Laboratory,Nanofab for electronicscomponents and sensors.

Industrial Relations: SummaryMembers: *Satya Sharma (USB) *Mike Furey (BNL) Clive Clayton (USB) Bruce Germano (LIPA) Peter Shkolnikov (USB) Jack Harran (Keyspan) David Winchester (HIA)Address two major challenges: I. Match technology developed in thelaboratory with needs/problems of industry.Need to develop a plan which will make BNLuser facilities i.e. the Center for FunctionalNanomaterials, available to industry.Build prototype testing and development facilityin “real world applications”.Consider expansion to house incubator facility.II. Develop Uniform IP protocols for allmembers,Very difficult task since the IP policies varygreatly between private, state, and federal taxlevy institutions.Issues must be resolved immediately, beforelarge research efforts are initiated and funding israised from these different sources.Must seek the assistance of qualified legal help.

Accredited Educational ProgramsMembers: *Marjane Issapour(Farmingdale) *Gary Halada (USB) Serdar Elgun (Farmingdale) Anthony Palmietti (Maritime) Sam Yahalom (Maritime) John Kincaid (USB) Establish accrediteddegree programs inenergy at the graduateand undergraduate level. Develop teacher training,workforce development,and continuing educationprograms in energy. Design distance learningcurriculum.

Community Outreach:SummaryMembers: *Pat Malone (USB)*Jack Kramer (Keyspan)*Melanie Krieger (POB School)Sam Yahalom (Maritime)Dave Ferguson (USB)Miriam Dietsch (Farmingdale)Yelleshpur Dathatri(Farmingdale)Ken White (BNL) David Manning (Keyspan)Challenge: Identify the Audience andPlan to Meet their Needs andinterestsFuture Generations: Sustain Develop enrichmentprograms for introducingenergy into the K-12curriculum.¾ “Intel” like sciencecompetitions in energy.¾ Teacher research andtraining courses.General Public: Public forums :museums,libraries, senior centers,NGO. Web resources. Writing and disseminatingliterature.Politicians: Provide advice on “hotbutton” topics. Assist in drafting policty Sponsor workshops.

Recommendations of the advisorycommittee: The building should be open, airy, and have wide public access areas whichencourage interdisciplinary interactions between scientists. The lobby should accommodate a public information areas, possible a smallenergy museum and showcase area. Research space should reflect the types of laboratory installations that willmeet the needs of the research focus groups of the center.¾Organic synthesis¾Bio-fuels greenhouse and Type 2 Micro-organism handling facility¾Nanofabrication¾Modular Systems Indoor/outdoor Large Testing Bay¾Environment/ Nanotechnology cross cutting themes Since new research directions are emerging, the space must be versatile inorder to accommodate these changes.

Technology BasedResearch & DevelopmentSite Promotion of InteractionAmongst like MindedScienceAERTC Foster collaboration viashared facilities andamenities AERTC; 50 permanent,and 50 visitingresearchers & staff

Mission: Encourage Collaboration and Interaction with PrivateDevelopment Separate Labs from OfficesFlexible Labs forOutside UsersBio-handlingLabCombustionHigh BayAreaMicro-fabLab

First Floor – Lobby/Entry

Front lawn and Lobby: Museum and exhibit areas.Platinum Standard Building Limitedparking spaces Solar power co-generation Waste water storage Exposure and vegetation to conserve energy

Identification of nine research targets inenergy-related science and technology inwhich nanoscience is expected to havethe greatest impact: hydrogen production Highly selective catalysts energy efficientmanufacturing Efficient and Inexpensive harvesting of solarenergy Solid-state lighting for lower power consumption Super-strong, non-flamable light-weightmaterials Reversible hydrogen storage materials operatingat ambient temperatures Power transmission lines capable of 1 gigawatttransmission Low-cost fuel cells, batteries, thermoelectrics,and ultra-capacitors. Energy Harvesting based on the efficient andselective mechanisms of biology .

