CRC (NZ) 9060, 9061, 9062 Repo Xtra Cut

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CRC (NZ) 9060, 9061, 9062 Repo Xtra CutCRC Industries (CRC Industries New Zealand)Chemwatch Hazard Alert Code: 4Chemwatch: 4552-25Issue Date: 12/09/2017Version No: 5.1.1.1Print Date: 19/06/2018Safety Data Sheet according to HSNO RegulationsS.GHS.NZL.ENSECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKINGProduct IdentifierProduct nameCRC (NZ) 9060, 9061, 9062 Repo Xtra CutSynonymsNot AvailableOther means ofidentificationNot AvailableRelevant identified uses of the substance or mixture and uses advised againstRelevant identified usesA water-in-oil emulsion applied by cloth for the restoration of existing automotive finishes.Details of the supplier of the safety data sheetRegistered companynameAddressTelephoneFaxWebsiteEmailCRC Industries (CRC Industries New Zealand)10 Highbrook Drive East Tamaki Auckland New Zealand 64 9 272 2700 64 9 274 cy telephone numberAssociation /OrganisationEmergency telephonenumbersOther emergencytelephone numbersNot AvailableNZ Poisons Centre 0800 POISON (0800 764 766)111 (NZ Emergency Services)SECTION 2 HAZARDS IDENTIFICATIONClassification of the substance or mixtureClassification[1]Legend:Determined byChemwatch usingGHS/HSNO criteriaFlammable Liquid Category 3, Acute Toxicity (Oral) Category 5, Acute Toxicity (Inhalation) Category 5, SkinCorrosion/Irritation Category 2, Germ cell mutagenicity Category 2, Carcinogenicity Category 1A, Specific target organtoxicity - single exposure Category 3 (narcotic effects), Specific target organ toxicity - repeated exposure Category 2,Aspiration Hazard Category 11. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ; 3. Classification drawn from EC Directive 1272/2008- Annex VI3.1C, 6.1E (aspiration), 6.1E (inhalation), 6.1E (oral), 6.3A, 6.6B, 6.7A, 6.9 (narcotic), 6.9B (inhalation)Label elementsHazard pictogram(s)SIGNAL WORDDANGERHazard statement(s)H226Flammable liquid and vapour.

H303May be harmful if swallowed.H333May be harmful if inhaled.H315Causes skin irritation.H341Suspected of causing genetic defects.H350May cause cancer.H336May cause drowsiness or dizziness.H373May cause damage to organs through prolonged or repeated exposure.H304May be fatal if swallowed and enters airways.Precautionary statement(s) PreventionP201Obtain special instructions before use.P210Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.P260Do not breathe dust/fume/gas/mist/vapours/spray.P271Use only outdoors or in a well-ventilated area.Precautionary statement(s) ResponseP301 P310IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician/first aider.P308 P313IF exposed or concerned: Get medical advice/ attention.P331P370 P378Do NOT induce vomiting.In case of fire: Use . to extinguish.Precautionary statement(s) StorageP403 P235P405Store in a well-ventilated place. Keep cool.Store locked up.Precautionary statement(s) DisposalP501Dispose of contents/container in accordance with local regulations.SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTSSubstancesSee section below for composition of MixturesMixturesCAS No%[weight]Name8052-41-3.10-30white spirit1317-95-91-10tripoliNot Available1-10mineral oilNot Available1-10additives7732-18-5 60waterNOTE: Manufacturer has supplied full ingredient information to allow CHEMWATCH assessment.SECTION 4 FIRST AID MEASURESDescription of first aid measuresEye ContactSkin ContactInhalationIf this product comes in contact with the eyes:Wash out immediately with fresh running water.Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids byoccasionally lifting the upper and lower lids.Seek medical attention without delay; if pain persists or recurs seek medical attention.Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.If skin contact occurs:Immediately remove all contaminated clothing, including footwear.Flush skin and hair with running water (and soap if available).Seek medical attention in event of irritation.If fumes or combustion products are inhaled remove from contaminated area.Lay patient down. Keep warm and rested.Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures.Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or

