Safety Data Sheet THERMOTEK GOLD PLUS BRUSH GRADE
Safety Data SheetTHERMOTEK GOLD PLUS BRUSH GRADERevision date : 2018/09/12Version: 2.1Page: 1/10(30686909/SDS GEN US/EN)1. IdentificationProduct identifier used on the labelTHERMOTEK GOLD PLUS BRUSH GRADERecommended use of the chemical and restriction on useRecommended use*: Use in Coatings* The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part ofthe seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express orimplied, including by incorporation into or reference in the seller's sales agreement.Details of the supplier of the safety data sheetCompany:BASF CORPORATION100 Park AvenueFlorham Park, NJ 07932, USATelephone: 1 973 245-6000Emergency telephone numberCHEMTREC: 1-800-424-9300BASF HOTLINE: 1-800-832-HELP (4357)Other means of identificationChemical family:No applicable information available.2. Hazards IdentificationAccording to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200Classification of the productSkin Sens.Aquatic AcuteAquatic ChronicLabel elementsPictogram:133Skin sensitizationHazardous to the aquatic environment - acuteHazardous to the aquatic environment - chronic
Safety Data SheetTHERMOTEK GOLD PLUS BRUSH GRADERevision date : 2018/09/12Version: 2.1Page: 2/10(30686909/SDS GEN US/EN)Signal Word:WarningHazard Statement:H317H402H412May cause an allergic skin reaction.Harmful to aquatic life.Harmful to aquatic life with long lasting effects.Precautionary Statements (Prevention):P280Wear protective gloves.P261Avoid breathing dust/fume/gas/mist/vapours/spray.P273Avoid release to the environment.P272Contaminated work clothing should not be allowed out of the workplace.Precautionary Statements (Response):P303 P352IF ON SKIN (or hair): Wash with plenty of soap and water.P333 P311If skin irritation or rash occurs: Call a POISON CENTER ordoctor/physician.P362 P364Take off contaminated clothing and wash it before reuse.Precautionary Statements (Disposal):P501Dispose of contents/container to hazardous or special waste collectionpoint.Hazards not otherwise classifiedIf applicable information is provided in this section on other hazards which do not result inclassification but which may contribute to the overall hazards of the substance or mixture.Labeling of special preparations (GHS):Product contains the following components and may cause an allergic skin reaction: The substancemay cause sensitization of the skin in particularly sensitive individuals. Based on our experience andthe information available, no adverse health effects are expected if handled as recommended withsuitable precautions for designated uses. 2-octyl-4-isothiazol-3-ones3. Composition / Information on IngredientsAccording to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200CAS 67-764742-52-5Weight % 1.0 - 3.0% 1.0 - 3.0% 0.1 - 0.2% 25.0 - 50.0% 5.0 - 7.0% 1.0 - 3.0%Chemical nameZinc oxide2-Methylpropanoic acid monoester with -3-onesLimestoneTitanium dioxideDistillates (petroleum), hydrotreated heavy naphthenic
Safety Data SheetTHERMOTEK GOLD PLUS BRUSH GRADERevision date : 2018/09/12Version: 2.1Page: 3/10(30686909/SDS GEN US/EN)4. First-Aid MeasuresDescription of first aid measuresGeneral advice:First aid personnel should pay attention to their own safety. Remove contaminated clothing.If inhaled:No applicable information available.If on skin:Wash thoroughly with soap and water. Under no circumstances should organic solvent be used. Ifirritation develops, seek medical attention.If in eyes:Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult aneye specialist.If swallowed:Rinse mouth and then drink plenty of water. Do not induce vomiting.Most important symptoms and effects, both acute and delayedSymptoms: The most important known symptoms and effects are described in the labelling (seesection 2) and/or in section 11.Hazards: No applicable information available.Indication of any immediate medical attention and special treatment neededNote to physicianTreatment:Treat according to symptoms (decontamination, vital functions), noknown specific antidote.5. Fire-Fighting MeasuresExtinguishing mediaSuitable extinguishing media:foam, water spray, dry powder, carbon dioxideUnsuitable extinguishing media for safety reasons:water jetSpecial hazards arising from the substance or mixtureHazards during fire-fighting:carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon blackAdvice for fire-fightersProtective equipment for fire-fighting:Wear a self-contained breathing apparatus.
