Transformer Oil Gas Analysis - Agilent
Get on the Analyzer “FAST TRACK”Transformer Oil Gas Analysis 1Helping customers protect the environment!Gas Chromatography for the Energy IndustryJuly 17, 2013
Why Analyzers – Value to CustomersAlleviates Resource PressureFacilitates ConfigurationUse Advanced TechnologiesOptimized PerformanceProduce Results Sooner2Gas Chromatography for the Energy IndustryJuly 17, 2013
Agilent Analyzer ConceptCommonComponentsw/o AnalyzerFactory Configured with Chemical TestingField VerificationCustomerCDApp. optimizedconsumablesStd. HW, SW3Customer’sResponsibilitySystem withapplication setupFamiliarizationApplicationreportAgilent’s AnalyzersProvideGas Chromatography for the Energy IndustryJuly 17, 2013
The Value of Analyzers and Application KitsReduce the time required for system tandardInstallation allation &FamiliarizationCustomer Method DevelopmentEnd User Configuredand ValidationCustomer MethodOptimization andValidationCustomerMethodValidationApplication KitsAgilent Analyzers Faster Application Startup with a Quality Method4Gas Chromatography for the Energy IndustryJuly 17, 2013
Easy-to-Order New Analyzer Process:Repackaged 50 Analyzers – G3445BG3445A Opt.Analyzer DescriptionGC/MS/MS Analyzers41xGC/MS/MS Pesticide Analyzers (2 versions)42xGC/MS/MS PAH AnalyzerWith noticeableidentification on GCGC/MSD/DRS Analyzers45xGC/MSD Pesticide DRS Screening Analyzers (2 versions)46xGC/MSD Environmental DRS Analyzers (2 versions)47xGC/MSD Toxicology DRS Analyzers (2 versions)48xHSS GCMSDFID Residual Solvents AnalyzerGC Gas Analysis Analyzers52xGC Refinery Gas Analyzers (6 versions)54xGC Natural Gas Analyzers (7 versions)56xGC Greenhouse Gas Analyzers (3 versions )57xTOGA Analyzer for use with HSSGC Gasoline, Fuel Analysis Analyzers561xGasoline Analyzer (inl. Oxygenates, Aromatics, 7 versions)63xBiodiesel Analyzers (4 versions)64xCO & CO 2 Analyzer w Methanizer (2 versions)65xSim Dis Analyzers (4 versions)66xS analysis with SCD Analyzer (2 versions)68xResidual Solvents GC-HSS analyzers (2 versions)Gas Chromatography for the Energy IndustryJuly 17, 2013
Analyzer Solutions – Transformer Oil Gas AnalysisEnergy and Chemical Industry6Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil GasConfirm Oil Integrity and Prevent Catastrophic Failure Transformer oil insulates and a cools internal components Exposure to electrical and thermal stress Affects long term stability With time chemical properties of oil change Aging, oxidation, vaporization, electrolytic action, and Decomposition results in gas formation Analyzing dissolved gases provides diagnostic information Current and future stability Helps determine timing for decommissioning7Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil GasConfirm Oil Integrity and Prevent Catastrophic FailureAnalyzers measure: H2, N2, O2, CO, and CO2 C2 (ethane, ethylene, acetylene) C3 (propane, propylene), C4 (1-butene)8Gas Chromatography for the Energy IndustryJuly 17, 2013