Selected Current Energy Research Projects Micro/Nano Mechanics Studies of SandwichFoam CompositesHydrogen Storage and Quantum LevelCalculationsLighting TechnologiesIn-Situ Monitoring of Gases and PollutantsElectric Load ForecastingMethane hydrate formationPhotovoltaic Cells for Electric PowerGenerationCombustion ProcessLaser Fusion and Turbulent MixingNanotechnology and Chemical SensingAlkaline Batteries for Primary BatteriesLithium Batteries for High-PowerApplicationsSolid Oxide Fuel Cells: Studies of IonicConductivityThermal Spray Center for Fuel Cells andEnginesEnvironmental Nanotechnologies for CleanEnergy Applications Water-Air Quality Sensing Project (WASP)Fuel CellsFuel Injection into the Plasma Reactor (ITER)Thermosetting Polymers as Lighter andTougher MaterialsInternal Combustion EngineThin-Film Photovoltaic Reliability and LifetimeAssessmentExtremely Low-Power HybridSilicon/Nanoelectronic CircuitsOxide Nanomaterials for Energy ApplicationsMeasurement of Carrier RecombinationParameters in III-V Compounds forPhotovoltaic Cell Design OptimizationInternal Combustion EngineBio-inspired Smart Green BuildingNanofibrous Membranes for EnergyApplicationsHarvesting Wave and Tidal EnergySurface Metrology for PV WafersWafering and Manufacturing of PhotovoltaicSolar and Thermal PV Cells

Methane Hydrate: A clean alternative fuelCH4Water cageHydrate formed:800 psi, 6oCMethane hydrate crystalLocation of Hydrate depositsAdvantages:around the globe. 20,000 trillion cubic meters of methane stored in the underwater deposits. Quantity is larger than all of the current fuel sources !! Hydrates uniformly distributed geographically, minimize political tensions.Higher qT. Koga, M. Rafailovich (USB), S. Satija (NIST), J. Jerome (SCC), D. Mahajan (BNL)High pressure cellNeutronsNG7, NISTThe challenge: Stable at low Temp (4 C) and high P ( 800 PSI) Must be mined from under the ocean floor . Very hard crystals. Known to foul mining equipment.The solution: Neutron scattering: High precision phase diagrams Molecular surfactants control nucleation Simulate underwater conditions, provide total control.Source:GasHydye Center

Methane Hydrates- Sediments CharacterizationPure Methane hydrate (without host sediment)sI3-D CMT Data at NSLSBrookhaven ScienceAssociatesU S Department of Energy

Polymers for EnergyPolymers are an enablingtechnology implicated indiverse applications. Proton Exchange Membrane Fuel Cell:Current is produced when charged Nafion polymericmembranes allow diffusion of H ions to the cathode.MRSEC researchers developed new thiolfunctionalized Pt or Pd nanoparticles films whichincreased power production by more than 30%.MIT Carbon-polymer nanocomposites: MRSECresearchers have demonstrated that carbonnanotubes can be electrospun into nanofibers whichare ultra strong and lightweight , conducting andfireproof. Millions can be twisted together to produceC NH CH Clow loss cables for high current applications.nCH3OH2COOCH3 Supercritical carbon dioxide processing: MRSECresearch has found new regime in supercritical CO2phase diagram where it becomes a universalsolvent. Potential for green, low energy processingand cleansing of LNG transmission networks.

-thiol 1:1Au-thiol 2:1Au-thiol 3:1Control0.00.10.2I (A)0.30.40.5P (mW)P olPd-thiol 2:1 Au-thiol 1:1

ChuEnergy Conservation & High-Efficiency Ultra-Filtration Hsiao-YoonEx: Wastewater Generation in Navy Ship300-man ship: 16,000 gal/day 66 ton/dayEnergy saved by a factor of 20EX: single stage RO plant with Diesel Gen-set1-lb water purification – 56 BTU (British Thermal Unit)- Black water (sewage) : 6,000 GPD- Gray water (kitchen, showers, laundry) : 4,000 GPDWith high flux thin film composite membrane- Bilge water (bilge) : 6,000 GPD20-lb water can be purified with the same power80% reduction in power for membraneprocessing method vs. other methodsNew approach for high flux membrane 20 times higher flux thanconventional membranes

Plastics RecyclingPlastic recycle industryMelt MixedClayPS/PMMPETE/CC typePSPS/PMMA/C20A PS/PMMA PS/PMMA/PET/C20A/C6A PS/PMMA/PETClayplatelet5Eh 1/4)α (,4(γ γ )PMMAA type

Conventional Energy Project: Smart Grid Critical first step in power conservation is tomaximize the efficiency of the power distributionsystem SBU, BNL , Blue Gene consortium and SUNYMaritime are applying their high levelcomputational techniques to evaluate powerdistribution networks, and to design “smartgrids” capable of making decisions toremediate local failures in nodes and tooptimize distribution when cogeneration frommultiple sources is activated.