Safety Data SheetTHERMOTEK GOLD PLUS BRUSH GRADERevision date : 2018/09/12Version: 2.1Page: 4/10(30686909/SDS GEN US/EN)Further information:The degree of risk is governed by the burning substance and the fire conditions. Contaminatedextinguishing water must be disposed of in accordance with official regulations.6. Accidental release measuresPersonal precautions, protective equipment and emergency proceduresUse personal protective clothing. Handle in accordance with good building materials hygiene andsafety practice.Environmental precautionsContain contaminated water/firefighting water. Do not discharge into drains/surfacewaters/groundwater.Methods and material for containment and cleaning upFor small amounts: Sweep/shovel up. Dispose of absorbed material in accordance with regulations.For large amounts: Sweep/shovel up. Dispose of absorbed material in accordance with regulations.7. Handling and StoragePrecautions for safe handlingAvoid contact with the skin, eyes and clothing.Protection against fire and explosion:Keep away from sources of ignition - No smoking. The relevant fire protection measures should benoted.Conditions for safe storage, including any incompatibilitiesNo applicable information available.Further information on storage conditions: Keep only in the original container in a cool, wellventilated place. Protect from direct sunlight. Store protected against freezing.8. Exposure Controls/Personal ProtectionComponents with occupational exposure limitsZinc oxideOSHA PELPEL 15 mg/m3 Total dust ; PEL 5 mg/m3Respirable fraction ; PEL 5 mg/m3fumes/smoke ; TWA value 5 mg/m3fumes/smoke ; TWA value 5 mg/m3 Respirablefraction ; TWA value 10 mg/m3 Total dust ;STEL value 10 mg/m3 fumes/smoke ;ACGIH TLVTWA value 2 mg/m3 Respirable fraction ; STELvalue 10 mg/m3 Respirable fraction ;LimestoneOSHA PELPEL 5 mg/m3 Respirable fraction ; PEL 15mg/m3 Total dust ; TWA value 5 mg/m3Respirable fraction ; TWA value 15 mg/m3Total dust ;Titanium dioxideOSHA PELPEL 15 mg/m3 Total dust ; TWA value 10mg/m3 Total dust ;
Safety Data SheetTHERMOTEK GOLD PLUS BRUSH GRADERevision date : 2018/09/12Version: 2.1Distillates (petroleum),hydrotreated heavynaphthenicPage: 5/10(30686909/SDS GEN US/EN)ACGIH TLVTWA value 10 mg/m3 ;OSHA PELPEL 500 ppm 2,000 mg/m3 ; PEL 5 mg/m3Mist ; TWA value 5 mg/m3 Mist ;TWA value 5 mg/m3 Inhalable fraction ; ;Exposure by all routes should be carefullycontrolled to levels as low as possible.;Included in the regulation, but with no data values- See the regulation for further detailsACGIH TLVAdvice on system design:No applicable information available.Personal protective equipmentHand protection:Wear chemical resistant protective gloves.Eye protection:Safety glasses with side-shields.Body protection:Body protection must be chosen based on level of activity and exposure.General safety and hygiene measures:Avoid contact with the skin, eyes and clothing. No special measures necessary if stored and handledcorrectly. Handle in accordance with good building materials hygiene and safety practice. Wearing ofclosed work clothing is recommended. When using, do not eat, drink or smoke. Hands and/or faceshould be washed before breaks and at the end of the shift. At the end of the shift the skin should becleaned and skin-care agents applied. Gloves must be inspected regularly and prior to each use.Replace if necessary (e.g. pinhole leaks).9. Physical and Chemical PropertiesForm:Odour:Odour threshold:Colour:pH value:Melting point:Boiling point:Sublimation point:Flash point:Flammability:Lower explosion limit:Upper explosion limit:Autoignition:Vapour pressure:Density:Relative density:Vapour density:Partitioning coefficient noctanol/water (log Pow):pasteslight odourNo applicable information available.white9No applicable information available.No applicable information available.No applicable information available.No applicable information available.No applicable information available.No applicable information available.No applicable information available.No applicable information available.No applicable information available.approx. 1.38 g/cm3( 20 C)No applicable information available.No applicable information available.No applicable information available.