Reference Methods for TOGAQuantitation Ranges for Compounds of InterestASTM D3612-AComponentH2HydrocarbonsCO2Atmospheric gasesMinimum Detection Limits for ASTM D3612-CGases Dissolved in Oil, ection Limits, ppm(signal/noise 3)0.611.0*11.20.060.090.10.050.040.040.2*Estimated from the H2 response.9Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas AnalysisAutomated sample handling with optional HSS sampler.7890 GC System, Column, c/o SampleOption 210 FID with EPCG3445BOption#571Option 220 TCD with EPCG7697A Headspace SamplerOption 002 or 003 Fast OvenOption 311 and 312 CryoConfigured per ASTM D3612-C10Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas AnalyzerG3445B#571Configuration: 1-valve/2-column/TCD/FID/ Methanizer/HeadspaceSample type: GasCompounds analyzed: H2, O2, N2, CH4, CO and CO2, C2 (ethane, ethylene, acetylene), C3 (propane, propylene), C4 (1-butene)Configured per method: ASTM D3612-C11Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas AnalysisG3445B#571 ChromatographyIncludes: 1-valve, 2-column, TCD, FID, Methanizer, Headspace12Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas AnalyzerG3445B#571Key Benefits and Features Single channel with PLOT columns Use direct transfer line to column connection Trace levels of CO and CO2 measured by conversion to CH4 anddetection with FID Ten (10) minute analysis time Improved precision through 7890 PCM backpressure regulation ofheadspace gas sampling valve loop13Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas AnalysisManual sample handing; self-extraction by customerG3440B 7890B GC SystemOption 102 Packed Inlet7890-0047Option 210 FID with EPCOption 220 TCD with EPCOption 309 Pneum. Control ModuleConfigured per: ASTM D3612-A14Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas Analysis Cont Manual sample handing; self-extraction by customerOption 307 Nickel Catalyst TubeOption 504 Gas Sampling Valve7890-0047Option 701 6-Pt Gas Sample ValveOption 702 6-Pt Column Isol. ValveOption 752 Automate Two ValvesConfigured per: ASTM D3612-A15Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas Analyzer7890-0047Configuration: 2-valve/2-column/TCD/FID/MethanizerSample type: GasCompounds analyzed: H2, O2, N2, CH4, CO and CO2, C2 (ethane, ethylene, acetylene), C3 (propane, propylene), C4 (1-butene)Configured per method: ASTM D3612-A16Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas Analysis7890-0047 ChromatographyIncludes: 2-valve, 2-column, TCD, FID, Methanizer17Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas Analyzer7890-0047Key Benefits and Features Single channel with packed columns Trace levels of CO and CO2 can be analyzed by conversion to CH4 anddetection with FID Fifteen (15) minute analysis time Includes macros for data reporting per ASTM D3612-A, requires MicrosoftExcel18Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas AnalysisIncludes back-flush valve and methanizer by-passG3440B 7890B GC SystemOption 210 FID with EPC7890-0552Option 220 TCD with EPCOption 301 Aux EPCOption 305 Factory Plumbing for GasesConfigured per: ASTM D3612-C19Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas AnalysisIncludes back-flush valve and methanizer by-passOption 307 Nickel Catalyst TubeOption 504 Gas Sampling Valve7890-0552Option 700 6-Pt Gas Smpl Vlv (2x)Option 702 6-Pt Column Isol. ValveOption 753 Automate Three ValvesOption 872 Interface ColumnAlso Order: G7697A Headspace Sampler20Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas AnalysisIncludes back-flush valve and methanizer by-passOption 307 Nickel Catalyst TubeOption 504 Gas Sampling Valve7890-0552Option 700 6-Pt Gas Smpl Vlv (2x)Option 702 6-Pt Column Isol. ValveOption 753 Automate Three ValvesConfigured per: ASTM D3612-C21Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas Analyzer7890-0552Configuration: 3-Valve/3-Column/TCD/FID/ Methanizer/HeadspaceSample type: GasCompounds analyzed: H2, O2, N2, CH4, CO and CO2, C2 (ethane, ethylene, acetylene), C3 (propane, propylene), C4 (1-butene)Configured per method: ASTM D3612-C22Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas Analysis7890-0552 ChromatographyIncludes: 3-Valve/3-Column/TCD/FID/ Methanizer/Headspace23Gas Chromatography for the Energy IndustryJuly 17, 2013
