ELECTRICAL RESINS FOR TODAY AND TOMORROW

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ELECTRICAL RESINS FOR TODAY AND TOMORROWELECTRICAL RESINS FR TODAY AND TOMORROSWITCH MODE POWER SUPPLYSWITCHMODEPOWERSUPPLYPresentedby: SeanMcCabeHead of Technical DepartmentImpregnating Resins and CompoundsELANTAS, ZHUHAIELECTRONICTRANSFORMERSS.McCABE

ElantasGroup StructureSales 2006EmployeesELECTRONICTRANSFORMERSS.McCABE 409m1.052*Sales 2006Employees 339m1.802*Sales 2006EmployeesSales 2006Employees 325m883* 1,3bn4,500Sales 2006Employees 221m655*

Elantasat a GlanceSales 2006EmployeesSales 2006Employees 409m1.052*Sales 2006Employees 339m1.802*Sales 2006Employees 325m883*Sales 2006Employees 221m655*BYK-Chemie GmbHECKART GmbH & Co. KGELANTAS GmbHACTEGA GmbHBYK Asia PacificECKART AmericaELANTAS BeckACTEGA ArtisticaBYK-CeraECKART AsiaELANTAS Beck IndiaACTEGA DSBYK-Chemie de MexicoECKART BeneluxELANTAS CamattiniACTEGA FoshanBYK-GardnerECKART CosmeticsELANTAS DeatechACTEGA KelstarBYK Gardner USAECKART FranceACTEGA RadcureBYK JapanECKART ItaliaELANTAS Isolantes Eletricosdo BrasilBYK SolutionsECKART MexicoBYK TonglingECKART PigmentsBYK USAECKART SuisseECKART SwitzerlandELECTRONICTRANSFORMERSS.McCABE 1,3bn4,500ECKART UK* (2006-12-31)ECKART ZhuhaiELANTAS PDGELANTAS TonglingELANTAS UKELANTAS ZhuhaiACTEGA RhenacoatACTEGA RhenaniaACTEGA Terra

ELANTASGlobal FootprintHeadquartersProduction, SalesSales officeELANTAS UK, GreatBritainELANTASHeadquarters,GermanyELANTAS Beck,GermanyELANTAS Camattini,ItalyELANTAS Tongling,ChinaELANTAS PDG,USAELANTAS Zhuhai,ChinaELANTAS IsolantesElétricos do Brasil,BrazilELECTRONICTRANSFORMERSS.McCABEELANTAS Deatech,ItalyELANTAS BeckIndia, IndiaWith production, R&D and technical service in Americas, Europe and Asia,ELANTAS is well positioned to benefit from ongoing globalization

Primary InsulationProducts and Applications Wire enamels for the primary insulation of magnet wire Magnet wire is applied in electric motors, generators andtransformersELECTRONICTRANSFORMERSS.McCABE

Secondary InsulationProducts and Applications Secondary Insulation of winding wire after it is mounted in a device(electric motor, generator or transformer) Applied through various application techniques(dip, roll-dip, hot-dip, trickle, VPI etc.)ELECTRONICTRANSFORMERSS.McCABE

Electronic and Engineering MaterialsProducts and Applications Resin systems for the overall protection of electronic circuits andelectric devices Resin systems with specific functionalities in ERSS.McCABE

ELANTAS, ZHUHAI:INVESTMENT AND PRODUCTION CAPABILITYRegistered Capital: 5.70 MillionUSDTotal Investment:9.50 Million USDFluid working capital:3.2 MillionUSDArea of Land: 70,000m²Building area of the firststage:12,500m²Production Capability:15,000 tons of high performanceimpregnating varnish per year.10,000 tons of wire enamels peryearELECTRONICTRANSFORMERSS.McCABE

CONSTRUCTION HISTORY¾ In October 2002, Decision wasmade to set up Elantas ElectricalInsulation (Zhuhai) Co. Ltd.¾ In August 2003, Construction ofZhuhai plant was formally started¾ By the end of July 2004,construction of the plant wasfinished and commissioningstarted¾ In September, 2004, Zhuhai plantbegan the trial production.ELECTRONICTRANSFORMERSS.McCABE

EQUIPMENT STATUS Six reactors(3 15 cubic meters, 1 8 cubicmeters, 1 4 cubic meters,1 500 liters) Eight dilutors(5 35 cubic meters, 2 15 cubicmeters, 1 1 cubic meter) Ten mixers(2 3 cubic meters, 2 5 cubicmeters,3 8 cubic meters, 3 1cubic meters)ELECTRONICTRANSFORMERSS.McCABE

