Chapter 7: Advanced Composite Material

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Chapter 7Advanced Composite MaterialsDescription of Composite StructuresIntroductionComposite materials are becoming more important in theconstruction of aerospace structures. Aircraft parts madefrom composite materials, such as fairings, spoilers, and flightcontrols, were developed during the 1960s for their weightsavings over aluminum parts. New generation large aircraftare designed with all composite fuselage and wing structures,and the repair of these advanced composite materials requiresan in-depth knowledge of composite structures, materials,and tooling. The primary advantages of composite materialsare their high strength, relatively low weight, and corrosionresistance.7-1

Laminated StructuresComposite materials consist of a combination of materialsthat are mixed together to achieve specific structuralproperties. The individual materials do not dissolve or mergecompletely in the composite, but they act together as one.Normally, the components can be physically identified as theyinterface with one another. The properties of the compositematerial are superior to the properties of the individualmaterials from which it is constructed.A matrix supports the fibers and bonds them together in thecomposite material. The matrix transfers any applied loadsto the fibers, keeps the fibers in their position and chosenorientation, gives the composite environmental resistance, anddetermines the maximum service temperature of a composite.Strength CharacteristicsAn advanced composite material is made of a fibrous materialembedded in a resin matrix, generally laminated with fibersoriented in alternating directions to give the material strengthand stiffness. Fibrous materials are not new; wood is the mostcommon fibrous structural material known to man.Structural properties, such as stiffness, dimensional stability,and strength of a composite laminate, depend on the stackingsequence of the plies. The stacking sequence describesthe distribution of ply orientations through the laminatethickness. As the number of plies with chosen orientationsincreases, more stacking sequences are possible. Forexample, a symmetric eight-ply laminate with four differentply orientations has 24 different stacking sequences.Applications of composites on aircraft include:Fiber Orientation Fairings Flight control surfaces Landing gear doors Leading and trailing edge panels on the wing andstabilizer Interior components Floor beams and floor boards Vertical and horizontal stabilizer primary structure onlarge aircraft Primary wing and fuselage structure on new generationlarge aircraft Turbine engine fan blades PropellersMajor Components of a LaminateAn isotropic material has uniform properties in all directions.The measured properties of an isotropic material areindependent of the axis of testing. Metals such as aluminumand titanium are examples of isotropic materials.A fiber is the primary load carrying element of the compositematerial. The composite material is only strong and stiff inthe direction of the fibers. Unidirectional composites havepredominant mechanical properties in one direction and aresaid to be anisotropic, having mechanical and/or physicalproperties that vary with direction relative to natural referenceaxes inherent in the material. Components made from fiberreinforced composites can be designed so that the fiberorientation produces optimum mechanical properties, butthey can only approach the true isotropic nature of metals,such as aluminum and titanium.7-2The strength and stiffness of a composite buildup dependson the orientation sequence of the plies. The practical rangeof strength and stiffness of carbon fiber extends from valuesas low as those provided by fiberglass to as high as thoseprovided by titanium. This range of values is determinedby the orientation of the plies to the applied load. Properselection of ply orientation in advanced composite materialsis necessary to provide a structurally efficient design. Thepart might require 0 plies to react to axial loads, 45 pliesto react to shear loads, and 90 plies to react to side loads.Because the strength design requirements are a function ofthe applied load direction, ply orientation and ply sequencehave to be correct. It is critical during a repair to replaceeach damaged ply with a ply of the same material and plyorientation.The fibers in a unidirectional material run in one directionand the strength and stiffness is only in the direction of thefiber. Pre-impregnated (prepreg) tape is an example of aunidirectional ply orientation.The fibers in a bidirectional material run in two directions,typically 90 apart. A plain weave fabric is an example ofa bidirectional ply orientation. These ply orientations havestrength in both directions but not necessarily the samestrength. [Figure 7-1]The plies of a quasi-isotropic layup are stacked in a 0 , –45 ,45 , and 90 sequence or in a 0 , –60 , and 60 sequence.[Figure 7-2] These types of ply orientation simulatethe properties of an isotropic material. Many aerospacecomposite structures are made of quasi-isotropic materials.

