Book On Epoxy Resins Technology (Manufacturing Process, Synthesis .

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IntroductionEpoxy resin is a significant raw material to many end-use chemicalcompounds, where per molecule holds the capability of being convertedto a useful thermosetting product. The major end-use markets for epoxyresins include electronics and paints & coatings, followed by adhesives,composites, wind turbines, and others.www.entrepreneurindia.co

The term epoxy has been widely adapted for many uses beyond itsoriginal use for fiber-reinforced polymer composites. Today, epoxyadhesives are sold in local hardware stores, and epoxy resin is used asthe binder in countertops or coatings for floors. The myriad uses forepoxy continue to expand, and variants of epoxies are constantly beingdeveloped to fit the industries and products they are used in.www.entrepreneurindia.co

Here are some things that epoxy resin is used in: General-purpose adhesives Binder in cement and mortars Rigid foams Nonskid coatings Solidifying sandy surfaces in oil drilling Industrial coatings Potting and encapsulating media Fiber-reinforced plasticswww.entrepreneurindia.co

Epoxy resin refers to a type of reactive prepolymer and polymercontaining epoxide groups. These resins react either with themselves inthe presence of catalysts, or with many co-reactants like amines,phenols, thiols, etc.Epoxy resin has many industrial applications for a variety of purposes.It possesses higher mechanical properties and more thermal andchemical resistance than other types of resin. Therefore, it hasexclusive use in making aircraft components. Epoxy resin is also calledpolyepoxides.Epoxy resin also finds uses in caulking and casting compounds,sealants, varnishes and paints, and other industrial applications.www.entrepreneurindia.co

ApplicationsApplications for epoxy resins are extensive and include: Paints and coatings. Adhesives. Composite materials such as those using carbon fibre and fiberglassreinforcements. Industrial tooling and composites. Electrical systems and electronics. Consumer applications. Marine applications. Aerospace applications. Biology. Art.www.entrepreneurindia.co

Market OutlookThe global epoxy resin market size was valued at 6,826 million in2015, and is anticipated to grow at a CAGR of 6.2% to reach 10,264million by 2022. Epoxy resin is corrosion, water, and chemicalresistant; and has superior adhesion, thermal stability, durability, andmechanical strength that makes it attractive for the aircraft industry.However, fluctuating raw material cost and high prices of epoxy couldhamper the market growth.In the rapidly growing paints & coatings industry, epoxy resins are usedin powder coatings applied to automotive & appliances parts, insolvent-borne coatings applied to substrates in corrosive environment,and water-based coatings as electrode position primers in automobiles.www.entrepreneurindia.co

In electronics industry theses are widely used in the manufacturing ofprinted circuit boards (PCBs).Modernized consumer electronics products in tandem with the growingurbanization and rising disposable income of consumers has resulted inmassive demand of such products, which in turn has risen demand forepoxy resins. Increase in construction activities in many countries andrevamping of the older structures coupled with consumer demand forfeature-rich coatings has mainly driven the demand of epoxy in paints& coatings industry.www.entrepreneurindia.co

The market is divided into liquid epoxy, waterborne epoxy, solvent cutepoxy, and others. The liquid epoxy resin segment accounted for thelargest share of the overall market due to its wide range of applications.Yet, waterborne epoxy is set to emerge as the fastest growing segmentin the overall Epoxy Resin Market due to its increasing use in powdercoating applications.www.entrepreneurindia.co

onstruction, automotive & transportation, electrical & electronics,adhesives & sealants, marine, and others. Building & constructionindustry is the leading segment, growing at a considerable CAGR toreach USD 2,988.8 million till 2023, on account of rapid eindustryisanothersubstantial segment in the Global Epoxy Resin Market, which is growingat the highest CAGR due to increasing use of epoxy resin basedmaterials for manufacturing parts of an automobiles.www.entrepreneurindia.co

Global Epoxy Resin Market Share, by Application,2016 (%):www.entrepreneurindia.co

Epoxy resins have a wide range of applications in the industry. Itsproperties have made it valuable in the paints & coatings industry. nandprotection. There are various types of paint and coatings used byindustries for different purposes. These are anti-corrosive primers,primer tie coats, primer finishes, abrasion resistant coatings, andchemical, heat and fire resistant coatings. Similarly, epoxy floor paintsand sealants are some other products that are used as coatings on thefloor, in order to make it decorative and durable.www.entrepreneurindia.co