EQUIPMENT STATUS¾ Ten intermediate storage tanks¾ (10 50 cubic meters)¾ Fourteen raw material storagetanks¾ ( 7 60 cubic meters, 7 100cubic meters)¾ One waste fluid collecting tank¾ (60 cubic meters)¾ One safety tank (50 cubic meters)ELECTRONICTRANSFORMERSS.McCABE

QUALITY CONTROL STATUS¾ISO 9000 was issued in May,2005¾ OHSAS 18000 & ISO14000 in2006;¾ TS16949 in May, 2007.¾ Major test equipment for lab ispositioned such as FTIR, TGA,DSC, Bond strength tester etc.which is enough for currentquality control requirements;¾Technical development &management systems areapplied to insure future quality.ELECTRONICTRANSFORMERSS.McCABE

QUALITY CONTROL STATUS¾ Both Chinese and English versions ofraw material specifications, testingprocedure and product specification,testing procedure and productionprocess are available;¾ UL approval work is done and we areauthorized to produce and sell allproducts transferred / approved from P.D. George and other sister companies.¾ A new lab has been established withmore advance equipment like VPI andEnameling machine.ELECTRONICTRANSFORMERSS.McCABE

A Strategic Approach toSpecific Applications –Electronic TransformersELECTRONICTRANSFORMERSS.McCABE

Topics:¾ Market size and development¾ Electronic transformers – what are they?¾ Resin requirements¾ Products offered by ELANTAS¾ Future resin systemsELECTRONICTRANSFORMERSS.McCABE

Market size and developmentElectronic Transformers1999 - 20042005 - 2010Explanation1.Market growth*20 % p.a.10-15 % p.a.(volume units: Mtons)2.Electronic Transformers10.008.003.6.00Electronic Transformers4.004.2.000.002003 2004 2005 2006 2007 2008 2009 2010Electronic Transformers 3.83 4.33 4.88 5.51 6.22 6.80 7.44 8.14Secondary data: CHEAA – appliance referenceELECTRONICTRANSFORMERSS.McCABE5.This market is dominatedby USA companies whohave OEM in China plusTaiwanese & Japanesebases. They continue tomove production to ChinaThis is the first industry inour field to absorb theforeign investment in Chinasince their end product ishighly labour intensive.Future growth will be thegrowth of the Chinesedomestic market for export.OEM and / or foreignmanufacturers focus onexport but products have tobe UL approved.Many manufacturers havespecified Elantas materials

Electronic Transformers – What are they?Component name:TransformersTransducersLightning and Surge Protection chgearUsed in:TelecommunicationsOffice equipmentAutomotiveAppliancesThe control circuit of BE

Electronic Transformers – Operation?¾ Inductance is the ability of a coil to establish (or induce) a voltage within itself tooppose changes in current through its windings.¾ When varying current (AC) flows through a coil, a voltage is induced within the coilin a direction so as to oppose the change of current through it.¾ Transformers are one of the major applications. These are made from "mutuallycoupled" coils where the magnetic field established in one coil, 'cuts' through theother coil and hence induces a voltage in the other coil. This is called 'mutualinductance'.¾ They are used in electronics to step-up or step-down voltages. When a varyingvoltage (like AC) is applied to one of the coils of the transformer a voltage is'induced' in the other coil due to mutual inductance.ELECTRONICTRANSFORMERSS.McCABE

Resin functions:¾ Transformers are noisy! : Electrical varnishes help the unit resist vibration¾ Transformer consolidation : Electrical varnishes help the unit resist wireseparation, by solidifying the core and holding the conductors together within thecoil.¾ Environmental: Electrical varnishes insulate the winding and core from theenvironment. This insulation prevents the oxidation of core material anddeterioration of magnet wire insulation due to contact with moisture orairborne impurities.¾ Insulation of minute "nicks" on the magnet wire, increased dielectric strength ofenamelled wire and fibrous and porous sheet insulation.¾ Raised operating temperature of low-temperature sheet insulation.¾ Fill of internal voids within the component : Playing a major role in heattransfer from "hot spots" within the part to the surface.ELECTRONICTRANSFORMERSS.McCABE

Resin requirements:¾ Flexible: To aid noise reduction and prevent wire movement¾ Low viscosity: To facilitate penetration between fine wires¾ Low exotherm / shrinkage: To prevent damage to fine wires and limitchanges in inductance¾ High chemical and moisture resistance: To repel the environment¾ Increased electrical performance: Dielectric strength.¾ Increased thermal conductivity: Dissipate heat quickly and prevent hotspots.¾ Coefficient of Thermal Expansion: Solids expand in response to heatingand contract on cooling; this response to temperature change isexpressed as its coefficient of thermal expansionELECTRONICTRANSFORMERSS.McCABE

Resin functions in detailFlexible: To aid noise reduction and prevent wire movementBase resin used must be able to “flex” according to the frequencypower of the transformer to prevent micro-cracking.Flexibility is measured using:Hardness MeasurementsDIN 53505Tensile strengthISO527Glass transition temperatureIEC1006ELECTRONICTRANSFORMERSS.McCABE