Transformer Oil Gas Analyzer7890-0552Key Benefits and Features Trace levels of CO and CO2 can be analyzed by conversion to CH4 anddetection with FID Backflush of C4 hydrocarbons present through pre-column to shortenanalysis time Through additional valve switching C2, C3, C4 hydrocarbons bypass nickelcatalyst for FID detection Ten (10) minute analysis time24Gas Chromatography for the Energy IndustryJuly 17, 2013
Why Analyzers? Benefit!Cutting Edge TechnologyReduced Development CostInstall w/ Performance VerificationAddresses Learning CurveResource AllocationFaster Return on Capital Investment25Gas Chromatography for the Energy IndustryJuly 17, 2013
Get on the Analyzer “FAST TRACK”Simultaneous Analysis of GreenhouseGases by Gas Chromatography 26Helping customers protect the environment!Gas Chromatography for the Energy IndustryJuly 17, 2013
Background: Greenhouse Gases (GHG)Importance of GHG Analysis Comprised of Carbon dioxide (CO2), methane (CH4) and nitrousoxide (N2O) Presences traps heat in the atmosphere thereby affecting theearth’s temperature. Fossil fuels consumption contributes to increasing concentrationof GHG.Industry Regulation EPA and CEN have initiated programs to inventory GHGemissions through continuous measurement. Continuous measurement provides meaningful information totrack trends and help in the fight against climate change.27Gas Chromatography for the Energy IndustryJuly 17, 2013
Greenhouse Gas 05057890-054228G3554BNumberTitleGreenhouse Gas Analyzer with the Detection of 0.4 PPMto 20% Carbon Dioxide，0.2 PPM to 20% Methane, anddown to 30 PPB Nitrous Oxide, expandable to includeSF6, not HSS compatibleG3445B#561 Greenhouse Gas Analyzer with the Detection of 0.4 PPMto 0.2% Carbon Dioxide，0.2 PPM to 20% Methane, anddown to 30 PPB Nitrous Oxide, expandable to includeSF6, HSS compatibleModified 7890-0467 Greenhouse Gas Analyzer withOxygen/Nitrogen Separation, not HSS compatibleModified 7890-0468 Greenhouse Gas Analyzer withHeadspace InterfaceFast Greenhouse Gas Analyzer, setup for atmospheric airGas Chromatography for the Energy IndustryJuly 17, 2013
Greenhouse Gas Analyzer(G3445B#561/7890-0468)Typical Chromatogram29Gas Chromatography for the Energy IndustryJuly 17, 2013
Chromatogram for Greenhouse GasesStandardsECD2 B, ECD2B, Back Signal (GREEN N2OE JULY283\GREEN JULY22 GC 2009-07-28 16-03-16\D000011.D)7.143Hz700600500N2OECDCH4 20.18ppm vCO2 376.4ppm vN2O 3.27ppm vN2: carry gasArCH4, 2mL/min, make up400300200246FID1 A, FID1A, Front Signal (GREEN N2OE JULY283\GREEN JULY22 GC 2009-07-28 D/ methanizer150N2: carry gasCH43.31410050023046810Gas Chromatography for the Energy IndustryJuly 17, 2013
Quantitative precisionRepeatability for Greenhouse Gases Standards(n 21)NameAverage (Area)STD .9611.060.13Greenhouse gases standards concentration, ppm VCH4: 20.18, CO2: 376.4, N2O:3.27 Excellent quantitative precision31Gas Chromatography for the Energy IndustryJuly 17, 2013