BidirectionalUnidirectional0 45 4590Unequal properties90Equal properties 45Figure 7-1. Bidirectional and unidirectional material properties. 4500 90 Figure 7-3. A warp clock. 45 Roving–45 –45 45 90 900 0 A roving is a single grouping of filament or fiber ends, suchas 20-end or 60-end glass rovings. All filaments are in thesame direction and they are not twisted. Carbon rovings areusually identified as 3K, 6K, or 12K rovings, K meaning1,000 filaments. Most applications for roving products utilizemandrels for filament winding and then resin cure to finalconfiguration.Unidirectional (Tape)Figure 7-2. Quasi-isotropic material lay-up.Warp ClockWarp indicates the longitudinal fibers of a fabric. The warpis the high strength direction due to the straightness of thefibers. A warp clock is used to describe direction of fiberson a diagram, spec sheet, or manufacturer’s sheets. If thewarp clock is not available on the fabric, the orientation isdefaulted to zero as the fabric comes off the roll. Therefore,90 to zero is the width of the fabric across. [Figure 7-3]Fiber FormsAll product forms generally begin with spooled unidirectionalraw fibers packaged as continuous strands. An individual fiberis called a filament. The word strand is also used to identifyan individual glass fiber. Bundles of filaments are identifiedas tows, yarns, or rovings. Fiberglass yarns are twisted,while Kevlar yarns are not. Tows and rovings do not haveany twist. Most fibers are available as dry fiber that needs tobe impregnated (impreg) with a resin before use or prepregmaterials where the resin is already applied to the fiber.Unidirectional prepreg tapes have been the standard withinthe aerospace industry for many years, and the fiber istypically impregnated with thermosetting resins. The mostcommon method of manufacture is to draw collimated raw(dry) strands into the impregnation machine where hot meltedresins are combined with the strands using heat and pressure.Tape products have high strength in the fiber direction andvirtually no strength across the fibers. The fibers are held inplace by the resin. Tapes have a higher strength than wovenfabrics. [Figure 7-4]Bidirectional (Fabric)Most fabric constructions offer more flexibility for layupof complex shapes than straight unidirectional tapes offer.Fabrics offer the option for resin impregnation either bysolution or the hot melt process. Generally, fabrics usedfor structural applications use like fibers or strands ofthe same weight or yield in both the warp (longitudinal)and fill (transverse) directions. For aerospace structures,tightly woven fabrics are usually the choice to save weight,minimizing resin void size, and maintaining fiber orientationduring the fabrication process.7-3

TapeFabricIndividual towsFilamentsResinIndividual tows0.0030 InchFigure 7-4. Tape and fabric products.Woven structural fabrics are usually constructed withreinforcement tows, strands, or yarns interlocking uponthemselves with over/under placement during the weavingprocess. The more common fabric styles are plain or satinweaves. The plain weave construction results from eachfiber alternating over and then under each intersecting strand(tow, bundle, or yarn). With the common satin weaves, suchas 5 harness or 8 harness, the fiber bundles traverse both inwarp and fill directions changing over/under position lessfrequently.These satin weaves have less crimp and are easier to distortthan a plain weave. With plain weave fabrics and most 5 or 8harness woven fabrics, the fiber strand count is equal in bothwarp and fill directions. Example: 3K plain weave often hasan additional designation, such as 12 x 12, meaning there aretwelve tows per inch in each direction. This count designationcan be varied to increase or decrease fabric weight or toaccommodate different fibers of varying weight. [Figure 7-5]Nonwoven (Knitted or Stitched)Knitted or stitched fabrics can offer many of the mechanicaladvantages of unidirectional tapes. Fiber placement can bestraight or unidirectional without the over/under turns ofwoven fabrics. The fibers are held in place by stitching withfine yarns or threads after preselected orientations of one ormore layers of dry plies. These types of fabrics offer a widerange of multi-ply orientations. Although there may be someadded weight penalties or loss of some ultimate reinforcementfiber properties, some gain of interlaminar shear and toughnessproperties may be realized. Some common stitching yarns arepolyester, aramid, or thermoplastics. [Figure 7-6]7-4Types of FiberFiberglassFiberglass is often used for secondary structure on aircraft,such as fairings, radomes, and wing tips. Fiberglass is alsoused for helicopter rotor blades. There are several types offiberglass used in the aviation industry. Electrical glass, orE-glass, is identified as such for electrical applications. Ithas high resistance to current flow. E-glass is made fromborosilicate glass. S-glass and S2-glass identify structuralfiberglass that have a higher strength than E-glass. S-glassis produced from magnesia-alumina-silicate. Advantagesof fiberglass are lower cost than other composite materials,chemical or galvanic corrosion resistance, and electricalproperties (fiberglass does not conduct electricity). Fiberglasshas a white color and is available as a dry fiber fabric orprepreg material.Kevlar Kevlar is DuPont’s name for aramid fibers. Aramid fibersare light weight, strong, and tough. Two types of Aramidfiber are used in the aviation industry. Kevlar 49 has a highstiffness and Kevlar 29 has a low stiffness. An advantageof aramid fibers is their high resistance to impact damage, sothey are often used in areas prone to impact damage. The maindisadvantage of aramid fibers is their general weakness incompression and hygroscopy. Service reports have indicatedthat some parts made from Kevlar absorb up to 8 percentof their weight in water. Therefore, parts made from aramidfibers need to be protected from the environment. Anotherdisadvantage is that Kevlar is difficult to drill and cut. Thefibers fuzz easily and special scissors are needed to cut the

