(G5 Epoxy Adhesive)
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วันที่ประกาศใช้ 18/9/13ข้ ��์ส่ วนประกอบทีส่ าคัญสั ญลักษณ์ความเป็ นอันตรายน้ ำยำเจำะเสี ยบเหล็ก (G5 Epoxy Adhesive)Bisphenol A Epoxy Resin, Amine Blendอันตรายจากการสั มผัสในปริมาณทีม่ าก ��ำ ตำบอดล้ำงด้วยน้ ำอย่ำงน้อย 15 �ำยเคืองผิวหนัง ทำให้เกิดผืน่ แดงล้ำงด้วยน้ ำปริ มำณมำกๆ อย่ำงน้อย 15 �ดเสื้ �เปรอะเปื้ อนออกทำงกำรหำยใจ �เดินหำยใจ ��พออำกำรไอ �ย้ำยไปยังบริ เวณที่มีอำกำศบริ ��ำหำร ริ � �ฝี ปำกไหม้ อำจเสี ยชีวติ �มิระหว่ำง 4.4 C – 26.7 ��อน, เปลวไฟ และประกำยไฟ1. �ำยไฟบริ �รั่วไหล2. ใช้วสั ดุดูดซับ เช่น ทรำย ผ้ำ3. �สะอำด4. �ดเร็ ว5. ��ถงั �ีแห้ง คำร์บอนไดออกไซด์ (CO2) หรื อโฟม และใช้น้ �ฉีดเป็ นฝอย (ห้ำมใช้น้ ำฉี ดโดยตรง)อุปกรณ์ ป้องกันอันตรายส่ วนบุคคล (PPE)
MATERIAL SAFETY DATA SHEETวันที่ประกาศใช้ 18/9/131. Product and Company IdentificationMaterial nameG5 Epoxy AdhesiveVersion #01Revision date06-09-2010CAS #MixtureProduct CodeG5Product useConcrete anchoring adhesive.Manufacturer/SupplierITW Red Head2171 Executive Drive, Suite 100Addison, IL 60101 USTelephone Number: (630) 350-0370Contact Person: Andrew RourkeEmergencyCHEMTREC: (800) 424-93002. Hazards IdentificationPhysical stateSolid.AppearancePaste.Emergency overviewDANGER!Causes skin and eye burns. Causes severe respiratory tract irritation. Harmful if inhaled,absorbed through skin, or swallowed. May cause sensitization by skin contact. Prolongedexposure may cause chronic effects.OSHA regulatory statusThis product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).Potential health effectsRoutes of exposureInhalation. Ingestion. Skin contact. Eye contact.EyesCauses eye burns. Risk of corneal damage. Contact may cause irritation, redness, tearing,blurred vision and/or burns.SkinCauses skin burns. Harmful if absorbed through the skin. May cause sensitization by skin contact.Contact may cause irritation, redness and/or drying.InhalationHarmful if inhaled. Causes severe respiratory tract irritation. Vapors irritate the respiratory system,and may cause coughing and difficulties in breathing.IngestionHarmful if swallowed. Ingestion may produce burns to the lips, oral cavity, upper airway,esophagus and possibly the digestive tract.Target organsEyes. Skin. Respiratory system. Lungs.Chronic effectsCan cause kidney, liver, lung and central nervous system damage. Can cause adversereproductive effects - such as birth defects, miscarriages, or infertility. Contains a component thatis listed as an IARC 1 (Known Human Carcinogen), a NTP Known Carcinogen and an ACGIH A2(Suspected Human Carcinogen). Overexposure can cause lung damage - pulmonary toxin.Potential environmental effectsThe product contains a substance which is toxic to aquatic organisms and which may causelong-term adverse effects in the aquatic environment.3. Composition / Information on IngredientsComponentsBisphenol A Epoxy Resin (Part A)Amine Blend (Part B)CAS #Percent25068-38-650 - 99Trade SecretTrade Secret4. First Aid MeasuresFirst aid proceduresEye contactSkin contactG5 Epoxy Adhesive4424 Version #: 01Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention immediately.Immediately flush with plenty of water for at least 15 minutes while removing contaminatedclothing and shoes. Get medical attention immediately. Wash clothing separately before reuse.Destroy or thoroughly clean contaminated shoes.CPH MSDS NARevision date: 06-09-2010Print date: 06-09-20101/7