pocket mask as trained. Perform CPR if necessary.Transport to hospital, or doctor.If swallowed do NOT induce vomiting.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airwayand prevent aspiration.Observe the patient carefully.Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.Seek medical advice.Avoid giving milk or oils.Avoid giving alcohol.IngestionIndication of any immediate medical attention and special treatment neededFor acute or short term repeated exposures to petroleum distillates or related hydrocarbons:Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen.Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has been reported;intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete inhaled solvents, so thathyperventilation improves clearance.A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect the presence ofpneumothorax.Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of potential myocardial sensitisation to catecholamines. Inhaledcardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a second choice.Lavage is indicated in patients who require decontamination; ensure use of cuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: MedicalToxicology]Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. Mechanicalmeans should be used if it is considered necessary to evacuate the stomach contents; these include gastric lavage after endotracheal intubation. Ifspontaneous vomiting has occurred after ingestion, the patient should be monitored for difficult breathing, as adverse effects of aspiration into the lungsmay be delayed up to 48 hours.Treat symptomatically.SECTION 5 FIREFIGHTING MEASURESExtinguishing mediaThe product contains a substantial proportion of water, therefore there are no restrictions on the type of extinguishing media which may be used. Choiceof extinguishing media should take into account surrounding areas.Though the material is non-combustible, evaporation of water from the mixture, caused by the heat of nearby fire, may produce floating layers ofcombustible substances.In such an event consider:foam.Special hazards arising from the substrate or mixtureFire IncompatibilityNone known.Advice for firefightersAlert Fire Brigade and tell them location and nature of hazard.Wear breathing apparatus plus protective gloves.Prevent, by any means available, spillage from entering drains or water courses.Use water delivered as a fine spray to control fire and cool adjacent area.Fire FightingFire/Explosion HazardCombustible. Will burn if ignited.Combustion products include:,carbon monoxide (CO),carbon dioxide (CO2),silicon dioxide (SiO2),other pyrolysis products typical of burning organic material.May emit poisonous fumes.SECTION 6 ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency proceduresSee section 8Environmental precautionsSee section 12Methods and material for containment and cleaning up

Minor SpillsClean up all spills immediately.Avoid contact with skin and eyes.Wear impervious gloves and safety goggles.Trowel up/scrape up.Clean up all spills immediately.Avoid breathing vapours and contact with skin and eyes.Control personal contact with the substance, by using protective equipment.Contain and absorb spill with sand, earth, inert material or vermiculite.Major SpillsClear area of personnel and move upwind.Alert Fire Brigade and tell them location and nature of hazard.Wear breathing apparatus plus protective gloves.Prevent, by any means available, spillage from entering drains or water course.Personal Protective Equipment advice is contained in Section 8 of the SDS.SECTION 7 HANDLING AND STORAGEPrecautions for safe handlingSafe handlingOther informationContainers, even those that have been emptied, may contain explosive vapours.Do NOT cut, drill, grind, weld or perform similar operations on or near containers.Electrostatic discharge may be generated during pumping - this may result in fire.Ensure electrical continuity by bonding and grounding (earthing) all equipment.Restrict line velocity during pumping in order to avoid generation of electrostatic discharge ( 1 m/sec until fill pipesubmerged to twice its diameter, then 7 m/sec).Avoid splash filling.Avoid all personal contact, including inhalation.Wear protective clothing when risk of exposure occurs.Use in a well-ventilated area.Prevent concentration in hollows and sumps.Store in original containers.Keep containers securely sealed.Store in a cool, dry, well-ventilated area.Store away from incompatible materials and foodstuff containers.Conditions for safe storage, including any incompatibilitiesSuitable containerStorage incompatibilityMetal can or drumPackaging as recommended by manufacturer.Check all containers are clearly labelled and free from leaks.None knownSECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTIONControl parametersOCCUPATIONAL EXPOSURE LIMITS (OEL)INGREDIENT DATASourceIngredientMaterial nameTWASTELPeakNotesNew Zealand WorkplaceExposure Standards (WES)white spiritWhite spirits(Stoddard solvent)100 ppm / 525mg/m3NotAvailableNotAvailableNot AvailableNew Zealand WorkplaceExposure Standards (WES)tripoliTripoli (see SilicaCrystalline)0.1 mg/m3NotAvailableNotAvailable(r) - The value for respirable dust.New Zealand WorkplaceExposure Standards (WES)mineral oilOil mist, mineral5 mg/m310 mg/m3NotAvailable(om) - Sampled by a method thatdoes not collect vapour.EMERGENCY LIMITSIngredientMaterial nameTEEL-1TEEL-2TEEL-3white spiritStoddard solvent; (Mineral spirits, 85% nonane and 15% dientOriginal IDLHRevised IDLHwhite spirit20000 mg/m3Not Availabletripoli50 mg/m3Not Availablemineral oil2500 mg/m3Not AvailableadditivesNot AvailableNot AvailablewaterNot AvailableNot Available