Safety Data SheetTHERMOTEK GOLD PLUS BRUSH GRADERevision date : 2018/09/12Version: 2.1Thermal decomposition:Viscosity, dynamic:Viscosity, kinematic:Solubility in water:Solubility (quantitative):Solubility (qualitative):Evaporation rate:Other Information:Page: 6/10(30686909/SDS GEN US/EN)No decomposition if stored and handled asprescribed/indicated.No applicable information available.No applicable information available.miscibleNo applicable information available.No applicable information available.No applicable information available.If necessary, information on other physical and chemicalparameters is indicated in this section.10. Stability and ReactivityReactivityNo hazardous reactions if stored and handled as prescribed/indicated.Chemical stabilityThe product is stable if stored and handled as prescribed/indicated.Possibility of hazardous reactionsThe product is stable if stored and handled as prescribed/indicated.Conditions to avoidSee MSDS section 7 - Handling and storage.Incompatible materialsstrong acids, strong bases, strong oxidizing agents, strong reducing agentsHazardous decomposition productsDecomposition products:No hazardous decomposition products if stored and handled as prescribed/indicated.Thermal decomposition:No decomposition if stored and handled as prescribed/indicated.11. Toxicological informationPrimary routes of exposureRoutes of entry for solids and liquids are ingestion and inhalation, but may include eye or skincontact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a routeof entry for liquefied gases.Acute Toxicity/EffectsAcute toxicityAssessment of acute toxicity: Virtually nontoxic after a single ingestion. Based on available Data, theclassification criteria are not met.OralNo applicable information available.InhalationNo applicable information available.
Safety Data SheetTHERMOTEK GOLD PLUS BRUSH GRADERevision date : 2018/09/12Version: 2.1Page: 7/10(30686909/SDS GEN US/EN)DermalNo applicable information available.Assessment other acute effectsBased on available Data, the classification criteria are not met.Irritation / corrosionAssessment of irritating effects: No irritation is expected under intended use and appropriatehandling. Based on available Data, the classification criteria are not met.SensitizationAssessment of sensitization: May cause sensitization by skin contact. The product contains 2-noctyl-4-isothiazolin-3-one (CAS-No.: 26530-20-1).The substance may cause sensitization of the skin in particularly sensitive individuals. Based on ourexperience and the information available, no adverse health effects are expected if handled asrecommended with suitable precautions for designated uses.Aspiration HazardNo aspiration hazard expected.Chronic Toxicity/EffectsRepeated dose toxicityAssessment of repeated dose toxicity: No reliable data was available concerning repeated dosetoxicity. Based on available Data, the classification criteria are not met.Genetic toxicityAssessment of mutagenicity: The chemical structure does not suggest a specific alert for such aneffect. Based on available Data, the classification criteria are not met.CarcinogenicityAssessment of carcinogenicity: The chemical structure does not suggest a specific alert for such aneffect. Based on available Data, the classification criteria are not met.Information on: Titanium dioxideAssessment of carcinogenicity: IARC (International Agency for Research on Cancer) has classifiedthis substance as group 2B (The agent is possibly carcinogenic to humans). In long-term studies inrats in which the substance was given by inhalation, a carcinogenic effect was observed. Tumorswere only observed in rats after chronic inhalative exposure to high concentrations which causedsustained lung inflammation. In long-term studies in rats and mice in which the substance was givenby feed, a carcinogenic effect was not observed. Dermal exposure is not expected to becarcinogenic.Information on: KaolinAssessment of carcinogenicity: The American Conference of Governmental Industrial Hygienists(ACGIH) has classified this substance as Group A4 - Not classifiable as human ductive toxicityAssessment of reproduction toxicity: The chemical structure does not suggest a specific alert forsuch an effect. Based on available Data, the classification criteria are not met.TeratogenicityAssessment of teratogenicity: The chemical structure does not suggest a specific alert for such aneffect. Based on available Data, the classification criteria are not met.Information on: ethylene glycol
Safety Data SheetTHERMOTEK GOLD PLUS BRUSH GRADERevision date : 2018/09/12Version: 2.1Page: 8/10(30686909/SDS GEN US/EN)Assessment of teratogenicity: Developmental toxicity was observed after oral ingestion of high dosesin studies with rats and mice, but this effect was not seen in a study with rabbits. Mechanistic studiesshow that the rabbit is the relevant species for the classification for human health. As such, andsince ethylene glycol is not a developmental toxicant in the rabbit, no classification is warranted.However, the relevance of this result for humans is unclear.---------------------------------Other InformationBased on our experience and the information available, no adverse health effects are expected ifhandled as recommended with suitable precautions for designated uses. The product has not beentested. The statements on toxicology have been derived from the properties of the individualcomponents.Symptoms of ExposureThe most important known symptoms and effects are described in the labelling (see section 2)and/or in section 11.12. Ecological InformationToxicityAquatic toxicityAssessment of aquatic toxicity:May cause long-term adverse effects in the aquatic environment. Acutely harmful for aquaticorganisms.Persistence and degradabilityAssessment biodegradation and elimination (H2O)Inherently biodegradable. The insoluble fraction can be removed by mechanical means in suitablewaste water treatment plants.The polymer component of the product is poorly biodegradable.Bioaccumulative potentialAssessment bioaccumulation potentialDischarge into the environment must be avoided.Mobility in soilAssessment transport between environmental compartmentsNo data available.Additional informationOther ecotoxicological advice:Do not discharge product into the environment without control. The product has not been tested. Thestatements on ecotoxicology have been derived from the properties of the individual components.13. Disposal considerationsWaste disposal of substance:Dispose of in accordance with local authority regulations. Do not discharge into drains/surfacewaters/groundwater.