Super-tough materials using biomimetic principles(1)(2)MD simulations of failure in polymernano-compositesPolymer nano-composites show similarbehavior to naturally occuring materials(3)(4)Super-toughening occurs only above Tg-- effect of fillers related to filler mobility

Improving processability and wettability of materials(1)(2)QuickTime and aTIFF (LZW) decompressorare needed to see this picture.Reduce energy cost of processing -polymer blends under shearRheology of polymer nanocomposites -percolation & flow(3)(4)3025250020001500Z A 100050000xis20510101520XAxisYAxis1552530 0Stability of thin films -- lubricationapplicationsEmulsions and surfactants in shear flows -improving mixing

How do they work?Source: http://www.ceficefra.org/frames/f how fr work.html? how fr work.html Polymers are decomposed by pyrolosis andemit hot flamable gases. These gases contain H and OH radicals,which react with oxygen in the air to “burn” toCO2, emitting heat.

Flame retardant and Self Extinguishing MaterialsClay plateletsClay9secEngineered NanocompositePolymers that are tough,conduct , and self-extinguish!(UL94-V5)

Photovoltaics: TiO2 particlesThe Enviroment: Social Responsibility Large particlesare Talc. Smaller ones( 10nm) areTiO2 particles. Titaniumdioxide is usedin mostsunscreens tohelp prevent UVradiation burns. Zinc is alsoused insunscreens asa UV blockingagent.

TiO2(with talc): microgram/ml0.10.30.5

Osteoblasts cultured on EVA with clay and Fe2O3BEVA Clay/NO magnetsEVA Clay/magnetsEVA Clay Fe2O3/magnetsTissue formation and cell orientation in externalfield.

A partnership betweenBasic Energy Sciences and the Center for Functional MaterialsChallenge: Meet Department of Energy Mandate to develop hydrogen batteries andfuel cells for powering cars, homes, and business by 2015.Conditions: Produce materials that are inexpensive, safe to handle and dispose,and can be mass produced, which have high reactivity and capacity to storehydrogen. Nanostructured catalysts: Nanoparticle Ru scaffold for Ptatomic Clusters. Pt atoms have the high catalytic efficiency,while Ru keeps the manufacturing costs low. Pt catalystsremove CO emissions for clean and efficient burning ofconventional fuels. LiAlH4 Lithium aluminum hydrides reversibly decompose toform nano-platelets, 100nm thick. New type of electrodes for Libatteries with extremely high efficiency for hydrogen storageand power generation.

Biofuels Combustion at BNLFocus on Stationary ApplicationsCombustion studies – boiler and turbinesField TrialsSupport for Codes and StandardsPropertiesStorage and Thermal StabilityBurner DevelopmentBlend SensorMicroCHP Engine DevelopmentUltra-high efficiency biofuel boiler

RFP 50K/yr to fund joint collaborative research Areas related to energy Seed grant for future funding

Conclusions Please join us in the ribbon cutting ceremonytomorrow for a new center for Advanced EnergyResearch and Technology. The center ispartnership between academic institutions, nationallaboratories, and industry. The mission of the center is to combinenanotechnology and engineering in order to (a)pursue cutting edge research on new and traditionalenergy sources, (b) establish demonstration sitesto test and evaluate new technologies, and (c)increase public awareness of energy issues andpolicy through outreach and education programs

SCC, NYIT, Hofstra, SUNY-Westbury, SUNY-MMA. Improving the present: continuing education programs with SUNY Maritime LNG terminal and depot in Louisiana Cadets at SUNY Maritime in basic training. The Empire State training ship . Micro-fab. Lab

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