Resin functions in detailLow viscosity: To facilitate penetration between fine wiresViscosity is the measure of a material's resistance to flow. It is a result ofthe internal friction of the material's molecules. Materials with a highviscosity do not flow readily; materials with a low viscosity are more fluid.The higher the viscosity the thicker the materialViscosity decreases as temperature increasesELECTRONICTRANSFORMERSS.McCABE

Resin functions in detailLow exotherm / shrinkage: To prevent damage to fine wires and limitchanges in inductanceWhen certain polymers cure they give out heat as an exotherm - theenergy dissipated in a chemical reaction. This heat is sufficient to breakwires and therefore change the overall inductanceELECTRONICTRANSFORMERSS.McCABE

Resin functions in detailIncreased thermal conductivity: Dissipate heat quickly and preventhot spots.Thermal conductivity is a measure of the heat transfer capability ofthe resin to prevent over-heating of the core. It is measuredaccording to ISO 8894-1.Inorganic fillers are used to increase this property but this can alsoincrease viscosity.ELECTRONICTRANSFORMERSS.McCABE

Resin functions in detailCoefficient of Thermal ExpansionMaterials expand / contract due to changes in temperature whichleads to changes in thermal vibration of the atoms in a material, andhence to an increase in the average separation distance of adjacentatoms.The linear coefficient of thermal expansion a describes by howmuch a material will expand for each degree of temperature increaseELECTRONICTRANSFORMERSS.McCABE

Resin ucibleCommon olyurethaneUnsaturated polyestersPBD resinsSaturated polyestersEpoxiesCommon SolventsXylene, tolueneStyrene, Vinyl tolueneSmall amounts of nonreactive organic solventTypical CureMethodsHeat / roomtemperatureHeat / room temperatureHeatTypical ProcessDip and BakePotting / Dip and Bake/VIDip and BakeMaterial TankStability (Pot Life)Very goodVery goodVery goodTank sYesNoNoPriceLowHighModerateDisposal CostsHighLowLowTypical Number ofPartsOneTwoOne / twoELECTRONICTRANSFORMERSS.McCABE

Resins and Compounds for the Electronic TransformerIndustryELECTRONICTRANSFORMERSS.McCABE

Elantas 468 rangeUsesChemical typeImpregnation of electronic componentsAdvantagesResilient epoxy resinSingle componentCure: 3-5hours at 135COutstanding Noise ReductionOutstanding Thermal DissipationHigh Dielectric StrengthExcellent Chemical and MoistureResistanceExcellent Tank StabilityLong product historyApplication MethodDip / Vacuum processELECTRONICTRANSFORMERSS.McCABEULrecognized up to Class 200C

Elantas V1630 / V1380 / 009-0008Chemical typeUsesImpregnation of motors andtransformersModified saturated polyestersSingle componentCure 20-30 minutes at 25 CAdvantagesFast air dryGood penetrationGood moisture resistanceApplication gnized up to Class 180CCUSTOMERSATC FrostDelco RemySignal TransformerJohnson ElectricVarious distributors

Elantas 003-1010Chemical typeUsesImpregnation of motors andtransformersSolvented saturated polyesterSingle componentCure 2-3 hours at 130-160 CAdvantagesHigh flexibilityHigh bond strengthGood moisture resistanceApplication zed up to Class 200CCUSTOMERSPhillips ShanghaiSanyoVarious distributors

Elantas U510SUsesPotting of electronic componentsAdvantagesVery flexibleGood adhesion to various substratesExcellent thermal shock characteristicsRoom temperature cureChemical type:Flexible polybutadieneDual component (100:24 pbw)Cure 72-168 hours at 25CULNot recognized by ULCustomersDelco Delphi ElectronicsApplication MethodPottingELECTRONICTRANSFORMERSS.McCABEHamlin

Elantas PED 300UsesImpregnation and potting oftransformersAdvantagesVery FlexibleExcellent for noise dampeningCan be highly filledExcellent field historyCost effectiveApplication l type:Unsaturated polyester – in styreneDual component (100:1)Cure 24 hours at 25 C (77 F)ULRecognized up to Class 180CCUSTOMERSHolophaneSolaJeffersonActown

Altana E471-5LLUsesImpregnation and potting ofelectronic transformersAdvantagesMinimal exotherm and shrinkage.Excellent for noise dampeninghighly filled – excellent heattransferLong pot life and low viscositymakes this compound ideal forfine wire applications.Application l typeHighly filled epoxy resinDual component (100:15)Cure 24 hours at 25 C (77 F)ULRecognized to UL94 V-0CUSTOMERSVarious agents