8 harness satin weaveExample:Style 3K-135-8H carbonPlain weaveExample:Style 3K-70-P carbonCrowfoot satin weaveExample:Style 285 Kevlar 4 shaft satin weaveExample:Style 120 fiberglass5 harness satin weaveExample:Style 1K-50-5H carbon8 shaft satin weaveExample:Style 1581 fiberglass8 shaft satin weaveExample:Style 181 fiberglassFigure 7-5. Typical fabric weave styles.0 90 45 90 45 Figure 7-6. Nonwoven material (stitched).material. Kevlar is often used for military ballistic andbody armor applications. It has a natural yellow color andis available as dry fabric and prepreg material. Bundles ofaramid fibers are not sized by the number of fibers like carbonor fiberglass but by the weight.7-5

Carbon/GraphiteOne of the first distinctions to be made among fibers is thedifference between carbon and graphite fibers, althoughthe terms are frequently used interchangeably. Carbon andgraphite fibers are based on graphene (hexagonal) layernetworks present in carbon. If the graphene layers, or planes,are stacked with three dimensional order, the material isdefined as graphite. Usually extended time and temperatureprocessing is required to form this order, making graphitefibers more expensive. Bonding between planes is weak.Disorder frequently occurs such that only two-dimensionalordering within the layers is present. This material is definedas carbon.Carbon fibers are very stiff and strong, 3 to 10 times stifferthan glass fibers. Carbon fiber is used for structural aircraftapplications, such as floor beams, stabilizers, flight controls,and primary fuselage and wing structure. Advantages includeits high strength and corrosion resistance. Disadvantagesinclude lower conductivity than aluminum; therefore, alightning protection mesh or coating is necessary for aircraftparts that are prone to lightning strikes. Another disadvantageof carbon fiber is its high cost. Carbon fiber is gray or blackin color and is available as dry fabric and prepreg material.Carbon fibers have a high potential for causing galvaniccorrosion when used with metallic fasteners and structures.[Figure 7-7]potential. The boron fiber is difficult to use if the parentmaterial surface has a contoured shape. The boron fibers arevery expensive and can be hazardous for personnel. Boronfibers are used primarily in military aviation applications.Ceramic FibersCeramic fibers are used for high-temperature applications,such as turbine blades in a gas turbine engine. The ceramicfibers can be used to temperatures up to 2,200 F.Lightning Protection FibersAn aluminum airplane is quite conductive and is able todissipate the high currents resulting from a lightning strike.Carbon fibers are 1,000 times more resistive than aluminumto current flow, and epoxy resin is 1,000,000 times moreresistive (i.e., perpendicular to the skin). The surface of anexternal composite component often consists of a ply or layerof conductive material for lightning strike protection becausecomposite materials are less conductive than aluminum.Many different types of conductive materials are usedranging from nickel-coated graphite cloth to metal meshesto aluminized fiberglass to conductive paints. The materialsare available for wet layup and as prepreg.In addition to a normal structural repair, the technician mustalso recreate the electrical conductivity designed into thepart. These types of repair generally require a conductivitytest to be performed with an ohmmeter to verify minimumelectrical resistance across the structure. When repairingthese types of structures, it is extremely important to use onlythe approved materials from authorized vendors, includingsuch items as potting compounds, sealants, adhesives, andso forth. [Figures 7-8 and 7-9]Figure 7-7. Fiberglass (left), Kevlar (middle), and carbon fibermaterial (right).BoronBoron fibers are very stiff and have a high tensile andcompressive strength. The fibers have a relatively largediameter and do not flex well; therefore, they are availableonly as a prepreg tape product. An epoxy matrix is often usedwith the boron fiber. Boron fibers are used to repair crackedaluminum aircraft skins, because the thermal expansion ofboron is close to aluminum and there is no galvanic corrosion7-6Figure 7-8. Copper mesh lightning protection material.