Exposure controlsAppropriate engineeringcontrolsEngineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactionsto provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker andventilation that strategically "adds" and "removes" air in the work environment.Personal protectionSafety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policydocument, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.Eye and face protectionSkin protectionHands/feet protectionBody protectionSee Hand protection belowWear chemical protective gloves, e.g. PVC.Wear safety footwear or safety gumboots, e.g. RubberNOTE:The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves andother protective equipment, to avoid all possible skin contact.Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.See Other protection belowOveralls.P.V.C. apron.Barrier cream.Other protectionRecommended material(s)Respiratory protectionGLOVE SELECTION INDEXGlove selection is based on a modified presentation of the:"Forsberg Clothing Performance Index".The effect(s) of the following substance(s) are taken into account in thecomputer-generated selection:CRC (NZ) 9060, 9061, 9062 Repo Xtra CutType A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000& 149:2001, ANSI Z88 or national equivalent)Required MinimumProtection d AirRespiratorup to 10 x ESA P1Air-line*-A PAPR-P1-MaterialCPIBUTYLCup to 50 x ESAir-line**A P2A PAPR-P2NATURAL RUBBERCup to 100 x ES-A P3-NEOPRENECAir-line*-PVACAir-line**A PAPR-P3VITONC* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of theglove, a final selection must be based on detailed observation. * Where the glove is to be used on a short term, casual or infrequentbasis, factors such as "feel" or convenience (e.g. disposability), maydictate a choice of gloves which might otherwise be unsuitable followinglong-term or frequent use. A qualified practitioner should be consulted.100 x ES-* - Negative pressure demand ** - Continuous flowA(All classes) Organic vapours, B AUS or B1 Acid gasses, B2 Acidgas or hydrogen cyanide(HCN), B3 Acid gas or hydrogen cyanide(HCN),E Sulfur dioxide(SO2), G Agricultural chemicals, K Ammonia(NH3),Hg Mercury, NO Oxides of nitrogen, MB Methyl bromide, AX Lowboiling point organic compounds(below 65 degC)Cartridge respirators should never be used for emergency ingress or inareas of unknown vapour concentrations or oxygen content. The wearermust be warned to leave the contaminated area immediately on detectingany odours through the respirator. The odour may indicate that the mask isnot functioning properly, that the vapour concentration is too high, or thatthe mask is not properly fitted. Because of these limitations, onlyrestricted use of cartridge respirators is considered appropriate.SECTION 9 PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical propertiesAppearancePhysical stateColoured paste with a mild odour; not miscible with water.Non Slump PasteRelative density (Water 1)OdourNot AvailablePartition coefficientn-octanol / waterOdour thresholdNot AvailableAuto-ignition temperature( C)0.94Not Available250