Global performance is underscored by capacity installation of windenergy and melting down of conventional sources of energy. The globalmarket has been attributed with a strong market thanks to growth ofend-use industries such as paints and coatings and adhesives. Thepaints and coatings industry advocates two parts of epoxies have beendeveloped for heavy duty services. These epoxy compounds take pridein applications to many formulations of protective coatings, automaticcoatings, powder coatings and many other solvent-based paints.Products are used in many dimensions including solid, liquid andsolution and are present in every type of paint.www.entrepreneurindia.co

Epoxy Resin Market, By Region, 2015-2026 (USDMillion)www.entrepreneurindia.co

Epoxy demand in automobile and industrial applications is projected togrow on account of superior heat resistance as compared to latex basedor alkyd based paints. Growing demand from water borne coatings,powder coatings, electrical & electronic laminates, flooring and pavingapplications is expected to further increase the growth.Major Players: DowDuPont, Nan Ya Plastics, BASF SE, Hexion,Huntsman, Jiangsu Sanmu Group, Changchun Chemicals, and DalianQihua, among otherswww.entrepreneurindia.co

Epoxy Resins Technology Handbook(Manufacturing Process, Synthesis, Epoxy Resin Adhesives and EpoxyCoatings) 2nd Revised Editionwww.entrepreneurindia.co

About the Book:Author:Dr. H. ages:576Indian Price:Rs. 1,895/-US :150-Published:2019Publisher:Asia Pacific Business Press Inc.www.entrepreneurindia.co

Epoxy is a term used to denote both the basic components and thecured end products of epoxy resins, as well as a colloquial name for theepoxide functional group. Epoxy resin are a class of thermosetmaterials used extensively in structural and specialty compositeapplications because they offer a unique combination of properties thatare unattainable with other thermoset resins.Epoxies are monomers or prepolymers that further reacts with curingagents to yield high performance thermosetting plastics. They havegained wide acceptance in protecting coatings, electrical and structuralapplications because of their exceptional combination of propertiessuchastoughness,adhesion,electrical nceandsuperior

Epoxy resins are characterized by the presence of a three memberedcycle ether group commonly referred to as an epoxy group 1, 2-epoxide,or oxirane. The most widely used epoxy resins are diglycidyl ethers ofbisphenol-A derived from bisphenol-A and epichlorohydrin.The market of epoxy resins are growing day by day. Today the totalbusiness of this product is more than 100 crores. Epoxy resins are usedfor about 75% of wind blades currently produced worldwide, whilepolyester resins account for the remaining 25%. A standard 1.5-MW(megawatt) wind turbine has approximately 10 tonnes of epoxy in itsblades. Traditionally, the markets for epoxy resins have been driven bydemand generated primarily in areas of adhesives, building and uitboards,protective coatings for consumer durables, amongst others.www.entrepreneurindia.coand

The major contents of the book are synthesis and characteristics ofepoxy resin, manufacture of epoxy resins, epoxide curing reactions, thedynamic mechanical properties of epoxy resins, physical and chemicalproperties of epoxy resins, epoxy resin adhesives, epoxy resin coatings,epoxy coating give into water, electrical and electronic applications,analysis of epoxides and epoxy resins and the toxicology of ssionalsandentrepreneurs. Those who are interested in this field can find thecomplete information from manufacture to final uses of epoxy reneurs,technocrats, research scholars, libraries and existing units.www.entrepreneurindia.co

Table of Contents1. Synthesis and Characteristics of Epoxy ResinIntroductionStructure of EpoxidesEpoxipation of Unsaturated HydrocarbonsCatalytic Oxidation of Ethylene and Higher OlefinsEpoxidation by Peroxy Acids and Their EstersPreparation of Peroxy AcidsIn Situ EpoxidationThe Epoxidation MechanismUnsaturated MaterialsEpoxidation by Inorganic Peroxy AcidsEpoxidation with Aliphatic and Aromatic Hydrocarbon HydroperoxidesEpoxidation with Chromic Acid and Chromyl CompoundsBiological EpoxidationDehydrohalogenation of Substituted Hydroxyl CompoundsThe Epoxidation MechanismHalohydrin FormationEpoxides from EpichlorohydrinGlycidyl EthersGlycidyl EstersNitrogen-Containing EpoxidesThioglycidyl EpoxidesSilicon-Containing Epoxideswww.entrepreneurindia.co

Organophosphorus EpoxidesHalogen-Containing EpoxidesEpoxides from Hydroxy Sulfonates or Halogenated AcetatesEpoxides from GlycolsEpoxidation by CondensationDarzens Glycidic Ester CondensationsEpoxides from YlidsEpoxides from Halogenated Ketones and Nickel CarbonylEpoxides from the Reaction of Diazomethane with Aldehydes or KetonesEpoxides Containing UnsaturationConclusions2. Manufacture of Epoxy ResinsRaw MaterialsManufacturePlant LocationMachinery NeededProfit3. Epoxide-Curing ReactionsThe Effect of Epoxide Structure on Reactivity with Curing AgentsThe Mechanism of the Curing ReactionPolyaddition swww.entrepreneurindia.co