Multi-level Calibration for Greenhouse Gases Standards Using DynamicBlending SystemN 2O , EC D 2 BA r e a 2 5 0 7 .4 0 3 0 4 * A m t 6 6 .9 3 3 5 0 4Standards sample informationA re aGreenhouse gases standards are diluted for multi-levelcalibration by dynamic blendingR e l. R e s % ( 1 ) : - 2 3 .1 7 48000Concentration, ppm V4N2O: 3.27 - 0.0327 ppm V700060005000Original 10 X diluting 20 X diluting 100X 918.820.1635400030000.20183.7640.0327200010002310C o r r e la tio n : 0 .9 9 9 8 801C O 2 , F ID 1 AA r e a 7 .4 0 3 9 9 6 8 4 * A m t - 5 .8 9 5 4 5 4 6A re aC H 4 , F ID 1 AA r e a 7 .4 0 4 9 5 0 9 8 * A m t - 0 .2 4 3 6 2 8 9A re aR e l. R e s % ( 1 ) : 2 7 .3 5 84CO2 : 376.4 - 3.764 ppm V2500A m o u n t[p p m ]2R e l. R e s % ( 1 ) : 2 3 .0 8 2140CH4 : 20.18 - 0.2018 ppm V41202000100150080601000405001232010C o r r e la tio n : 0 .9 9 9 9 6032100200300A m o u n t[p p m ]230C o r r e la tio n : 0 .9 9 9 9 6010A m o u n t[p p m ]Gas Chromatography for the Energy IndustryJuly 17, 2013
Chromatogram for CH4, CO2 and N2O Standards with a 100-fold DilutionECDHz146N2O: 32.7ppb144N2: carrier gasAr/CH4, 2mL/min, make up142140138136134pA24681012minFID/ methanizer10CH4: 0.2 ppmCO2: 3.76 ppmN2: carrier gas987246810min Excellent Sensitivity33Gas Chromatography for the Energy IndustryJuly 17, 2013
Chromatogram of SF6 Standard at Approximately0.5 ppb34Gas Chromatography for the Energy IndustryJuly 17, 2013
Chromatogram of Real Sample (Laboratory Air)ECD2 B, ECD2B, Back Signal (AIR JULY30\GREEN JUN26 GC 2009-07-30 21-21-32\D000007.D)7.143Hz220ECDN2O, 473ppb (calculated)N2: carrier gas200Ar/CH4, 2mL/min, make up180160A9.658rea:37.9268SF614024FID1 A, FID1A, Front Signal (AIR JULY30\GREEN JUN26 GC 2009-07-30 21-21-32\D000007.D)81012min12min5.712pA627.5FID/ methanizer2522.5CH4,2.7ppm(calculated)20N2: carrier gas3.31517.5CO2, 380ppm(calculated)1512.51023546810Gas Chromatography for the Energy IndustryJuly 17, 2013
Greenhouse Gas Analyzer(G3445B#561/7890-0468)Key Features and Benefits 36Simultaneous analysis of greenhousegas with one injectionHSS Compatibleppb sensitivity for N2O by ECDExpandable to include SF6HSS CompatibleEasy-to-use union based on CFTconnects valves and μECD Improves chromatographicperformance Better peak shapeGas Chromatography for the Energy IndustryJuly 17, 2013
Greenhouse Gas Analyzer(7890-0467)Typical Chromatogram37Gas Chromatography for the Energy IndustryJuly 17, 2013
Chromatogram for Greenhouse Gases StandardsSampleECD2 B, ECD2B, Back Signal (GREEN WHOL.N26 ARCH4 1M JUN26\GREEN JUN26 GC 2009-06-26 15-48-39\D000285.D)5.140 - N2OHz700600500400300CH4 20.18ppm vCO2 376.4ppm vN2O 3.27ppm vN2OECD channelN2: carry gasArCH4, 2ml/min, make up2001234FID1 A, FID1A, Front Signal (GREEN WHOL.26 ARCH4 1M JUN26\GREEN JUN26 GC 2009-06-26 15-48-39\D000285.D)567minCO21753.080 - CH4150125100CH475505.464 - CO2pA200FID/ methanizer channelHe: carry gas2501.8015160140120100CO28067minTCD : channel5.441 - CO21234TCD3 C, TCD3C, Aux Signal (GREEN WHOL.UN26 ARCH4 1M JUN26\GREEN JUN26 GC 2009-06-26 15-48-39\D000285.D)25 µVHe: carry gas604020138234567minGas Chromatography for the Energy IndustryJuly 17, 2013
Quantitative precision for Greenhouse Gases Standards(n 20)NameAverage enhouse gases standards concentration, ppm VCH4: 20.18, CO2: 376.4, N2O:3.27 Excellent Quantitative precision39Gas Chromatography for the Energy IndustryJuly 17, 2013