Move to fresh air. If breathing is difficult, give oxygen. Get medical ��้ 18/9/13InhalationIngestionRinse mouth thoroughly. Do not induce vomiting. If vomiting occurs, keep head low so thatstomach content does not get into the lungs. Never give anything by mouth to a victim who isunconscious or is having convulsions. Get medical attention immediately.Notes to physicianKeep victim under observation. In case of shortness of breath, give oxygen. Symptoms may bedelayed.General adviceTake off contaminated clothing and shoes immediately. Ensure that medical personnel are awareof the material(s) involved, and take precautions to protect themselves. Show this safety datasheet to the doctor in attendance. Wash contaminated clothing before re-use.5. Fire Fighting MeasuresFlammable propertiesNot flammable by OSHA criteria. Material may burn but not ignite readily.Extinguishing mediaSuitable extinguishingmediaWater. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Protection of firefightersProtective equipment andprecautions for firefightersFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire areaif you can do so without risk. Cool containers exposed to flames with water until well after the fireis out. Water runoff can cause environmental damage.Special protective equipmentfor fire-fightersWear full protective clothing, including helmet, self-contained positive pressure or pressuredemand breathing apparatus, protective clothing and face mask.Specific methodsIn the event of fire and/or explosion do not breathe fumes.Hazardous combustionproductsCarbon monoxide. Carbon Dioxide. Nitrogen oxides (NOx). Hydrogen chloride. Silicon oxides.6. Accidental Release MeasuresPersonal precautionsKeep unnecessary personnel away. Local authorities should be advised if significant spillagescannot be contained. Keep upwind. Keep out of low areas. Ventilate closed spaces beforeentering them. Do not touch damaged containers or spilled material unless wearing appropriateprotective clothing. See Section 8 of the MSDS for Personal Protective Equipment.Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not contaminate water.Methods for containmentStop leak if you can do so without risk. Dike the spilled material, where this is possible. Collectspillage. Prevent entry into waterways, sewers, basements or confined areas.Methods for cleaning upSmall Spills: Absorb spill with vermiculite or other inert material. Clean surface thoroughly toremove residual contamination. This material and its container must be disposed of as hazardouswaste. Should not be released into the environment.Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the productand place into a container for later disposal. Prevent product from entering drains. Do not allowmaterial to contaminate ground water system.Other informationClean up in accordance with all applicable regulations.7. Handling and StorageHandlingWear personal protective equipment. Avoid breathing vapor. Do not get in eyes, on skin, onclothing. Avoid prolonged exposure. Do not taste or swallow. Use only with adequate ventilation.Wash thoroughly after handling. When using, do not eat, drink or smoke. Avoid release to theenvironment.StorageKeep container tightly closed. For maximum shelf life, store between 4.4 C (40 F) to 26.7 C(80 F). Do not store above 43.3 C (110 F). Keep away from food, drink and animal feedingstuffs.Keep out of the reach of children.8. Exposure Controls / Personal ProtectionOccupational exposure limitsACGIHComponentsAmine Blend (Part B) (Trade Secret)G5 Epoxy Adhesive4424 Version #: 01TypeValueFormCeilingTWA0.1 mg/m30.025 mg/m35 ppmAmine Blend Ingredient 2Amine Blend Ingredient 3Amine Blend Ingredient 1CPH MSDS NARevision date: 06-09-2010Print date: 06-09-20102/7