pH (as supplied)Not AvailableDecompositiontemperatureNot AvailableMelting point / freezingpoint ( C)Not AvailableViscosity (cSt)Not AvailableInitial boiling point andboiling range ( C)100-200Molecular weight (g/mol)Flash point ( C)45 (OC)TasteNot AvailableExplosive propertiesNot AvailableEvaporation rateNot AvailableOxidising propertiesNot Available3.5Surface Tension (dyn/cmor mN/m)Not AvailableLower Explosive Limit(%)1.0Volatile Component(%vol)Not AvailableVapour pressure (kPa)Not AvailableFlammabilityUpper Explosive Limit(%)Flammable.Not ApplicableSolubility in water (g/L)ImmiscibleVapour density (Air 1) 1Gas groupNot AvailablepH as a solution (1%)Not AvailableVOC g/LNot AvailableSECTION 10 STABILITY AND REACTIVITYReactivityChemical stabilitySee section 7Product is considered stable and hazardous polymerisation will not occur.Possibility of hazardousreactionsSee section 7Conditions to avoidSee section 7Incompatible materialsSee section 7Hazardousdecomposition productsSee section 5SECTION 11 TOXICOLOGICAL INFORMATIONInformation on toxicological effectsInhaledInhalation of vapours may cause drowsiness and dizziness. This may be accompanied by sleepiness, reduced alertness,loss of reflexes, lack of co-ordination, and vertigo.Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may bedamaging to the health of the individual.There is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's responseto such irritation can cause further lung damage.Inhaling high concentrations of mixed hydrocarbons can cause narcosis, with nausea, vomiting and lightheadedness. Lowmolecular weight (C2-C12) hydrocarbons can irritate mucous membranes and cause incoordination, giddiness, nausea,vertigo, confusion, headache, appetite loss, drowsiness, tremors and stupor.Central nervous system (CNS) depression may include general discomfort, symptoms of giddiness, headache, dizziness,nausea, anaesthetic effects, slowed reaction time, slurred speech and may progress to unconsciousness. Seriouspoisonings may result in respiratory depression and may be fatal.Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and nausea, central nervousdepression with headache and dizziness, slowing of reflexes, fatigue and inco-ordination.Exposure to white spirit may cause nausea and vertigo.IngestionSwallowing of the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis; serious consequencesmay result. (ICSC13733)Ingestion of petroleum hydrocarbons can irritate the pharynx, oesophagus, stomach and small intestine, and causeswellings and ulcers of the mucous. Symptoms include a burning mouth and throat; larger amounts can cause nausea andvomiting, narcosis, weakness, dizziness, slow and shallow breathing, abdominal swelling, unconsciousness andconvulsions.Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 grammay be fatal or may produce serious damage to the health of the individual.Skin ContactThis material can cause inflammation of the skin on contact in some persons.The material may accentuate any pre-existing dermatitis conditionRepeated exposure may cause skin cracking, flaking or drying following normal handling and use.Open cuts, abraded or irritated skin should not be exposed to this materialAromatic hydrocarbons may produce sensitivity and redness of the skin. They are not likely to be absorbed into the bodythrough the skin but branched species are more likely to.EyeChronicThere is some evidence to suggest that this material can cause eye irritation and damage in some persons.Direct eye contact with petroleum hydrocarbons can be painful, and the corneal epithelium may be temporarily damaged.Aromatic species can cause irritation and excessive tear secretion.Strong evidence exists that this substance may cause irreversible mutations (though not lethal) even following a singleexposure.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-termoccupational exposure.There is limited evidence that, skin contact with this product is more likely to cause a sensitisation reaction in some

persons compared to the general population.On the basis of limited epidemiological or animal data, it has been concluded that prolonged inhalation of the material, in anoccupational setting, may increase the risk of cancer in humans.The absence of clinical silicosis among workers exposed to tripoli may be due to the lack of potential activity of tripoli.The dielectric properties of tripoli ensure rapid agglomeration and settling of dust particles, thus reducing the opportunityfor exposure. Animal studies have shown tripoli may cause p

CRC (NZ) 9060, 9061, 9062 Repo Xtra Cut Chemwatch: 4552-25 Version No: 5.1.1.1 Safety Data Sheet according to HSNO Regulations Issue Date: 12/09/2017 Print Date: 19/06/2018 S.GHS.NZL.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name CRC (NZ) 9060, 9061, 9062 Repo Xtra Cut

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