temperature use. Phenolic resins are used for interiorcomponents because of their low smoke and flammabilitycharacteristics.Figure 7-9. Aluminum mesh lightning protection material.Matrix MaterialsThermosetting ResinsResin is a generic term used to designate the polymer. Theresin, its chemical composition, and physical propertiesfundamentally affect the processing, fabrication, andultimate properties of a composite material. Thermosettingresins are the most diverse and widely used of all man-madematerials. They are easily poured or formed into any shape,are compatible with most other materials, and cure readily(by heat or catalyst) into an insoluble solid. Thermosettingresins are also excellent adhesives and bonding agents.Polyester ResinsPolyester resins are relatively inexpensive, fast processingresins used generally for low cost applications. Low smokeproducing polyester resins are used for interior parts ofthe aircraft. Fiber-reinforced polyesters can be processedby many methods. Common processing methods includematched metal molding, wet layup, press (vacuum bag)molding, injection molding, filament winding, pultrusion,and autoclaving.Vinyl Ester ResinThe appearance, handling properties, and curing characteristicsof vinyl ester resins are the same as those of conventionalpolyester resins. However, the corrosion resistance andmechanical properties of vinyl ester composites are muchimproved over standard polyester resin composites.Phenolic ResinPhenol-formaldehyde resins were first produced commerciallyin the early 1900s for use in the commercial market. Ureaformaldehyde and melamine-formaldehyde appeared inthe 1920–1930s as a less expensive alternative for lowerEpoxyEpoxies are polymerizable thermosetting resins and areavailable in a variety of viscosities from liquid to solid.There are many different types of epoxy, and the technicianshould use the maintenance manual to select the correct typefor a specific repair. Epoxies are used widely in resins forprepreg materials and structural adhesives. The advantagesof epoxies are high strength and modulus, low levels ofvolatiles, excellent adhesion, low shrinkage, good chemicalresistance, and ease of processing. Their major disadvantagesare brittleness and the reduction of properties in the presenceof moisture. The processing or curing of epoxies is slowerthan polyester resins. Processing techniques includeautoclave molding, filament winding, press molding, vacuumbag molding, resin transfer molding, and pultrusion. Curingtemperatures vary from room temperature to approximately350 F (180 C). The most common cure temperatures rangebetween 250 and 350 F (120–180 C). [Figure 7-10]Figure 7-10. Two part wet layup epoxy resin system with pumpdispenser.PolyimidesPolyimide resins excel in high-temperature environmentswhere their thermal resistance, oxidative stability, lowcoefficient of thermal expansion, and solvent resistancebenefit the design. Their primary uses are circuit boards andhot engine and airframe structures. A polyimide may be eithera thermoset resin or a thermoplastic. Polyimides require highcure temperatures, usually in excess of 550 F (290 C).Consequently, normal epoxy composite bagging materials arenot usable, and steel tooling becomes a necessity. Polyimidebagging and release films, such as Kapton are used. It isextremely important that Upilex replace the lower costnylon bagging and polytetrafluoroethylene (PTFE) releasefilms common to epoxy composite processing. Fiberglass7-7

fabrics must be used for bleeder and breather materialsinstead of polyester mat materials due to the low meltingpoint of polyester.and chemical stability. The stability results in unlimitedshelf life, eliminating the cold storage requirements ofthermoset prepregs.Polybenzimidazoles (PBI)Polybenzimidazole resin is extremely high temperatureresistant and is used for high temperature materials. Theseresins are available as adhesive and fiber.Polyether Ether Ketone (PEEK)Polyether ether ketone, better known as PEEK, is a hightemperature thermoplastic. This aromatic ketone materialoffers outstanding thermal and combustion characteristicsand resistance to a wide range of solvents and proprietaryfluids. PEEK can also be reinforced with glass and carbon.Bismaleimides (BMI)Bismaleimide resins have a higher temperature capabilityand higher toughness than epoxy resins, and they provideexcellent performance at ambient and elevated temperatures.The pr

are designed with all composite fuselage and wing structures, and the repair of these advanced composite materials requires an in-depth knowledge of composite structures, materials, and tooling .

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Composite 3 19 57 37. Prime 38. Prime 39. Neither 40. Neither 41. Composite 11 11 121 42. Composite 3 23 69 43. Prime 44. Prime 45. Composite 3 13 39 46. Composite 7 7 49 47. There are two whole numbers that are neither prime nor composite, 0 and 1. 48. False; the square of a