U.S. - OSHAComponentsAmine Blend (Part B) (Trade Secret)ValueFormPELTWA5 ppm0.42 mg/m3Amine Blend Ingredient 1Amine Blend Ingredient 3(total dust)Amine Blend Ingredient 3(respirable)0.14 mg/m3Canada - AlbertaComponentsAmine Blend (Part B) (Trade Secret)Canada - British ColumbiaComponentsAmine Blend (Part B) (Trade Secret)Canada - OntarioComponentsAmine Blend (Part B) (Trade Secret)Canada - QuebecComponentsAmine Blend (Part B) (Trade Secret)MexicoComponentsAmine Blend (Part B) (Trade Secret)Engineering controlsPersonal protective equipmentEye / face ��้ 18/9/13TypeTypeValueFormCeilingTWA0.1 mg/m30.025 mg/m35 ppmAmine Blend Ingredient 2Amine Blend Ingredient 3Amine Blend Ingredient 1TypeValueFormCeilingTWA0.1 mg/m30.025 mg/m35 ppmAmine Blend Ingredient 2Amine Blend Ingredient 3Amine Blend Ingredient 1TypeValueFormCeilingTWA0.1 mg/m30.1 mg/m35 ppmAmine Blend Ingredient 2Amine Blend Ingredient 3Amine Blend Ingredient 1TypeValueFormCeilingSTEL0.1 mg/m30.1 mg/m35 ppmAmine Blend Ingredient 2Amine Blend Ingredient 3Amine Blend Ingredient 1TypeValueFormCeilingSTELTWA0.1 mg/m310 ppm5 ppm0.1 mg/m3Amine Blend Ingredient 2Amine Blend Ingredient 1Amine Blend Ingredient 1Amine Blend Ingredient 3Use process enclosures, local exhaust ventilation, or other engineering controls to controlairborne levels below recommended exposure limits.Wear safety glasses with side shields (or goggles) and a face shield.Skin protectionWear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure.Contact glove manufacturer for specific information.Respiratory protectionIn case of insufficient ventilation, wear suitable respiratory equipment. If permissible levels areexceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator.General hygieneconsiderationsAvoid contact with eyes. Avoid contact with skin. Provide eyewash station and safety shower.When using, do not eat, drink or smoke. Handle in accordance with good industrial hygiene andsafety practice.9. Physical & Chemical acteristic.Odor thresholdNot available.Physical stateSolid.FormPaste.pHNot available.Melting pointNot available.Freezing pointNot available.Boiling point 212 F ( 100 C) Part B 400 F ( 204.4 C) Part AG5 Epoxy Adhesive4424 Version #: 01CPH MSDS NARevision date: 06-09-2010Print date: 06-09-20103/7
Flash point 212 F ( 100 C)Evaporation rateNot available.FlammabilityNot ��้ 18/9/13Flammability limits in air, upper, Not available.% by volumeFlammability limits in air, lower, Not available.% by volumeVapor pressureNot available.Vapor densityNot available.Specific gravityNot available.Solubility (water)None.Partition coefficient(n-octanol/water)Not available.Auto-ignition temperatureNot available.Decomposition temperatureNot available.Density1.2 g/cm3 Part A1.7 g/cm3 Part B10. Chemical Stability & Reactivity InformationChemical stabilityStable at normal conditions.Conditions to avoidElevated temperatures.Incompatible materialsStrong oxidizing agents. Strong acids.Hazardous decompositionproductsCarbon oxides. Nitrogen oxides (NOx). Silicon oxides. Hydrogen chloride.Possibility of hazardousreactionsWill not occur.11. Toxicological InformationLocal effectsCauses skin and eye burns. Causes severe respiratory tract irritation. Harmful if inhaled,absorbed through skin, or swallowed. May cause sensitization by skin contact.SensitizationMay cause an allergic skin reaction.Chronic effectsCan cause kidney, liver, lung and central nervous system damage. Overexposure can cause lungdamage.CarcinogenicityContains a component that is listed as an IARC 1 (Known Human Carcinogen), a NTP KnownCarcinogen and an ACGIH A2 (Suspected Human Carcinogen).MutagenicityThis product is not expected to cause mutagenic or genotoxic effects.Neurological effectsMay cause central nervous system disorder (e.g., narcosis involving a loss of coordination,weakness, fatigue) and/or damage.Reproductive effectsCan