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Nonlinear Opticsand PhotonicsMarkus Krecik16.6.2011

Carbon: ApplicationsF. Bonaccorso, Z. Sun, T. Hasan, A. C. Ferrari, Nature Photonics 4, 611 - 622 (2010)http://www.elektroniknet.de/fileadmin/user upload/wor pics/186eb793c950fac9e3b8e8303b1b49f9 010/07/06 spaceelevator.jpgNonlinear Optics and Photonics - Markus Krecik2

Outline Fiber Laser: Femtosecond Pulse Generation–– Plasmonics: Enhanced Raman Spectroscopy–––– Mode-Locking with Saturable AbsorberCNT/Graphene as ModelockerIntroductionSurface Enhanced Raman Scattering (SERS)Tip-Enhanced Raman Scattering (TERS)TERS on CNTsSummaryNonlinear Optics and Photonics - Markus Krecik3

Fiber LaserU. Keller, Nature 424, 831-838 (2003)http://www.rp-photonics.com/fiber lasers.htmlNonlinear Optics and Photonics - Markus Krecik4

Fiber LaserSun et al., Nano Res. 2010, 3(9): 653–660Nonlinear Optics and Photonics - Markus Krecik5

Fiber Laser Mode-Locking:Saturable Absorber Types: Semiconductor (SESAM), CNT, Graphene.Nonlinear Absorption: I C. Rulliere, Femtosecond Laser Pulses, Springer, 2 nd ed. (1947)U. Keller, Nature 424, 831-838 (2003)Nonlinear Optics and Photonics - Markus Krecik6

Fiber Laser:Graphene, CNTGraphene:a) Light absorptionb) Carrier-carrier collisions ( 100fs)c) Filled states, no further absorption (Pauli blocking)CNT: Distribution of bandgapsQ. Bao et al. Adv. Funct. Mater. 19, 3077–3083 (2010)Nonlinear Optics and Photonics - Markus Krecik7

Fiber Laser:Pulse Profile e.g. Graphene:Z. Sun et al., Nano Res. 2010, 3(9): 653–660Nonlinear Optics and Photonics - Markus Krecik8

Fiber Laser:Graphene, CNTComparisonGrapheneCNTBroadband tuneablilityFast relaxation timesLow saturation intensityLow costOff-resonance producesadditional lossNonlinear Optics and Photonics - Markus Krecik9

/n4/images/nphoton.2007.38-f1.jpgNonlinear Optics and Photonics - Markus Krecik10

Plasmonics:Applications Waveguides Nonlinear Light Generation Metamaterials: Negative Refraction Index SuperlensesSurface/Tip EnhancedRaman Scattering(SERS/TERS).S. A. Maier, Plasmonics: Fundamentals and Applications, Springer, 1st ed. (2007)Nonlinear Optics and Photonics - Markus Krecik11

Plasmonics:Types Volume Plasmon:Surface Plasmon Polariton(SPP):Localized Surface PlasmonPolariton:S. A. Maier, Plasmonics: Fundamentals and Applications, Springer, 1st ed. s/6/65/Electron density wave - plasmon excitations.jpgM. Pelton et al., Laser & Photon. Rev. 2, No. 3, 136–159 (2008)Nonlinear Optics and Photonics - Markus Krecik12

Plasmonics:Surface Plasmon Polariton 2d plasma oscillationsat metal surface 0Coupling by prism orgrating 0S. A. Maier, Plasmonics: Fundamentals and Applications, Springer, 1 st ed. s/6/65/Electron density wave - plasmon excitations.jpgNonlinear Optics and Photonics - Markus Krecik13

Plasmonics:Localized SPP SPP confined to small volumed Electric field enhancementdue to localized SPPand lightning rod effectM. Pelton et al., Laser & Photon. Rev. 2, No. 3, 136–159 (2008)Nonlinear Optics and Photonics - Markus Krecik14

Plasmonics:SERS on GrapheneF. Schedin et al, ACS Nano 4, 5617 (2010)Nonlinear Optics and Photonics - Markus Krecik15

Plasmonics:TERS Localized SPP at AFM-tip No averaging, high spatial resolution, high sensitivityL. G. Cançado et al., J. of Raman Spec. 40, Issue: 10, Pages: 1420-1426 (2009)Nonlinear Optics and Photonics - Markus Krecik16

Plasmonics:TERS with CNT RBM: diameter, chirality D-band: defects G-band: metallic/semiconductor G'-band: dopantsL. G. Cançado et al., J. of Raman Spec. 40, Issue: 10, Pages: 1420-1426 (2009)Nonlinear Optics and Photonics - Markus Krecik17

Summary Fiber Laser powerful and flexible type of pulse laserGreat advantages of CNT/Graphene in femtosecondpulse generation (especially Graphene)Greatly enhanced electric field in vicinity ofnanoparticlesApplication in TERS for high spatially resolved,intensity enhanced Raman spectroscopyObtain properties of single CNTsNonlinear Optics and Photonics - Markus Krecik18

Thank you foryour Attention!Nonlinear Optics and Photonics - Markus Krecik19

References Title image taken from:http://www.halderschneidtechnik.de/ bilder/laserschneiden/laserschneiden.jpgS. A. Maier, Plasmonics: Fundamentals and Applications, Springer, 1st ed. (2007)F. Bonaccorso, Z. Sun, T. Hasan, A. C. Ferrari, Nature Photonics 4, 611 - 622 (2010)T. Hasan et al., Adv. Mat., 21 (38-39). pp. 3874-3899U. Keller, Nature 424, 831-838 (2003)Z. Sun et al., Nano Res. 2010, 3(9): 653–660Z. Sun et al., ACS Nano 4, 803 (2010)F. Wang et al., Nature Nanotechnology 3, 738 - 742 (2008)M. Pelton et al., Laser & Photon. Rev. 2, No. 3, 136–159 (2008)L. G. Cançado et al., J. of Raman Spec. 40, Issue: 10, Pages: 1420-1426 (2009)N. Hayazawa et al., Chem. Phys. Lett. 376 (2003) 174–180F. Schedin et al., ACS Nano 4, 5617 (2010)S. Lefrant, Curr. Appl. Phys. 2 (2002) 479–482Nonlinear Optics and Photonics - Markus Krecik20

Nonlinear Optics and Photonics - Markus Krecik 11 Plasmonics: Applications Waveguides Nonlinear Light Generation Metamaterials: Negative Refraction Index Superlenses Surface/Tip Enhanced Raman Scattering (SERS/TERS) . S. A. Maier, Plasmonics: Fundamentals and Applications, Springer, 1st ed. (2007)

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