Safety Data SheetTHERMOTEK GOLD PLUS BRUSH GRADERevision date : 2018/09/12Version: 2.1Page: 9/10(30686909/SDS GEN US/EN)14. Transport InformationLand transportUSDOTNot classified as a dangerous good under transport regulationsSea transportIMDGNot classified as a dangerous good under transport regulationsAir transportIATA/ICAONot classified as a dangerous good under transport regulations15. Regulatory InformationFederal RegulationsRegistration status:ChemicalTSCA, USreleased / listedEPCRA 311/312 (Hazard categories): Refer to SDS section 2 for GHS hazard classes applicablefor this product.EPCRA 313:CAS Number1314-13-2CERCLA RQ5000 LBS1000 LBS100 LBS10 LBSState regulationsState RTKNJPAChemical nameZinc oxideCAS Number107-21-175-07-0; 1336-216; 1310-73-275-56-9; 111-42-2;123-91-175-21-8CAS 3-21317-65-313463-67-764742-52-5Chemical nameethylene glycolacetaldehyde; Ammonium hydroxide; SodiumHydroxidePropylene oxide; 2,2'-iminodiethanol; 1,4-dioxaneEthylene OxideChemical nameZinc oxideLimestoneTitanium dioxideDistillates (petroleum), hydrotreated heavy naphthenicZinc oxideLimestoneTitanium dioxideDistillates (petroleum), hydrotreated heavy naphthenicSafe Drinking Water & Toxic Enforcement Act, CA Prop. 65:
Safety Data SheetTHERMOTEK GOLD PLUS BRUSH GRADERevision date : 2018/09/12Version: 2.1Page: 10/10(30686909/SDS GEN US/EN)WARNING: This product can expose you to chemicals including ETHYLENE OXIDE, which is knownto the State of California to cause cancer and birth defects or other reproductive harm. For moreinformation, go to www.P65Warnings.ca.gov.NFPA Hazard codes:Health: 2Fire: 0Reactivity: 0Special:16. Other InformationSDS Prepared by:BASF NA Product RegulationsSDS Prepared on: 2018/09/12We support worldwide Responsible Care initiatives. We value the health and safety of ouremployees, customers, suppliers and neighbors, and the protection of the environment. Ourcommitment to Responsible Care is integral to conducting our business and operating our facilities ina safe and environmentally responsible fashion, supporting our customers and suppliers in ensuringthe safe and environmentally sound handling of our products, and minimizing the impact of ouroperations on society and the environment during production, storage, transport, use and disposal ofour products.IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINEDHEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT ISPROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECTPROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TODETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIORTO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDINGWARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, AREMADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SETFORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USEDWITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASESHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDEREDA PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLYUNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATIONFURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NOOBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATIONGIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.END OF DATA SHEET
Safety Data Sheet THERMOTEK GOLD PLUS BRUSH GRADE Revision date : 2018/09/12 Page: 3/10 Version: 2.1 (30686909/SDS_GEN_US/EN) 4. First-Aid Measures Description of first aid measures General advice: First aid personnel should pay attention to their own safety. Remove contaminated clothing. If
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