Pearson Centre Number Candidate Number Edexcel GCE Chemistry

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Write your name hereSurnameOther namesPearsonEdexcel GCECentre NumberCandidate NumberChemistryAdvanced SubsidiaryPaper 1: Core Inorganic and Physical ChemistryTuesday 22 May 2018 – MorningTime: 1 hour 30 minutesCandidates must have: Scientific calculatorData BookletPaper Reference8CH0/01Total MarksInstructionsblack ink or black ball-point pen. UseFill in the boxes at the top of this page with your name, centrenumber and candidate number.Answer Answer allthequestions.in the spaces provided – there may bequestionsmore space than you need.Informationtotal mark for this paper is 80. Themarks for each question are shown in brackets The– use this as a guide as to how much time to spend on each question.the question marked with an asterisk (*), marks will be awarded for your Forability to structure your answer logically showing the points that you make are related or follow on from each other where appropriate.A Periodic Table is printed on the back cover of this paper.Adviceeach question carefully before you start to answer it. ReadCheckif you have time at the end. Show allyouryouranswersworking in calculations and include units where appropriate. Turn overP51459A 2018 Pearson Education Ltd.5/4/5/2/2/*P51459A0124*

1 This question is about covalent bonds.(a) State what is meant by the term covalent bond.(2). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREASome questions must be answered with a cross in a box .If you change your mind about an answer, put a line through the boxand then mark your new answer with a cross .DO NOT WRITE IN THIS AREAAnswer ALL questions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA(2)DO NOT WRITE IN THIS AREA(b) Draw a diagram of the ammonia molecule, clearly showing its shape.Include any lone pairs of electrons and the value of the bond angle.DO NOT WRITE IN THIS AREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .(c) The dot-and-cross diagram of BF3 isFFBFWhat is the bond angle in BF3?A 90 B 107 C 109.5 D 120 2*P51459A0224*(1)

DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA(d) (i) Ammonia and boron trifluoride react to form a compound NH3BF3 whichcontains a dative covalent bond. Each of the molecules, NH3 and BF3, has adifferent feature of its electronic structure that allows this to happen.Use these two different features to explain how a dative covalent bond is formed.(2). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA(ii) During this reaction, the bond angles about the nitrogen atom and theboron atom change.State the new HN H and FB F bond angles.(2). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA(Total for Question 1 9 marks)*P51459A0324*3Turn over

IsotopeNumber of protonsNumber of neutrons11H21H(ii) Use the data in the table to explain the term isotopes.DO NOT WRITE IN THIS AREA(a) (i) Hydrogen has two stable isotopes, 11H and 21H. Complete the table to show the numberof subatomic particles present in the nuclei of these two isotopes of hydrogen.(1)DO NOT WRITE IN THIS AREA2 This question is about hydrogen, the element with atomic number Z 1.(2). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .(b) The relative atomic mass of hydrogen in the Periodic Table is 1.0.This is correct to two significant figures.The table gives data for the relative isotopic mass and natural abundance of thetwo stable isotopes of hydrogen.IsotopeRelative isotopic massPercentage abundance111.00782599.9885212.0141010.0115HH(i) Using the data in the table, give a reason why it can be estimated that therelative atomic mass of hydrogen is greater than 1.0.(1). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4*P51459A0424*DO NOT WRITE IN THIS AREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA(ii) Calculate the relative atomic mass of hydrogen from these data, giving youranswer to four decimal places.(c) (i) Write an equation to represent the first ionisation energy of hydrogen.Include state symbols.(2)(2)(ii) The sequence of the first three elements in the Periodic Table is hydrogen,helium and then lithium.Explain why the first ionisation energy of hydrogen is less than that of helium,but greater than that of lithium.(4). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .*P51459A0524*5Turn over

Criticise the position of hydrogen immediately above lithium by givingone reason in favour and two against.(3). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA(d) Hydrogen can be placed in several different positions in periodic tables. One isimmediately above lithium in Group 1. Another is in the centre of the first row, asshown in the Periodic Table on the back cover. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .(Total for Question 2 15 marks)6*P51459A0624*DO NOT WRITE IN THIS AREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA3 The reaction of sulfuric acid with potassium hydroxide is a neutralisation.The equation for this reaction isH2SO4(aq) 2KOH(aq) K2SO4(aq) 2H2O(l)A titration was carried out using the following method.1. Potassium hydroxide solution of unknown concentration was placed in a buretteand the initial reading was recorded.2. 25.0 cm3 of sulfuric acid solution, concentration 0.0800 mol dm 3, was transferredto a conical flask.3. Three drops of phenolphthalein indicator were added to the sulfuric acid.4. Potassium hydroxide was added from the burette until the solution just changedcolour and then the burette reading was recorded.5. Repeat titrations were carried out until concordant titres were obtained.DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA(a) Select the most appropriate piece of apparatus to measure the 25.0 cm3 ofsulfuric acid.(1)A buretteB measuring cylinderC pipetteD volumetric flask(b) What is the colour of the solution when neutralisation has just occurred?(1)A colourlessB orangeC pale pinkDO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREAD red*P51459A0724*7Turn over