PolyisocyanatesPolymercaptansPolyhydric AlcoholsPolyphenolsPolycarboxylic AcidsPolybasic Acid AnhydridesSilanes and SilanolsOthersPolymerizationAnionic CatalystsCationic Catalysts4. The Dynamic Mechanical Properties of Epoxy ResinsBasic ParametersThe Glassy Transition and Dynamic Mechanical DispersionTemperature and Frequency InterdependenceExperimentalResults and DiscussionStandard MeasurementsDynamic MeasurementsComparison of ResultsTreatment by Reduced VariablesConclusions5. Physical and Chemical Properties of Epoxy ResinsSolubility and Surface PropertiesNetwork Structure and Physical Propertieswww.entrepreneurindia.co

Aging and ChemorheologyBisphenol a Epoxy Homopolymers and CopolymersThermal Transition EffectsDynamic Mechanical ResponseRelaxation and Fracture PropertiesProperties Compared with Elastomers and Thermoplastics6. Epoxy Resin AdhesivesIntroductionTheories of Adhesion and Aohesive-joint StrengthWetting and Spreading PhenomenaBoundary-Layer TheorySurface-Attachment Theory of Adhesive-Joint StrengthsStress Distribution in Adhesive JointsRheological Aspects of AdhesivesUnified Interpretation of Adhesive-Joint StrengthsPhysical and Mechanical Aspects of Epoxy-Resin AdhesivesDynamic Mechanical TechniquesMechanical Behavior of Epoxy Adhesives During Joint FormationStrength of Adhesive MaterialsChemical Aspects of Epoxy-based AdhesivesCuring Agents for Bisphenol A Epoxy AdhesivesModifiers for Bisphenol A Epoxy AdhesivesAdhesives Based on Other Epoxy MaterialsTechnological Properties of Epoxy-adhesive SystemsCure and Thermal Softening Behavior of Epoxy AdhesivesStress and Environmental Durability of Adhesive Jointswww.entrepreneurindia.co

Applications of Epoxy AdhesivesFuture Prospects7. Epoxy Resin CoatingsClassification of Epoxy-Resin CoatingsEpoxy Resins Commonly Used in CoatingsEpoxy-Resin EstersEsters Produced from Solid Epoxy ResinsGeneral RemarksFormulation LatitudeEsters Produced from Liquid Epoxy ResinsPrecatalyzed Liquid Epoxy Resin for the Production of Solid Epoxy Resins and Epoxy-Resin EstersCooking Procedure“Two-Step” Liquid-Epoxy-Resin Route to Epoxy-Resin EstersCooking ProcedureSolid-Epoxy-Resin Solution CoatingsCold-Cured Epoxy-Resin SystemsPolyamine Curing AgentsPolyamine-Adduct Curing AgentsPolyamide-Resin Curing AgentsPolyamide-Adduct Curing AgentsTertiary Amine Curing AgentsIndustrial Maintenance Coatings Based on Cold-Cured Epoxy-Resin SystemsHigh-Film-Build Cold-Cured Epoxy-Resin CoatingsApplication InstructionsManufacturing InstructionsEpoxy Baking Finisheswww.entrepreneurindia.co

Epoxy-Phenolic Coating SystemsEpoxy-Urea-Formaldehyde Resin Coating SystemsEpoxy-Thermosetting Acrylic Coating SystemsLiquid Epoxy Resins in Solventless and Super-High-Solids SystemsSpecial Application Equipment and Formulation for Solventless SystemsManufacturing InstructionsApplicationKetimine Curing AgentsManufacturing InstructionsApplicationCuring CharacteristicsPowder CoatingsApplication EquipmentEpoxy-Resin Powder-Coating FormulationsFusion-Produced Epoxy-Resin PowdersManufacturing InstructionsApplications InstructionsDry-blended Epoxy-Resin PowdersManufacturing InstructionsApplication InstructionsProperties and ApplicationsThermoplastic Epoxy ResinsZinc-Rich and General Purpose Shop PrimersManufacturing InstructionsApplication InstructionsManufacturing InstructionsApplication Instructionswww.entrepreneurindia.co