Multi-level Calibration for Greenhouse GasesStandards Using Dynamic Blending SystemN 2O , E C D 2 BA re a 2 2 5 7 .0 9 7 4 4 * A m t 8 6 .2 5 6 3 3 1Standards sample informationA re a8 0 0 0Greenhouse gases standards are diluted for multi-level calibration bydynamic blending7 0 0 0Concentration, ppm VR e l. R e s % ( 1 ) : - 4 1 .4 7 8N2O: 3.27 - 0.0327 ppm V46 0 0 05 0 0 04 0 0 0Original 10 X diluting 20 X diluting 100X diluting3 0 0 .16350.20183.7640.03272 0 0 031 0 0 0210C o r r e la tio n : 0 .9 9 9 5 901C H 4 , F ID 1 AA re a 7 .4 7 5 5 3 2 2 4 * A m t 0 .2 7 0 2 8 3 9C O 2 , F ID 1 AA re a 7 .3 8 6 7 6 2 8 9 * A m t -0 .1 4 2 7 8 3 4A re aA m o u n t[ p p m ]2A re aR e l. R e s % ( 1 ) : - 4 .6 3 9R e l. R e s % ( 1 ) : - 2 3 .1 1 11 6 0CO2 : 376.4 - 3.764 V42 5 0 0CH4 : 20.18 - 0.2018 ppm V1 4 041 2 02 0 0 01 0 01 5 0 08 06 01 0 0 04 05 0 03140210C o r r e la tio n : 1 .0 0 0 0 0032 021 0 02 0 03 0 0A m o u n t[ p p m ]0C o r r e la tio n : 0 .9 9 9 9 601 0A m o u n t[ p p m ]Gas Chromatography for the Energy IndustryJuly 17, 2013
Greenhouse Gases Analyzer(7890-0467)Key Features and Benefits 41Simultaneous analysis of greenhouse gas with one injection uses 2separate channels with three detectors Achieve faster results Uses third TCD to expand concentration range for CO2determinationsppb sensitivity for N2O by ECDExpandable to include SF6Not HSS compatibleEasy-to-use union based on CFT connects valves and μECD Improves chromatographic performance Better peak shapeGas Chromatography for the Energy IndustryJuly 17, 2013
Greenhouse Gas Analyzer(7890-0542)Typical Chromatogram42Gas Chromatography for the Energy IndustryJuly 17, 2013
Greenhouse Gas Analyzer(7890-0542)Key Features and Benefits 43Simultaneous analysis of greenhouse gas with one injection TCD and FID connected in series to measure CH4 by FID andCO2 by TCD Simplified configuration (no Methanizer) for analysis of CO2 atconcentrations 50ppmSensitivity of μECD ensures the detection of N2O at ppb levelNot HSS CompatibleEasy-to-use union based on CFT connects valves and μECD Improves chromatographic performance Better peak shapeGas Chromatography for the Energy IndustryJuly 17, 2013
Greenhouse Gas Analyzer(7890-0504)Typical Chromatogram44Gas Chromatography for the Energy IndustryJuly 17, 2013
Greenhouse Gases Analyzer(7890-0504)Key Features and Benefits 45Simultaneous analysis of greenhouse gas with one injection Includes additional packed column to separate O2 and N2 in airSensitivity of μECD ensures the detection of N2O at ppb levelNot HSS compatibleEasy-to-use union based on CFT connects valves and μECD Improves chromatographic performance Better peak shapeGas Chromatography for the Energy IndustryJuly 17, 2013
Greenhouse Gas Analyzer(7890-0505)Typical Chromatogram46Gas Chromatography for the Energy IndustryJuly 17, 2013
Selected Resources: Application NotesPublication5990-5129ENTitleSimultaneous Analysis of Greenhouse Gases by GasChromatographyApplication Note inventory under review for revision and development.47Gas Chromatography for the Energy IndustryJuly 17, 2013
48Gas Chromatography for the Energy IndustryJuly 17, 2013
GC Gas Analysis Analyzers 52x GC Refinery Gas Analyzers (6 versions) 54x GC Natural Gas Analyzers (7 versions) 56x GC Greenhouse Gas Analyzers (3 versions) 57x TOGA Analyzer for use with HSS GC Gasoline, Fuel Analysis Analyzers 61x Gasoline Analyzer (inl. Oxygenates, Aromatics, 7 versions) 63x Biodiesel Analyzers (4 versions) 64x CO & CO 2
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