cause adverse reproductive effects - such as birth defects, miscarriages, or infertility.TeratogenicityComponents in this product have been shown to cause teratogenic effects in laboratory animals.Further informationSymptoms may be delayed.12. Ecological InformationEcotoxicityContains a substance which causes risk of hazardous effects to the environment.Environmental effectsThe product contains a substance which is toxic to aquatic organisms and which may causelong-term adverse effects in the aquatic environment. An environmental hazard cannot beexcluded in the event of unprofessional handling or disposal.Persistence and degradabilityNot available.Bioaccumulation /AccumulationNo data available.Partition coefficient(n-octanol/water)Not available.Mobility in environmentalmediaNo data available.G5 Epoxy Adhesive4424 Version #: 01CPH MSDS NARevision date: 06-09-2010Print date: 06-09-20104/7
วันที่ประกาศใช้ 18/9/1313. Disposal ConsiderationsDisposal instructionsDispose of contents/container in accordance with local/regional/national/international regulations.Incinerate the material under controlled conditions in an approved incinerator. Do not incineratesealed containers. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer.14. Transport InformationProduct Specific Note:This product meets the limited quantities exception requirements for the below listedtransportation agencies. Under DOT and TDG regulations, this product may be reclassified as aConsumer Commodity (ORM-D). Please see the specific regulations for the shipping andpackaging requirements.DOTBasic shipping requirements:Consumer commodityProper shipping nameORM-DHazard classNoneSubsidiary hazard classNoneLabels requiredAdditional information:156, 306Packaging exceptions156, 306Packaging non bulkNonePackaging bulkIATABasic shipping requirements:2735UN numberAmines, liquid, corrosive, n.o.s. (Amine Blend (Part B))Proper shipping name8Hazard classIIIPacking groupIMDGBasic shipping requirements:2735UN numberAMINES, LIQUID, CORROSIVE, N.O.S. (Amine Blend (Part B))Proper shipping name8Hazard classIIIPacking groupF-A, S-BEmS No.TDGBasic shipping requirements:Consumer commodityProper shipping nameORM-DHazard classNoneSubsidiary hazard classNoneLabels requiredAdditional information:156, 306Packaging exceptions156, 306Packaging non bulkNonePackaging bulkIATAG5 Epoxy Adhesive4424 Version #: 01IMDGCPH MSDS NARevision date: 06-09-2010Print date: 06-09-20105/7
วันที่ประกาศใช้ 18/9/1315. Regulatory InformationUS federal regulationsThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.CERCLA (Superfund) reportable quantity (lbs)Amine Blend (Part B) 1000Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categoriesImmediate Hazard - YesDelayed Hazard - YesFire Hazard - NoPressure Hazard - NoReactivity Hazard - NoSection 302 extremelyhazardous substanceNoSection 311 hazardouschemicalNoDrug Enforcement Agency(DEA)Not controlledCanadian regulationsThis product has been classified in accordance with the hazard criteria of the CPR and the MSDScontains all the information required by the CPR.WHMIS statusControlledWHMIS classificationD2A - Other Toxic Effects-VERY TOXICD2B - Other Toxic Effects-TOXICE - CorrosiveWHMIS labelingInventory statusCountry(s) or regionAustraliaInventory nameAustralian Inventory of Chemical Substances (AICS)On inventory (yes/no)*YesCanadaDomestic Substances List (DSL)CanadaNon-Domestic Substances List (NDSL)ChinaInventory of Existing Chemical Substances in China (IECSC)YesEuropeEuropean Inventory of Existing Commercial ChemicalSubstances (EINECS)YesEuropeEuropean List of Notified Chemical Substances (ELINCS)JapanInventory of Existing and New Chemical