Thermoplastic-Epoxy-Resin Crosslinked SystemsWater-Reducible Epoxy Resin CoatingsWater-Reducible Epoxy-Ester Baking FinishesManufacturing InstructionsApplication InstructionsWater-Reducible Polyamide-Cured Epoxy-Resin CoatingsManufacturing InstructionsManufacturing InstructionsWater-Reducible Epoxy-Resin Coatings for ElectrodepositionGeneral RemarksMaleinization Step After Complete Esterification of the Epoxy Resin with Organic AcidsCooking ProcedureApplication Instructions8. Epoxy Coating Give into Water9. Electrical and Electronic Applications : Sealants and FoamsElectronic and Electrical nCoatingsSealingMoldingFormulation of the Resin SystemInternal Stresseswww.entrepreneurindia.co

Rapid CuresFlexibilizing Epoxy ResinsFillersReactive DiluentsCycloaliphatic EpoxidesHigh-Temperature Epoxy-Resin SystemsFlame-Retardant Epoxy ResinsColorless Epoxy ResinsEpoxy FormulationsMoldingMolding CompoundsMolding TechnologyLiquid-Injection MoldingPellets and PreformsEpoxy SealantsEpoxy FoamsGas-Blown FoamsSyntactic FoamsOne-Package FoamsEpoxy-Foam ApplicationsEpoxy StrippersHandling of Epoxy Casting Systems10. Analysis of Epoxides and Epoxy ResinsUncured Epoxy ResinsQualitative TestsDetection of Free Epoxy GroupsDetermination of Epoxy Group—Lithium-Chloride Testwww.entrepreneurindia.co

ReagentsProcedureDetermination of Epoxy Group—Periodic Acid TestReagentsProcedureDetermination of Epoxy Group—Pyrolysis TestReagentsProcedureDetermination of Epoxy Group—Lepidine TestReagentsProcedureDetection of the Bisphenol A SkeletonDetermination of Bisphenol A Epoxy Resins—Mercuric Oxide and Nitric Acid TestsReagentsProcedureDetermination of Bisphenol A Epoxy Resins in Coatings—Nitric Acid Test ReagentsReagentProcedureDetermination of Bisphenol A Epoxy Resins—Filter-Paper TestReagentsProcedureDetermination of Bisphenol A Epoxy Resin—Formaldehyde TestReagentsProcedureDetermination of Bisphenol A Epoxy Resins—Phenylenediamine TestReagentProcedurewww.entrepreneurindia.co

Detection of Epoxy Resins Based on 4,4-’-Diamino-diphenylmethaneDetermination of Epoxy Resins Based on ion of Other Epoxy ResinsQuantitative Tests of the Epoxy GroupHydrohalogenation MethodsEstimation of Epoxy Group—Hydrochloric Acid in Dioxane, Methyl Ethyl Ketone, timation of the Epoxy Group—Pyridinium Chloride in PyridineReagentsProcedureHydrohalogenation by Direct TitrationEstimation of Epoxy GroupReagentsProcedureCalculationsOther Chemical MethodsEstimation of Other Functional GroupsHydroxyl Group-Glycol GroupEstimation of a-Glycol ndia.co

ChlorineEsterification Equivalent WeightEstimation of Esterification Equivalent WeightReagentsProcedureCalculationInfrared SpectroscopyTechniqueEpoxide Absorption BandsEpoxy ResinsQuantitative EstimationFollowing the Degree of CureOther Physical MethodsUltraviolet SpectroscopyElectron Spin and Nuclear Magnetic Resonance MethodsGas ChromatographyPaper ChromatographyThin-Layer and Gel-Permeation ChromatographyHandling PropertiesMolecular WeightSoftening PointViscosityColorBlends and CompoundsHardeners and AcceleratorsOrganic Acid AnhydridesDetermination of Acid and Anhydride Contentwww.entrepreneurindia.co

ReagentsProcedureCalculationsAminesDetermination of Amine NumberReagentsProcedureCalculationThe Curing ProcessCuring Characteristics of Epoxy Resin-Hardener SystemsDetermining the Degree of CureAnalysis of Cured Epoxy Resins11. The Toxicology of Epoxy ResinsIntroductionExperimental MethodMaterialsAcute ToxicityChronic ToxicityIrritationSensitizationResultsAcute ToxicityChronic ToxicityIrritationSensitizationMedical Experience with Epoxy ResinsComment12.Photographs of Machinery with SuppliersContact Detailswww.entrepreneurindia.co

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Epoxy resins are characterized by the presence of a three membered cycle ether group commonly referred to as an epoxy group 1, 2-epoxide, or oxirane. The most widely used epoxy resins are diglycidyl ethers of bisphenol-A derived from bisphenol-A and epichlorohydrin. The market of epoxy resins are growing day by day. Today the total

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