Altana 200 PolyurethaneUsesImpregnation and potting of highvoltage electric and electronictransformersChemical typeFilled polyurethane resinDual component (100:16.7)Cure 1-2 hours at 107-121 CAdvantagesGood electrical properties atelevated temperaturesExcellent mechanical resiliency.Excellent heat shock.Low temperature cure.Application MethodPottingELECTRONICTRANSFORMERSS.McCABEULNot recognized by ULCUSTOMERSVarious agents

Future Developments – Resin Choices?Environmentally DrivenWater Based resinsystemsLow emission ResinsLow viscosity solventlessepoxy systemsELECTRONICTRANSFORMERSS.McCABE

Future Developments – Resin Choices?Environmentally DrivenEPA programs have been set up to improve air quality.The clean air act has added an extra dimension in making a decision as to thetype of varnish to use in the manufacturing of transformers and other electricaldevices.The figure below shows the typical % of VOC (Volatile Organic Compound) foreach type of varnish.Percentage Volatiles Of VarnishesSolvent basedWater basedStyrene polyesterVT polyesterDAP 0405060

Future Developments – Resin Choices?Environmentally DrivenThe figure below shows the % volatiles stripped off under vacuum levels of 10and 20mmHg. Solvent based and water based were not tested as the vapourpressure of the solvents and water.The solventless epoxy and DAP systems exhibited good resultsChemical Loss under .McCABE0EpoxyDAP polyesterVT polyesterStyrene polyester

Future Developments – Resin Choices?Temperature Rating Driven Filled resins to improve thermalconductivity High Temperature co-polymersystems High Temperature Epoxy ResinsELECTRONICTRANSFORMERSS.McCABE

Future DevelopmentsTemperature rating drivenHeat rise Comparison of Varnishes¾ The transformer processed in thesolvent-less epoxy exhibited heatrise of 20C less than the othersystems.159158160140152130120100¾ The reason for this is that thesolvented polyester and the waterbased varnishes didn’t meet thetemperature requirement of 150Cfor the transformer is that whenthese are cure they also out-gas.These emissions cause ahoneycomb effect, trapping airwhich is a poor thermal conductorand traps ter based resin Water based resin12Solvent basedNote that the acceptable upper limit for heat risein this case was 150C.

Future DevelopmentsTemperature rating drivenThe figure (below) shows how the correct choice of impregnant even amongstdifferent 100% solids varnishes of like and dissimilar chemistries, can have variedresults pertaining to heat rise.Heat Reduction Comparison RANSFORMERSS.McCABESolventlesspolyesterDAP polyesterEpoxy resinRipley E468-2

Future DevelopmentsTemperature rating driven¾ The correct choice of resin has a direct effect on the heat rise of thetransformer. Whilst this is a physical function of the varnish, theresults directly impact the decision of the varnish choice byreflecting into the final cost of the transformer.¾ How does heat rise and heat reduction calculate into the costingfactor of the varnish?Providing that the heat rise is within specified limits, the engineerwill be able to achieve a significant cost reduction of thetransformer by eliminating some of the core steel and magneticwire. The major cost of the transformer is in the insulation, steel andcopper. If you can eliminate even a small percentage the costsavings are real.ELECTRONICTRANSFORMERSS.McCABE

So? Investigate!!!As can be seen different applications require different properties fromthe system used.Investigate what exact properties are important and define in order ofimportance.ALSO: The resin will be used with other insulation materials –Good compatibility between these is essential!!!!CheckCompatibility in the wet stateCompatibility of by-products after cure due to thermal degradationELECTRONICTRANSFORMERSS.McCABE

What else must be considered?1. COSHH – Control of Substances Hazardous to HealthThese place obligations on employers to use more safe chemicals2.EPA – Environmental Protection ActLimits to the release of hazardous substances into the environment3. COST!!!This covers the cost of the resin and also the cost of the equipmentELECTRONICTRANSFORMERSS.McCABE

CONSTRAINTS ON A SYSTEMELECTRICAL OSTCOSHHELECTRONICTRANSFORMERSS.McCABEEPA

Conclusion – Choice of resin?Challenges of performance criteria, cost, and environmentalissues fact the engineers decision.¾What are the performance characteristics of theresin?¾What does the varnish cost?¾What are the costs with disposal of varnish?¾Will I need to change in the future due to environmentallegislation?¾Will this varnish suit my process without impacting theair quality?ELECTRONICTRANSFORMERSS.McCABE

Thank you foryour attention.

PBD resins Phenolic, Epoxies, Saturated Polyesters Common Resins Solvent-less Water-Reducible Non-reactive Solvents Resin profiles: ELECTRONIC TRANSFORMERS S.McCABE Resins and Compounds for the Electronic Transformer Industry. ELEC

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