32533Initial reading / cm3Titration volume / (ii) The best value for the mean titre of this reaction isDO NOT WRITE IN THIS AREAFinal reading / cm3Titration numberDO NOT WRITE IN THIS AREATable of resultsDO NOT WRITE IN THIS AREAFinal readingDO NOT WRITE IN THIS AREAInitial readingDO NOT WRITE IN THIS AREA4(2)DO NOT WRITE IN THIS AREA(c) (i) Complete the table of results for titration number 1, using the diagrams tofind the initial and final burette readings.(1)A 27.00 cm3B 27.15 cm3C 27.25 cm3D 27.30 cm38*P51459A0824*

DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA(iii) Calculate the concentration, in mol dm 3, of the potassium hydroxide solution,giving your answer to an appropriate number of significant figures.(3)DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA(Total for Question 3 8 marks)*P51459A0924*9Turn over

A sample of MN.xH2O was dissolved in distilled water to produce a colourlesssolution, with a concentration of about 0.5 mol dm 3. 2 cm3 of the resulting solutionwas transferred to each of two test tubes.The following tests were carried out to identify the ions present.(a) Test 1(i) Addition of a few drops of a solution of barium chloride to one of the testtubes gave a white precipitate.Identify, by name or formula, two possible anions that would give this result.DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA4 An ionic compound contains a metal cation and a non-metal anion in a 1 : 1 ratio, andwater of crystallisation. The compound can be represented as MN.xH2O, where x isthe number of moles of water of crystallisation per mole of MN.(1)(1). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .(iii) What is the charge on the cation?A 1B 1(1)DO NOT WRITE IN THIS AREAGive the formula of the anion.DO NOT WRITE IN THIS AREA(ii) Addition of 1 cm3 of dilute hydrochloric acid to the test tube in (a)(i) resultedin no further change.DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .C 2D 210*P51459A01024*

DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA(b) Test 2A flame test on a sample of solid MN.xH2O gave no change in the flame colour.Give a possible identity of the cation, M.(1). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .(c) Heating the hydrated compound results in the formation of the anhydrous ionicsolid MN by the following reaction:MN.xH2O(s) MN(s) xH2O(g)Heating a sample of the hydrated compound reduced the mass to 48.9 % of itsoriginal value.Use this information and your answer to (a)(ii) and (b) to calculate the value of x.[Note: If you have been unable to identify MN, you may use this hydrated compound,CoCl2.yH2O in which the sample reduced in mass to 54.6% of its original value.Use this information to calculate the value of y.](4)(Total for Question 4 8 marks)*P51459A01124*11Turn over

DO NOT WRITE IN THIS AREAProcedureStep 1 150 cm3 of hydrochloric acid, concentration 0.80 mol dm 3, was transferred to a400 cm3 conical flask. The flask was warmed gently using a Bunsen burner.A spatula measure (about 1.0 g) of metal carbonate was added to the acid.Step 2 When the reaction in Step 1 was finished, more metal carbonate was addeduntil the metal carbonate was in excess.Step 3 The resulting mixture was filtered into an evaporating basin.Step 4 The evaporating basin was heated using a Bunsen burner to concentrate thesolution. The concentrated solution was allowed to cool and crystallise.DO NOT WRITE IN THIS AREA5 A student made crystals of a metal chloride, JCl2.6H2O, by reacting themetal carbonate, JCO3 , with hydrochloric acid, HCl(aq). The product was purified.Step 5 Once crystal formation was complete, the resulting mixture was filtered for asecond time.(2). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .DO NOT WRITE IN THIS AREA(a) (i) Describe two observations that the student might make which show that thereaction in Step 1 has finished.DO NOT WRITE IN THIS AREAJCO3(s) 2HCl(aq) JCl2(aq) H2O(l) CO2(g)DO NOT WRITE IN THIS AREAThe equation for the reaction between the metal carbonate and hydrochloric acid isDO NOT WRITE IN THIS AREAStep 6 The resulting white crystals were rinsed with a small volume of ice-cold water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .(ii) State the purpose of the filtration in Step 3.(1). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12*P51459A01224*

DO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREADO NOT WRITE IN THIS AREA(iii) Explain the use of a small volume of ice-cold water in Step 6.(2). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Paper 1: Core Inorganic and Physical Chemistry Tuesday 22 May 2018 - Morning Time: . Edexcel GCE. 2 *P51459A0224* DO NOT RITE IN THIS AREA DO NOT RITE IN THIS AREA DO NOT RITE IN THIS AREA DO NOT RITE IN THIS AREA DO NOT RITE IN THIS AREA DO NOT RITE IN THIS AREA Answer ALL questions. Some questions must be answered with a cross in a box .

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