Substances (ENCS)YesKoreaExisting Chemicals List (ECL)YesNew ZealandNew Zealand InventoryYesPhilippinesPhilippine Inventory of Chemicals and Chemical Substances(PICCS)YesUnited States & Puerto RicoToxic Substances Control Act (TSCA) InventoryYesYesNoNo*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)State regulationsWARNING: This product contains chemicals known to the State of California to cause cancer.16. Other InformationFurther informationHMISÆ is a registered trade and service mark of the NPCA.HMISÆ ratingsHealth: 3*Flammability: 1Physical hazard: 0NFPA ratingsHealth: 3Flammability: 1Instability: 0DisclaimerThe information in the sheet was written based on the best knowledge and experience currentlyavailable.G5 Epoxy Adhesive4424 Version #: 01CPH MSDS NARevision date: 06-09-2010Print date: 06-09-20106/7
Issue dateG5 Epoxy Adhesive4424 Version #: �ช้ 18/9/13CPH MSDS NARevision date: 06-09-2010Print date: 06-09-20107/7
Material name G5 Epoxy Adhesive Version # 01. Revision date. 06-09-2010. CAS # Mixture. Product Code. G5. Product use. Concrete anchoring adhesive. Manufacturer/Supplier. ITW Red Head 2171 Executive Drive, Suite 100 Addison, IL 60101 US Telephone Number: (630) 350-0370 Contact Person: Andrew Rourke. Emergency. CHEMTREC: (800) 424-9300. 2 .
Contents 3 Epoxy resins, water-reducible 4 Epoxy hardeners, water-reducible 5 Epoxy resins solid and solutions 6 Epoxy resins liquid and reactive diluted 7 Reactive diluents for epoxy resins 7 Epoxy hardeners, polyamines 8 Epoxy hardeners, adducts 9 Epoxy hardeners, mannich bases 10 Epoxy hardeners, polyamidoamines 11 Survey of the qu
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mechanical properties of epoxy resins, physical and chemical properties of epoxy resins, epoxy resin adhesives, epoxy resin coatings, epoxy coating give into water, electrical and electronic applications, analysis of epoxides and epoxy resins and the toxicology of epoxy resins. It will be a standard reference book for professionals and .
plication. The u se of epoxy- silicone monomers in encapsulation is very attractive because epoxy -silicone offers the benefits of both silicone and epoxy resins. The siloxane bond is stable under heat and ultraviolet (UV) light , while epoxy resin has a high adhesive strength [14]. Epoxy- silicone hybrid materials based on sol-gel -derived
3. drill and install injection entry and venting ports with sikadur 31 or sikadur 33 adhesive. 4. seal crack with sikadur 31 high-modulus epoxy gel adhesive or sikadur 33 high-modulus epoxy paste adhesive. allow to cure. 5. fill crack injecting sikadur 35 high-modulus, low viscosity, epoxy adhesive. maximum
Casting epoxy cures at a slower rate than table top epoxy, typically taking between 24-36 hours. Since curing takes so long with this type of epoxy, users have a long working time. However, it is important to ensure no dust or debris falls into the resin before it has fully set. The typical mix ratio of a casting epoxy is 2:1 epoxy-to-hardener .
Epoxy resin products were commercialised in 1946 and since then, modern adhesive technology has led to the . development of many types of epoxy-based systems. Since commercial introduction, epoxy resins are being used for structural applications including laminates, moulding, casting and bonding. Epoxy resins can be
The epoxy-based adhesive (Epcon G5) is manufactured by ITW Ramset/Red Head. The adhesive is a two component structural epoxy, consisting of an epoxy resin and an amine-based hardener. The manufacturer reported properties of Epcon G5 are: tensile strength of 30 MPa, compressive strength of 71 MPa, and bond strength to concrete of 23 MPa. (a) (b)
